CN103917488B - 具氧空缺的正极材料及其制法 - Google Patents

具氧空缺的正极材料及其制法 Download PDF

Info

Publication number
CN103917488B
CN103917488B CN201280054243.2A CN201280054243A CN103917488B CN 103917488 B CN103917488 B CN 103917488B CN 201280054243 A CN201280054243 A CN 201280054243A CN 103917488 B CN103917488 B CN 103917488B
Authority
CN
China
Prior art keywords
oxygen vacancies
positive electrode
lithium
phosphate
electrode material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201280054243.2A
Other languages
English (en)
Chinese (zh)
Other versions
CN103917488A (zh
Inventor
林翔斌
谢瀚纬
林元凯
赖明慧
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Advanced Lithium Electrochemistry Co Ltd
Original Assignee
Advanced Lithium Electrochemistry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Advanced Lithium Electrochemistry Co Ltd filed Critical Advanced Lithium Electrochemistry Co Ltd
Publication of CN103917488A publication Critical patent/CN103917488A/zh
Application granted granted Critical
Publication of CN103917488B publication Critical patent/CN103917488B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/45—Phosphates containing plural metal, or metal and ammonium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/51—Particles with a specific particle size distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/10—Solid density
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
CN201280054243.2A 2011-12-21 2012-12-21 具氧空缺的正极材料及其制法 Active CN103917488B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161578329P 2011-12-21 2011-12-21
US61/578,329 2011-12-21
PCT/CN2012/087171 WO2013091573A1 (zh) 2011-12-21 2012-12-21 具氧空缺的正极材料及其制法

Publications (2)

Publication Number Publication Date
CN103917488A CN103917488A (zh) 2014-07-09
CN103917488B true CN103917488B (zh) 2016-06-01

Family

ID=48667716

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201280054243.2A Active CN103917488B (zh) 2011-12-21 2012-12-21 具氧空缺的正极材料及其制法

Country Status (10)

Country Link
US (2) US9515320B2 (enExample)
EP (1) EP2796407B1 (enExample)
JP (1) JP6041893B2 (enExample)
KR (1) KR101646429B1 (enExample)
CN (1) CN103917488B (enExample)
CA (1) CA2860076C (enExample)
IN (1) IN2014MN01256A (enExample)
RU (1) RU2014124916A (enExample)
TW (1) TWI484689B (enExample)
WO (1) WO2013091573A1 (enExample)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MA38379B1 (fr) 2015-09-04 2017-12-29 Univ Mohammed V De Rabat Synthese d'un nouveau materiau : phosphite de titane ti2(hpo3)3
KR102042895B1 (ko) * 2017-08-29 2019-11-08 한양대학교 에리카산학협력단 금속 산화물 입자 및 탄소막을 포함하는 복합 소재, 그 제조 방법, 및 이를 포함하는 리튬 이차 전지
CN115312885A (zh) * 2022-02-25 2022-11-08 深圳市德方创域新能源科技有限公司 正极补锂添加剂及其制备方法和应用
TWI815629B (zh) * 2022-08-29 2023-09-11 台灣立凱電能科技股份有限公司 正極材料的製造方法及其製成的電池

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1691380A (zh) * 2004-04-23 2005-11-02 中国科学院物理研究所 一种用于二次锂电池的氮磷酸盐的正极材料及其用途
CN1797823A (zh) * 2004-12-21 2006-07-05 中国科学院物理研究所 用于二次锂电池的含氧空位的磷酸铁锂正极材料及其用途
CN1876565A (zh) * 2005-06-08 2006-12-13 立凯电能科技股份有限公司 具有橄榄石结构的LixMyPO4化合物的制备方法
EP1755183A1 (en) * 1996-04-23 2007-02-21 Board of Regents, The University of Texas System Cathode materials for secondary (rechargeable) lithium batteries

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8057769B2 (en) * 2000-04-27 2011-11-15 Valence Technology, Inc. Method for making phosphate-based electrode active materials
US7482097B2 (en) * 2002-04-03 2009-01-27 Valence Technology, Inc. Alkali-transition metal phosphates having a +3 valence non-transition element and related electrode active materials
US8617745B2 (en) * 2004-02-06 2013-12-31 A123 Systems Llc Lithium secondary cell with high charge and discharge rate capability and low impedance growth
CN101332987B (zh) * 2008-07-31 2011-05-04 福建师范大学 一种利用亚磷酸或亚磷酸盐制备磷酸亚铁锂正极材料的制备方法
TWI474970B (zh) * 2008-12-29 2015-03-01 Basf Se 於水熱條件下合成鋰－金屬－磷酸鹽
KR100939647B1 (ko) * 2009-01-22 2010-02-03 한화석유화학 주식회사 전극 활물질인 음이온 부족형 비화학양론 리튬 전이금속 다중산 화합물, 그 제조 방법 및 그를 이용한 전기화학 소자
KR20110139281A (ko) 2009-03-17 2011-12-28 바스프 에스이 열수 조건 하의 리튬-철-포스페이트의 합성 방법

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1755183A1 (en) * 1996-04-23 2007-02-21 Board of Regents, The University of Texas System Cathode materials for secondary (rechargeable) lithium batteries
CN1691380A (zh) * 2004-04-23 2005-11-02 中国科学院物理研究所 一种用于二次锂电池的氮磷酸盐的正极材料及其用途
CN1797823A (zh) * 2004-12-21 2006-07-05 中国科学院物理研究所 用于二次锂电池的含氧空位的磷酸铁锂正极材料及其用途
CN1876565A (zh) * 2005-06-08 2006-12-13 立凯电能科技股份有限公司 具有橄榄石结构的LixMyPO4化合物的制备方法

Also Published As

Publication number Publication date
US20160308211A1 (en) 2016-10-20
CA2860076C (en) 2016-10-04
CN103917488A (zh) 2014-07-09
KR20140110942A (ko) 2014-09-17
US9748571B2 (en) 2017-08-29
TWI484689B (zh) 2015-05-11
JP6041893B2 (ja) 2016-12-14
KR101646429B1 (ko) 2016-08-12
US9515320B2 (en) 2016-12-06
WO2013091573A1 (zh) 2013-06-27
EP2796407B1 (en) 2016-12-21
CA2860076A1 (en) 2013-06-27
TW201328003A (zh) 2013-07-01
RU2014124916A (ru) 2016-02-10
JP2015507323A (ja) 2015-03-05
IN2014MN01256A (enExample) 2015-07-03
EP2796407A4 (en) 2015-06-03
EP2796407A1 (en) 2014-10-29
US20150021517A1 (en) 2015-01-22

Similar Documents

Publication Publication Date Title
EP4506306A1 (en) Preparation method for lithium iron manganese phosphate, anode electrode material and lithium-ion battery
CN103299456B (zh) 锂离子电池用正极活性物质、锂离子电池用正极和锂离子电池
CN103066258A (zh) 一种高振实密度的钒氧化物与磷酸铁锂复合材料的制备方法
TW201221469A (en) Manufacturing method for lithium iron phosphate material and lithium iron phosphate powder produced thereby
JP6008024B2 (ja) オリビン型リチウム遷移金属酸化物の製造方法
CN103917488B (zh) 具氧空缺的正极材料及其制法
JP6261624B2 (ja) 改良されたセル性能を備えるオリビン組成物
Liu et al. Reproduction of Li battery LiNixMnyCo1− x− yO2 positive electrode material from the recycling of waste battery
CN102468489B (zh) 磷酸锂铁材料的制造方法及由其制得的磷酸锂铁粉末
KR101539408B1 (ko) 리튬 망간 보레이트계 화합물 및 망간 산화물을 포함하는 리튬이온 이차전지용 양극 활물질 및 이의 제조방법
Yahia et al. New fluorophosphate Li2− xNaxFe [PO4] F as cathode material for lithium ion battery
CN105932249A (zh) 一种锂离子电池用复合正极材料的制备方法
CN104393296B (zh) 一种锂离子电池复合正极材料及其制备方法
Ling et al. From Lab to Plant: Technical Barriers in Scaling Up LiMnyFe1‐yPO4 Production‐A Process Engineering Perspective
CN105870420B (zh) 一种锂离子动力电池用磷酸锰锂正极材料及其制备方法
CN102208619B (zh) 镁掺杂xLiFePO4·yLi3V2(PO4)3锂离子电池正极材料的制备方法
JP5830842B2 (ja) チタン酸リチウム粒子粉末の製造法及び非水電解質二次電池
CN107146877B (zh) 一种氟氧磷酸盐锂离子电池材料的制备方法及正极片与锂离子电池
Masquelier Synchrotron X-rays and neutrons as essential tools in Li battery research: Examples of oxide, phosphate and silicate-based positive electrodes
CN118062817A (zh) 一种高容量高压实磷酸锰铁锂复合磷酸钒锂材料的制备方法
CN120887401A (zh) 一种磷酸铁锂正极材料及其制备方法和应用
CN119637831A (zh) 聚阴离子型前驱体、钠离子电池正极材料及其制备方法、钠离子电池和涉电设备
CN119674038A (zh) 磷酸锰铁锂正极材料及其制备方法与应用
CN119750528A (zh) 一种镁钴改性磷酸亚锰铁前驱体材料及其制备方法和应用、碳包覆磷酸锰铁锂正极材料及应用
Zhang et al. Preparation and electrochemical performance of 2LiFe1–xCoxPO4–Li3V2 (PO4) 3/C cathode material for lithium-ion batteries

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C41 Transfer of patent application or patent right or utility model
TR01 Transfer of patent right

Effective date of registration: 20161031

Address after: Grand Cayman British Cayman Islands

Patentee after: British Gayman Islands Shanglikai Power Technology Co.,Ltd.

Address before: China Taiwan Taoyuan County

Patentee before: ADVANCED LITHIUM ELECTROCHEMISTRY Co.,Ltd.

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20220819

Address after: Taoyuan City, Taiwan, China

Patentee after: ADVANCED LITHIUM ELECTROCHEMISTRY Co.,Ltd.

Address before: Cayman Islands, Grand Cayman, UK

Patentee before: British Gayman Islands Shanglikai Power Technology Co.,Ltd.