CN103938820B - A kind of crystallite foam ceramic thermal insulation decoration composite plate and preparation method thereof - Google Patents
A kind of crystallite foam ceramic thermal insulation decoration composite plate and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a kind of crystallite foam ceramic thermal insulation decoration composite plate, the decorative layer (2) being fixed on described heat-insulation layer (1) including heat-insulation layer (1) and employing flame retardant type binding agent (8), described heat-insulation layer (1) is crystallite foamed ceramic insulation board, described decorative layer (2) covers material for flexible facing, it includes flexible composite sheet material (3), colored finish mortar (4) and finishing coat (5) the most successively, wherein, described flame retardant type binding agent (8) is polymer-modified cement mortar binding agent.Crystallite foam ceramic thermal insulation decoration composite plate of the present invention is covered by the way of material combines by having the crystallite foamed ceramic insulation board of fire-proof function by fire-resistant binder with flexible decorative, has factory's component, construction assemblingization, high temperature of fire fire-retardant fireproof, the advantage of heat insulating and sound isolating decorative Composite.
Description
Technical field
The present invention relates to building energy saving field, be specifically related to a kind of crystallite foam ceramic thermal insulation decoration composite plate and preparation method thereof.
Background technology
Although External Thermal Insulation Technology for External the nearlyest 30 years in China's promotion and application, but due to the research of existing heat preserving and insulating material and technology
The restriction of level, the widely used material of current architectural engineering the exterior wall external insulation is mainly styrofoam, polyurethane sheet, phenol
The lightweight organic foam materials such as aldehyde plate, the warming plate thermal property that these are made up of petrochemical industry spin-off is good, and light-weight water-proof,
But fire rating belongs to flammable and difficult combustion, sheet material can generate substantial amounts of toxic and harmful while removing release high heat when burning,
Cause serious personal injury and environmental pollution.For avoiding these defects come with raw tool of organic insulation material, part external thermal insulation item
Mesh is also using the light inorganic heat preserving material that the such as fire savety such as rock cotton board, block of glass wool is high.But in actual applications,
Rock (stone) cotton insulation material exposes and is easily generated dust and micro fiber, can cause during production and processing and construction and installation
Personal injury and environmental pollution, thus leverage the promotion and application commercially of this series products.Find safer, more ring
Guarantor and thermal property and mechanical strength can reach again the heat preserving and insulating material that technology requires, always material science researcher is diligent not
Tired pursuit.Patent ZL032520530 " compound asbestos foam glass thermal insulation decorative material " proposes foam glass and large format
Ceramic tile is compound in factory, it is achieved heat preservation decoration integrative, had both improve the fire savety of exterior insulation work, and had greatly reduced again
The wet trade of site operation, but the shortcoming of this patent is not consider that foam glass mechanical strength is the highest, in transport, carries and executes
Work process easily causes product breakage, and percent defective is high, and composite plate weight is big, and pole is not easy to the unfavorable factors such as the work high above the ground of exterior wall.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of has insulation, fire-proof and water-proof for external wall enclosed structure
With sound insulation noise reduction function and with building with the crystallite foam ceramic thermal insulation decoration composite plate and preparation method thereof in life-span.
A kind of crystallite foam ceramic thermal insulation decoration composite plate, is fixed on described heat-insulation layer including heat-insulation layer and employing flame retardant type binding agent
On decorative layer, described heat-insulation layer is crystallite foamed ceramic insulation board, and described decorative layer covers material for flexible facing, and it is from the bottom to top
Including flexible composite sheet material, colored finish mortar and finishing coat successively, wherein, described flame retardant type binding agent is that polymer changes
Property cement mortar binding agent.
Crystallite foam ceramic thermal insulation decoration composite plate of the present invention, wherein said crystallite foamed ceramic insulation board thickness is
50mm～700mm, it is 15mm～30mm that described flexible facing covers material thickness.
Crystallite foam ceramic thermal insulation decoration composite plate of the present invention, wherein said crystallite foam ceramic thermal insulation decoration composite plate
Specification is for long: 2000mm, 2440mm, 3000mm or 3200mm；Wide: 1220mm, 1250mm or 1500mm.
Crystallite foam ceramic thermal insulation decoration composite plate of the present invention, is wherein coated with in the both sides of described crystallite foamed ceramic insulation board
Being covered with interfacial agents, described interfacial agents is made up of the material of following weight portion:
Solid content is the BC-700 acrylic emulsion of 45～49%: 5～10 parts；
Solid content is the BC-200 acrylic emulsion of 45～47%: 10～15 parts；
Deionized water: 15～30 parts；
Ethylene glycol: 0.4～0.8 part；
Wollastonite in powder: 6～10 parts；
Kaolin: 8～10 parts；
Triple superphosphate: 10～14.8 parts；
Anionic wetting agents: 0.5～0.8 part；
Coalescents: 0.7～1 part；
Dispersant: 0.2～0.4 part；
Defoamer: 0.2～0.3 part；
PH adjusting agent: 0.6～0.8 part；
Antisepticize and mildew preventive: 0.5～0.8 part；
Plasticizer: 0.1～0.3 part；
Wherein, described coalescents is Lauryl Alcohol ester, and described dispersant is sodium polyphosphate, and described defoamer is polyether polyols
Alcohol, described Antisepticize and mildew preventive is that OBPA contains arsenic Organic substance antifungus agent, and described plasticizer is polyacrylic acid lipid plasticizer.
Crystallite foam ceramic thermal insulation decoration composite plate of the present invention, wherein said polymer-modified cement mortar binding agent is by such as
The material stirring of lower weight portion forms:
52.5 cement: 300～350 parts；
The silica sand of 40～120 mesh: 500～550 parts；
The triple superphosphate of 200 mesh: 50～100 parts；
Viscosity is the hydroxypropyl methyl cellulose ether of 20,000-40,000mPa s: 2～3 parts；
Re-dispersible glue powder: 25～44 parts；
Wood fibre: 4 parts.
Crystallite foam ceramic thermal insulation decoration composite plate of the present invention, wherein said flexible composite sheet material is by tire base and coating
Flexible polymer cement mortar in its both sides is composited, and described tire base is the composite felt of polyester-cotton blend non-woven fabrics and glass fiber reticular cloth.
Crystallite foam ceramic thermal insulation decoration composite plate of the present invention, wherein said flexible polymer cement mortar is by following weight
The material composition of part:
BC-200 acrylic emulsion: 60 parts；
BC-700 acrylic emulsion: 150 parts；
The silica sand of 80～120 mesh: 410 parts；
52.5 cement: 140 parts；
Viscosity is the hydroxypropyl methyl cellulose ether of 20,000-40,000mPa s: 30 parts；
Ethylene glycol: 10 parts.
Crystallite foam ceramic thermal insulation decoration composite plate of the present invention, former by following weight portion of wherein said colored finish mortar
Material is mixed with and forms:
The colorful quartz sands of 40～120 mesh: 700 parts；
Pure-acrylic emulsion: 200 parts；
Coalescents: 6 parts；
Ethylene glycol: 2 parts；
Defoamer: 2 parts；
Anticorrosion and bactericidal agent: 1 part；
Viscosity is the ethoxyl methyl cellulose ether of 400000mPa s: 3 parts；
Color stuffing: 2 parts；
Deionized water: 56.7 parts；
Wherein, described coalescents is Lauryl Alcohol ester, and described defoamer is polyether polyol, and described anticorrosion and bactericidal agent is different thiophene
Oxazoline ketone preservative.
Crystallite foam ceramic thermal insulation decoration composite plate of the present invention, wherein said finishing coat is formed by the coating of anti-fouling and self-cleaning coating,
Described anti-fouling and self-cleaning coating be particle diameter be nano level organosilicon-modified acrylic coating, it is made up of following weight portion:
Deionized water: 500～620 parts；
Solid content is the silicone resin emulsion of 47%: 170～320 parts；
Anionic wetting agents: 3 parts；
Thickening agent: 10～18 parts；
Coalescents: 5～10 parts；
Dispersant: 4 parts；
Defoamer: 3 parts；
PH adjusting agent: 2～5 parts；
Antisepticize and mildew preventive: 6 parts；
Ethylene glycol: 8 parts；
Plasticizer: 3 parts；
Wherein, described thickening agent is cellulose ether, and described coalescents is Lauryl Alcohol ester, and described dispersant is PTPP (potassium tripolyphosphate),
Described defoamer is polyethers, and described Antisepticize and mildew preventive is that OBPA contains arsenic Organic substance antifungus agent, and described plasticizer is synthesis vegetable esters
Plasticiser.
The preparation method of crystallite foam ceramic thermal insulation decoration composite plate of the present invention, comprises the steps:
Step one, the preparation of heat-insulation layer:
Warming plate is crystallite foamed ceramic insulation board, crystallite foamed ceramics be processed into, and crystallite foamed ceramics is with cullet, powder
The industrial tailings waste residue such as coal ash, gangue is raw material, adds auxiliary agent, including foaming agent, nucleator and additive, size-reduced
Rear mix homogeneously forms batch, is then put in special grinding tool by batch, puts in electric furnace and heats, and through preheating, melts
Melt, foam, crystallize, annealing process are made；
Manufactured crystallite foamed ceramics is cut into thickness is 50mm～700mm, processed of polishing its surface and corner,
Guarantee that upper surface is smooth, horizontal error ± 2mm, facade vertical error ± 2mm, external corner Founder error ± 3mm, remove sheet material table
Face attachment；Method in sheet material two sides cylinder and spraying coats 2～3 times interfacial agents, it is ensured that without holiday, micro-to improve foam
The adhesive force of brilliant ceramic board outer surface；
Step 2, flexible facing cover the preparation of material: first by flexible polymer cement mortar by machine-processed scraper plate be spread evenly across by
Polyester-cotton blend non-woven fabrics and the tire base both sides of the composite felt composition of glass fiber reticular cloth, form the flexible composite sheet material of wide 1.2 meters, will
It carries out mechanical thermal blowing dries, and standby after natural drying maintenance 28 days under the indoor temperature of 5～38 DEG C；
Use mechanism scraper plate or spraying technology that colored finish mortar is evenly applied to described flexible composite sheet material outer surface one
Side, and make described colored finish mortar film forming solidify by the method for mechanical thermal blowing drying and natural drying；Again use spraying or
Anti-fouling and self-cleaning coating is coated in the outer surface of described colored finish mortar by the method for roller coating；Finally with cutting machine, sheet material is cut into
Consistent with the specification of described sheet material；
Step 3, the preparation of polymer-modified cement mortar binding agent: first each component in raw material is weighed one by one, then by stirring
Mix machine water by fully dispersed to hydroxypropyl methyl cellulose ether, re-dispersible glue powder and starch ether additive；Again cement is slowly fallen
Enter in blender and uniformly mix with described additive；Finally silica sand is gradually added in blender and unclassified stores moderate-speed mixer, directly
To slurry by the paste of mix uniformly thickness, discharging barrelling is standby；
Step 4, merging encapsulation: with polymer-modified cement mortar binding agent by soft with described for foam micro-crystalline ceramic warming plate end face
Property facing cover bottom material bonding compound, by the foam micro-crystalline ceramic heat-insulating decorative composite board that has been combined at roll-in and autoclave
Reason, makes described heat-insulation layer and described decorative layer close adhesion；
Step 5, maintenance cutting: by sheet material at room temperature maintenance 28 days, or maintenance 14 days in the fog room of 50 DEG C of temperature,
After, material step 4 obtained uses machine to cut into specification for long: 2000mm, 2440mm, 3000mm or 3200mm；
Wide: the heat insulating decorative board of 1220mm, 1250mm or 1500mm, obtain product.
Crystallite foam ceramic thermal insulation decoration composite plate difference from prior art of the present invention is:
Crystallite foam ceramic thermal insulation decoration composite plate of the present invention have employed the crystallite foamed ceramic insulation board with fire-proof function with flexible
Decoration covers the mode that material combines, and has factory's component, construction assemblingization, high temperature of fire fire-retardant fireproof, heat insulating and sound isolating decorative
The advantage of Composite.The heat-insulation layer materials'use crystallite foamed ceramics of composite plate of the present invention, this material belongs to inorganic mineral to be protected
Adiabator, has the characteristics such as lightweight, heat conductivity is low, thermal property good, environmental protection, durability are strong, fire-retardant, it has also become building
One of external wall outer insulation fire proofing material is first-selected.Described crystallite foamed ceramic insulation board is processed into by crystallite foamed ceramics, and crystallite steeps
Foam pottery, with industrial tailings waste residues such as cullet, flyash, gangues as raw material, adds auxiliary agent, including foaming agent, nucleation
Agent and additive, mix homogeneously forms batch after crushed, is then put in special grinding tool by batch, puts in electric furnace
Heating, makes through preheating, melted, foaming, crystallize, annealing process；Described foam micro-crystalline ceramic proportion: 0.1～0.6, holds
Weight: 767～1076kg/m3, heat conductivity :≤0.029w/m k, water absorption rate: 5～20Vol%, comprcssive strength: 9～18MPa,
Rupture strength: 5.6～19MPa:, high-temperature capability: 740～800MPa, refractoriness: > 100, fire protecting performance reaches country " A "
Grade standard, energy acid resistance: 0.08～5.0, alkali resistance: 0.05～0.8, frost resistance: 0.03～0.38, the most fluorine-containing chlorination charcoal and hydrogen fluorine
Chloric acid.Being coated with interfacial agents in the both sides of described heat-insulation layer, its effect is to increase the viscosity on foam pyroceram plate surface, improves
Its adhesive force with adhesive mortar.
Below in conjunction with the accompanying drawings the crystallite foam ceramic thermal insulation decoration composite plate of the present invention is described further.
Accompanying drawing explanation
Fig. 1 is the structural representation of crystallite foam ceramic thermal insulation decoration composite plate of the present invention.
Detailed description of the invention
Embodiment 1
As it is shown in figure 1, a kind of crystallite foam ceramic thermal insulation decoration composite plate, including heat-insulation layer 1 and employing flame retardant type binding agent 8
Being fixed on the decorative layer 2 on described heat-insulation layer 1, described heat-insulation layer 1 is crystallite foamed ceramic insulation board, and described decorative layer 2 is
Flexible facing covers material, and it includes flexible composite sheet material 3, colored finish mortar 4 and finishing coat 5 the most successively, wherein,
Described flame retardant type binding agent 8 is polymer-modified cement mortar binding agent.
Described crystallite foamed ceramic insulation board thickness is 50mm；It is 15mm that described flexible facing covers material thickness；Described crystallite foam
The specification of ceramic thermal insulation decoration composite plate is for long: 2000mm；Wide: 1220mm.
Being coated with interfacial agents in the both sides of described crystallite foamed ceramic insulation board, described interfacial agents is made up of the material of following weight portion:
Solid content is the BC-700 acrylic emulsion of 45～49%: 5 parts；
Solid content is the BC-200 acrylic emulsion of 45～47%: 10 parts；
Deionized water: 15 parts；
Ethylene glycol: 0.8 part；
Wollastonite in powder: 6 parts；
Kaolin: 10 parts；
Triple superphosphate: 10 parts；
Anionic wetting agents: 0.8 part；
Coalescents: 0.7 part；
Dispersant: 0.4 part；
Defoamer: 0.2 part；
PH adjusting agent: 0.8 part；
Antisepticize and mildew preventive: 0.5 part；
Plasticizer: 0.3 part；
Wherein, described coalescents is Lauryl Alcohol ester, and described dispersant is sodium polyphosphate, and described defoamer is polyether polyols
Alcohol, described Antisepticize and mildew preventive is that OBPA contains arsenic Organic substance antifungus agent, and described plasticizer is polyacrylic acid lipid plasticizer.
Described polymer-modified cement mortar binding agent is stirred by the material of following weight portion and forms:
52.5 cement: 300 parts；
The silica sand of 40～120 mesh: 550 parts；
The triple superphosphate of 200 mesh: 50 parts；
Viscosity is the hydroxypropyl methyl cellulose ether of 20,000-40,000mPa s: 3 parts；
Re-dispersible glue powder: 25 parts；
Wood fibre: 4 parts.
Described flexible composite sheet material 3 is composited by tire base 6 and the flexible polymer cement mortar 7 being coated on its both sides,
Described tire base 6 is the composite felt of polyester-cotton blend non-woven fabrics and glass fiber reticular cloth.
Described flexible polymer cement mortar 7 is made up of the material of following weight portion:
BC-200 acrylic emulsion: 60 parts；
BC-700 acrylic emulsion: 150 parts；
The silica sand of 80～120 mesh: 410 parts；
52.5 cement: 140 parts；
Viscosity is the hydroxypropyl methyl cellulose ether of 20,000-40,000mPa s: 30 parts；
Ethylene glycol: 10 parts.
Described colored finish mortar 4 is formed by the mixed raw material of following weight portion is standby:
The colorful quartz sands of 40～120 mesh: 700 parts；
Pure-acrylic emulsion: 200 parts；
Coalescents: 6 parts；
Ethylene glycol: 2 parts；
Defoamer: 2 parts；
Anticorrosion and bactericidal agent: 1 part；
Viscosity is the ethoxyl methyl cellulose ether of 400000mPa s: 3 parts；
Color stuffing: 2 parts；
Deionized water: 56.7 parts；
Wherein, described coalescents is Lauryl Alcohol ester, and described defoamer is polyether polyol, and described anticorrosion and bactericidal agent is different thiophene
Oxazoline ketone preservative.
Described finishing coat 5 by anti-fouling and self-cleaning coating coating form, described anti-fouling and self-cleaning coating be particle diameter be that nano level organosilicon changes
Property acrylic coating, it is made up of following weight portion:
Deionized water: 500 parts；
Solid content is the silicone resin emulsion of 47%: 320 parts；
Anionic wetting agents: 3 parts；
Thickening agent: 10 parts；
Coalescents: 10 parts；
Dispersant: 4 parts；
Defoamer: 3 parts；
PH adjusting agent: 2 parts；
Antisepticize and mildew preventive: 6 parts；
Ethylene glycol: 8 parts；
Plasticizer: 3 parts；
Wherein, described thickening agent is cellulose ether, and described coalescents is Lauryl Alcohol ester, and described dispersant is PTPP (potassium tripolyphosphate),
Described defoamer is polyethers, and described Antisepticize and mildew preventive is that OBPA contains arsenic Organic substance antifungus agent, and described plasticizer is synthesis vegetable esters
Plasticiser.
The preparation method of a kind of described crystallite foam ceramic thermal insulation decoration composite plate, comprises the steps:
Step one, the preparation of heat-insulation layer 1:
Warming plate is crystallite foamed ceramic insulation board, crystallite foamed ceramics be processed into, by manufactured crystallite foam crystallite
It is 50mm that pottery cuts into thickness, processed of polishing its surface and corner, it is ensured that upper surface is smooth, horizontal error ± 2mm,
Facade vertical error ± 2mm, external corner Founder error ± 3mm, remove plate surface attachment；In sheet material two sides cylinder and spraying
Method coat twice interfacial agents, it is ensured that without holiday, to improve the adhesive force of foam micro-crystalline ceramic sheet material outer surface；
Step 2, flexible facing cover the preparation of material: first flexible polymer cement mortar 7 be spread evenly across by mechanism scraper plate
Tire base 6 both sides being made up of the composite felt of polyester-cotton blend non-woven fabrics Yu glass fiber reticular cloth, form the flexible composite sheet material of wide 1.2 meters,
Carried out mechanical thermal blowing to dry, and standby after natural drying maintenance 28 days under the indoor temperature of 5 DEG C；
Use mechanism scraper plate or spraying technology that colored finish mortar 4 is evenly applied to described flexible composite sheet material 3 outer surface
Side, and make described colored finish mortar 4 film forming solidify by the method for mechanical thermal blowing drying and natural drying；Use spray again
Anti-fouling and self-cleaning coating is coated in the outer surface of described colored finish mortar 4 by the method being coated with；Finally with cutting machine, sheet material is cut into
Consistent with the specification of described sheet material；
Step 3, the preparation of polymer-modified cement mortar binding agent: first each component in raw material is weighed one by one, then by stirring
Mix machine water by fully dispersed to hydroxypropyl methyl cellulose ether, re-dispersible glue powder and starch ether additive；Again cement is slowly fallen
Enter in blender and uniformly mix with described additive；Finally silica sand is gradually added in blender and unclassified stores moderate-speed mixer, directly
To slurry by the paste of mix uniformly thickness, discharging barrelling is standby；
Step 4, merging encapsulation: with polymer-modified cement mortar binding agent by soft with described for foam micro-crystalline ceramic warming plate end face
Property facing cover bottom material bonding compound, by the foam micro-crystalline ceramic heat-insulating decorative composite board that has been combined at roll-in and autoclave
Reason, makes described heat-insulation layer 1 and described decorative layer 2 close adhesion；
Step 5, maintenance cutting: after sheet material at room temperature maintenance 28 days, material step 4 obtained uses machine to cut into
Specification is for long: 2000mm；Wide: the heat insulating decorative board of 1220mm, obtain product.
Embodiment 2
As it is shown in figure 1, a kind of crystallite foam ceramic thermal insulation decoration composite plate, including heat-insulation layer 1 and employing flame retardant type binding agent 8
Being fixed on the decorative layer 2 on described heat-insulation layer 1, described heat-insulation layer 1 is crystallite foamed ceramic insulation board, and described decorative layer 2 is
Flexible facing covers material, and it includes flexible composite sheet material 3, colored finish mortar 4 and finishing coat 5 the most successively, wherein,
Described flame retardant type binding agent 8 is polymer-modified cement mortar binding agent.
Described crystallite foamed ceramic insulation board thickness is 700mm, and it is 30mm that described flexible facing covers material thickness, and described crystallite steeps
The specification of foam ceramic thermal insulation decoration composite plate is for long: 2440mm；Wide: 1250mm.
Being coated with interfacial agents in the both sides of described crystallite foamed ceramic insulation board, described interfacial agents is made up of the material of following weight portion:
Solid content is the BC-700 acrylic emulsion of 45～49%: 10 parts；
Solid content is the BC-200 acrylic emulsion of 45～47%: 10 parts；
Deionized water: 30 parts；
Ethylene glycol: 0.4 part；
Wollastonite in powder: 10 parts；
Kaolin: 8 parts；
Triple superphosphate: 14.8 parts；
Anionic wetting agents: 0.5 part；
Coalescents: 1 part；
Dispersant: 0.2 part；
Defoamer: 0.3 part；
PH adjusting agent: 0.6 part；
Antisepticize and mildew preventive: 0.8 part；
Plasticizer: 0.1 part；
Wherein, described coalescents is Lauryl Alcohol ester, and described dispersant is sodium polyphosphate, and described defoamer is polyether polyols
Alcohol, described Antisepticize and mildew preventive is that OBPA contains arsenic Organic substance antifungus agent, and described plasticizer is polyacrylic acid lipid plasticizer.
Described polymer-modified cement mortar binding agent is stirred by the material of following weight portion and forms:
52.5 cement: 350 parts；
The silica sand of 40～120 mesh: 500 parts；
The triple superphosphate of 200 mesh: 100 parts；
Viscosity is the hydroxypropyl methyl cellulose ether of 20,000-40,000mPa s: 2 parts；
Re-dispersible glue powder: 44 parts；
Wood fibre: 4 parts.
Described flexible composite sheet material 3 is composited by tire base 6 and the flexible polymer cement mortar 7 being coated on its both sides,
Described tire base 6 is the composite felt of polyester-cotton blend non-woven fabrics and glass fiber reticular cloth.
Described flexible polymer cement mortar 7 is made up of the material of following weight portion:
BC-200 acrylic emulsion: 60 parts；
BC-700 acrylic emulsion: 150 parts；
The silica sand of 80～120 mesh: 410 parts；
52.5 cement: 140 parts；
Viscosity is the hydroxypropyl methyl cellulose ether of 20,000-40,000mPa s: 30 parts；
Ethylene glycol: 10 parts.
Described colored finish mortar 4 is formed by the mixed raw material of following weight portion is standby:
The colorful quartz sands of 40～120 mesh: 700 parts；
Pure-acrylic emulsion: 200 parts；
Coalescents: 6 parts；
Ethylene glycol: 2 parts；
Defoamer: 2 parts；
Anticorrosion and bactericidal agent: 1 part；
Viscosity is the ethoxyl methyl cellulose ether of 400000mPa s: 3 parts；
Color stuffing: 2 parts；
Deionized water: 56.7 parts；
Wherein, described coalescents is Lauryl Alcohol ester, and described defoamer is polyether polyol, and described anticorrosion and bactericidal agent is different thiophene
Oxazoline ketone preservative.
Described finishing coat 5 by anti-fouling and self-cleaning coating coating form, described anti-fouling and self-cleaning coating be particle diameter be that nano level organosilicon changes
Property acrylic coating, it is made up of following weight portion:
Deionized water: 620 parts；
Solid content is the silicone resin emulsion of 47%: 170 parts；
Anionic wetting agents: 3 parts；
Thickening agent: 18 parts；
Coalescents: 5 parts；
Dispersant: 4 parts；
Defoamer: 3 parts；
PH adjusting agent: 5 parts；
Antisepticize and mildew preventive: 6 parts；
Ethylene glycol: 8 parts；
Plasticizer: 3 parts；
Wherein, described thickening agent is cellulose ether, and described coalescents is Lauryl Alcohol ester, and described dispersant is PTPP (potassium tripolyphosphate),
Described defoamer is polyethers, and described Antisepticize and mildew preventive is that OBPA contains arsenic Organic substance antifungus agent, and described plasticizer is synthesis vegetable esters
Plasticiser.
The preparation method of a kind of described crystallite foam ceramic thermal insulation decoration composite plate, comprises the steps:
Step one, the preparation of heat-insulation layer 1:
Warming plate is crystallite foamed ceramic insulation board, crystallite foamed ceramics be processed into, by manufactured crystallite foamed ceramics
Cutting into thickness is 700mm, processed of polishing its surface and corner, it is ensured that upper surface is smooth, horizontal error ± 2mm,
Facade vertical error ± 2mm, external corner Founder error ± 3mm, remove plate surface attachment；In sheet material two sides cylinder and spraying
Method coating 3 times interfacial agents, it is ensured that without holiday, to improve the adhesive force of foam micro-crystalline ceramic sheet material outer surface；
Step 2, flexible facing cover the preparation of material: first flexible polymer cement mortar 7 be spread evenly across by mechanism scraper plate
Tire base 6 both sides being made up of the composite felt of polyester-cotton blend non-woven fabrics Yu glass fiber reticular cloth, form the flexible composite sheet material of wide 1.2 meters,
Carried out mechanical thermal blowing to dry, and standby after natural drying maintenance 28 days under the indoor temperature of 38 DEG C；
Use mechanism scraper plate or spraying technology that colored finish mortar 4 is evenly applied to described flexible composite sheet material 3 outer surface
Side, and make described colored finish mortar 4 film forming solidify by the method for mechanical thermal blowing drying and natural drying；Use rolling again
Anti-fouling and self-cleaning coating is coated in the outer surface of described colored finish mortar 4 by the method being coated with；Finally with cutting machine, sheet material is cut into
Consistent with the specification of described sheet material；
Step 3, the preparation of polymer-modified cement mortar binding agent: first each component in raw material is weighed one by one, then by stirring
Mix machine water by fully dispersed to hydroxypropyl methyl cellulose ether, re-dispersible glue powder and starch ether additive；Again cement is slowly fallen
Enter in blender and uniformly mix with described additive；Finally silica sand is gradually added in blender and unclassified stores moderate-speed mixer, directly
To slurry by the paste of mix uniformly thickness, discharging barrelling is standby；
Step 4, merging encapsulation: with polymer-modified cement mortar binding agent by soft with described for foam micro-crystalline ceramic warming plate end face
Property facing cover bottom material bonding compound, by the foam micro-crystalline ceramic heat-insulating decorative composite board that has been combined at roll-in and autoclave
Reason, makes described heat-insulation layer 1 and described decorative layer 2 close adhesion；
Step 5, maintenance cutting: by sheet material in the fog room of 50 DEG C of temperature after maintenance 14 days, material step 4 obtained is adopted
It is long for cutting into specification with machine: 2440mm；Wide: 1250mm.
Embodiment 3
As it is shown in figure 1, a kind of crystallite foam ceramic thermal insulation decoration composite plate, including heat-insulation layer 1 and employing flame retardant type binding agent 8
Being fixed on the decorative layer 2 on described heat-insulation layer 1, described heat-insulation layer 1 is crystallite foamed ceramic insulation board, and described decorative layer 2 is
Flexible facing covers material, and it includes flexible composite sheet material 3, colored finish mortar 4 and finishing coat 5 the most successively, wherein,
Described flame retardant type binding agent 8 is polymer-modified cement mortar binding agent.
Described crystallite foamed ceramic insulation board thickness is 300mm, and it is 25mm that described flexible facing covers material thickness, and described crystallite steeps
The specification of foam ceramic thermal insulation decoration composite plate is for long: 3200mm；Wide: 1500mm.
Being coated with interfacial agents in the both sides of described crystallite foamed ceramic insulation board, described interfacial agents is made up of the material of following weight portion:
Solid content is the BC-700 acrylic emulsion of 45～49%: 7 parts；
Solid content is the BC-200 acrylic emulsion of 45～47%: 12 parts；
Deionized water: 25 parts；
Ethylene glycol: 0.6 part；
Wollastonite in powder: 8 parts；
Kaolin: 9 parts；
Triple superphosphate: 12.5 parts；
Anionic wetting agents: 0.6 part；
Coalescents: 0.9 part；
Dispersant: 0.3 part；
Defoamer: 0.25 part；
PH adjusting agent: 0.7 part；
Antisepticize and mildew preventive: 0.7 part；
Plasticizer: 0.2 part；
Wherein, described coalescents is Lauryl Alcohol ester, and described dispersant is sodium polyphosphate, and described defoamer is polyether polyols
Alcohol, described Antisepticize and mildew preventive is that OBPA contains arsenic Organic substance antifungus agent, and described plasticizer is polyacrylic acid lipid plasticizer.
Described polymer-modified cement mortar binding agent is stirred by the material of following weight portion and forms:
52.5 cement: 330 parts；
The silica sand of 40～120 mesh: 520 parts；
The triple superphosphate of 200 mesh: 75 parts；
Viscosity is the hydroxypropyl methyl cellulose ether of 20,000-40,000mPa s: 2.5 parts；
Re-dispersible glue powder: 35 parts；
Wood fibre: 4 parts.
Described flexible composite sheet material 3 is composited by tire base 6 and the flexible polymer cement mortar 7 being coated on its both sides,
Described tire base 6 is the composite felt of polyester-cotton blend non-woven fabrics and glass fiber reticular cloth.
Described flexible polymer cement mortar 7 is made up of the material of following weight portion:
BC-200 acrylic emulsion: 60 parts；
BC-700 acrylic emulsion: 150 parts；
The silica sand of 80～120 mesh: 410 parts；
52.5 cement: 140 parts；
Viscosity is the hydroxypropyl methyl cellulose ether of 20,000-40,000mPa s: 30 parts；
Ethylene glycol: 10 parts.
Described colored finish mortar 4 is formed by the mixed raw material of following weight portion is standby:
The colorful quartz sands of 40～120 mesh: 700 parts；
Pure-acrylic emulsion: 200 parts；
Coalescents: 6 parts；
Ethylene glycol: 2 parts；
Defoamer: 2 parts；
Anticorrosion and bactericidal agent: 1 part；
Viscosity is the ethoxyl methyl cellulose ether of 400000mPa s: 3 parts；
Color stuffing: 2 parts；
Deionized water: 56.7 parts；
Wherein, described coalescents is Lauryl Alcohol ester, and described defoamer is polyether polyol, and described anticorrosion and bactericidal agent is different thiophene
Oxazoline ketone preservative.
Described finishing coat 5 by anti-fouling and self-cleaning coating coating form, described anti-fouling and self-cleaning coating be particle diameter be that nano level organosilicon changes
Property acrylic coating, it is made up of following weight portion:
Deionized water: 580 parts；
Solid content is the silicone resin emulsion of 47%: 260 parts；
Anionic wetting agents: 3 parts；
Thickening agent: 15 parts；
Coalescents: 8 parts；
Dispersant: 4 parts；
Defoamer: 3 parts；
PH adjusting agent: 4 parts；
Antisepticize and mildew preventive: 6 parts；
Ethylene glycol: 8 parts；
Plasticizer: 3 parts；
Wherein, described thickening agent is cellulose ether, and described coalescents is Lauryl Alcohol ester, and described dispersant is PTPP (potassium tripolyphosphate),
Described defoamer is polyethers, and described Antisepticize and mildew preventive is that OBPA contains arsenic Organic substance antifungus agent, and described plasticizer is synthesis vegetable esters
Plasticiser.
The preparation method of a kind of described crystallite foam ceramic thermal insulation decoration composite plate, comprises the steps:
Step one, the preparation of heat-insulation layer 1:
Warming plate is crystallite foamed ceramic insulation board, crystallite foamed ceramics be processed into, by manufactured crystallite foamed ceramics
Cutting into thickness is 300mm, processed of polishing its surface and corner, it is ensured that upper surface is smooth, horizontal error ± 2mm,
Facade vertical error ± 2mm, external corner Founder error ± 3mm, remove plate surface attachment；In sheet material two sides cylinder and spraying
Method coat twice interfacial agents, it is ensured that without holiday, to improve the adhesive force of foam micro-crystalline ceramic sheet material outer surface；
Step 2, flexible facing cover the preparation of material: first flexible polymer cement mortar 7 be spread evenly across by mechanism scraper plate
Tire base 6 both sides being made up of the composite felt of polyester-cotton blend non-woven fabrics Yu glass fiber reticular cloth, form the flexible composite sheet material of wide 1.2 meters,
Carried out mechanical thermal blowing to dry, and standby after natural drying maintenance 28 days under the indoor temperature of 20 DEG C；
Use mechanism scraper plate or spraying technology that colored finish mortar 4 is evenly applied to described flexible composite sheet material 3 outer surface
Side, and make described colored finish mortar 4 film forming solidify by the method for mechanical thermal blowing drying and natural drying；Use spray again
Anti-fouling and self-cleaning coating is coated in the outer surface of described colored finish mortar 4 by the method for painting or roller coating；Finally with cutting machine by sheet material
It is cut into consistent with the specification of described sheet material；
Step 3, the preparation of polymer-modified cement mortar binding agent: first each component in raw material is weighed one by one, then by stirring
Mix machine water by fully dispersed to hydroxypropyl methyl cellulose ether, re-dispersible glue powder and starch ether additive；Again cement is slowly fallen
Enter in blender and uniformly mix with described additive；Finally silica sand is gradually added in blender and unclassified stores moderate-speed mixer, directly
To slurry by the paste of mix uniformly thickness, discharging barrelling is standby；
Step 4, merging encapsulation: with polymer-modified cement mortar binding agent by soft with described for foam micro-crystalline ceramic warming plate end face
Property facing cover bottom material bonding compound, by the foam micro-crystalline ceramic heat-insulating decorative composite board that has been combined at roll-in and autoclave
Reason, makes described heat-insulation layer 1 and described decorative layer 2 close adhesion；
Step 5, maintenance cutting: after sheet material at room temperature maintenance 28 days, material step 4 obtained uses machine to cut into
Specification is for long: 3200mm；Wide: the heat insulating decorative board of 1500mm, obtain product.
Embodiment described above is only to be described the preferred embodiment of the present invention, not carries out the scope of the present invention
Limiting, on the premise of designing spirit without departing from the present invention, technical scheme is made by those of ordinary skill in the art
Various deformation and improvement, all should fall in the protection domain that claims of the present invention determines.
Claims (9)
1. a crystallite foam ceramic thermal insulation decoration composite plate, it is characterised in that: include heat-insulation layer (1) and use flame retardant type
Binding agent (8) is fixed on the decorative layer (2) on described heat-insulation layer (1), and described heat-insulation layer (1) is crystallite foamed ceramics
Warming plate, described decorative layer (2) covers material for flexible facing, its include the most successively flexible composite sheet material (3),
Colored finish mortar (4) and finishing coat (5), wherein, described flame retardant type binding agent (8) is polymer-modified cement mortar
Binding agent；
Being coated with interfacial agents in the both sides of described crystallite foamed ceramic insulation board, described interfacial agents is by the material group of following weight portion
Become:
Solid content is the BC-700 acrylic emulsion of 45～49%: 5～10 parts；
Solid content is the BC-200 acrylic emulsion of 45～47%: 10～15 parts；
Deionized water: 15～30 parts；
Ethylene glycol: 0.4～0.8 part；
Wollastonite in powder: 6～10 parts；
Kaolin: 8～10 parts；
Triple superphosphate: 10～14.8 parts；
Anionic wetting agents: 0.5～0.8 part；
Coalescents: 0.7～1 part；
Dispersant: 0.2～0.4 part；
Defoamer: 0.2～0.3 part；
PH adjusting agent: 0.6～0.8 part；
Antisepticize and mildew preventive: 0.5～0.8 part；
Plasticizer: 0.1～0.3 part；
Wherein, described coalescents is Lauryl Alcohol ester, and described dispersant is sodium polyphosphate, and described defoamer is that polyethers is many
Unit's alcohol, described Antisepticize and mildew preventive is that OBPA contains arsenic Organic substance antifungus agent, and described plasticizer is polyacrylic acid lipid plasticizer.
Crystallite foam ceramic thermal insulation decoration composite plate the most according to claim 1, it is characterised in that: described crystallite foam
Ceramic thermal insulation plate thickness is 50mm～700mm, and it is 15mm～30mm that described flexible facing covers material thickness.
Crystallite foam ceramic thermal insulation decoration composite plate the most according to claim 1, it is characterised in that: described crystallite foam
The specification of ceramic thermal insulation decoration composite plate is for long: 2000mm, 2440mm, 3000mm or 3200mm；Wide: 1220mm,
1250mm or 1500mm.
Crystallite foam ceramic thermal insulation decoration composite plate the most according to claim 1, it is characterised in that: described polymer changes
Property cement mortar binding agent by following weight portion material stir form:
52.5 cement: 300～350 parts；
The silica sand of 40～120 mesh: 500～550 parts；
The triple superphosphate of 200 mesh: 50～100 parts；
Viscosity is the hydroxypropyl methyl cellulose ether of 20,000-40,000mPa s: 2～3 parts；
Re-dispersible glue powder: 25～44 parts；
Wood fibre: 4 parts.
Crystallite foam ceramic thermal insulation decoration composite plate the most according to claim 1, it is characterised in that: described flexible compound
Material sheet (3) is composited by tire base (6) and the flexible polymer cement mortar (7) being coated on its both sides, described
Tire base (6) is the composite felt of polyester-cotton blend non-woven fabrics and glass fiber reticular cloth.
Crystallite foam ceramic thermal insulation decoration composite plate the most according to claim 5, it is characterised in that: described flexible polymer
Thing cement mortar (7) is made up of the material of following weight portion:
BC-200 acrylic emulsion: 60 parts；
BC-700 acrylic emulsion: 150 parts；
The silica sand of 80～120 mesh: 410 parts；
52.5 cement: 140 parts；
Viscosity is the hydroxypropyl methyl cellulose ether of 20,000-40,000mPa s: 30 parts；
Ethylene glycol: 10 parts.
Crystallite foam ceramic thermal insulation decoration composite plate the most according to claim 1, it is characterised in that: described colored finish
Mortar (4) is formed by the mixed raw material of following weight portion is standby:
The colorful quartz sands of 40～120 mesh: 700 parts；
Pure-acrylic emulsion: 200 parts；
Coalescents: 6 parts；
Ethylene glycol: 2 parts；
Defoamer: 2 parts；
Anticorrosion and bactericidal agent: 1 part；
Viscosity is the ethoxyl methyl cellulose ether of 400000mPa s: 3 parts；
Color stuffing: 2 parts；
Deionized water: 56.7 parts；
Wherein, described coalescents is Lauryl Alcohol ester, and described defoamer is polyether polyol, and described anticorrosion and bactericidal agent is different
Thiazolinone preservative.
Crystallite foam ceramic thermal insulation decoration composite plate the most according to claim 7, it is characterised in that: described finishing coat (5)
By anti-fouling and self-cleaning coating coating form, described anti-fouling and self-cleaning coating be particle diameter be nano level organosilicon-modified acrylic coating,
It is made up of following weight portion:
Deionized water: 500～620 parts；
Solid content is the silicone resin emulsion of 47%: 170～320 parts；
Anionic wetting agents: 3 parts；
Thickening agent: 10～18 parts；
Coalescents: 5～10 parts；
Dispersant: 4 parts；
Defoamer: 3 parts；
PH adjusting agent: 2～5 parts；
Antisepticize and mildew preventive: 6 parts；
Ethylene glycol: 8 parts；
Plasticizer: 3 parts；
Wherein, described thickening agent is cellulose ether, and described coalescents is Lauryl Alcohol ester, and described dispersant is tripolyphosphate
Potassium, described defoamer is polyethers, and described Antisepticize and mildew preventive is that OBPA contains arsenic Organic substance antifungus agent, and described plasticizer is synthesis
Vegetable esters plasticiser.
9. the preparation method of the crystallite foam ceramic thermal insulation decoration composite plate that any one is described, its feature in claim 5-8
It is: comprise the steps:
Step one, the preparation of heat-insulation layer (1):
Warming plate is crystallite foamed ceramic insulation board, crystallite foamed ceramics be processed into, and is made pottery by manufactured crystallite foam
Porcelain cuts into the sheet material that thickness is 50mm～700mm, processed of polishing its surface and corner, it is ensured that upper surface is smooth,
Horizontal error ± 2mm, facade vertical error ± 2mm, external corner Founder error ± 3mm, remove plate surface attachment；At plate
Method 2～3 times interfacial agents of coating of material two sides cylinder and spraying, it is ensured that without holiday, to improve outside foam micro-crystalline ceramic sheet material
The adhesive force on surface；
Step 2, flexible facing cover the preparation of material: first flexible polymer cement mortar (7) be uniformly coated with by mechanism scraper plate
It is distributed in tire base (6) both sides being made up of the composite felt of polyester-cotton blend non-woven fabrics Yu glass fiber reticular cloth, forms the flexible compound of wide 1.2 meters
Material sheet, is carried out mechanical thermal blowing and is dried, and natural drying maintenance standby in 28 days under the indoor temperature of 5～38 DEG C
With；
Use mechanism scraper plate or spraying technology that colored finish mortar (4) is evenly applied to described flexible composite sheet material (3)
Outer surface side, and make described colored finish mortar (4) film forming solid by the method for mechanical thermal blowing drying and natural drying
Change；Use the method for spraying or roller coating that anti-fouling and self-cleaning coating is coated in the outer surface of described colored finish mortar (4) again；
Finally sheet material is cut into consistent with the specification of described sheet material with cutting machine；
Step 3, the preparation of polymer-modified cement mortar binding agent: first each component in raw material is weighed one by one, then pass through
Blender water is by fully dispersed to hydroxypropyl methyl cellulose ether, re-dispersible glue powder and starch ether additive；Again cement is delayed
Slowly pour in blender and uniformly mix with described additive；Finally silica sand is gradually added in blender and stirs with unclassified stores middling speed
Mixing, until slurry is by the paste of mix uniformly thickness, discharging barrelling is standby；
Step 4, merging encapsulation: with polymer-modified cement mortar binding agent by foam micro-crystalline ceramic warming plate end face with described
Flexible facing covers bottom material bonding compound, by the foam micro-crystalline ceramic heat-insulating decorative composite board that has been combined through roll-in and high pressure
Still processes, and makes described heat-insulation layer (1) and described decorative layer (2) close adhesion；
Step 5, maintenance cutting: by sheet material at room temperature maintenance 28 days or in the fog room of 50 DEG C of temperature after maintenance 14 days,
Material step 4 obtained uses machine to cut into specification for long: 2000mm, 2440mm, 3000mm or 3200mm；
Wide: the heat insulating decorative board of 1220mm, 1250mm or 1500mm, obtain product.
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| CN112874069B (en) * | 2021-01-22 | 2022-09-30 | 山东电盾科技股份有限公司 | Preparation technology of energy-saving and decoration integrated ceramic plate and glass fiber sheet composite material |
| CN115262897A (en) * | 2022-08-03 | 2022-11-01 | 温州海螺孚瓯科技有限公司 | Stone paint simulated baking-free decorative material for building exterior wall |
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| JP4562299B2 (en) * | 2000-04-28 | 2010-10-13 | 株式会社エーアンドエーマテリアル | Ceramic-based decorative board and manufacturing method thereof |
| US7179546B1 (en) * | 2004-12-03 | 2007-02-20 | Vapor Technologies, Inc. | Decorative and protective coating |
| CN102174847B (en) * | 2011-01-22 | 2012-07-25 | 谭钦文 | Weatherable flexible tapestry brick and manufacturing method thereof |
| CN102584141A (en) * | 2012-02-06 | 2012-07-18 | 凯诺(青岛)化学建材有限公司 | Exterior wall facing mortar with inorganic characteristic and excellent crystalline bloom resistant performance |
| CN202925697U (en) * | 2012-08-01 | 2013-05-08 | 王志勇 | Composite insulation board |
| CN102786268A (en) * | 2012-08-14 | 2012-11-21 | 北京市建筑工程研究院有限责任公司 | Preparation method of polymer cement base sheet |
| CN203257027U (en) * | 2013-03-28 | 2013-10-30 | 刘德文 | Microcrystal foam ceramic composite brick |
| CN103410279B (en) * | 2013-08-22 | 2016-05-04 | 烟台斯坦普精工建设有限公司 | A kind of insulation photovoltaic tile and preparation method thereof |
| CN103410289B (en) * | 2013-08-22 | 2016-05-18 | 烟台斯坦普精工建设有限公司 | A kind of foam glass heat insulating photovoltaic decoration integrated board and preparation method thereof |
| CN203821745U (en) * | 2014-03-22 | 2014-09-10 | 烟台斯坦普精工建设有限公司 | Microcrystal foam ceramic thermal insulation decoration composite board |
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