CN103938820A - Microcrystalline foamed ceramic thermal insulation decoration composite plate and manufacturing method thereof - Google Patents
Microcrystalline foamed ceramic thermal insulation decoration composite plate and manufacturing method thereof Download PDFInfo
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- CN103938820A CN103938820A CN201410109093.1A CN201410109093A CN103938820A CN 103938820 A CN103938820 A CN 103938820A CN 201410109093 A CN201410109093 A CN 201410109093A CN 103938820 A CN103938820 A CN 103938820A
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Abstract
The invention discloses a microcrystalline foamed ceramic thermal insulation decoration composite plate which comprises a thermal insulation layer (1) and a decoration layer (2), wherein the decoration layer (2) is fixed onto the thermal insulation layer (1) by the adoption of an anti-flaming binder (8). The thermal insulation layer (1) is a microcrystalline foamed ceramic thermal insulation plate, the decoration layer (2) is a flexible facing clad material, and the decoration layer (2) sequentially comprises a flexible composite material sheet (3), color facing mortar (4) and a finishing coat (5) from bottom to top, wherein the anti-flaming binder (8) is a polymer modified cement mortar adhesive. Through the mode that the microcrystalline foamed ceramic thermal insulation plate with a fireproof function is combined with the flexible facing clad material through the anti-flaming binder, the microcrystalline foamed ceramic thermal insulation decoration composite plate has the advantages of factory component industrialization, construction assembly, fire hazard high-temperature anti-flaming fire prevention, thermal insulation, sound insulation and decoration composition.
Description
Technical field
The present invention relates to building energy saving field, be specifically related to a kind of crystallite foam ceramic thermal insulation decoration composite plate and preparation method thereof.
Background technology
Although External Thermal Insulation Technology for External nearly 30 years in China's promotion and application, but the restriction due to existing heat preserving and insulating material research and technical level, the material that construction work the exterior wall external insulation extensively adopts is at present mainly the lightweight organic foam materials such as polyphenyl plate, polyurethane sheet, phenolic board, these warming plate thermal properties of being made by petrochemical industry spin-off are good, and light-weight water-proof, but fire rating belongs to flammable and difficult combustion, sheet material can generate a large amount of toxic and harmfuls when burning when discharging high heat, causes serious personal injury and environment pollution.For avoid organic insulation material these with the defect of raw tool, the outer insulation project of part is also at the high light inorganic heat preserving material of fire saveties such as rock cotton board, block of glass wool of employing.But in actual applications, the cotton class heat insulating material of rock (stone) exposes easy generation dust and micro fiber, in production and processing and construction and installation process, can cause personal injury and environment pollution, thereby has greatly affected the promotion and application of this series products on market.Find safer, more environmental protection and thermal property and mechanical strength can reach the heat preserving and insulating material of technical requirements again, are the tireless pursuits of material science researcher always.Patent ZL032520530 " compound asbestos foam glass thermal insulation decorative material " proposes foam glass and large format ceramic tile is compound in factory, realize heat preservation decoration integrative, both improved the fire savety of exterior insulation work, greatly reduced again the wet trade of site operation, but the shortcoming of this patent is not consider that foam glass mechanical strength is not high, at transportation, carrying and work progress, very easily cause product breakage, percent defective is high, composite plate weight is large, and the utmost point is not easy to the unfavorable factors such as work high above the ground of exterior wall.
Summary of the invention
The technical problem to be solved in the present invention be to provide a kind of for external wall enclosed structure there is thermal insulation, fire-proof and water-proof and sound insulation noise reduction function and with building with the crystallite foam ceramic thermal insulation decoration composite plate in life-span and preparation method thereof.
A kind of crystallite foam ceramic thermal insulation decoration composite plate, comprise insulation layer and adopt flame retardant type cementing agent to be fixed on the decorative layer on described insulation layer, described insulation layer is crystallite foamed ceramic insulation board, described decorative layer is flexible facing cover material, it comprises flexible composite sheet material, colored finish mortar and skin coat from the bottom to top successively, wherein, described flame retardant type cementing agent is polymer-modified cement mortar cementing agent.
Crystallite foam ceramic thermal insulation decoration composite plate of the present invention, wherein said crystallite foamed ceramic insulation board thickness is 50mm～700mm, described flexible facing cover material thickness is 15mm～30mm.
Crystallite foam ceramic thermal insulation decoration composite plate of the present invention, the specification of wherein said crystallite foam ceramic thermal insulation decoration composite plate is for long: 2000mm, 2440mm, 3000mm or 3200mm; Wide: 1220mm, 1250mm or 1500mm.
Crystallite foam ceramic thermal insulation decoration composite plate of the present invention, wherein the coating on both sides at described crystallite foamed ceramic insulation board has interfacial agents, and described interfacial agents is comprised of the material of following weight portion:
Solid content is 45～49% BC-700 acrylic emulsion: 5～10 parts;
Solid content is 45～47% BC-200 acrylic emulsion: 10～15 parts;
Deionized water: 15～30 parts;
Ethylene glycol: 0.4～0.8 part;
Wollastonite in powder: 6～10 parts;
Kaolin: 8～10 parts;
Coarse whiting: 10～14.8 parts;
Anionic wetting agent: 0.5～0.8 part;
Coalescents: 0.7～1 part;
Dispersing agent: 0.2～0.4 part;
Defoamer: 0.2～0.3 part;
PH adjusting agent: 0.6～0.8 part;
Antisepticize and mildew preventive: 0.5～0.8 part;
Plasticizing agent: 0.1～0.3 part;
Wherein, described coalescents is Lauryl Alcohol ester, and described dispersing agent is sodium polyphosphate, and described defoamer is PPG, and described Antisepticize and mildew preventive is that OBPA contains arsenic organic matter mould inhibitor, and described plasticizing agent is polyacrylic acid lipid plasticizing agent.
Crystallite foam ceramic thermal insulation decoration composite plate of the present invention, wherein said polymer-modified cement mortar cementing agent is formed by the material stirring of following weight portion:
52.5 cement: 300～350 parts;
40～120 object silica sands: 500～550 parts;
200 object coarse whitings: 50～100 parts;
Viscosity is 20,000-40, the hydroxypropyl methyl cellulose ether of 000mpas: 2～3 parts;
Re-dispersible glue powder: 25～44 parts;
Wood fibre: 4 parts.
Crystallite foam ceramic thermal insulation decoration composite plate of the present invention, wherein said flexible composite sheet material is composited by tire base and the flexible polymer cement mortar that is coated on its both sides, and described tire base is the composite felt of polyester-cotton blend nonwoven and glass fiber reticular cloth.
Crystallite foam ceramic thermal insulation decoration composite plate of the present invention, wherein said flexible polymer cement mortar is comprised of the material of following weight portion:
BC200-acrylic emulsion: 60 parts;
BC700-acrylic emulsion: 150 parts;
80～120 object silica sands: 410 parts;
52.5 cement: 140 parts;
Viscosity is 20,000-40, the hydroxypropyl methyl cellulose ether of 000mpas: 30 parts;
Ethylene glycol: 10 parts.
Crystallite foam ceramic thermal insulation decoration composite plate of the present invention, wherein said colored finish mortar forms by the mixed raw material of following weight portion is standby:
40～120 object colorful quartz sands: 700 parts;
Pure-acrylic emulsion: 200 parts;
Coalescents: 6 parts;
Ethylene glycol: 2 parts;
Defoamer: 2 parts;
Anticorrosion and bactericidal agent: 1 part;
Viscosity is the hydroxyethylmethyl-cellulose ether of 400000mpas: 3 parts;
Color stuffing: 2 parts;
Deionized water: 56.7 parts;
Wherein, described coalescents is Lauryl Alcohol ester, and described defoamer is PPG, and described anticorrosion and bactericidal agent is OIT anticorrisive agent.
Crystallite foam ceramic thermal insulation decoration composite plate of the present invention, wherein said skin coat is applied and is formed by anti-fouling and self-cleaning coating, and described anti-fouling and self-cleaning coating is that particle diameter is nano level organosilicon-modified acrylic coating, and it is comprised of following weight portion:
Deionized water: 500～620 parts;
Solid content is 47% organic siliconresin emulsion: 170～320 parts;
Anionic wetting agent: 3 parts;
Thickener: 10～18 parts;
Coalescents: 5～10 parts;
Dispersing agent: 4 parts;
Defoamer: 3 parts;
PH adjusting agent: 2～5 parts;
Antisepticize and mildew preventive: 6 parts;
Ethylene glycol: 8 parts;
Plasticizing agent: 3 parts;
Wherein, described thickener is cellulose ether, and described coalescents is Lauryl Alcohol ester, and described dispersing agent is PTPP (potassium tripolyphosphate), and described defoamer is polyethers, and described Antisepticize and mildew preventive is that OBPA contains arsenic organic matter mould inhibitor, and described plasticizing agent is synthetic vegetable esters fluidizer.
The preparation method of crystallite foam ceramic thermal insulation decoration composite plate of the present invention, comprises the steps:
The preparation of step 1, insulation layer:
Described warming plate is processed into by crystallite foamed ceramics by crystallite foamed ceramic insulation board, it is raw material that crystallite foamed ceramics be take the industrial tailings waste residues such as cullet, flyash, gangue, add auxiliary agent, comprise blowing agent, nucleator and Admixture, mix after crushed formation batch, then batch is put in special grinding tool, puts into electric furnace and heat, through preheating, melting, foaming, crystallization, annealing process, make;
It is 50mm～700mm that manufactured foam micro-crystalline ceramic is cut into thickness, and its surface and corner polishing processing are processed, and guarantees that upper surface is smooth, horizontal error ± 2mm, facade vertical error ± 2mm, the upright error ± 3mm of external corner, removes plate surface attachment; Method on sheet material two sides with cylinder and spraying applies 2～3 times interfacial agents, guarantees without holiday, to improve the adhesive power of foam micro-crystalline ceramic sheet material external surface;
The preparation of step 2, flexible facing cover material: first flexible polymer cement mortar is evenly coated to the described tire base both sides that consist of the composite felt of polyester-cotton blend nonwoven and glass fiber reticular cloth by machine-processed scraper plate, form the flexible composite sheet material of wide 1.2 meters, carried out mechanical thermal blowing and dry, and natural drying maintenance is standby after 28 days under the interior temperature of 5～38 ℃;
Adopt machine-processed scraper plate or spraying technology that colored finish mortar is evenly coated on to described flexible composite sheet material external surface one side, and dry and dry and natural drying method makes described colored finish mortar film forming curing by mechanical thermal; Adopt again the method for spraying or roller coating anti-fouling and self-cleaning coating to be coated in to the external surface of described colored finish mortar; Finally with cutting machine, sheet material is cut into consistent with the specification of described sheet material;
The preparation of step 3, polymer-modified cement mortar cementing agent: first the each component in raw material is weighed one by one, then by mixer water, hydroxypropyl methyl cellulose ether, re-dispersible glue powder and starch ether additive are fully disperseed; Again cement is slowly poured in mixer and evenly mixed with described additive; Finally silica sand is progressively added in mixer and stir with its material middling speed, until slurry is become the paste of even thickness by mix, discharging barrelling is standby;
Step 4, merging encapsulation: foam micro-crystalline ceramic warming plate end face and described flexible facing cover material bottom is bonding compound with polymer-modified cement mortar cementing agent, compound good foam micro-crystalline ceramic heat-insulating decorative composite board is processed through roll-in and autoclave, made described insulation layer and described decorative layer close adhesion;
Step 5, maintenance cutting: by room temperature maintenance of sheet material 28 days, or maintenance 14 days in the fog room of 50 ℃ of temperature, after, the material that step 4 is obtained adopts machine to cut into specification for long: 2000mm, 2440mm, 3000mm or 3200mm; Wide: the heat insulating decorative board of 1220mm, 1250mm or 1500mm, obtains product.
Crystallite foam ceramic thermal insulation decoration composite plate difference from prior art of the present invention is:
Crystallite foam ceramic thermal insulation decoration composite plate of the present invention has adopted the crystallite foamed ceramic insulation board and the mode that flexible decoration cover material combines with fire-proof function, has advantages of factory's component, construction assemblingization, high temperature of fire fire-retardant fireproof, heat insulating and sound isolating decorative Composite.The insulation layer materials'use crystallite foamed ceramics of composite plate of the present invention, this material belongs to inorganic mineral heat insulating material, the characteristic such as have lightweight, coefficient of thermal conductivity is low, thermal property good, environmental protection, durability are strong, fire-retardant, has become one of outer heat preservation fireproofing material first-selection of external wall.Described crystallite foamed ceramic insulation board is processed into by crystallite foamed ceramics, it is raw material that crystallite foamed ceramics be take the industrial tailings waste residues such as cullet, flyash, gangue, add auxiliary agent, comprise blowing agent, nucleator and Admixture, mix after crushed formation batch, then batch is put in special grinding tool, puts into electric furnace and heat, through preheating, melting, foaming, crystallization, annealing process, make; Described foam micro-crystalline ceramic proportion: 0.1～0.6, unit weight: 767～1076kg/m
3coefficient of thermal conductivity :≤0.029w/mk, water absorption rate: 5～20Vol%, compressive strength: 9～18MPa, rupture strength: 5.6～19MPa:, high-temperature capability: 740～800MPa, degree of fire resistance: >100, fireproof performance reaches country's " A " grade standard, energy acid resistance: 0.08～5.0, alkali resistance: 0.05～0.8, frost resistance: 0.03～0.38, not fluorine-containing chlorination charcoal and hydrogen fluorine chloric acid.Coating on both sides at described insulation layer has interfacial agents, and its effect is the viscosity that increases foam pyroceram plate surface, improves the adhesive power of itself and adhesive mortar.
Below in conjunction with accompanying drawing, crystallite foam ceramic thermal insulation decoration composite plate of the present invention is described further.
Accompanying drawing explanation
Fig. 1 is the structural representation of crystallite foam ceramic thermal insulation decoration composite plate of the present invention.
The specific embodiment
Embodiment 1
As shown in Figure 1, a kind of crystallite foam ceramic thermal insulation decoration composite plate, comprise insulation layer 1 and the decorative layer 2 that adopts flame retardant type cementing agent 8 to be fixed on described insulation layer 1, described insulation layer 1 is crystallite foamed ceramic insulation board, described decorative layer 2 is flexible facing cover material, it comprises flexible composite sheet material 3, colored finish mortar 4 and skin coat 5 from the bottom to top successively, and wherein, described flame retardant type cementing agent 8 is polymer-modified cement mortar cementing agent.
Described crystallite foamed ceramic insulation board thickness is 50mm; Described flexible facing cover material thickness is 15mm; The specification of described crystallite foam ceramic thermal insulation decoration composite plate is for long: 2000mm; Wide: 1220mm.
Coating on both sides at described crystallite foamed ceramic insulation board has interfacial agents, and described interfacial agents is comprised of the material of following weight portion:
Solid content is 45～49% BC-700 acrylic emulsion: 5 parts;
Solid content is 45～47% BC-200 acrylic emulsion: 10 parts;
Deionized water: 15 parts;
Ethylene glycol: 0.8 part;
Wollastonite in powder: 6 parts;
Kaolin: 10 parts;
Coarse whiting: 10 parts;
Anionic wetting agent: 0.8 part;
Coalescents: 0.7 part;
Dispersing agent: 0.4 part;
Defoamer: 0.2 part;
PH adjusting agent: 0.8 part;
Antisepticize and mildew preventive: 0.5 part;
Plasticizing agent: 0.3 part;
Wherein, described coalescents is Lauryl Alcohol ester, and described dispersing agent is sodium polyphosphate, and described defoamer is PPG, and described Antisepticize and mildew preventive is that OBPA contains arsenic organic matter mould inhibitor, and described plasticizing agent is polyacrylic acid lipid plasticizing agent.
Described polymer-modified cement mortar cementing agent is formed by the material stirring of following weight portion:
52.5 cement: 300 parts;
40～120 object silica sands: 550 parts;
200 object coarse whitings: 50 parts;
Viscosity is 20,000-40, the hydroxypropyl methyl cellulose ether of 000mpas: 3 parts;
Re-dispersible glue powder: 25 parts;
Wood fibre: 4 parts.
Described flexible composite sheet material 3 is composited by tire base 6 and the flexible polymer cement mortar 7 that is coated on its both sides, and described tire base 6 is the composite felt of polyester-cotton blend nonwoven and glass fiber reticular cloth.
Described flexible polymer cement mortar 7 is comprised of the material of following weight portion:
BC200-acrylic emulsion: 60 parts;
BC700-acrylic emulsion: 150 parts;
80～120 object silica sands: 410 parts;
52.5 cement: 140 parts;
Viscosity is 20,000-40, the hydroxypropyl methyl cellulose ether of 000mpas: 30 parts;
Ethylene glycol: 10 parts.
Described colored finish mortar 4 forms by the mixed raw material of following weight portion is standby:
40～120 object colorful quartz sands: 700 parts;
Pure-acrylic emulsion: 200 parts;
Coalescents: 6 parts;
Ethylene glycol: 2 parts;
Defoamer: 2 parts;
Anticorrosion and bactericidal agent: 1 part;
Viscosity is the hydroxyethylmethyl-cellulose ether of 400000mpas: 3 parts;
Color stuffing: 2 parts;
Deionized water: 56.7 parts;
Wherein, described coalescents is Lauryl Alcohol ester, and described defoamer is PPG, and described anticorrosion and bactericidal agent is OIT anticorrisive agent.
Described skin coat 5 is applied and is formed by anti-fouling and self-cleaning coating, and described anti-fouling and self-cleaning coating is that particle diameter is nano level organosilicon-modified acrylic coating, and it is comprised of following weight portion:
Deionized water: 500 parts;
Solid content is 47% organic siliconresin emulsion: 320 parts;
Anionic wetting agent: 3 parts;
Thickener: 10 parts;
Coalescents: 10 parts;
Dispersing agent: 4 parts;
Defoamer: 3 parts;
PH adjusting agent: 2 parts;
Antisepticize and mildew preventive: 6 parts;
Ethylene glycol: 8 parts;
Plasticizing agent: 3 parts;
Wherein, described thickener is cellulose ether, and described coalescents is Lauryl Alcohol ester, and described dispersing agent is PTPP (potassium tripolyphosphate), and described defoamer is polyethers, and described Antisepticize and mildew preventive is that OBPA contains arsenic organic matter mould inhibitor, and described plasticizing agent is synthetic vegetable esters fluidizer.
A preparation method for described crystallite foam ceramic thermal insulation decoration composite plate, comprises the steps:
The preparation of step 1, insulation layer 1:
Described warming plate 1 is processed into by crystallite foamed ceramics by crystallite foamed ceramic insulation board, it is 50mm that manufactured foam micro-crystalline ceramic is cut into thickness, its surface and corner polishing processing are processed, guarantee that upper surface is smooth, horizontal error ± 2mm, facade vertical error ± 2mm, the upright error ± 3mm of external corner, removes plate surface attachment; Method on sheet material two sides with cylinder and spraying applies interfacial agents twice, guarantees without holiday, to improve the adhesive power of foam micro-crystalline ceramic sheet material external surface;
The preparation of step 2, flexible facing cover material: first flexible polymer cement mortar 7 is evenly coated to described tire base 6 both sides that consist of the composite felt of polyester-cotton blend nonwoven and glass fiber reticular cloth by machine-processed scraper plate, form the flexible composite sheet material of wide 1.2 meters, carried out mechanical thermal blowing and dry, and natural drying maintenance is standby after 28 days under the interior temperature of 5 ℃;
Adopt machine-processed scraper plate or spraying technology that colored finish mortar 4 is evenly coated on to described flexible composite sheet material 3 external surface one sides, and dry and dry and natural drying method makes described colored finish mortar 4 film forming curing by mechanical thermal; Adopt again the method for spraying anti-fouling and self-cleaning coating to be coated in to the external surface of described colored finish mortar 4; Finally with cutting machine, sheet material is cut into consistent with the specification of described sheet material;
The preparation of step 3, polymer-modified cement mortar cementing agent: first the each component in raw material is weighed one by one, then by mixer water, hydroxypropyl methyl cellulose ether, re-dispersible glue powder and starch ether additive are fully disperseed; Again cement is slowly poured in mixer and evenly mixed with described additive; Finally silica sand is progressively added in mixer and stir with its material middling speed, until slurry is become the paste of even thickness by mix, discharging barrelling is standby;
Step 4, merging encapsulation: foam micro-crystalline ceramic warming plate end face and described flexible facing cover material bottom is bonding compound with polymer-modified cement mortar cementing agent, compound good foam micro-crystalline ceramic heat-insulating decorative composite board is processed through roll-in and autoclave, made described insulation layer 1 and described decorative layer 2 close adhesion;
Step 5, maintenance cutting: by room temperature maintenance of sheet material, after 28 days, the material that step 4 is obtained adopts machine to cut into specification for long: 2000mm; Wide: the heat insulating decorative board of 1220mm, obtains product.
Embodiment 2
As shown in Figure 1, a kind of crystallite foam ceramic thermal insulation decoration composite plate, comprise insulation layer 1 and the decorative layer 2 that adopts flame retardant type cementing agent 8 to be fixed on described insulation layer 1, described insulation layer 1 is crystallite foamed ceramic insulation board, described decorative layer 2 is flexible facing cover material, it comprises flexible composite sheet material 3, colored finish mortar 4 and skin coat 5 from the bottom to top successively, and wherein, described flame retardant type cementing agent 8 is polymer-modified cement mortar cementing agent.
Described crystallite foamed ceramic insulation board thickness is 700mm, and described flexible facing cover material thickness is 30mm, and the specification of described crystallite foam ceramic thermal insulation decoration composite plate is for long: 2440mm; Wide: 1250mm.
Coating on both sides at described crystallite foamed ceramic insulation board has interfacial agents, and described interfacial agents is comprised of the material of following weight portion:
Solid content is 45～49% BC-700 acrylic emulsion: 10 parts;
Solid content is 45～47% BC-200 acrylic emulsion: 10 parts;
Deionized water: 30 parts;
Ethylene glycol: 0.4 part;
Wollastonite in powder: 10 parts;
Kaolin: 8 parts;
Coarse whiting: 14.8 parts;
Anionic wetting agent: 0.5 part;
Coalescents: 1 part;
Dispersing agent: 0.2 part;
Defoamer: 0.3 part;
PH adjusting agent: 0.6 part;
Antisepticize and mildew preventive: 0.8 part;
Plasticizing agent: 0.1 part;
Wherein, described coalescents is Lauryl Alcohol ester, and described dispersing agent is sodium polyphosphate, and described defoamer is PPG, and described Antisepticize and mildew preventive is that OBPA contains arsenic organic matter mould inhibitor, and described plasticizing agent is polyacrylic acid lipid plasticizing agent.
Described polymer-modified cement mortar cementing agent is formed by the material stirring of following weight portion:
52.5 cement: 350 parts;
40～120 object silica sands: 500 parts;
200 object coarse whitings: 100 parts;
Viscosity is 20,000-40, the hydroxypropyl methyl cellulose ether of 000mpas: 2 parts;
Re-dispersible glue powder: 44 parts;
Wood fibre: 4 parts.
Described flexible composite sheet material 3 is composited by tire base 6 and the flexible polymer cement mortar 7 that is coated on its both sides, and described tire base 6 is the composite felt of polyester-cotton blend nonwoven and glass fiber reticular cloth.
Described flexible polymer cement mortar 7 is comprised of the material of following weight portion:
BC200-acrylic emulsion: 60 parts;
BC700-acrylic emulsion: 150 parts;
80～120 object silica sands: 410 parts;
52.5 cement: 140 parts;
Viscosity is 20,000-40, the hydroxypropyl methyl cellulose ether of 000mpas: 30 parts;
Ethylene glycol: 10 parts.
Described colored finish mortar 4 forms by the mixed raw material of following weight portion is standby:
40～120 object colorful quartz sands: 700 parts;
Pure-acrylic emulsion: 200 parts;
Coalescents: 6 parts;
Ethylene glycol: 2 parts;
Defoamer: 2 parts;
Anticorrosion and bactericidal agent: 1 part;
Viscosity is the hydroxyethylmethyl-cellulose ether of 400000mpas: 3 parts;
Color stuffing: 2 parts;
Deionized water: 56.7 parts;
Wherein, described coalescents is Lauryl Alcohol ester, and described defoamer is PPG, and described anticorrosion and bactericidal agent is OIT anticorrisive agent.
Described skin coat 5 is applied and is formed by anti-fouling and self-cleaning coating, and described anti-fouling and self-cleaning coating is that particle diameter is nano level organosilicon-modified acrylic coating, and it is comprised of following weight portion:
Deionized water: 620 parts;
Solid content is 47% organic siliconresin emulsion: 170 parts;
Anionic wetting agent: 3 parts;
Thickener: 18 parts;
Coalescents: 5 parts;
Dispersing agent: 4 parts;
Defoamer: 3 parts;
PH adjusting agent: 5 parts;
Antisepticize and mildew preventive: 6 parts;
Ethylene glycol: 8 parts;
Plasticizing agent: 3 parts;
Wherein, described thickener is cellulose ether, and described coalescents is Lauryl Alcohol ester, and described dispersing agent is PTPP (potassium tripolyphosphate), and described defoamer is polyethers, and described Antisepticize and mildew preventive is that OBPA contains arsenic organic matter mould inhibitor, and described plasticizing agent is synthetic vegetable esters fluidizer.
A preparation method for described crystallite foam ceramic thermal insulation decoration composite plate, comprises the steps:
The preparation of step 1, insulation layer 1:
Described warming plate 1 is processed into by crystallite foamed ceramics by crystallite foamed ceramic insulation board, it is 700mm that manufactured foam micro-crystalline ceramic is cut into thickness, its surface and corner polishing processing are processed, guarantee that upper surface is smooth, horizontal error ± 2mm, facade vertical error ± 2mm, the upright error ± 3mm of external corner, removes plate surface attachment; Method on sheet material two sides with cylinder and spraying applies 3 times interfacial agents, guarantees without holiday, to improve the adhesive power of foam micro-crystalline ceramic sheet material external surface;
The preparation of step 2, flexible facing cover material: first flexible polymer cement mortar 7 is evenly coated to described tire base 6 both sides that consist of the composite felt of polyester-cotton blend nonwoven and glass fiber reticular cloth by machine-processed scraper plate, form the flexible composite sheet material of wide 1.2 meters, carried out mechanical thermal blowing and dry, and natural drying maintenance is standby after 28 days under the interior temperature of 38 ℃;
Adopt machine-processed scraper plate or spraying technology that colored finish mortar 4 is evenly coated on to described flexible composite sheet material 3 external surface one sides, and dry and dry and natural drying method makes described colored finish mortar 4 film forming curing by mechanical thermal; Adopt again the method for roller coating anti-fouling and self-cleaning coating to be coated in to the external surface of described colored finish mortar 4; Finally with cutting machine, sheet material is cut into consistent with the specification of described sheet material;
The preparation of step 3, polymer-modified cement mortar cementing agent: first the each component in raw material is weighed one by one, then by mixer water, hydroxypropyl methyl cellulose ether, re-dispersible glue powder and starch ether additive are fully disperseed; Again cement is slowly poured in mixer and evenly mixed with described additive; Finally silica sand is progressively added in mixer and stir with its material middling speed, until slurry is become the paste of even thickness by mix, discharging barrelling is standby;
Step 4, merging encapsulation: foam micro-crystalline ceramic warming plate end face and described flexible facing cover material bottom is bonding compound with polymer-modified cement mortar cementing agent, compound good foam micro-crystalline ceramic heat-insulating decorative composite board is processed through roll-in and autoclave, made described insulation layer 1 and described decorative layer 2 close adhesion;
Step 5, maintenance cutting: by sheet material, in the fog room of 50 ℃ of temperature, maintenance is after 14 days, and the material that step 4 is obtained adopts machine to cut into specification for long: 2440mm; Wide: 1250mm.
Embodiment 3
As shown in Figure 1, a kind of crystallite foam ceramic thermal insulation decoration composite plate, comprise insulation layer 1 and the decorative layer 2 that adopts flame retardant type cementing agent 8 to be fixed on described insulation layer 1, described insulation layer 1 is crystallite foamed ceramic insulation board, described decorative layer 2 is flexible facing cover material, it comprises flexible composite sheet material 3, colored finish mortar 4 and skin coat 5 from the bottom to top successively, and wherein, described flame retardant type cementing agent 8 is polymer-modified cement mortar cementing agent.
Described crystallite foamed ceramic insulation board thickness is 300mm, and described flexible facing cover material thickness is 25mm, and the specification of described crystallite foam ceramic thermal insulation decoration composite plate is for long: 3200mm; Wide: 1500mm.
Coating on both sides at described crystallite foamed ceramic insulation board has interfacial agents, and described interfacial agents is comprised of the material of following weight portion:
Solid content is 45～49% BC-700 acrylic emulsion: 7 parts;
Solid content is 45～47% BC-200 acrylic emulsion: 12 parts;
Deionized water: 25 parts;
Ethylene glycol: 0.6 part;
Wollastonite in powder: 8 parts;
Kaolin: 9 parts;
Coarse whiting: 12.5 parts;
Anionic wetting agent: 0.6 part;
Coalescents: 0.9 part;
Dispersing agent: 0.3 part;
Defoamer: 0.25 part;
PH adjusting agent: 0.7 part;
Antisepticize and mildew preventive: 0.7 part;
Plasticizing agent: 0.2 part;
Wherein, described coalescents is Lauryl Alcohol ester, and described dispersing agent is sodium polyphosphate, and described defoamer is PPG, and described Antisepticize and mildew preventive is that OBPA contains arsenic organic matter mould inhibitor, and described plasticizing agent is polyacrylic acid lipid plasticizing agent.
Described polymer-modified cement mortar cementing agent is formed by the material stirring of following weight portion:
52.5 cement: 330 parts;
40～120 object silica sands: 520 parts;
200 object coarse whitings: 75 parts;
Viscosity is 20,000-40, the hydroxypropyl methyl cellulose ether of 000mpas: 2.5 parts;
Re-dispersible glue powder: 35 parts;
Wood fibre: 4 parts.
Described flexible composite sheet material 3 is composited by tire base 6 and the flexible polymer cement mortar 7 that is coated on its both sides, and described tire base 6 is the composite felt of polyester-cotton blend nonwoven and glass fiber reticular cloth.
Described flexible polymer cement mortar 7 is comprised of the material of following weight portion:
BC200-acrylic emulsion: 60 parts;
BC700-acrylic emulsion: 150 parts;
80～120 object silica sands: 410 parts;
52.5 cement: 140 parts;
Viscosity is 20,000-40, the hydroxypropyl methyl cellulose ether of 000mpas: 30 parts;
Ethylene glycol: 10 parts.
Described colored finish mortar 4 forms by the mixed raw material of following weight portion is standby:
40～120 object colorful quartz sands: 700 parts;
Pure-acrylic emulsion: 200 parts;
Coalescents: 6 parts;
Ethylene glycol: 2 parts;
Defoamer: 2 parts;
Anticorrosion and bactericidal agent: 1 part;
Viscosity is the hydroxyethylmethyl-cellulose ether of 400000mpas: 3 parts;
Color stuffing: 2 parts;
Deionized water: 56.7 parts;
Wherein, described coalescents is Lauryl Alcohol ester, and described defoamer is PPG, and described anticorrosion and bactericidal agent is OIT anticorrisive agent.
Described skin coat 5 is applied and is formed by anti-fouling and self-cleaning coating, and described anti-fouling and self-cleaning coating is that particle diameter is nano level organosilicon-modified acrylic coating, and it is comprised of following weight portion:
Deionized water: 580 parts;
Solid content is 47% organic siliconresin emulsion: 260 parts;
Anionic wetting agent: 3 parts;
Thickener: 15 parts;
Coalescents: 8 parts;
Dispersing agent: 4 parts;
Defoamer: 3 parts;
PH adjusting agent: 4 parts;
Antisepticize and mildew preventive: 6 parts;
Ethylene glycol: 8 parts;
Plasticizing agent: 3 parts;
Wherein, described thickener is cellulose ether, and described coalescents is Lauryl Alcohol ester, and described dispersing agent is PTPP (potassium tripolyphosphate), and described defoamer is polyethers, and described Antisepticize and mildew preventive is that OBPA contains arsenic organic matter mould inhibitor, and described plasticizing agent is synthetic vegetable esters fluidizer.
A preparation method for described crystallite foam ceramic thermal insulation decoration composite plate, comprises the steps:
The preparation of step 1, insulation layer 1:
Described warming plate 1 is processed into by crystallite foamed ceramics by crystallite foamed ceramic insulation board, it is 300mm that manufactured foam micro-crystalline ceramic is cut into thickness, its surface and corner polishing processing are processed, guarantee that upper surface is smooth, horizontal error ± 2mm, facade vertical error ± 2mm, the upright error ± 3mm of external corner, removes plate surface attachment; Method on sheet material two sides with cylinder and spraying applies interfacial agents twice, guarantees without holiday, to improve the adhesive power of foam micro-crystalline ceramic sheet material external surface;
The preparation of step 2, flexible facing cover material: first flexible polymer cement mortar 7 is evenly coated to described tire base 6 both sides that consist of the composite felt of polyester-cotton blend nonwoven and glass fiber reticular cloth by machine-processed scraper plate, form the flexible composite sheet material of wide 1.2 meters, carried out mechanical thermal blowing and dry, and natural drying maintenance is standby after 28 days under the interior temperature of 20 ℃;
Adopt machine-processed scraper plate or spraying technology that colored finish mortar 4 is evenly coated on to described flexible composite sheet material 3 external surface one sides, and dry and dry and natural drying method makes described colored finish mortar 4 film forming curing by mechanical thermal; Adopt again the method for spraying or roller coating anti-fouling and self-cleaning coating to be coated in to the external surface of described colored finish mortar 4; Finally with cutting machine, sheet material is cut into consistent with the specification of described sheet material;
The preparation of step 3, polymer-modified cement mortar cementing agent: first the each component in raw material is weighed one by one, then by mixer water, hydroxypropyl methyl cellulose ether, re-dispersible glue powder and starch ether additive are fully disperseed; Again cement is slowly poured in mixer and evenly mixed with described additive; Finally silica sand is progressively added in mixer and stir with its material middling speed, until slurry is become the paste of even thickness by mix, discharging barrelling is standby;
Step 4, merging encapsulation: foam micro-crystalline ceramic warming plate end face and described flexible facing cover material bottom is bonding compound with polymer-modified cement mortar cementing agent, compound good foam micro-crystalline ceramic heat-insulating decorative composite board is processed through roll-in and autoclave, made described insulation layer 1 and described decorative layer 2 close adhesion;
Step 5, maintenance cutting: by room temperature maintenance of sheet material, after 28 days, the material that step 4 is obtained adopts machine to cut into specification for long: 3200mm; Wide: the heat insulating decorative board of 1500mm, obtains product.
Above-described embodiment is described the preferred embodiment of the present invention; not scope of the present invention is limited; design under the prerequisite of spirit not departing from the present invention; various distortion and improvement that those of ordinary skills make technical scheme of the present invention, all should fall in the definite protection domain of the claims in the present invention book.
Claims (10)
1. a crystallite foam ceramic thermal insulation decoration composite plate, it is characterized in that: comprise insulation layer (1) and adopt flame retardant type cementing agent (8) to be fixed on the decorative layer (2) on described insulation layer (1), described insulation layer (1) is crystallite foamed ceramic insulation board, described decorative layer (2) is flexible facing cover material, it comprises flexible composite sheet material (3), colored finish mortar (4) and skin coat (5) from the bottom to top successively, wherein, described flame retardant type cementing agent (8) is polymer-modified cement mortar cementing agent.
2. crystallite foam ceramic thermal insulation decoration composite plate according to claim 1, is characterized in that: described crystallite foamed ceramic insulation board thickness is 50mm～700mm, and above-mentioned flexible facing cover material thickness is 1.5mm～3.0mm.
3. crystallite foam ceramic thermal insulation decoration composite plate according to claim 1, is characterized in that: the specification of described crystallite foam ceramic thermal insulation decoration composite plate is for long: 2000mm, 2440mm, 3000mm or 3200mm; Wide: 1220mm, 1250mm or 1500mm.
4. according to the crystallite foam ceramic thermal insulation decoration composite plate described in claim 1 or 2 or 3, it is characterized in that: the coating on both sides at described crystallite foamed ceramic insulation board has interfacial agents, described interfacial agents is comprised of the material of following weight portion:
Solid content is 45～49% BC-700 acrylic emulsion: 5～10 parts;
Solid content is 45～47% BC-200 acrylic emulsion: 10～15 parts;
Deionized water: 15～30 parts;
Ethylene glycol: 0.4～0.8 part;
Wollastonite in powder: 6～10 parts;
Kaolin: 8～10 parts;
Coarse whiting: 10～14.8 parts;
Anionic wetting agent: 0.5～0.8 part;
Coalescents: 0.7～1 part;
Dispersing agent: 0.2～0.4 part;
Defoamer: 0.2～0.3 part;
PH adjusting agent: 0.6～0.8 part;
Antisepticize and mildew preventive: 0.5～0.8 part;
Plasticizing agent: 0.1～0.3 part;
Wherein, described coalescents is Lauryl Alcohol ester, and described dispersing agent is sodium polyphosphate, and described defoamer is PPG, and described Antisepticize and mildew preventive is that OBPA contains arsenic organic matter mould inhibitor, and described plasticizing agent is polyacrylic acid lipid plasticizing agent.
5. crystallite foam ceramic thermal insulation decoration composite plate according to claim 4, is characterized in that: described polymer-modified cement mortar cementing agent is stirred and formed by the material of following weight portion:
52.5 cement: 300～350 parts;
40～120 object silica sands: 500～550 parts;
200 object coarse whitings: 50～100 parts;
Viscosity is 20,000-40, the hydroxypropyl methyl cellulose ether of 000mpas: 2～3 parts;
Re-dispersible glue powder: 25～44 parts;
Wood fibre: 4 parts.
6. crystallite foam ceramic thermal insulation decoration composite plate according to claim 1, it is characterized in that: described flexible composite sheet material (3) is composited by tire base (6) and the flexible polymer cement mortar (7) that is coated on its both sides, and described tire base (6) is the composite felt of polyester-cotton blend nonwoven and glass fiber reticular cloth.
7. crystallite foam ceramic thermal insulation decoration composite plate according to claim 6, is characterized in that: described flexible polymer cement mortar (7) is comprised of the material of following weight portion:
BC200-acrylic emulsion: 60 parts;
BC700-acrylic emulsion: 150 parts;
80～120 object silica sands: 410 parts;
52.5 cement: 140 parts;
Viscosity is 20,000-40, the hydroxypropyl methyl cellulose ether of 000mpas: 30 parts;
Ethylene glycol: 10 parts.
8. according to the crystallite foam ceramic thermal insulation decoration composite plate described in claim 1 or 7, it is characterized in that: described colored finish mortar (4) forms by the mixed raw material of following weight portion is standby:
40～120 object colorful quartz sands: 700 parts;
Pure-acrylic emulsion: 200 parts;
Coalescents: 6 parts;
Ethylene glycol: 2 parts;
Defoamer: 2 parts;
Anticorrosion and bactericidal agent: 1 part;
Viscosity is the hydroxyethylmethyl-cellulose ether of 400000mpas: 3 parts;
Color stuffing: 2 parts;
Deionized water: 56.7 parts;
Wherein, described coalescents is Lauryl Alcohol ester, and described defoamer is PPG, and described anticorrosion and bactericidal agent is OIT anticorrisive agent.
9. crystallite foam ceramic thermal insulation decoration composite plate according to claim 8, it is characterized in that: described skin coat (5) is applied and formed by anti-fouling and self-cleaning coating, described anti-fouling and self-cleaning coating is that particle diameter is nano level organosilicon-modified acrylic coating, and it is comprised of following weight portion:
Deionized water: 500～620 parts;
Solid content is 47% organic siliconresin emulsion: 170～320 parts;
Anionic wetting agent: 3 parts;
Thickener: 10～18 parts;
Coalescents: 5～10 parts;
Dispersing agent: 4 parts;
Defoamer: 3 parts;
PH adjusting agent: 2～5 parts;
Antisepticize and mildew preventive: 6 parts;
Ethylene glycol: 8 parts;
Plasticizing agent: 3 parts;
Wherein, described thickener is cellulose ether, and described coalescents is Lauryl Alcohol ester, and described dispersing agent is PTPP (potassium tripolyphosphate), and described defoamer is polyethers, and described Antisepticize and mildew preventive is that OBPA contains arsenic organic matter mould inhibitor, and described plasticizing agent is synthetic vegetable esters fluidizer.
10. the preparation method of the crystallite foam ceramic thermal insulation decoration composite plate described in any one in claim 1-9, is characterized in that: comprise the steps:
The preparation of step 1, insulation layer (1):
Described warming plate (1) is processed into by crystallite foamed ceramics by crystallite foamed ceramic insulation board, manufactured foam micro-crystalline ceramic is cut into the sheet material that thickness is 50mm～700mm, its surface and corner polishing processing are processed, guarantee that upper surface is smooth, horizontal error ± 2mm, facade vertical error ± 2mm, the upright error ± 3mm of external corner, removes plate surface attachment; Method on sheet material two sides with cylinder and spraying applies 2～3 times interfacial agents, guarantees without holiday, to improve the adhesive power of foam micro-crystalline ceramic sheet material external surface;
The preparation of step 2, flexible facing cover material: first flexible polymer cement mortar (7) is evenly coated to described tire base (6) both sides that consist of the composite felt of polyester-cotton blend nonwoven and glass fiber reticular cloth by machine-processed scraper plate, form the flexible composite sheet material of wide 1.2 meters, carried out mechanical thermal blowing and dry, and natural drying maintenance is standby after 28 days under the interior temperature of 5～38 ℃;
Adopt machine-processed scraper plate or spraying technology that colored finish mortar (4) is evenly coated on to described flexible composite sheet material (3) external surface one side, and dry and dry and natural drying method makes described colored finish mortar (4) film forming curing by mechanical thermal; Adopt again the method for spraying or roller coating anti-fouling and self-cleaning coating to be coated in to the external surface of described colored finish mortar (4); Finally with cutting machine, sheet material is cut into consistent with the specification of described sheet material;
The preparation of step 3, polymer-modified cement mortar cementing agent: first the each component in raw material is weighed one by one, then by mixer water, hydroxypropyl methyl cellulose ether, re-dispersible glue powder and starch ether additive are fully disperseed; Again cement is slowly poured in mixer and evenly mixed with described additive; Finally silica sand is progressively added in mixer and stir with its material middling speed, until slurry is become the paste of even thickness by mix, discharging barrelling is standby;
Step 4, merging encapsulation: foam micro-crystalline ceramic warming plate end face and described flexible facing cover material bottom is bonding compound with polymer-modified cement mortar cementing agent, compound good foam micro-crystalline ceramic heat-insulating decorative composite board is processed through roll-in and autoclave, made described insulation layer (1) and described decorative layer (2) close adhesion;
Step 5, maintenance cutting: by room temperature maintenance of sheet material 28 days or in the fog room of 50 ℃ of temperature, maintenance is after 14 days, and the material that step 4 is obtained adopts machine to cut into specification for long: 2000mm, 2440mm, 3000mm or 3200mm; Wide: the heat insulating decorative board of 1220mm, 1250mm or 1500mm, obtains product.
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