CN104010726B - 用于合成烷基硫醇的催化剂及其制造方法 - Google Patents

用于合成烷基硫醇的催化剂及其制造方法 Download PDF

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Publication number
CN104010726B
CN104010726B CN201280062865.XA CN201280062865A CN104010726B CN 104010726 B CN104010726 B CN 104010726B CN 201280062865 A CN201280062865 A CN 201280062865A CN 104010726 B CN104010726 B CN 104010726B
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China
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catalyst
alkali metal
tungsten
compound
carrier material
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Expired - Fee Related
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CN201280062865.XA
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English (en)
Chinese (zh)
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CN104010726A (zh
Inventor
B·丰夫
S·富斯
F·维尔茨
H·雅各布
C·韦克贝克
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Evonik Operations GmbH
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Evonik Degussa GmbH
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B01J23/04—Alkali metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B01J35/32—Bulk density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/80—Catalysts, in general, characterised by their form or physical properties characterised by their amorphous structures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0036—Grinding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
    • C07C319/08—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols by replacement of hydroxy groups or etherified or esterified hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C321/00—Thiols, sulfides, hydropolysulfides or polysulfides
    • C07C321/02—Thiols having mercapto groups bound to acyclic carbon atoms
    • C07C321/04—Thiols having mercapto groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201280062865.XA 2011-12-19 2012-11-27 用于合成烷基硫醇的催化剂及其制造方法 Expired - Fee Related CN104010726B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11194327.0A EP2606967A1 (de) 2011-12-19 2011-12-19 Katalysator zur Synthese von Alkylmercaptanen und Verfahren zu seiner Herstellung
EP11194327.0 2011-12-19
PCT/EP2012/073724 WO2013092129A1 (en) 2011-12-19 2012-11-27 Catalyst for the synthesis of alkyl mercaptans and process for producing it

Publications (2)

Publication Number Publication Date
CN104010726A CN104010726A (zh) 2014-08-27
CN104010726B true CN104010726B (zh) 2017-09-12

Family

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CN201280062865.XA Expired - Fee Related CN104010726B (zh) 2011-12-19 2012-11-27 用于合成烷基硫醇的催化剂及其制造方法

Country Status (12)

Country Link
US (1) US9764309B2 (cg-RX-API-DMAC7.html)
EP (2) EP2606967A1 (cg-RX-API-DMAC7.html)
JP (1) JP6226875B2 (cg-RX-API-DMAC7.html)
KR (1) KR102058418B1 (cg-RX-API-DMAC7.html)
CN (1) CN104010726B (cg-RX-API-DMAC7.html)
BR (1) BR112014014648A8 (cg-RX-API-DMAC7.html)
IN (1) IN2014KN01202A (cg-RX-API-DMAC7.html)
MX (1) MX2014007085A (cg-RX-API-DMAC7.html)
MY (1) MY167904A (cg-RX-API-DMAC7.html)
RU (1) RU2635922C2 (cg-RX-API-DMAC7.html)
SG (1) SG11201403338UA (cg-RX-API-DMAC7.html)
WO (1) WO2013092129A1 (cg-RX-API-DMAC7.html)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3023288B1 (fr) 2014-07-04 2016-07-15 Arkema France Procede de preparation de disulfure de dimethyle
FR3023287B1 (fr) 2014-07-04 2016-07-22 Arkema France Procede de preparation de methylmercaptan
EP3034490A1 (en) 2014-12-19 2016-06-22 Evonik Degussa GmbH Process for the preparation of alkyl mercaptans
EP3035046A1 (de) 2014-12-19 2016-06-22 Evonik Degussa GmbH Verfahren zur Bestimmung eines Dialkyldisulfids
FR3041636B1 (fr) 2015-09-30 2018-11-16 Arkema France Procede de production de mercaptans par hydrogenolyse enzymatique de disulfures a l'aide d'hydrogene
FR3041635B1 (fr) 2015-09-30 2019-01-25 Arkema France Procede de production de mercaptans par hydrogenolyse enzymatique de disulfures
EP3187261A1 (de) * 2015-12-30 2017-07-05 Evonik Degussa GmbH Verfahren zur herstellung eines ein alkalimetall und eines übergangsmetall in oxidierter form enthaltenden katalysators
FR3091869B1 (fr) 2019-01-18 2021-01-22 Adisseo France Sas Procede de preparation d’un compose de formule rsh par hydrosulfuration
EP3689451A1 (en) 2019-01-29 2020-08-05 Evonik Operations GmbH Catalyst for the synthesis of alkyl mercaptan and process for its preparation

Citations (5)

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CN1141915A (zh) * 1995-06-23 1997-02-05 罗纳-普朗克动物营养素公司 甲硫醇的制备方法
WO1999014172A2 (en) * 1997-09-18 1999-03-25 Institut Kataliza Imeni G.K.Boreskova Sibirskogo Otdelenia Rossiiskoi Akademii Nauk Catalyst for the synthesis of methylmercaptan
CN1780814A (zh) * 2003-04-30 2006-05-31 巴斯福股份公司 用于由甲醇和硫化氢制备甲硫醇的催化剂
CN1993177A (zh) * 2004-08-04 2007-07-04 德古萨股份公司 用于合成烷基硫醇的含钨酸盐的催化剂及其制备方法
CN101432067A (zh) * 2006-04-28 2009-05-13 巴斯夫欧洲公司 用于氨氧化的新型负载型催化剂

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US2820062A (en) 1954-08-11 1958-01-14 Pure Oil Co Preparation of organic thiols
US3312751A (en) * 1963-11-19 1967-04-04 Mobil Oil Corp Production of mercaptans or their olefinic derivatives
DE19639520C2 (de) 1996-09-26 1998-10-01 Degussa Katalysator, Verfahren zu seiner Herstellung und Verwendung zur Synthese von Alkylmercaptanen
AU2003297257A1 (en) * 2002-11-11 2004-06-03 Conocophillips Company Improved supports for high surface area catalysts
US7229946B2 (en) * 2003-03-24 2007-06-12 Saudi Basic Industries Corporation Catalyst composition for the selective conversion of alkanes to unsaturated carboxylic acids, method of making and method of using thereof
DE10338887A1 (de) 2003-08-23 2005-03-17 Degussa Ag Katalysator zur Synthese von Alkylmercaptan und Verfahren zu seiner Herstellung
JP4499513B2 (ja) * 2004-09-03 2010-07-07 株式会社日本触媒 窒素酸化物および臭気成分を含む排ガスの処理方法
US20060199730A1 (en) * 2005-03-02 2006-09-07 Seely Michael J Composition and method for improving density and hardness of fluid bed catalysts
DE102007004351A1 (de) * 2007-01-29 2008-07-31 Evonik Degussa Gmbh Neue Katalysatoren und Verfahren zur Dehydratisierung von Glycerin
WO2008093711A1 (ja) * 2007-01-31 2008-08-07 Osaka University 固相系酸化反応システム
EP1982764A1 (en) * 2007-04-17 2008-10-22 Evonik Degussa GmbH Catalyst for the preparation of methyl mercaptan
DE102007024576A1 (de) * 2007-05-25 2009-05-20 Evonik Degussa Gmbh Verfahren zur kontinuierlichen Herstellung von Methylmercaptan aus kohlenstoff- und wasserstoffhaltigen Verbindungen
JP5493928B2 (ja) * 2009-07-10 2014-05-14 三菱化学株式会社 炭化水素の製造方法
WO2011046232A1 (en) 2009-10-15 2011-04-21 Nippon Kayaku Kabushiki Kaisha Process for preparing catalyst used in production of unsaturated aldehyde and/or unsaturated carboxylic acid by dehydration reaction of glycerin, and catalyst obtained

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1141915A (zh) * 1995-06-23 1997-02-05 罗纳-普朗克动物营养素公司 甲硫醇的制备方法
WO1999014172A2 (en) * 1997-09-18 1999-03-25 Institut Kataliza Imeni G.K.Boreskova Sibirskogo Otdelenia Rossiiskoi Akademii Nauk Catalyst for the synthesis of methylmercaptan
CN1780814A (zh) * 2003-04-30 2006-05-31 巴斯福股份公司 用于由甲醇和硫化氢制备甲硫醇的催化剂
CN1993177A (zh) * 2004-08-04 2007-07-04 德古萨股份公司 用于合成烷基硫醇的含钨酸盐的催化剂及其制备方法
CN101432067A (zh) * 2006-04-28 2009-05-13 巴斯夫欧洲公司 用于氨氧化的新型负载型催化剂

Also Published As

Publication number Publication date
EP2606967A1 (de) 2013-06-26
US20140357897A1 (en) 2014-12-04
US9764309B2 (en) 2017-09-19
MX2014007085A (es) 2014-07-22
JP6226875B2 (ja) 2017-11-08
RU2014129624A (ru) 2016-02-10
KR20140104962A (ko) 2014-08-29
RU2635922C2 (ru) 2017-11-17
BR112014014648A2 (pt) 2017-06-13
EP2794095A1 (en) 2014-10-29
BR112014014648A8 (pt) 2017-06-13
KR102058418B1 (ko) 2019-12-24
IN2014KN01202A (cg-RX-API-DMAC7.html) 2015-10-16
CN104010726A (zh) 2014-08-27
JP2015506825A (ja) 2015-03-05
SG11201403338UA (en) 2014-07-30
MY167904A (en) 2018-09-26
WO2013092129A1 (en) 2013-06-27

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