CN103904160A - 一种基于CdZnTe薄膜的X射线探测器的制备方法 - Google Patents

一种基于CdZnTe薄膜的X射线探测器的制备方法 Download PDF

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CN103904160A
CN103904160A CN201410107249.2A CN201410107249A CN103904160A CN 103904160 A CN103904160 A CN 103904160A CN 201410107249 A CN201410107249 A CN 201410107249A CN 103904160 A CN103904160 A CN 103904160A
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王林军
陶骏
唐荣烨
秦凯丰
王君楠
黄健
唐可
沈忠文
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    • HELECTRICITY
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Abstract

本发明公开了一种应用于X射线探测的CdZnTe薄膜的制备方法。所述制备方法是基于近空间升华(CSS)技术。该方法以CdZnTe单晶切片为升华源,使用氩气作为工作气体,并通过一定的表面处理获得理想的整流电极接触。该方法具有工艺简单、成本更低、可重复性高等特点,可以制备应用于大面积、低漏电流、高分辨率的X射线探测器的薄膜,有望X射线薄膜探测器的产业化生产。

Description

一种基于CdZnTe薄膜的X射线探测器的制备方法
技术领域
本发明涉及一种基于CdZnTe薄膜的X射线探测器的制备方法,属于无机非金属材料制造工艺技术领域。
背景技术
CdZnTe是重要的                                                
Figure 2014101072492100002DEST_PATH_IMAGE001
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Figure 647244DEST_PATH_IMAGE002
族化合物半导体,由于其具有较高的平均原子序数和较大的禁带宽度,所以用这种材料制备的探测器具有较大的吸收系数、较高的能量分辨率,尤其不需任何的冷却设备就能在室温下工作。其优越的光电性能,可广泛应用于X射线等高能辐射探测、安全检测、医学成像以及空间研究。但由于CdZnTe固有的物性,熔体法生长的晶体存在成分不均匀性、晶界、孪晶、位错、夹杂相与沉淀相等许多缺陷,CdZnTe单晶材料不适合大面积平板探测器。为此,我们要寻找一种适合制备大面积CdZnTe薄膜、成本低的方法。
薄膜制备工艺相比单晶生长工艺简单,成本更低,批量生长可行性高,且基于薄膜的平面特性适合制备大面积的平板探测器。CdZnTe薄膜可由化学气相沉积等化学方法制备,也可通过热蒸发、磁控溅射、近空间升华法等物理气相沉积得到。在这些薄膜制备方法中,近空间升华法是最有前途的一种方法,这种方法成本低、速度快、质量好,适用于大面积沉积薄膜。目前,近空间升华法已用于CdTe薄膜的制备,但在CdZnTe薄膜的制备上较少。
采用近空间升华法制备的CdZnTe薄膜是多晶薄膜,可以通过改变制备的条件来获得表面平整,电阻率相对较高的CdZnTe薄膜。此外,在制备接触电极前,我们可以通过不同的表面处理工艺来制备肖特基(Schottky)接触电极,并获得有较小漏电流的X射线探测器,解决了一般X射线探测器漏电流大,电荷收集率低的问题。
发明内容
本发明的目的是采用近空间升华方法制备基于CdZnTe薄膜的X射线探测器,给制备高性能核辐射辐射探测器提供了新的方案。
为达到上述目的, 本发明是基于CdZnTe薄膜的X射线探测器的制备方法,其特征在于该方法包括如下过程和步骤:
A.    CdZnTe单晶升华源的准备:根据已知的先有技术,将高纯Cd、Zn、Te放入石英管中,在高真空下,采用移动加热法生长出质量好、成分分布相对均匀的CdZnTe单晶体,其中锌的摩尔含量为2~20%,将生长好的晶体切片作为升华源。
B.     衬底预处理:采用镀有透明导电层ITO玻璃或普通钠钙玻璃作为衬底,将衬底用去离子水、丙酮和乙醇分别超声清洗5~15分钟,洗去表面的杂质与有机物,烘干后放入近空间升华反应室内
C.     CdZnTe薄膜生长过程:开机械泵抽真空,将升华腔内气压抽至1Pa以下后关闭机械泵,通入氩气将气压调至10~100Pa,关闭气瓶;将升华源及衬底分别加热到500~650℃和400~550℃;生长30min~180min后开机械泵抽真空至气压为10Pa以下,关机械泵,待样品冷却至室温,取出CdZnTe薄膜样品,薄膜厚度50-500mm。
D.    CdZnTe薄膜退火及腐蚀:将样品在1Pa以下的真空升华腔中200~350°C退火20~60分钟;配制摩尔浓度为0.1~0.5%的溴甲醇溶液以及重铬酸钾和硫酸混合溶液,将退过火的样品依此浸入两种溶液腐蚀10~60s,腐蚀后的样品用去离子水清洗后用N2吹干。
E.     制备肖特基(Schottky)接触电极及后退火:采用离子溅射仪在样品表面沉积金电极,在样品表面放置孔洞直径为1mm的圆形电极掩膜版,溅射离子流为1~5mA,溅射时间10~30分钟;紧接着制备完电极后,再1Pa以下真空退火中200~350°C退火10~30分钟。
本发明是基于CdZnTe薄膜的X射线探测器,其特点在于,采用近空间升华方法制备的CdZnTe薄膜,制备出的薄膜具有较高的电阻率,较好的X射线能谱响应,薄膜的厚度为50~500mm,同现有技术相比,本发明具有如下显著优点:
近空间升华法(CSS)是一种实用性薄膜生长的工艺,已在CdTe薄膜制备上已经得到应用。近空间升华法CdZnTe薄膜制备工艺相比CdZnTe单晶生长工艺简单、成本更低、可大面积制备、批量生长可行性高。
制备接触电极前的表面处理,直接影响了金半接触的类型,本发明采用的表面处理工艺可以制得理想的肖特基(Schottky)整流电极接触,大幅减小了期间的漏电流,比常规的X射线探测器有更小的漏电流和更好的能谱响应。
附图说明
图1为本发明基于CdZnTe薄膜的X射线探测器的结构图。
具体实施方式
下面结合实施例对本发明进行详细说明:
实施例一   具体步骤如下:
A.CdZnTe单晶升华源的准备:根据已知的先有技术,将高纯Cd、Zn、Te放入石英管中,在高真空下,采用移动加热法生长出质量好、成分分布相对均匀的CdZnTe单晶体,其中锌的摩尔含量为4%,将生长好的晶体切片作为升华源。
B.衬底预处理:采用镀有透明导电层ITO的玻璃作为衬底,将衬底用去离子水、丙酮和乙醇分别超声清洗15分钟,洗去表面的杂质与有机物,烘干后放入近空间升华反应室内。
C.CdZnTe薄膜生长过程:开机械泵抽真空,将升华腔内气压抽至1Pa以下后关闭机械泵,通入氩气将气压调至12Pa,关闭气瓶;将升华源及衬底分别加热到650℃和500℃保持不变,生长30min后关闭加热源,开机械泵抽真空至气压为10Pa以下,关机械泵,待样品冷却至室温,取出样品。
D.CdZnTe薄膜退火及腐蚀:将样品在真空0.5Pa中250°C退火30min;配制摩尔浓度为0.1%的溴甲醇溶液以及0.2%的重铬酸钾和硫酸混合溶液,将退过火的样品浸入溶液腐蚀30s。
E.制备肖特基(Schottky)接触电极及后退火:在样品表面放置孔洞直径为1mm的圆形电极掩膜版,并放入溅射室,溅射离子流为1mA,溅射时间20分钟;紧接着在1Pa真空退火中200°C退火20分钟。获得厚度为200μm,40V时漏电流密度为15nA/cm2的X射线探测器。
实施例二
A.      CdZnTe单晶升华源的准备:根据已知的先有技术,将高纯Cd、Zn、Te放入石英管中,在高真空下,采用移动加热法生长出质量好、成分分布相对均匀的CdZnTe单晶体,其中锌的摩尔含量为4%,将生长好的晶体切片作为升华源;
B.       衬底预处理:采用普通钠钙玻璃玻璃作为衬底,将衬底用去离子水、丙酮和乙醇分别超声清洗15分钟,洗去表面的杂质与有机物,烘干后放入近空间升华反应室内;
C.       CdZnTe薄膜生长过程:开机械泵抽真空,将升华腔内气压抽至1Pa以下后关闭机械泵,通入氩气将气压调至25Pa,关闭气瓶;将升华源及衬底分别加热到650℃和500℃保持不变,生长60min后关闭加热源,开机械泵抽真空至气压为10Pa以下,关机械泵,待样品冷却至室温,取出样品;
D.      CdZnTe薄膜退火及腐蚀:将样品在真空0.4Pa中250°C退火25min;配制摩尔浓度为0.1%的溴甲醇溶液以及0.2%的重铬酸钾和硫酸混合溶液,将退过火的样品浸入溶液腐蚀40s;
E.       制备肖特基(Schottky)接触电极及后退火:在样品表面放置孔洞直径为1mm的圆形电极掩膜版,并放入溅射室,溅射离子流为1mA,溅射时间20分钟;紧接着在1Pa真空退火中250°C退火20分钟。获得厚度为400μm,40V时漏电流密度为18nA/cm2的X射线探测器。 

Claims (1)

1.一种基于CdZnTe薄膜的X射线探测器的制备方法,其特征在于该方法具有以下步骤:
A.    CdZnTe单晶升华源的准备:将高纯Cd、Zn、Te放入石英管中,在高真空下,采用移动加热法生长出质量好、成分分布相对均匀的CdZnTe单晶体,其中锌的摩尔含量为2~20%,将生长好的晶体切片作为升华源;
B.     衬底预处理:采用镀有透明导电层ITO玻璃或普通钠钙玻璃作为衬底,将衬底用去离子水、丙酮和乙醇分别超声清洗5~15分钟,洗去表面的杂质与有机物,烘干后放入近空间升华反应室内;
C.     CdZnTe薄膜生长过程:开机械泵抽真空,将升华腔内气压抽至1Pa以下后关闭机械泵,通入氩气将气压调至10~100Pa,关闭气瓶;将升华源及衬底分别加热到500~650℃和400~550℃;生长30min~180min后开机械泵抽真空至气压为10Pa以下,关机械泵,待样品冷却至室温,取出CdZnTe薄膜样品,薄膜厚度50-500mm;
D.    CdZnTe薄膜退火及腐蚀:将样品在1Pa以下的真空升华腔中200~350°C退火20~60分钟;配制摩尔浓度为0.1~0.5%的溴甲醇溶液以及重铬酸钾和硫酸混合溶液,将退过火的样品依此浸入两种溶液腐蚀10~60s,腐蚀后的样品用去离子水清洗后用N2吹干;
E.     制备肖特基(Schottky)接触电极及后退火:采用离子溅射仪在样品表面沉积金电极,在样品表面放置孔洞直径为1mm的圆形电极掩膜版,溅射离子流为1~5mA,溅射时间10~30分钟;紧接着制备完电极后,再1Pa以下真空退火中200~350°C退火10~30分钟。
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104952972A (zh) * 2015-04-14 2015-09-30 上海大学 自支撑CdZnTe薄膜的制备方法
CN105161565A (zh) * 2015-06-29 2015-12-16 上海大学 含有石墨烯过渡层的CdZnTe光电探测器及其制备方法
CN107170853A (zh) * 2017-05-08 2017-09-15 上海大学 一种复合结构的GaN/CdZnTe薄膜紫外光探测器的制备方法
CN110148627A (zh) * 2019-04-28 2019-08-20 上海大学 具有金属缓冲层的czt薄膜复合材料及其制备方法
CN112103350A (zh) * 2020-08-19 2020-12-18 上海大学 具有复合钝化层的czt膜复合材料、核辐射探测器件及其制备方法
CN113113508A (zh) * 2021-03-17 2021-07-13 西北工业大学 条形电极结构的电流型CdZnTe探测器及其制备方法

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CN103500776A (zh) * 2013-09-26 2014-01-08 上海大学 一种硅基CdZnTe薄膜紫外光探测器的制备方法

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104952972A (zh) * 2015-04-14 2015-09-30 上海大学 自支撑CdZnTe薄膜的制备方法
CN105161565A (zh) * 2015-06-29 2015-12-16 上海大学 含有石墨烯过渡层的CdZnTe光电探测器及其制备方法
CN107170853A (zh) * 2017-05-08 2017-09-15 上海大学 一种复合结构的GaN/CdZnTe薄膜紫外光探测器的制备方法
CN107170853B (zh) * 2017-05-08 2019-02-22 上海大学 一种复合结构的GaN/CdZnTe薄膜紫外光探测器的制备方法
CN110148627A (zh) * 2019-04-28 2019-08-20 上海大学 具有金属缓冲层的czt薄膜复合材料及其制备方法
CN112103350A (zh) * 2020-08-19 2020-12-18 上海大学 具有复合钝化层的czt膜复合材料、核辐射探测器件及其制备方法
CN113113508A (zh) * 2021-03-17 2021-07-13 西北工业大学 条形电极结构的电流型CdZnTe探测器及其制备方法

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