CN104025351A - 用于固体氧化物电化学电池的改进的阳极/电解质结构以及制造所述结构的方法 - Google Patents

用于固体氧化物电化学电池的改进的阳极/电解质结构以及制造所述结构的方法 Download PDF

Info

Publication number
CN104025351A
CN104025351A CN201280052077.2A CN201280052077A CN104025351A CN 104025351 A CN104025351 A CN 104025351A CN 201280052077 A CN201280052077 A CN 201280052077A CN 104025351 A CN104025351 A CN 104025351A
Authority
CN
China
Prior art keywords
anode
electrolyte
assembly
ceramic
interlayer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201280052077.2A
Other languages
English (en)
Chinese (zh)
Inventor
M.H.A.贾布巴
J.霍格
E.斯塔马特
N.博纳诺斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Danmarks Tekniske Universitet
Original Assignee
Danmarks Tekniske Universitet
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Danmarks Tekniske Universitet filed Critical Danmarks Tekniske Universitet
Publication of CN104025351A publication Critical patent/CN104025351A/zh
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/12Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M8/1213Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the electrode/electrolyte combination or the supporting material
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/055Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/055Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
    • C25B11/069Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of at least one single element and at least one compound; consisting of two or more compounds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605Porous electrodes
    • H01M4/8621Porous electrodes containing only metallic or ceramic material, e.g. made by sintering or sputtering
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88Processes of manufacture
    • H01M4/8825Methods for deposition of the catalytic active composition
    • H01M4/8846Impregnation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88Processes of manufacture
    • H01M4/8878Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
    • H01M4/8882Heat treatment, e.g. drying, baking
    • H01M4/8885Sintering or firing
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/9041Metals or alloys
    • H01M4/905Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC
    • H01M4/9058Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC of noble metals or noble-metal based alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/9041Metals or alloys
    • H01M4/905Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC
    • H01M4/9066Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC of metal-ceramic composites or mixtures, e.g. cermets
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/12Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M8/124Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/12Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293Fuel cells with solid oxide electrolytes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Composite Materials (AREA)
  • Inert Electrodes (AREA)
  • Fuel Cell (AREA)
CN201280052077.2A 2011-10-24 2012-10-23 用于固体氧化物电化学电池的改进的阳极/电解质结构以及制造所述结构的方法 Pending CN104025351A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DKPA201100810 2011-10-24
DKPA201100810 2011-10-24
PCT/EP2012/070949 WO2013060669A1 (en) 2011-10-24 2012-10-23 A modified anode/electrolyte structure for a solid oxide electrochemical cell and a method for making said structure

Publications (1)

Publication Number Publication Date
CN104025351A true CN104025351A (zh) 2014-09-03

Family

ID=47046629

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201280052077.2A Pending CN104025351A (zh) 2011-10-24 2012-10-23 用于固体氧化物电化学电池的改进的阳极/电解质结构以及制造所述结构的方法

Country Status (10)

Country Link
US (1) US20140287341A1 (https=)
EP (1) EP2771931A1 (https=)
JP (1) JP2014534576A (https=)
KR (1) KR20140096309A (https=)
CN (1) CN104025351A (https=)
AU (1) AU2012327276A1 (https=)
CA (1) CA2850780A1 (https=)
EA (1) EA201490857A1 (https=)
IN (1) IN2014CN03488A (https=)
WO (1) WO2013060669A1 (https=)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2814100A1 (en) 2013-06-12 2014-12-17 Topsøe Fuel Cell A/S Impregnation of an electrochemical cell cathode backbone
WO2015054024A1 (en) 2013-10-08 2015-04-16 Phillips 66 Company Gas phase modification of solid oxide fuel cells
US10418657B2 (en) 2013-10-08 2019-09-17 Phillips 66 Company Formation of solid oxide fuel cells by spraying
WO2015054065A1 (en) * 2013-10-08 2015-04-16 Phillips 66 Company Liquid phase modification of electrodes of solid oxide fuel cells
KR102196248B1 (ko) * 2019-08-20 2020-12-29 한국과학기술연구원 박막 전해질 고체 산화물 셀 연료극용 촉매 중간층 및 이의 형성방법
CN111834662B (zh) 2020-08-31 2022-07-08 珠海冠宇电池股份有限公司 界面功能层及其制备方法和锂离子电池

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1747212A (zh) * 2005-10-11 2006-03-15 厦门大学 一种固体氧化物燃料电池电极/夹层/电解质结构
CN101383417A (zh) * 2007-08-31 2009-03-11 丹麦技术大学 基于二氧化铈和钛酸锶的电极
CN101383418A (zh) * 2007-08-31 2009-03-11 丹麦技术大学 基于二氧化铈和不锈钢的电极

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2912031B2 (ja) * 1991-01-31 1999-06-28 三洋電機株式会社 固体電解質燃料電池の製造方法
CZ301735B6 (cs) 1999-10-08 2010-06-09 Fuelcell Energy, Ltd. Kompozitní elektrody pro pevné elektrochemické soucástky a zarízení
ATE454721T1 (de) * 2000-11-09 2010-01-15 Univ Pennsylvania Verwendung von schwefelhaltigen brennstoffen für direktoxidationsbrennstoffzellen
US20040018409A1 (en) * 2002-02-28 2004-01-29 Shiqiang Hui Solid oxide fuel cell components and method of manufacture thereof
UA83400C2 (uk) * 2003-12-02 2008-07-10 Нанодайнемікс, Інк. Твердооксидні паливні елементи з керметним електролітом та спосіб їх одержання
DE102006030393A1 (de) * 2006-07-01 2008-01-03 Forschungszentrum Jülich GmbH Keramische Werkstoffkombination für eine Anode für eine Hochtemperatur-Brennstoffzelle
US20090011314A1 (en) * 2007-07-05 2009-01-08 Cheng-Chieh Chao Electrode/electrolyte interfaces in solid oxide fuel cells
WO2009058388A2 (en) 2007-10-31 2009-05-07 The Board Of Trustees Of The Leland Stanford Junior University Layer-structured fuel cell catalysts and current collectors
US8828618B2 (en) 2007-12-07 2014-09-09 Nextech Materials, Ltd. High performance multilayer electrodes for use in reducing gases
US9276267B2 (en) 2008-09-23 2016-03-01 Delphi Technologies, Inc. Low-temperature bonding of refractory ceramic layers

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1747212A (zh) * 2005-10-11 2006-03-15 厦门大学 一种固体氧化物燃料电池电极/夹层/电解质结构
CN101383417A (zh) * 2007-08-31 2009-03-11 丹麦技术大学 基于二氧化铈和钛酸锶的电极
CN101383418A (zh) * 2007-08-31 2009-03-11 丹麦技术大学 基于二氧化铈和不锈钢的电极

Also Published As

Publication number Publication date
IN2014CN03488A (https=) 2015-10-09
JP2014534576A (ja) 2014-12-18
AU2012327276A1 (en) 2014-05-15
KR20140096309A (ko) 2014-08-05
WO2013060669A1 (en) 2013-05-02
EP2771931A1 (en) 2014-09-03
US20140287341A1 (en) 2014-09-25
CA2850780A1 (en) 2013-05-02
EA201490857A1 (ru) 2014-10-30

Similar Documents

Publication Publication Date Title
JP5208518B2 (ja) 可逆式固体酸化物型燃料電池を製造する方法
JP5192944B2 (ja) セリア及びステンレス鋼に基づく電極
JP5213589B2 (ja) 金属支持型固体酸化物型燃料電池
JP5430009B2 (ja) 電気化学デバイスからの不純物相の除去
JP5591526B2 (ja) 固体酸化物セル及び固体酸化物セルスタック
US8518605B2 (en) Ceramic material combination for an anode of a high-temperature fuel cell
US11283084B2 (en) Fabrication processes for solid state electrochemical devices
CN104025352A (zh) 用于固体氧化物电化学电池的高性能燃料电极
Zhang et al. High-performance, thermal cycling stable, coking-tolerant solid oxide fuel cells with nanostructured electrodes
CN101383417A (zh) 基于二氧化铈和钛酸锶的电极
JP2009110934A5 (https=)
CN1672283A (zh) 陶瓷阳极及其制造方法
CA2516226A1 (en) Porous electrode, solid oxide fuel cell, and method of producing the same
JP2012033418A (ja) 固体酸化物型燃料電池、及びその製造方法
CN104025351A (zh) 用于固体氧化物电化学电池的改进的阳极/电解质结构以及制造所述结构的方法
US12385151B2 (en) Methods to improve the durability of metal-supported solid oxide electrochemical devices
CN105762391A (zh) 组件组成一体化的质子导体低温固体氧化物电池及其制备
JP2006351405A (ja) Sofc燃料極およびその製造方法
CN100573979C (zh) 燃料电池用阴极及其制造方法
EP2814099A1 (en) Electrochemical cell
He et al. Investigation of La0. 75Sr0. 25Cr0. 5Mn0. 5O3-δ–Ag composite anodes for solid oxide fuel cells obtained via a low-temperature sintering process
Li et al. Enhanced electrode reaction for La0. 8Sr0. 2FeO3-δ-Sm0. 2Ce0. 8O1. 9 composite cathode by barium carbonate nanoparticles as a synergistic catalyst
Tucker et al. Fabrication processes for solid state electrochemical devices
HK1129955A (en) Metal supported solid oxide fuel cell
EP2814100A1 (en) Impregnation of an electrochemical cell cathode backbone

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20140903