CN104003804B - A kind of composite microbiological fertilizer of holding water and fixing nitrogen and preparation method thereof - Google Patents

A kind of composite microbiological fertilizer of holding water and fixing nitrogen and preparation method thereof Download PDF

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CN104003804B
CN104003804B CN201410251834.XA CN201410251834A CN104003804B CN 104003804 B CN104003804 B CN 104003804B CN 201410251834 A CN201410251834 A CN 201410251834A CN 104003804 B CN104003804 B CN 104003804B
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fertilizer
liquid
water
powder
compound
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CN104003804A (en
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李秉政
刘卫平
王文刚
张儒全
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Shandong Hongri Chemical Co ltd
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Shandong Hongri Acron Chemical Joint Stock Co Ltd
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Abstract

The invention belongs to biological organic fertilizer field, disclose the composite microbiological fertilizer of a kind of holding water and fixing nitrogen, its preparation method comprises the steps, step 1) prepares fermentation liquid, step 2) prepare the organic material liquid of compound and step 3) prepares composite microbiological fertilizer。Fertilizer of the present invention is effectively utilized agricultural waste material, and employs microbial fermentation technology, improves Soil structure, controls the loss in nutrient use procedure so that fertilizer efficiency is more lasting, has higher yield of crops stable yields, the effects such as seedlings are uniform and strong。

Description

A kind of composite microbiological fertilizer of holding water and fixing nitrogen and preparation method thereof
Technical field
The invention belongs to technical field of fertilizers, be specifically related to composite microbiological fertilizer of a kind of holding water and fixing nitrogen and preparation method thereof。
Background technology
Development along with agricultural modernization, the enthusiasm for production of mass peasants is unprecedentedly surging, for improving the yield of agricultural product, it is endless that to throw in soil that chemical fertilizer carries out improving grain yield be main operating type, once make grain and gourd, fruit and vegetable yield be able to rapid lifting, meet people's life requirement。But then, have high input while quantization fertilizer carries out carrying product and but have ignored the chemical fertilizer adverse effect to the quality of agricultural product, soil compaction, subsoil water and ecological environment。Owing to using chemical fertilizer amount abruptly increase, and kind unification (inorganic salt fertilizer is in the majority), organic fertilizer is less, so that the organic matter in soil sharply declines, destroy original soil ecology balance, soil compaction, water and soil pollution, ecological deterioration, disruption of ecological balance, agriculture production cost increases and agricultural product quality decline contradiction, thus occurring in that Higher output is not accompanied by a higher income and the vicious cycle of environmental pollution madness such as (grow) rivers and lakes water baths。This fertilization mode and modern agricultural development are runed counter to and are speeded, so country actively advocates and call agricultural sector and each farming unit to carry out a large amount of application of organic fertilizers and organic-inorganic compound fertilizer at present, in order to build up fertility while improving soil。Increase fertile the promoting the use of of soil measurement formula, thoroughly to solve the bottleneck problem of the high-quality of agricultural, high yield simultaneously。
The development of China's fertilizer and application history, be Main Stage from farm manure to using inorganic fertilizer, and because farm manure polluter is many, freight volume is big, operationally wastes time and energy and effect is not obvious especially;And inorganic fertilizer composition is single, utilization rate is relatively low, and often causes soil compaction and with soil erosion polluted source, influence ecological environment。The fertilizer of agricultural use mainly has (NH in the early time2)2CO、(NH4)2SO4、NH4HCO3、NH4Cl、(NH4)2HPO4、NH4H2PO4、NH4NO3The inorganic composite fertilizer etc. of calcium superphosphate, nitrophosphate fertilizer and Nitrogen-and Phosphorus-containing potassium。For the crop that trophophase is longer, manuring late is also crucial。Except base fertilizer, topdress and generally all adopt NH4HCO3、NH4Cl、(NH2)2CO、NH4NO3Deng, these belong to inorganic fertilizer and NH4HCO3、NH4Cl、(NH4)2SO4、NH4NO3Etc. broadly falling into ammonium fertilizer category, can directly be absorbed by crop, but because its volatilization is fast, utilization rate is low, plant absorption is received and affects the drawbacks such as environment, not only increases production cost, and very easily cause that water resource environment worsens。(NH2)2CO belongs to acyl ammonium fertilizer, contained nitrogen need to after the urine enzyme decomposition and inversion of urea bacterium secretion be ammonium nitrogen, can being absorbed by plants, its utilization rate is typically in 30~40%, and it has, and fertilizer efficiency utilization rate is low, volatile, the drawback such as leaf and soil compaction is burnt in contaminated environment, precipitation, burn seedlings。
In recent years, occur in that some Chemical Mixed Fertilizers and biological organic fertilizer, which raises grain yield, and the fertilizer efficiency persistent period improves, and the destructive power of environment is reduced;Such as Chinese patent CN102503650 discloses a kind of amino acid chelate fertilizer, this chelating fertilizer is by adding chelating aminoacid and trace element, improve fertilizer efficiency, but it is higher to there is cost of material in this technology, need to add various trace elements and aminoacid, general enterprises cannot bear high cost, and causing can not large-scale industrial production。
Biological organic fertilizer is a kind of fertilizer being inoculated with beneficial microorganism on the basis of tradition organic fertilizer and producing。A large amount of organic and beneficial microbe contained by biological organic fertilizer, it is possible to improve Soil structure, rehabilitating soil microbiota, it is suppressed that harmful microbe spreads, safeguard that soil ecology balances。Except a great number of elements and trace element necessary to crop growthing development, biological organic fertilizer, possibly together with microbial metabolic products and a large amount of activity beneficial microbe, can promote plant growth, can strengthen again crop resistance, improve crop yield, improve quality of agricultural product。But, biological organic fertilizer relates to the selection of microorganism, and preparation technology is loaded down with trivial details, it is thus achieved that the fertilizer that effect is good, cost is low is more difficult。
Summary of the invention
The present invention be directed to the defect of prior art fertilizer production technology, it is proposed to the composite microbiological fertilizer of a kind of holding water and fixing nitrogen and preparation method thereof。The present invention effectively utilizes agricultural waste material, and employ microbial fermentation technology, prepare a kind of holding water and fixing nitrogen effect preferably fertilizer, this fertilizer can be substantially improved Soil structure, control the loss in nutrient use procedure, make fertilizer efficiency more lasting, there is higher yield of crops stable yields, the effects such as seedlings are uniform and strong。The preparation method of the present invention has the features such as technological process is short, investment is taken up an area less, energy consumption is low, pollution-free。
For achieving the above object, the present invention is by the following technical solutions:
A kind of composite microbiological fertilizer of holding water and fixing nitrogen, it is prepared as follows and forms:
1) fermentation liquid is prepared: dried by wheat stalk, then it is ground into powder of straw with pulverizer, put in fermentation tank, in fermentation tank, add the water of bean cake, wheat bran and 100 DEG C subsequently, stir, during to be lowered to 30 DEG C, add composite bacteria liquid, under 100-150 rev/min of stirring condition, ferment 48 hours, obtain fermentation liquid;Wherein, the mass ratio of powder of straw, bean cake, wheat bran, water and mixed bacteria liquid is 10:3:3:50:1;Described composite bacteria liquid is mixed according to the volume ratio of 1:1:1:1 by bacillus megaterium liquid, Bacillus licheniformis liquid, Trichoderma harzianum bacterium solution and azotobacter chroococcum liquid, and the concentration of four kinds of bacterium solution is 5 × 107Individual/ml;
2) the organic material liquid of compound is prepared:By the peat composed of rotten mosses, humic acids, zeolite powder and waterAdding in agitator tank according to the mass ratio of 2:2:1:10,300-400 rev/min is stirred 30 minutes, subsequently into retort, heat after 100 DEG C with the programming rate of 10 DEG C/min, insulation reaction 5-10 minute, be subsequently cooled to room temperature, stand 12-24 hour, obtain the organic material liquid of compound;
3) composite microbiological fertilizer is prepared: according to brown coal powder, MAP, potassium chloride, carbamide, the organic material liquid of compound and water mixing and stirring; join in double-screw extruding pelletizing machine; pelletizer outlet sets pelleter; bar shaped fertilizer is cut off; finally spray fermentation liquid; stirring, it is 1-2%(mass/mass that cold drying controls moisture) left and right, pack and get final product;
Wherein, the mass ratio of brown coal powder, MAP, potassium chloride, carbamide, the organic material liquid of compound, water and fermentation liquid is 10:5:3:2:1:10:1;
Wherein, the particle diameter of powder of straw, the peat composed of rotten mosses, humic acids, zeolite powder and brown coal powder all controls between 50-100 order。
The preparation method that the invention also discloses the composite microbiological fertilizer of above-mentioned holding water and fixing nitrogen。
Note, the strain used in above-mentioned steps is the conventional strain of this area, and those skilled in the art can obtain its bacterium solution according to its conventional culture methods。Strain of the present invention all can be commercially available from commercial sources such as American Type Culture collection warehousing (ATCC)。
The present invention obtain beneficial effect mainly include following some:
The present invention, by effectively utilizing the agricultural waste material of naturally occurring, in conjunction with microbial technique, greatly reduces the turnover rate of fertilizer;Adding the peat composed of rotten mosses, humic acids, zeolite powder etc. in fertilizer of the present invention, supplement multiple nutriment, fertilizer efficiency is persistently comprehensive, strengthens crop disease-resistant anti-adversity ability, and decreases water loss;The present invention adopts microbial fermentation technology, agricultural wastes is carried out organic decomposition, turns waste into wealth, and is greatly saved the cost of fertilizer production;
The multiple-microorganism that the present invention selects adopts rational proportion, by symbiosis Relationship With Proliferation, defines a complexity and stable microecosystem, effectively fixed nitrogen fertilizer conservation, improves fertilizer efficiency;Preparation method of the present invention possesses the advantages such as flow process is short, investment is taken up an area less, energy consumption is low, environment friendly and pollution-free, is suitable for large-scale industrial production。
Detailed description of the invention
Hereinafter the present invention is carried out detailed description by the mode adopting specific embodiment, but should not be construed limitation of the present invention。
Embodiment 1
A kind of composite microbiological fertilizer of holding water and fixing nitrogen, it is prepared as follows and forms:
1) fermentation liquid is prepared: dried by wheat stalk, then it is ground into powder of straw with pulverizer, put in fermentation tank, in fermentation tank, add the water of bean cake, wheat bran and 100 DEG C subsequently, stir, during to be lowered to 30 DEG C, add composite bacteria liquid, under 100 revs/min of stirring conditions, ferment 48 hours, obtain fermentation liquid;Wherein, the mass ratio of powder of straw, bean cake, wheat bran, water and mixed bacteria liquid is 10:3:3:50:1;Described composite bacteria liquid is mixed according to the volume ratio of 1:1:1:1 by bacillus megaterium liquid, Bacillus licheniformis liquid, Trichoderma harzianum bacterium solution and azotobacter chroococcum liquid, and the concentration of four kinds of bacterium solution is 5 × 107Individual/ml;
2) the organic material liquid of compound is prepared: add in agitator tank by the peat composed of rotten mosses, humic acids, zeolite powder and water according to the mass ratio of 2:2:1:10,300 revs/min are stirred 30 minutes, subsequently into retort, heat after 100 DEG C with the programming rate of 10 DEG C/min, insulation reaction 5 minutes, it is subsequently cooled to room temperature, stands 12 hours, obtain the organic material liquid of compound;
3) composite microbiological fertilizer is prepared: according to brown coal powder, MAP, potassium chloride, carbamide, the organic material liquid of compound and water mixing and stirring; join in double-screw extruding pelletizing machine; pelletizer outlet sets pelleter; bar shaped fertilizer is cut off; finally spray fermentation liquid; stirring, it is 1% that cold drying controls moisture, packs and get final product;
Wherein, the mass ratio of brown coal powder, MAP, potassium chloride, carbamide, the organic material liquid of compound, water and fermentation liquid is 10:5:3:2:1:10:1;
Wherein, the particle diameter of powder of straw, the peat composed of rotten mosses, humic acids, zeolite powder and brown coal powder all controls at 50 orders。
Embodiment 2
A kind of composite microbiological fertilizer of holding water and fixing nitrogen, it is prepared as follows and forms:
1) fermentation liquid is prepared: dried by wheat stalk, then it is ground into powder of straw with pulverizer, put in fermentation tank, in fermentation tank, add the water of bean cake, wheat bran and 100 DEG C subsequently, stir, during to be lowered to 30 DEG C, add composite bacteria liquid, under 150 revs/min of stirring conditions, ferment 48 hours, obtain fermentation liquid;Wherein, the mass ratio of powder of straw, bean cake, wheat bran, water and mixed bacteria liquid is 10:3:3:50:1;Described composite bacteria liquid is mixed according to the volume ratio of 1:1:1:1 by bacillus megaterium liquid (ATCC15450), Bacillus licheniformis liquid (ATCC14580), Trichoderma harzianum bacterium solution (ATCC20873) and azotobacter chroococcum liquid (ATCC4412), and the concentration of four kinds of bacterium solution is 5 × 107Individual/ml;
2) the organic material liquid of compound is prepared: add in agitator tank by the peat composed of rotten mosses, humic acids, zeolite powder and water according to the mass ratio of 2:2:1:10,400 revs/min are stirred 30 minutes, subsequently into retort, heat after 100 DEG C with the programming rate of 10 DEG C/min, insulation reaction 10 minutes, it is subsequently cooled to room temperature, stands 24 hours, obtain the organic material liquid of compound;
3) composite microbiological fertilizer is prepared: according to brown coal powder, MAP, potassium chloride, carbamide, the organic material liquid of compound and water mixing and stirring; join in double-screw extruding pelletizing machine; pelletizer outlet sets pelleter; bar shaped fertilizer is cut off; finally spray fermentation liquid; stirring, it is 2% that cold drying controls moisture, packs and get final product;
Wherein, the mass ratio of brown coal powder, MAP, potassium chloride, carbamide, the organic material liquid of compound, water and fermentation liquid is 10:5:3:2:1:10:1;
Wherein, the particle diameter of powder of straw, the peat composed of rotten mosses, humic acids, zeolite powder and brown coal powder all controls at 100 orders。
Embodiment 3
The manure trial of fertilizer of the present invention:
The impact on Yield of Strawberry and quality of the fertilizer of the embodiment of the present invention 1。Test kind is Feng Xiang。Test group uses this product 80kg/ mu, and matched group uses commercially available compound fertilizer (N20P10K10) 80kg/ mu, all adopts conventional cultivation。Result is as shown in table 1, and compared with commercially available compound fertilizer, the fertilizer of the embodiment of the present invention 1 can improve Fructus Fragariae Ananssae sugar content, improves color and luster, improves yield。
Table 1
Embodiment 4
Use fertilizer:
Comparison 1: compound fertilizer: containing 35% carbamide, 35% MAP, 30% potassium chloride;
Comparison 2: compound fertilizer: preparation method is with embodiment 2, but without fermentation liquid;
Comparison 3: compound fertilizer: preparation method is with embodiment 2, but without the organic material liquid of compound;
Experimental group: the fertilizer of embodiment 2 preparation。
Experimental technique:
Experimental plot is positioned at blue proving ground, Mt. Mountain town, Ling County, rice cultivation, and the experimental plot area that four groups of fertilizer processes respectively is 0.07 hectare, often the consumption that makes of group experimental plot fertilizer is 50kg, planting conditions is identical, gathers in the crops Oryza sativa L. simultaneously, measures Oryza sativa L. per mu yield and rate of growth;Detection Oryza sativa L. grain number per spike, mass of 1000 kernel and unfilled gtains number simultaneously。
Experimental result: referring to table 2
Table 2
Group Unfilled gtains number (grain/fringe) Grain number per spike (grain/fringe) Mass of 1000 kernel (g) Per mu yield (kg)
Comparison one 7.3 53.7 18.86 398.1
Comparison two 5.4 63.9 25.03 446.3
Comparison three 4.9 63.4 25.72 453.8
Experimental group 3.1 70.7 31.46 502.9
By comparing discovery, experimental group Oryza sativa L. unfilled gtains number, grain number per spike, mass of 1000 kernel and per mu yield are better than matched group one apparently higher than matched group two and three, matched group two and matched group three。
The specific embodiment of the present invention is described although above-mentioned in conjunction with the embodiments; but not limiting the scope of the invention; one of ordinary skill in the art should be understood that; on the basis of technical scheme, those skilled in the art need not pay various amendments or deformation that creative work can make still within protection scope of the present invention。

Claims (2)

1. the composite microbiological fertilizer of a holding water and fixing nitrogen, it is characterised in that described fertilizer is prepared as follows and forms:
Step 1) prepares fermentation liquid: dried by wheat stalk, then it is ground into powder of straw with pulverizer, put in fermentation tank, in fermentation tank, add the water of bean cake, wheat bran and 100 DEG C subsequently, stir, during to be lowered to 30 DEG C, add composite bacteria liquid, under 100-150 rev/min of stirring condition, ferment 48 hours, obtain fermentation liquid;Wherein, the mass ratio of powder of straw, bean cake, wheat bran, water and composite bacteria liquid is 10:3:3:50:1;
Step 2) prepare the organic material liquid of compound: the peat composed of rotten mosses, humic acids, zeolite powder and water are added in agitator tank according to the mass ratio of 2:2:1:10,300-400 rev/min is stirred 30 minutes, subsequently into retort, heat after 100 DEG C with the programming rate of 10 DEG C/min, insulation reaction 5-10 minute, it is subsequently cooled to room temperature, stands 12-24 hour, obtain the organic material liquid of compound;
Step 3) prepares composite microbiological fertilizer: according to brown coal powder, MAP, potassium chloride, carbamide, the organic material liquid of compound and water mixing and stirring; join in double-screw extruding pelletizing machine; pelletizer outlet sets pelleter; bar shaped fertilizer is cut off; finally spray fermentation liquid; stirring, it is 1-2% that cold drying controls moisture, packs and get final product;
Described composite bacteria liquid is mixed according to the volume ratio of 1:1:1:1 by bacillus megaterium liquid, Bacillus licheniformis liquid, Trichoderma harzianum bacterium solution and azotobacter chroococcum liquid, and the concentration of four kinds of bacterium solution is 5 × 107Individual/ml;
In described step 3), the mass ratio of the organic material liquid of brown coal powder, MAP, potassium chloride, carbamide, compound, water and fermentation liquid is 10:5:3:2:1:10:1。
2. fertilizer as claimed in claim 1, it is characterised in that the particle diameter of described powder of straw, the described peat composed of rotten mosses, described humic acids, described zeolite powder and described brown coal powder all controls between 50-100 order。
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