CN103889229B - 农园艺用杀菌剂组合物 - Google Patents

农园艺用杀菌剂组合物 Download PDF

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CN103889229B
CN103889229B CN201280045920.4A CN201280045920A CN103889229B CN 103889229 B CN103889229 B CN 103889229B CN 201280045920 A CN201280045920 A CN 201280045920A CN 103889229 B CN103889229 B CN 103889229B
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agent
compound
formula
group
methyl
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CN103889229A (zh
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桑原赖人
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Nippon Soda Co Ltd
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Nippon Soda Co Ltd
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    • A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals

Abstract

本发明提供一种农园艺用杀菌剂组合物，其含有化合物A和化合物B，上述化合物A是选自含式（1）表示的化合物的特定结构的含氮杂环化合物及其盐中的至少一种，上述化合物B是选自特定的农药活性化合物中的至少一种。｛式（1）中，X各自独立地表示卤代基或者C1～6烷基。n表示X的个数，是0～6中的任一整数。X’表示卤代基。R1、R2和R3各自独立地表示C1～6烷基或者羟基。｝

Description

农园艺用杀菌剂组合物
技术领域
本发明涉及农园艺用杀菌剂组合物。更详细而言，本发明涉及用低药量就能对植物病害显示优异的防除效果、且不用担心对有用植物产生药害的农园艺用杀菌剂组合物。
本申请基于2011年9月26日在日本申请的特愿2011-209969号要求优先权，在此引用其内容。
背景技术
以往，栽培农园艺作物时，针对作物的病害使用大量的防除药剂。然而，其防除效力不充分，或者因耐药性病原菌的出现而导致其使用受限，另外，由于对植物体产生药害、污染，或者对人畜鱼类等的毒性强，所以难以称之为令人满意的防除药剂并不少。因此，迫切期望开发一种上述缺点少的能安全使用的杀菌剂组合物。例如，在专利文献1和2中记载了含氮杂环化合物和/或其盐可用作杀菌剂组合物的有效成分。
现有技术文献
专利文献
专利文献1：WO2010/018686号小册子
专利文献2：WO2011/081174号小册子
发明内容
本发明的课题在于提供用低药量能就对植物病害显示优异的防除效果且不用担心对有用植物产生药害的农园艺用杀菌剂组合物。
本发明人为了解决上述课题，对专利文献1和2中记载的以含氮杂环化合物和/或其盐为有效成分的杀菌剂组合物进一步进行了深入研究。其结果发现通过将上述含氮杂环化合物和/或其盐与特定的农药活性化合物并用，用低药量就能对植物病害显示优异的防除效果且不用担心对有用植物产生药害。本发明是基于该见解进一步反复研究而完成的。
即，本发明如下。
〔1〕一种农园艺用杀菌剂组合物，其特征在于，含有选自式(1)表示的含氮杂环化合物、式(2)表示的含氮杂环化合物及它们的盐中的至少一种和选自下述化合物中的至少一种化合物，即，SBI剂、苯并咪唑类剂、酸酰胺类杀菌剂、二羧基酰亚胺类杀菌剂、苯基吡咯类杀菌剂、有机(硫代)磷酸酯类剂、胍类杀菌剂、线粒体电子传递链复合体II抑制剂、线粒体电子传递链复合体III抑制剂、苯胺基嘧啶类剂、新烟碱类剂、SH抑制剂、环氟菌胺、霜脲氰、丙氧喹啉、苯菌酮、喹氧灵、哒菌清、稻瘟灵、乙嘧酚磺酸酯、噻螨酮、虫酰肼、硫双威、多杀菌素、醚菊酯、氟虫腈、乙虫腈、吡蚜酮、噻嗪酮、溴虫腈、式(3)表示的化合物、式(4)表示的化合物以及它们的盐。
{式(1)中，X各自独立地表示卤代基或者C1～6烷基。n表示X的个数，是0～6中的任一整数。X’表示卤代基。R1、R2和R3各自独立地表示C1～6烷基或者羟基。}
{式(2)中，X各自独立地表示卤代基或者C1～6烷基。n表示X的个数，是0～6中的任一整数。X’表示卤代基。R4、R5、R6以及R7各自独立地表示氢原子，C1～6烷基或者羟基。}
{式(3)中，W表示C1～6烷基、C1～6烷氧基、卤素原子、硝基、氰基、C6～10芳基、或者C1～6烷基磺酰基。Y表示C1～6烷基。m表示W的个数，是0～5中的任一整数。Z表示氢原子、氨基、或者由式：-NHC(＝O)-Q表示的基团(式中，Q表示氢原子、C1～8烷基、C1～6卤代烷基、C3～6环烷基、C1～8烷氧基、C3～6环烷基氧基、C7～20芳烷基氧基、C1～4烷基硫基C1～8烷基、C1～4烷氧基C1～2烷基、C1～4酰基氨基C1～6烷基、C1～4酰基氨基C1～6烷氧基、C1～8烷基氨基、C2～6链烯基、芳烷基或苯基)。R表示卤素原子。n表示R的个数，是0～3中的任一整数。}
{式(4)中，Y表示O或者由NR1表示的基团(式中，R1表示氢原子或者甲基)。Z表示由CR2R3或者NR2表示的基团(式中，R2和R3独立地表示氢原子或者甲基)。R表示羟基、卤素原子、C1～4烷基、C1～4卤代烷基、C1～4烷氧基、或者C1～4卤代烷氧基。m表示R的个数，是0～3中的任一整数。R’和R”独立地表示氢原子、羟基、卤素原子、C1～4烷基、C1～4卤代烷基、C1～4烷氧基、或者C1～4卤代烷氧基。R”’表示羟基、卤素原子、C1～4烷基、C1～4卤代烷基、C1～4烷氧基、或者C1～4卤代烷氧基。n表示R”’的个数，是0～4中的任一整数。另外＝Y和R’可以一起表示由＝N-O-表示的基团，R’和R”可以一起表示C2～3亚烷基。}
〔2〕根据〔1〕所述的农园艺用杀菌剂组合物，其特征在于，上述SBI剂是选自氟菌唑、苯醚甲环唑以及戊唑醇中的1种以上。
〔3〕根据〔1〕或〔2〕所述的农园艺用杀菌剂组合物，其特征在于，上述苯并咪唑类剂是甲基硫菌。
〔4〕根据〔1〕～〔3〕中任一项所述的农园艺用杀菌剂组合物，其特征在于，上述酸酰胺类杀菌剂是选自甲霜灵、苯噻菌胺、氟吡菌胺、氟吡菌酰胺、苯酰菌胺、氟酰胺、萎锈灵、噻呋酰胺以及啶酰菌胺中的1种以上。
〔5〕根据〔1〕～〔4〕中任一项所述的农园艺用杀菌剂组合物，其特征在于，上述二羧基酰亚胺类杀菌剂是异菌脲。
〔6〕根据〔1〕～〔5〕中任一项所述的农园艺用杀菌剂组合物，其特征在于，上述苯基吡咯类杀菌剂是咯菌腈。
〔7〕根据〔1〕～〔6〕中任一项所述的农园艺用杀菌剂组合物，其特征在于，上述有机(硫代)磷酸酯类剂是选自式(5)表示的化合物中的1种以上。
{式(5)中，R1和R2表示甲基或者乙基。Ar表示苯基或者6元杂芳环基。R3表示卤素原子或者甲基。n表示R3的个数，是0～5中的任一整数。}
〔8〕根据〔1〕～〔7〕中任一项所述的农园艺用杀菌剂组合物，其特征在于，上述有机(硫代)磷酸酯类剂是选自三乙膦酸、甲基立枯磷以及氯吡硫磷中的1种以上。
〔9〕根据〔1〕～〔8〕中任一项所述的农园艺用杀菌剂组合物，其特征在于，上述胍类杀菌剂是双胍辛胺。
〔10〕根据〔1〕～〔9〕中任一项所述的农园艺用杀菌剂组合物，其特征在于，上述线粒体电子传递链复合体II抑制剂是由酰苯胺类杀菌剂构成的1种以上。
〔11〕根据〔1〕～〔10〕中任一项所述的农园艺用杀菌剂组合物，其特征在于，上述线粒体电子传递链复合体III抑制剂是选自QoI剂、QiI剂以及唑嘧菌胺中的1种以上。
〔12〕根据〔11〕所述的农园艺用杀菌剂组合物，其特征在于，上述QoI剂是选自肟菌酯、嘧菌酯、醚菌酯、肟醚菌胺、唑菌酮以及吡菌苯威中的1种以上。
〔13〕根据〔11〕或〔12〕所述的农园艺用杀菌剂组合物，其特征在于，上述QiI剂是氰霜唑。
〔14〕根据〔1〕～〔13〕中任一项所述的农园艺用杀菌剂组合物，其特征在于，上述苯胺基嘧啶类剂是嘧菌环胺。
〔15〕根据〔1〕～〔14〕中任一项所述的农园艺用杀菌剂组合物，其特征在于，上述新烟碱类剂是选自式(6)表示的化合物中的1种以上。
{式(6)中，A表示N或者CH。B表示甲基或者由-NR21R22表示的基团(R21表示氢原子或者甲基。R22表示甲基或者与R3一起形成5～6元环)。R1表示氰基或者硝基。R2表示无取代或者具有取代基的5～6元杂环基。R3表示氢原子、甲基、乙基或者与R22一起形成5～6元环。}
〔16〕根据〔1〕～〔15〕中任一项所述的农园艺用杀菌剂组合物，其特征在于，上述新烟碱类剂是选自啶虫脒、吡虫啉、噻虫嗪、噻虫胺以及呋虫胺中的1种以上。
〔17〕根据〔1〕～〔16〕中任一项所述的农园艺用杀菌剂组合物，其特征在于，上述SH抑制剂是选自代森锰锌、福美双、百菌清、克菌丹、灭菌丹以及氟啶胺中的1种以上。
〔18〕根据〔1〕～〔17〕中任一项所述的农园艺用杀菌剂组合物，其中，上述式(3)表示的化合物是式(7)表示的化合物。
〔19〕根据〔1〕～〔18〕中任一项所述的农园艺用杀菌剂组合物，其中，上述式(4)表示的化合物是式(8)或式(9)表示的化合物。
本发明的农园艺用杀菌剂组合物用极低药量就能对植物病害显示优异的防除效果且不用担心对有用植物产生药害。
具体实施方式
本发明的农园艺用杀菌剂组合物含有选自特定结构的含氮杂环化合物及其盐中的至少一种(以下，有时记为化合物A)和选自特定的农药活性化合物中的至少一种(以下，有时记为化合物B)。本发明的农园艺用杀菌剂组合物起到由仅使用化合物A或者仅使用化合物B所取得的植物病害防除效果无法预测的显著的协同的植物病害防除效果。
(化合物A)
化合物A是选自上述式(1)表示的含氮杂环化合物、上述式(2)表示的含氮杂环化合物以及它们的盐中的至少一种。
式(1)或者式(2)中的X各自独立地表示卤代基或者C1～6烷基。n表示X的个数，是0～6中的任一整数。
作为X中的C1～6烷基，可举出甲基、乙基、正丙基、异丙基、正丁基、仲丁基、异丁基、叔丁基、正戊基、正己基等。在不阻碍本发明效果的范围内，C1～6烷基中的一部分或者全部氢原子可以被其他基团取代。作为该取代基，可举出卤代基、羟基等。
作为X中的卤代基，可举出氟基、氯基、溴基、碘基。
式(1)或者式(2)中的X’表示卤代基。X’中的卤代基是与X中的卤代基相同的意思。
式(1)中的R1、R2和R3各自独立地表示C1～6烷基或者羟基。R1、R2和R3中的C1～6烷基是与X中的烷基相同的意思。
式(2)中的R4、R5、R6以及R7各自独立地表示氢原子、C1～6烷基或者羟基。R4、R5、R6以及R7中的C1～6烷基是与X中的烷基相同的意思。
作为式(1)或者式(2)表示的含氮杂环化合物的盐，只要是农园艺学上允许的盐，就没有特别限制。例如，可举出盐酸盐、硝酸盐、硫酸盐、磷酸盐等无机酸的盐；乙酸盐、乳酸盐、丙酸盐、苯甲酸盐等有机酸的盐等。
本发明中使用的式(1)表示的含氮杂环化合物是公知物质，作为具体例，可举出WO2011/081174号小册子中记载的化合物等。另外，式(1)表示的含氮杂环化合物及其盐可以利用公知的方法制造。作为具体的制造方法，可举出WO2011/081174号小册子中记载的方法等。
本发明中使用的式(2)表示的含氮杂环化合物是公知物质，作为具体例，可举出WO2010/018686号小册子中记载的化合物等。另外，式(2)表示的含氮杂环化合物及其盐可以利用公知的方法制造。作为具体的制造方法，可举出WO2010/018686号小册子中记载的方法等。
(化合物B)
化合物B是选自下述化合物中的至少一种化合物，即，SBI剂、苯并咪唑类剂、酸酰胺类杀菌剂、二羧基酰亚胺类杀菌剂、苯基吡咯类杀菌剂、有机(硫代)磷酸酯类剂、胍类杀菌剂、线粒体电子传递链复合体II抑制剂、线粒体电子传递链复合体III抑制剂、苯胺基嘧啶类剂、新烟碱类剂、SH抑制剂、环氟菌胺、霜脲氰、丙氧喹啉、苯菌酮、喹氧灵、哒菌清、稻瘟灵、乙嘧酚磺酸酯、噻螨酮、虫酰肼、硫双威、多杀菌素、醚菊酯、氟虫腈、乙虫腈、吡蚜酮、噻嗪酮、溴虫腈、式(10)表示的化合物、式(11)表示的化合物以及它们的盐。
{式(10)中，W表示C1～6烷基、C1～6烷氧基、卤素原子、硝基、氰基、C6～10芳基、或者C1～6烷基磺酰基。Y表示C1～6烷基。m表示W的个数，是0～5中的任一整数。Z表示氢原子、氨基、或者由式：-NHC(＝O)-Q表示的基团(式中，Q表示氢原子、C1～8烷基、C1～6卤代烷基、C3～6环烷基、C1～8烷氧基、C3～6环烷基氧基、C7～20芳烷基氧基、C1～4烷基硫基C1～8烷基、C1～4烷氧基C1～2烷基、C1～4酰基氨基C1～6烷基、C1～4酰基氨基C1～6烷氧基、C1～8烷基氨基、C2～6链烯基、芳烷基或苯基)。R表示卤素原子。n表示R的个数，是0～3中的任一整数。}
{式(11)中，Y表示O或者由NR1表示的基团(式中，R1表示氢原子或者甲基)。Z表示由CR2R3或者NR2(式中，R2和R3独立地表示氢原子或者甲基)表示的基团。R表示羟基、卤素原子、C1～4烷基、C1～4卤代烷基、C1～4烷氧基、或者C1～4卤代烷氧基。m表示R的个数，是0～3中的任一整数。R’和R”独立地表示氢原子、羟基、卤素原子、C1～4烷基、C1～4卤代烷基、C1～4烷氧基、或者C1～4卤代烷氧基。R”’表示羟基、卤素原子、C1～4烷基、C1～4卤代烷基、C1～4烷氧基、或者C1～4卤代烷氧基。n表示R”’的个数，是0～4中的任一整数。另外＝Y和R’可以一起表示由＝N-O-表示的基团，R’和R”可以一起表示C2～3亚烷基。}
式(11)表示的化合物优选是式(12)表示的化合物。
{式(12)中，Y、Z、R’、R”、R”’以及n表示与式(11)中记载的Y、Z、R’、R”、R”’以及n相同的意思。}
应予说明，化合物B中也包含其光学活性化合物。例如，像与甲霜灵相对的精甲霜灵一样。化合物B包含公知物质，这些物质可以通过公知的制造方法或者由商业购买而得到。
本发明中所说的SBI剂(甾醇生物合成抑制剂)是抑制麦角甾醇生物合成的化合物群。作为优选的SBI剂的例子，可例示氟菌唑、苯醚甲环唑、戊唑醇、糠菌唑、环唑醇、腈苯唑、氟硅唑、粉唑醇、己唑醇、丙环唑、氟醚唑、三唑酮、三唑醇、氟菌唑、双苯三唑醇、亚胺唑、烯唑醇、烯唑醇-M、氟环唑、氟喹唑、咪鲜胺、叶菌唑、种菌唑、腈菌唑、戊菌唑、氯苯嘧啶醇、稻瘟酯、啶斑肟、嗪氨灵、苄氯三唑醇、克霉唑、抑霉唑、抑霉唑·硫酸盐、硅氟唑、灭菌唑、乙环唑、氟苯嘧啶醇、戊环唑、氟康唑、咪唑、丁硫啶、丙硫菌唑、萘替芬、烯效唑P、烯效唑、伏立康唑、丁苯吗啉、苯锈啶、十三吗啉、十二环吗啉、十二吗啉、苯锈啶、粉病灵、螺环菌胺、环酰菌胺、稗草丹以及特比萘芬等。
作为SBI剂中包含的代表性的化合物群，有作为细胞色素P450的一种的与14α去甲基化酶(CYP51)结合而抑制甾醇C14位的去甲基化的DMI剂(去甲基化酶抑制剂)。作为优选的DMI剂的例子，可例示氟菌唑、苯醚甲环唑、戊唑醇、糠菌唑、环唑醇、腈苯唑、氟硅唑、粉唑醇、己唑醇、丙环唑、氟醚唑、三唑酮、三唑醇、氟菌唑、双苯三唑醇、亚胺唑、烯唑醇、烯唑醇-M、氟环唑、氟喹唑、咪鲜胺、叶菌唑、种菌唑、腈菌唑、戊菌唑、氯苯嘧啶醇、稻瘟酯、啶斑肟、嗪氨灵、苄氯三唑醇、克霉唑、抑霉唑、抑霉唑·硫酸盐、硅氟唑、灭菌唑、乙环唑、氟苯嘧啶醇、戊环唑、氟康唑、咪唑、丁硫啶、丙硫菌唑、萘替芬、烯效唑P、烯效唑以及伏立康唑等。
其中作为特别优选的化合物，可例示氟菌唑、苯醚甲环唑以及戊唑醇。
本发明中所说的苯并咪唑类剂是指具有苯并咪唑骨架并与构成微管的微管蛋白结合而抑制核分裂的化合物群，以及作为它们的前体、可变成具有苯并咪唑骨架的形态而发挥相同的抑制效果的化合物群。作为优选的苯并咪唑类剂，可例示苯菌灵、多菌灵、麦穗宁、氯苯咪唑(Chlorfenazole)和噻菌灵等，以及作为前体的硫菌灵和甲基硫菌灵等。
作为其中特别优选的化合物，可例示甲基硫菌灵。
本发明中所说的酸酰胺类杀菌剂是指以羧酸酰胺结构为特征且具有杀菌效果的化合物群。作为优选的酸酰胺类杀菌剂的例子，可例示氟吡菌酰胺、氟酰胺、萎锈灵、氧化萎锈灵、噻呋酰胺、啶酰菌胺、吡噻菌胺、灭锈胺、呋吡菌胺、异非他米多(isofetamid)、氟唑菌苯胺、甲霜灵、苯噻菌胺、氟吡菌胺、苯酰菌胺、戊菌隆、噻酰菌胺、氯菌胺、烯酰吗啉、氟吗啉、丙森锌、双炔酰菌胺、霜霉灭等。
作为酸酰胺类杀菌剂中包含的代表性的化合物群，有被称为酰苯胺类杀菌剂的化合物群。其通常以具有式(13)的结构作为特征。
{式(13)中，Cy1和Cy2独立地表示无取代的或具有取代基的苯基、或者无取代的或具有取代基的5～6元杂环基，R表示单键、亚甲基或亚乙基。}
另外，本发明中所说的线粒体电子传递链复合体II抑制剂是指具有与线粒体的电子传递链复合体II(琥珀酸脱氢酶复合体)结合而抑制呼吸的性质的化合物群。
作为线粒体电子传递链复合体II抑制剂中包含的代表性的化合物群，有上述的酰苯胺类杀菌剂。
作为优选的酰苯胺类杀菌剂的例子，可例示氟吡菌酰胺、氟酰胺、萎锈灵、氧化萎锈灵、噻呋酰胺、啶酰菌胺、吡噻菌胺、灭锈胺、呋吡菌胺、异非他米多(isofetamid)、氟唑菌苯胺、麦锈灵、甲呋酌苯胺(fenfuran)、联苯吡菌胺、吡唑萘菌胺(Isopyrazam)、氟唑菌酰胺(Fluxapyroxad)以及环苯吡菌胺(sedaxane)等。
在作为酸酰胺类杀菌剂或线粒体电子传递链复合体II抑制剂例示的化合物群中，作为特别优选的化合物，可例示氟吡菌酰胺、氟酰胺、萎锈灵、噻呋酰胺、啶酰菌胺、甲霜灵、苯噻菌胺、氟吡菌胺以及苯酰菌胺。
本发明中所说的二羧基酰亚胺类杀菌剂是具有由二羧基酰亚胺结构构成的5元环的化合物群，以菌类中涉及渗透压控制的信号转导系统蛋白OS-1为靶。作为优选的二羧基酰亚胺类杀菌剂的例子，可例示异菌脲、腐霉利、乙烯菌核利、乙菌利以及唑呋草等。
作为其中特别优选的化合物，可例示异菌脲。
本发明中所说的苯基吡咯类杀菌剂是具有3-苯基吡咯结构的化合物群，以菌类中涉及渗透压控制的信号转导系统蛋白OS-2为靶。作为优选的苯基吡咯类杀菌剂的例子，可例示咯菌腈和拌种咯等。
作为其中特别优选的化合物，可例示咯菌腈。
本发明中所说的有机(硫代)磷酸酯类剂是具有磷酸酯结构或者硫代磷酸酯结构的化合物群，包括有机(硫代)磷酸酯类杀菌剂和有机(硫代)磷酸酯类杀虫剂。作为有机(硫代)磷酸酯类杀菌剂，可例示EDDP、IBP、甲基立枯磷、三乙膦酸以及吡菌磷等。作为有机(硫代)磷酸酯类杀虫剂，可例示DDVP、硫线磷、马拉硫磷、乐果、蚜灭多、伏杀硫磷、吡唑硫磷、谷硫磷、乙基谷硫磷、吡菌磷、吡氟硫磷、氯吡硫磷、甲基氯吡硫磷、乙基氯吡硫磷、二嗪农、杀扑磷、氯甲硫磷、杀螟硫磷、倍硫磷、对硫磷、甲基对硫磷、乙酰甲胺磷、甲基吡啶磷、乙基溴硫磷、溴苯烯磷、BRP、毒虫畏、三硫磷、氯氧磷、氯甲磷、蝇毒磷、苯腈磷、杀螟腈、CYAP、敌敌畏、百治磷、乙拌磷、甲基内吸磷、甲基毒虫畏、甲基内吸磷砜、氯亚磷、二嗪磷、水胺硫磷、水杨硫磷、乙拌磷、乙硫磷、丙线磷、乙嘧硫磷、EPN、苯线磷、丰索磷、地虫硫磷、安果、甲基异柳磷、庚烯磷、氯唑磷、碘硫磷、异柳磷、唑磷、异稻瘟净、马拉硫磷、速灭磷、甲胺磷、久效磷、灭蚜磷、杀灭磷、二溴磷、氧化乐果、亚砜吸磷、对氧磷、稻丰散、亚胺硫磷、磷胺、甲拌磷、辛硫磷、甲基嘧啶磷、乙基嘧啶磷、丙溴磷、丙硫磷、噻唑磷、磷虫威、丙虫磷、异丙氧磷、发果、哒嗪硫磷、喹硫磷、蔬果磷、甲丙硫磷、治螟磷、杀虫威、特丁硫磷、三唑磷、敌百虫、丁基嘧啶磷、双硫磷、甲基乙拌磷等。
其中优选的化合物是式(14)表示的化合物。
{式(14)中，R1和R2表示甲基或者乙基。Ar表示苯基或者6元杂芳环基。R3表示卤素原子或者甲基。n表示R3的个数，是0～5中的任一整数。}
作为有机(硫代)磷酸酯类剂中更优选的化合物，可例示三乙膦酸、甲基立枯磷以及氯吡硫磷。
本发明中所说的胍类杀菌剂是指具有胍部分结构的化合物群。作为优选的胍类杀菌剂，可例示双胍辛胺乙酸盐(iminoctadine acetate)、双胍辛胺烷苯磺酸盐(iminoctadine albesilate)、多果定以及双胍盐等。
本发明中所说的线粒体电子传递链复合体III抑制剂是指具有与线粒体电子传递链的复合体III(bc1复合体)结合而抑制呼吸的性质的化合物群，用于杀菌剂、杀螨剂等用途。它们根据在复合体III中的结合部位而被分成Qo部位抑制剂(QoI剂)、Qi部位抑制剂(QiI剂)以及其他化合物。
作为QoI剂的代表性的化合物群，可举出嗜球果伞素(Strobilurin)类剂，其他还可举出唑菌酮、吡菌苯威等。作为QiI剂，可举出氰霜唑、吲唑磺菌胺、咪唑菌酮、拌种胺等，特别优选氰霜唑。作为其他的化合物，可举出唑嘧菌胺、二甲叔丁氟乙酰喹啉(Tebufloquin)等，特别优选唑嘧菌胺。
嗜球果伞素类剂是指具有3-甲氧基丙烯酸酯(甲氧基丙烯酸酯类)、N-甲氧基氨基甲酸酯(甲氧基氨基甲酸酯类)、甲氧基亚氨基乙酸酯(甲氧基亚氨基乙酸酯类)、2-甲氧基亚氨基乙酰胺(甲氧基亚氨基乙酰胺类)等部分结构，与呼吸链复合体III的Qo部位结合而抑制呼吸的化合物群。作为嗜球果伞素类剂，可例示甲氧基丙烯酸酯类的嘧菌酯、啶氧菌酯、吡唑醚菌酯、烯肟菌酯、菌螨酯(fenoxystrobin)；甲氧基氨基甲酸酯类的吡唑醚菌酯、唑胺菌酯、氯啶菌酯；甲氧基亚氨基乙酸酯类的醚菌酯、肟菌酯；甲氧基亚氨基乙酰胺类的肟醚菌胺、苯氧菌胺(metominostrobin)、苯氧菌胺(metominofen)、醚菌胺；其他还有氟嘧菌酯等。
作为嗜球果伞素类剂优选的化合物是式(15)表示的化合物。
{式(15)中，A表示CH或者N。B表示O或者NH。Ar-R-表示由Ar-O-、Ar-CH2-、Ar-CH2O-、Ar-OCH2-、Ar-C(CH3)＝NOCH2-中任一个表示的基团，Ar表示无取代或具有取代基的苯基或者无取代或具有取代基的6元杂芳环基。}
作为嗜球果伞素类剂中更优选的化合物，可例示肟菌酯、醚菌酯、嘧菌酯以及肟醚菌胺。
本发明中所说的苯胺基嘧啶类剂是具有2-苯基氨基嘧啶骨架且具有蛋氨酸生物合成抑制和细胞壁分解酶的分泌抑制作用的杀菌剂。作为优选的苯胺基嘧啶类剂的例子，可例示安朵普灵(andoprim)、嘧菌环胺、嘧菌胺以及嘧霉胺等。其中特别优选嘧菌环胺。
本发明中所说的新烟碱类剂是作为烟碱性乙酰胆碱受体的阻断剂发挥功能的杀虫剂。作为新烟碱类剂，可例示啶虫脒、吡虫啉、噻虫嗪、噻虫胺、呋虫胺、烯啶虫胺以及噻虫啉等。作为新烟碱类剂优选的化合物是式(16)表示的化合物。
{式(16)中，A表示N或者CH。B表示甲基或者由-NR21R22表示的基团(R21表示氢原子或者甲基。R22表示甲基或者与R3一起形成5～6元环)。R1表示氰基或者硝基。R2表示无取代或者具有取代基的5～6元杂环基。R3表示氢原子、甲基、乙基或者与R22一起形成5～6元环。}
作为其中特别优选的化合物，可例示啶虫脒、吡虫啉、噻虫嗪、噻虫胺以及呋虫胺。
本发明中所说的SH抑制剂是指以主要抑制具有SH基的呼吸系统的酶、具有抑制胞子萌发活性且不具有治疗活性为特征的保护杀菌剂。作为优选的SH抑制剂的例子，可例示无机铜、有机铜、代森锌、代森锰、代森锰锌、福美锌、代森福美锌、福美双、百菌清、氟啶胺、克菌丹、敌菌丹、灭菌丹、溴甲烷、棉隆、啶菌腈、敌菌灵、苯氟磺胺、二氯萘醌、氟酰亚胺以及二氰蒽醌等。
作为其中特别优选的化合物，可例示代森锰锌、福美双、百菌清、氟啶胺、克菌丹以及灭菌丹。
上述式(10)表示的化合物没有特别限定，特别优选式(17)表示的化合物。
上述式(12)表示的化合物没有特别限定，特别优选式(18)或式(19)表示的化合物。
应予说明，以上记载的“无取代的”和“具有取代基的”的意思如下。
“无取代的”用语意味着仅是成为母核的基团。没有记载“具有取代基的”而仅用成为母核的基团的名称记载时，在没有特殊说明的情况下，就是“无取代的”意思。
另一方面，“具有取代基的”用语意味着成为母核的基团的任一氢原子被与母核同种或不同种的结构的基团取代。因此，“取代基”是与成为母核的基团键合的其他基团。取代基可以为1个，也可以为2个以上。2个以上的取代基可以相同，也可以不同。
“C1～6”等用语表示成为母核的基团的碳原子数为1～6个等。该碳原子数不包括在取代基中的碳原子的个数。例如，具有乙氧基作为取代基的丁基分类为C2烷氧基C4烷基。
“取代基”只要是化学上允许并具有本发明的效果，就没有特别限定。
作为可成为“取代基”的基团，可举出氟基、氯基、溴基、碘基等卤代基；甲基、乙基、正丙基、异丙基、正丁基、仲丁基、异丁基、叔丁基、正戊基、正己基等C1～6烷基；环丙基、环丁基、环戊基、环己基等C3～6环烷基；乙烯基、1-丙烯基、2-丙烯基、1-丁烯基、2-丁烯基、3-丁烯基、1-甲基-2-丙烯基、2-甲基-2-丙烯基、1-戊烯基、2-戊烯基、3-戊烯基、4-戊烯基、1-甲基-2-丁烯基、2-甲基-2-丁烯基、1-己烯基、2-己烯基、3-己烯基、4-己烯基、5-己烯基等C2～6链烯基；2-环丙烯基、2-环戊烯基、3-环己烯基等C3～6环烯基；乙炔基、1-丙炔基、2-丙炔基、1-丁炔基、2-丁炔基、3-丁炔基、1-甲基-2-丙炔基、2-甲基-3-丁炔基、1-戊炔基、2-戊炔基、3-戊炔基、4-戊炔基、1-甲基-2-丁炔基、2-甲基-3-戊炔基、1-己炔基、1,1-二甲基-2-丁炔基等C2～6炔基；
甲氧基、乙氧基、正丙氧基、异丙氧基、正丁氧基、仲丁氧基、异丁氧基、叔丁氧基等C1～6烷氧基；乙烯基氧基、烯丙基氧基、丙烯基氧基、丁烯基氧基等C2～6链烯基氧基；乙炔基氧基、炔丙基氧基等C2～6炔基氧基；苯基、萘基等C6～10芳基；苯氧基、1-萘氧基等C6～10芳氧基；苄基、苯乙基等C7～11芳烷基；苄氧基、苯乙基氧基等C7～11芳烷基氧基；甲酰基、乙酰基、丙酰基、苯甲酰基、环己基羰基等C1～7酰基；甲酰氧基、乙酰氧基、丙酰氧基、苯甲酰氧基、环己基羰基氧基等C1～7酰氧基；甲氧基羰基、乙氧基羰基、正丙氧基羰基、异丙氧基羰基、正丁氧基羰基、叔丁氧基羰基等C1～6烷氧基羰基；羧基；
羟基；氧代基；氯甲基、氯乙基、三氟甲基、1,2-二氯正丙基、1-氟正丁基、全氟正戊基等C1～6卤代烷基；2-氯-1-丙烯基、2-氟-1-丁烯基等C2～6卤代链烯基；4,4-二氯-1-丁炔基、4-氟-1-戊炔基、5-溴-2-戊炔基等C2～6卤代炔基；2-氯正丙氧基、2,3-二氯丁氧基等C1～6卤代烷氧基；2-氯丙烯基氧基、3-溴丁烯基氧基等C2～6卤代链烯基氧基；4-氯苯基、4-氟苯基、2,4-二氯苯基等C6～10卤代芳基；4-氟苯氧基、4-氯-1-萘氧基等C6～10卤代芳氧基；氯乙酰基、三氟乙酰基、三氯乙酰基、4-氯苯甲酰基等卤素取代C1～7卤代酰基；
氰基；异氰基；硝基；异氰氧基；氰氧基；叠氮基；氨基；甲氨基、二甲氨基、二乙氨基等C1～6烷基氨基；苯胺基、萘基氨基等C6～10芳基氨基；苄基氨基、苯基乙基氨基等C7～11芳烷基氨基；甲酰基氨基、乙酰基氨基、丙酰基氨基、丁酰基氨基、异丙基羰基氨基、苯甲酰基氨基等C1～7酰基氨基；甲氧基羰基氨基、乙氧基羰基氨基、正丙氧基羰基氨基、异丙氧基羰基氨基等C1～6烷氧基羰基氨基；氨基甲酰基；二甲基氨基甲酰基、苯基氨基甲酰基、N-苯基-N-甲基氨基甲酰基等取代氨基甲酰基；亚氨基甲基、(1-亚氨基)乙基、(1-亚氨基)正丙基等亚氨基C1～6烷基；羟基亚氨基甲基、(1-羟基亚氨基)乙基、(1-羟基亚氨基)丙基等羟基亚氨基C1～6烷基；甲氧基亚氨基甲基、(1-甲氧基亚氨基)乙基等C1～6烷氧基亚氨基C1～6烷基；
巯基；异硫氰酸基；硫氰酸基；甲硫基、乙硫基、正丙硫基、异丙硫基、正丁硫基、异丁硫基、仲丁硫基、叔丁硫基等C1～6烷基硫基；乙烯基硫基、烯丙基硫基等C2～6链烯基硫基；乙炔基硫基、炔丙基硫基等C2～6炔基硫基；苯基硫基、萘基硫基等C6～10芳基硫基；噻唑基硫基、吡啶基硫基等杂芳基硫基；苄基硫基、苯乙基硫基等C7～11芳烷基硫基；(甲硫基)羰基、(乙硫基)羰基、(正丙硫基)羰基、(异丙硫基)羰基、(正丁硫基)羰基、(异丁硫基)羰基、(仲丁硫基)羰基、(叔丁硫基)羰基等(C1～6烷基硫基)羰基；
甲基亚磺酰基、乙基亚磺酰基、叔丁基亚磺酰基等C1～6烷基亚磺酰基；烯丙基亚磺酰基等C2～6链烯基亚磺酰基；炔丙基亚磺酰基等C2～6炔基亚磺酰基；苯基亚磺酰基等C6～10芳基亚磺酰基；噻唑基亚磺酰基、吡啶基亚磺酰基等杂芳基亚磺酰基；苄基亚磺酰基、苯乙基亚磺酰基等C7～11芳烷基亚磺酰基；甲基磺酰基、乙基磺酰基、叔丁基磺酰基等C1～6烷基磺酰基；烯丙基磺酰基等C2～6链烯基磺酰基；炔丙基磺酰基等C2～6炔基磺酰基；苯基磺酰基等C6～10芳基磺酰基；噻唑基磺酰基、吡啶基磺酰基等杂芳基磺酰基；苄基磺酰基、苯乙基磺酰基等C7～11芳烷基磺酰基；
吡咯基、呋喃基、噻嗯基、咪唑基、吡唑基、唑基、异唑基、噻唑基、异噻唑基、三唑基、二唑基、噻二唑基、四唑基等5元杂芳基；吡啶基、吡嗪基、嘧啶基、哒嗪基、三嗪基等6元杂芳基；氮丙啶基、环氧基、吡咯烷基、四氢呋喃基、哌啶基、哌嗪基、吗啉基等饱和杂环基；三甲基甲硅烷基、三乙基甲硅烷基、叔丁基二甲基甲硅烷基等三C1～6烷基甲硅烷基；三苯基甲硅烷基等。
另外，这些“取代基”可以在其中进一步具有其他的“取代基”。例如，可以是在作为取代基的丁基上具有乙氧基作为其他的取代基的基团，即乙氧基丁基这样的基团。
在本发明的农园艺用杀菌剂组合物中，化合物A和化合物B的重量比以(化合物A):(化合物B)计，通常为1:10000000～10000000:1，优选为1:1000000～1000000:1，更优选为1:100000～100000:1，特别优选为1:10000～10000:1。
本发明的农园艺用杀菌剂组合物除含有上述的化合物A和化合物B以外，有时通过混合使用公知的杀虫剂、杀螨剂、除草剂、植物成长调节剂等，能够带来省力等效果。
作为本发明的杀菌剂组合物的制造方法，例如，有(a)包括将化合物A和化合物B分别制成制剂，再混合这些制剂的步骤的方法；(b)包括将化合物A制成制剂，再向该制剂中混合化合物B的步骤的方法；(c)包括将化合物B制成制剂，再向该制剂中混合化合物A的步骤的方法；(d)包括将化合物A和化合物B混合，根据需要将该混合物制成制剂的步骤的方法等。
在不对本发明的效果造成影响的范围内，本发明的杀菌剂组合物中可以含有肥料、固体载体、增粘剂、表面活性剂、铺展剂、添加剂、溶剂等。
作为肥料，可举出堆肥、油渣、鱼粉、牛粪、鸡粪等或者将它们加工而成的有机材料；硫酸铵、硝酸铵、硝酸钙、尿素等氮肥；过磷酸钙、磷酸氢二铵、熔融磷肥等磷酸肥；氯化钾、硫酸钾、硝酸钾等钾肥；苦土石灰等镁肥；消石灰等钙肥；硅酸钾等硅酸肥；硼酸盐等硼肥；含有各种无机肥而成的复合肥料等。
作为固体载体，可举出大豆粒、小麦粉等植物性粉末；二氧化硅、硅藻土、磷灰石、石膏、滑石、膨润土、叶蜡石、粘土、过筛腐殖质砂粘土等矿物性微粉末等。
作为添加剂，可举出苯甲酸钠、尿素、芒硝等有机和无机化合物等；菜籽油、大豆油、葵花籽油、蓖麻油、松(pine)油、棉籽油、以及这些油的衍生物、这些油的浓缩物等。
作为溶剂，可举出煤油、二甲苯；溶剂石脑油等石油馏分；环己烷、环己酮、二甲基甲酰胺、二甲基亚砜、醇、丙酮、甲基异丁基酮、矿物油、植物油、水等。
作为表面活性剂，例如，可以举出加成了聚氧乙烯的烷基苯基醚、加成了聚氧乙烯的烷基醚、加成了聚氧乙烯的高级脂肪酸酯、加成了聚氧乙烯的山梨糖醇酐高级脂肪酸酯、加成了聚氧乙烯的三苯乙烯基苯基醚等非离子性表面活性剂、加成了聚氧乙烯的烷基苯基醚的硫酸酯盐、烷基苯磺酸盐、高级醇的硫酸酯盐、烷基萘磺酸盐、多羧酸盐、木质素磺酸盐、烷基萘磺酸盐的甲醛缩合物、异丁烯-马来酸酐共聚物等。
只要不降低本发明的效果，本发明的农园艺用杀菌剂组合物中还可以进一步混合其他的杀菌剂、杀虫·杀螨剂、增效剂中的1种或者2种以上。
以下示出可混合使用的其他的杀菌剂、杀虫剂、杀螨剂、植物生长调节剂的代表例。
杀菌剂：
苯基酰胺类：苯霜灵、精苯霜灵、柯罗泽尔昆(clozylacon)、呋霜灵、霜灵、呋酰胺；
羟基-(2-氨基)嘧啶类：二甲嘧酚、乙嘧酚；
N-苯基氨基甲酸酯类：乙霉威；
AH杀菌剂(芳香族烃)类：联苯、氯苯甲醚、氯硝胺、五氯硝基苯、四氯硝基苯；
MBI-R类：四氯苯酞、咯喹酮、三环唑；
MBI-D类：环丙酰菌胺、双氯氰菌胺、氰菌胺；
烯醇吡喃糖醛酸类：杀稻瘟菌素、米多霉素；
己吡喃糖基类：春雷霉素、春雷霉素盐酸盐；
吡喃葡萄糖基类：链霉素、井冈霉素、井冈霉素A；
氨基甲酸酯类：碘代丙炔基正丁氨基甲酸酯(Iodocarb)、霜霉威、硫菌威、代森福美锌；
脱共轭剂：乐杀螨、消螨普、嘧菌腙、敌螨普；
有机锡化合物：三苯基乙酸锡、三苯基氯化锡、三苯基氢氧化锡；
磷酸酯：亚磷酸；
酞氨酸类：叶枯酞；
苯并三嗪类：咪唑嗪(triazoxide)；
苯磺胺类：磺菌胺；
四环素：土霉素；
硫代氨基甲酸酯类：磺菌威；
抗性诱导剂：阿拉酸式苯-S-甲基、烯丙苯噻唑、噻酰菌胺、异噻菌胺；
其他的化合物：土菌灵、多抗霉素、多氧霉素、喹酸、羟基异唑、辛噻酮、硅噻菌胺、二氟林、噻唑菌胺、苯菌酮、福美铁、代森联、丙森锌、代森锌、福美锌、二氰蒽醌、氯化苦、棉隆、灭螨猛、酯菌胺、农杆菌、唑呋草；异非他米多(isofetamid)、托普罗卡布(tolprocarb)、胺苯吡菌酮(fenpyrazamine)、甲氧苯唳菌(pyriofenone)、异丁乙氧喹啉(tebufloquin)；丙烷脒、克瘟散；苯噻硫氰(Benthiazole)、贝斯氧杂嗪(bethoxazin)、卡巴西霉素(capsimycin)、香芹酮、硫杂灵(cufraneb)、环丙磺酰胺、咪菌威(debacarb)、双氯酚、野燕枯、野燕枯硫酸二甲酯、二苯胺、氟联苯菌、氟酰亚胺、氟噻菌净(flutianil)、人间霉素(irumamycin)、异硫氰酸甲酯(MITC)、米多霉素、纳他霉素、酞菌酯(Nitrotalisopropyl)、奥克斯莫卡宾(oxamocarb)、氧代奋欣(oxyfenthiin)、霜霉威乙膦酸盐、丙醇菌素钠(propanosin-sodium)、丁吡吗啉(pyrimorph)、硝吡咯菌素、甲磺菌胺(Tolnifanide)、水杨菌胺；
杀虫·杀螨剂、杀线虫剂、杀土壤害虫剂、驱虫剂：
氨基甲酸酯类：棉铃威、涕灭威、虫威、丙硫克百威、西维因、呋喃丹、丁硫克百威、苯氧威、苯硫威、灭虫威、灭多威、杀线威、抗蚜威、残杀威、灭多威、唑蚜威、乙硫苯威、仲丁威、MIPC、MPMC、MTMC、呋线威、XMC、砜灭威、除害威、灭害威、合杀威、畜虫威、丁叉威、氧丁叉威、除线威、敌蝇威、伐虫脒、异丙威、威百亩钠、速灭威、猛杀威、久效威、混杀威、灭杀威；
拟除虫菊酯类：槟榔碱、联苯菊酯、氟氯氰菊酯、β-氟氯氰菊酯、氯氟氰菊酯、λ-氯氟氰菊酯、苯氰菊酯、氯氰菊酯、α-氯氰菊酯、β-氯氰菊酯、Z-氯氰菊酯、溴氰菊酯、氰戊菊酯、甲氰菊酯、氰戊菊酯、炔咪菊酯、氯菊酯、炔丙菊酯、除虫菊酯、除虫菊酯I、除虫菊酯II、苄呋菊酯、氟硅菊酯、氟胺氰菊酯、七氟菊酯、胺菊酯、四溴菊酯、四氟菊酯、丙氟菊酯、四氟甲醚菊酯、氟丙菊酯、乙氰菊酯、苄螨醚、氟氰戊菊酯、烯丙菊酯、苄呋烯菊酯(bioethanomethrin)、生物氯菊酯、生物苄呋菊酯、顺式氯菊酯、烯炔菊酯、五氟苯菊醋、氯氰吡菊酯、溴氟菊酯、三氟醚菊酯、氟氯苯菊酯、甲氧苄氟菊酯、苯醚菊酯、丙苯烃菊酯、反灭虫菊、环戊烯丙菊酯；
成长调节物质：
(a)壳多糖合成抑制剂：氟啶脲、除虫脲、氟环脲、氟虫脲、氟铃脲、虱螨脲、双苯氟脲、伏虫隆、杀铃脲、双三氟虫脲、多氟脲，乙螨唑，四螨嗪，吡虫隆，氟幼脲；
(b)蜕皮激素拮抗剂：氯虫酰肼、甲氧虫酰肼、环虫酰肼、印楝素；
(c)保幼激素类似物：吡丙醚、烯虫酯、苯虫醚、保幼醚、烯虫乙酯、烯虫炔酯、烯虫硫酯；
(d)脂质生物合成抑制剂：螺螨酯、螺甲螨酯、螺虫乙酯、氟啶虫酰胺；
烟碱受体激动剂/拮抗剂化合物：烟碱、杀虫磺、杀螟丹、4-[(6-氯-3-吡啶基甲基)(2,2-二氟乙基)氨基]呋喃-2(5H)-酮(flupyradifurone)；
GABA拮抗剂化合物：
(a)乙酰虫腈、氟吡唑虫、嘧咬威、吡咬醇；
(b)有机氯类；毒杀芬、氯丹、硫丹、HCH、γ-HCH、七氯、甲氧滴滴涕；
大环状内酯杀虫剂：除虫菌素、甲氨基阿维菌素苯甲酸盐、密比霉素、雷皮菌素，伊维菌素、赛拉菌素、多拉霉素、爱普瑞菌素、莫西霉素、米尔贝霉素、米尔贝霉素肟；
METI I化合物：喹螨醚、哒螨灵、吡螨胺、唑虫酰胺、嘧虫胺、伏蚁腙、唑螨酯、嘧螨醚、三氯杀螨醇；
METI II和III化合物：灭螨醌、嘧螨酯、鱼藤酮；
脱共轭剂化合物：乐杀螨、消螨通、消螨普、DNOC；
氧化磷酸化抑制剂化合物：三环锡、丁醚脲、苯丁锡、克螨特、三唑锡；
蜕皮干扰化合物：灭蝇胺；
混合功能氧化酶抑制剂化合物：增效醚；
钠通道阻断剂化合物：茚虫威、氰氟虫腙；
微生物农药：BT剂、昆虫病原病毒剂、昆虫病原丝状菌剂、线虫病原丝状菌剂；芽孢杆菌属、白僵菌、黑僵菌、拟青霉属、苏云金素、黄萎病菌属；
蜘蛛毒素亲和蛋白(latrophilin)受体激动剂：缩酚酸肽(depsipeptide)、环状缩酚酸肽、24元环状缩酚酸肽、艾莫德赛(emodepside)；
章鱼胺能激动剂：双甲脒；
兰尼碱受体激动剂：氟虫酰胺、氯虫苯甲酰胺、氰虫酰胺；
镁刺激性ATP酶的抑制剂：杀虫环、杀虫双、沙蚕毒素；
螨生长抑制剂：四螨嗪、乙螨唑；
其他的化合物：异噻虫唑(benclothiaz)、联苯肼酯、啶虫丙醚、硫、腈吡螨酯、丁氟螨酯、磺胺螨酯、三氯杀螨、杀虫脒、1,3-二氯丙烯、DCIP、溴螨酯(Phenisobromolate)、苯螨特(Benzomate)、四聚乙醛、多虫菌素、氟虫吡喹(pyrifluquinazon)、苯螨特(Benzoximate)、溴螨酯(Bromopropylate)、灭螨猛、乙酯杀螨醇、氯化苦、氯噻苯、环虫腈、分萨克林(fenoxacrim)、氟硝二苯胺、氟螨噻、氟奋乃静、诱虫十六酯、(R,Z)-5-(1-癸烯)二氢呋喃-2(3H)-酮(Japonilure)、虫酮、石油、油酸钾、氟虫胺、杀螨硫醚、苯螨噻；阿非多皮罗奋(afidopyropen)、皮福鲁不米多(pyflubumide)、氟麦托醌(Flometoquin)、丁虫腈(flufiprole)、氟噻虫砜(fluensulfone)、氯氟醚菊酯、四氟醚菊酯、氟啶虫胺腈、新烟磷(imicyafos)、溴代吡咯腈、氟螨嗪、四氟甲醚菊酯、甲基新癸酰胺(Methylneodecanamide)；
驱虫剂：
(a)苯并咪唑类：芬苯达唑、阿苯达唑、三氯苯达唑、奥苯达唑；
(b)水杨酰胺类：氯氰碘柳胺、五氯柳胺；
(c)取代酚类：硝碘酚腈；
(d)嘧啶类：噻嘧啶；
(e)咪唑并噻唑类：左旋咪唑；
(f)四氢嘧啶：吡喹酮；
(g)其它的驱虫药：环二烯、鱼尼丁、克洛素隆、甲硝唑、得米地曲(demiditraz)；
植物生长调节剂：
脱落酸、吲哚丁酸、烯效唑、吲唑酯、乙烯利、座果酸、矮壮素、小球藻提取液、过氧化钙、氰胺、2,4-滴丙酸、赤霉素、丁酰肼、癸醇、抗倒酯、甲哌啶、多效唑、石蜡、增效醚、吡草醚、呋嘧醇、茉莉酸丙酯、调环酸钙盐、苄氨基嘌呤、二甲戊乐灵、氯吡苯脲、马来酰肼钾、1-萘乙酰胺、4-CPA、MCPB、胆碱、硫酸羟喹啉、吲唑酯、丁乐灵、1-甲基环丙烯、四烯雌酮盐酸盐。
通过化合物A、化合物B或者它们的混合物的制剂化而得到的剂型没有特别限制，可以采用通常的农园艺用农药能够采取的形态，例如，粉剂、可湿性粉剂、可溶性粉剂、乳剂、流动剂(flowable agent)、颗粒剂、粒剂等形态。
经制剂化的本发明的杀菌剂组合物中的有效成分浓度(化合物A和化合物B的总计浓度)没有特别限定，可根据上述制剂的形态采用各种浓度。例如，可湿性粉剂中，通常为5～90重量％，优选为10～85重量％；乳剂中，通常为3～70重量％，优选为5～60重量％；粒剂中，通常为0.01～50重量％，优选为0.05～40重量％。
经制剂化的本发明的杀菌剂组合物可以直接或者用水稀释成规定的浓度以溶解液、悬浮液或乳浊液的形式散布于植物，或者通过灌注、混合或散布于土壤中来使用。将本发明的杀菌剂组合物用于田地时，通常每1公顷施用有效成分(按化合物A和化合物B的总量计)0.1g以上的适当量。
作为本发明的杀菌剂组合物的处理对象的有用植物，可举出谷物类、蔬菜类、根菜类、薯类、树木类、牧草类、草坪类等。在此，也可以将这些植物类的各部位作为对象进行处理。作为植物类的各部位，可举出叶、茎、柄、花、蕾、果实、种子、芽、根、块茎、块根、苗、插枝等。另外，也可以将这些植物类的改良品种·变种、栽培品种、以及突变体、杂交体、转基因体(GMO)作为对象进行处理。
以下举出有用植物类的一个例子。
(1)锦葵科(Malvaceae)的植物，例如，咖啡黄葵(Abelmoschus esculentus)、棉花(Gossypium hirsutum)；
(2)梧桐科(Sterculiaceae)的植物，例如，可可树(Theobroma cacao)；
(3)藜科(Chenopodiaceae)的植物，例如，甜菜(Beta vulgaris)、红菾菜(瑞士甜菜)(Beta vulgaris var.cicla L.)、菠菜(Spinacia oleracea)；
(4)茜草科(Rubiaceae)的植物，例如，咖啡(Coffea spp)；
(5)大麻科(Cannabaceae)的植物，例如，蛇麻(Humulus lupulus)
(6)十字花科(Cruciferae)的植物，例如，小松菜(Brassica cempestris)、芥菜(Brassica juncea)、高菜(Brassica juncea var.integrifolia)、欧洲油菜(Brassicanapus)、花椰菜(Brassica oleracea var.botrytis)、甘蓝(Brassica oleraceavar.capitata)、西兰花(Brassica oleracea var.italica)、芜菁(Brassica rapa)、小白菜(Brassica rapa var.chinensis)、大白菜(Brassica rapa var.glabra)、野沢菜(Brassica rapa var.hakabura)、日本芜菁(Brassica rapa var.lancinifolia)、荠菜(Capsella bursa-pastoris)、西洋菜(Nasturtium spp.)、萝卜(Raphanus sativus)、芥末(Wasabia japonica)；
(7)亚麻科(Linaceae)的植物，例如，亚麻(Linaceae usitatissimum)；
(8)禾本科(Gramineae)的植物，例如，燕麦(Avena sativa)、薏苡(Coix lacryma-jobi var.ma-yuen)、鸭茅(Dactylis glomerata)、大麦(Hordeum vulgare)、水稻(Oryzasativa)、梯牧草(TPhleum pratense)、甘蔗(Saccharum officinarum)、黑麦(Secalecereale)、小米(Setaria italica)、小麦(Triticum aestivum)、玉米(Zea meys)、中国结缕草(Zoysia spp.)；
(9)葫芦科(Cucurbitaceae)的植物，例如，冬瓜(Benincasa hispida)、西瓜(Citrulus lanatus)、西洋南瓜(Cucurbita maxima)、东洋南瓜(Cucurbita moschata)、西葫芦(夏南瓜)(Cucurbita pepo)、葫芦(Lagenaria siceraria)、丝瓜(Luffacylindrica)；
(10)漆树科(Anacardiaceae)的植物，例如，腰果树(Anacardium)、杧果(Mangifera)；
(11)柿树科(Ebenaceae)的植物，例如，柿树(Diospyros kaki)；
(12)桦木科(Betulaceae)的植物，例如，欧洲榛(Corylus avellana)；
(13)菊科(Compositae)的植物，例如，蒿草(Artemisia indicavar.maximowiczii)、牛蒡(Arctium lappa L.)、菊苣(Cichorium intybus)、洋蓟(Cynarascolymus)、茼蒿(Glebionis coronaria)、向日葵(Helianthus annuus)、莴苣(Lactucasativa)；
(14)天门冬科(Asparagaceae)的植物，例如，芦笋(Asparagus officinalis L.)；
(15)桑科(Moraceae)的植物，例如，无花果(Ficus carica L.)；
(16)胡桃科(Juglandaceae)的植物，例如，黑胡桃(Juglans spp.)；
(17)胡麻科(Pedaliaceae)的植物，例如，芝麻(Sesamum indicum)；
(18)胡椒科(Piperaceae)的植物，例如，胡椒(Piper nigrum)；
(19)天南星科(Araceae)的植物，例如，魔芋(Amorphophallus rivierivar.konjac)、芋(Colocasia esculenta)；
(20)唇形科(Lamiaceae)的植物，例如，薄荷(mint)(Mentha spp.)、罗勒(Ocimumbasilicum)、紫苏(Perilla frutescens var.crispa)、鼠尾草(Salvia officinalis)；
(21)姜科(Zingiberaceae)的植物，例如，姜黄(Curcuma longa)、山姜(Hedychiumspp.)、野姜(Zingiber mioga)；
(22)伞形科(Umbelliferae)的植物，例如，芹菜(Apium graveolens L.)、胡萝卜(Daucus carota var.sativa)、水芹(Oenanthe javanica)、紫萁(Osmunda japonicaThunb)、香芹(Petroselium crispum)；
(23)茶藨子科(Grossulariaceae)的植物，例如，醋栗(鹅莓)(Ribes uva-crispa)；
(24)蓼科(Polygonaceae)的植物，例如，荞麦(Fagopyrum esculentum)；
(25)杜鹃花科(Ericaceae)的植物，例如，蓝莓(Vaccinium spp)；
(26)山茶科(Theaceae)的植物，例如，茶树(Camellia sinensis)；
(27)茄科(Solanaceae)的植物，例如，牛角椒(Capsicum annuum)、菜椒(Capsicumannuum var.’grossum’)、番茄(Lycopersicon esculentum)、烟草(Nicotiana tabacum)、茄子(Solanum melongena)、马铃薯(Solanum tuberosum)；
(28)凤梨科(Bromeliaceae)的植物，例如，菠萝(Ananas comosus)；
(29)芭蕉科(Musaceae)的植物，例如，香蕉(Musa spp.)；
(30)莲科(Nelumbonaceae)的植物，例如，莲花(Nelumbo nucifera)
(31)木瓜科(Caricaceae)的植物，例如，木瓜(Carica papaya)
(32)蔷薇科(Rosaceae)的植物，例如，木瓜海棠(Chaenomeles sinensis)、枇杷(Eriobotrya japonica Lindl.)、草莓(Fragaria spp.)、苹果(Malus pumila)、杏(Prunusarmeniaca)、甜樱桃(Prunus avium)、酸樱桃(Prunus cerasus)、杏仁(Prunus dulcis)、梅(Prunus mume)、桃(Prunus persica)、李子(Prunus salicina)、梨(Pyrus pyrifoliavar.culta)、西洋梨(Pyrus communis)、黑莓(Rubus spp.)；
(33)旋花科(Convolvulaceae)的植物，例如，红薯(Ipomoea batatasLam.var.edulis Makino)；
(34)葡萄科(Vitaceae)的植物，例如，葡萄(Vitis spp.)；
(35)壳斗科(Fagaceae)的植物，例如，板栗(Castanea crenata Sieb.Et Zucc.)；
(36)猕猴桃科(Actinidiaceae)的植物，例如，美味奇异果(Actinidiadeliciosa)；
(37)豆科(Leguminosae)的植物，例如，花生(Arachis hypogaea)、大豆(Glycinemax subsp.max)、蔓豆(Glycine max subsp.soja)、扁豆(Lens culinaris)、紫苜蓿(Medicago sativa)、豌豆(Pisum sativum L.)、菜豆(Phaseolus vulgaris)、窄叶野豌豆(Vicia angustifolia)、蚕豆(Vicia faba)、红豆(Vigna angularis)；
(38)芸香科(Rutaceae)的植物，例如，香橙(Citrus junos)、南丰蜜桔(纪州蜜桔)(Citrus kinokuni)、柠檬(Citrus limon)、橙子(Citrus sinensis)、温州蜜柑(Citrusunshiu)、柚子(Citrus X paradisi)、金橘(Fortunella japonica)、秦椒(Zanthoxylumpiperitum)；
(39)木犀科(Oleaceae)的植物，例如，茉莉花(Jasminum spp.)、橄榄(Oleaeuropaea)；
(40)薯蓣科(Dioscoreaceae)的植物，例如，日本薯蓣(Dioscorea japonicaThunb.)、山药(Dioscorea batatas)；
(41)百合科(Liliaceae)的植物，例如，洋葱(Allium cepa)、大葱(Alliumfistulosum)、大蒜(Allium sativum)、虾夷葱(Allium schoenoprasum)、韭菜(Alliumtuberosum)、郁金香(Tulipa gesneriana)；
本发明的杀菌剂组合物对广泛种类的丝状菌例如属于卵菌类(Oomycetes)、子囊菌类(Ascomycetes)、半知菌类(Deuteromycetes)、担子菌类(Basidiomycetes)的菌具有优异的杀菌力。
本发明的杀菌剂组合物可以通过种子处理、茎叶散布、土壤施用或水面施用等而用于在栽培包括花卉、草坪、牧草的农园艺作物时发生的各种病害的防除。
例如，可以用于如下病害的防除，即，
甜菜：褐斑病(Cercospora beticola)、黑根病(Aphanomyces cochlloides)、根腐病(Thanatephorus cucumeris)、叶腐病(Thanatephorus cucumeris)；
花生：褐斑病(Mycosphaerella arachidis)、黑斑病(Mycosphaerellaberkeleyi)；
黄瓜：白粉病(Sphaerotheca fuliginea)、霜霉病(Pseudoperonosporacubensis)、蔓枯病(Mycosphaerella melonis)、枯萎病(Fusarium oxysporum)、菌核病(Sclerotinia sclerotiorum)、灰霉病(Botrytis cinerea)、炭疽病(Colletotrichumorbiculare)、黑星病(Cladosporium cucumerinum)、褐斑病(Corynespora cassicola)、纹枯病(Pythium debaryanam、Rhizoctonia solani Kuhn)、细菌性斑病(Pseudomonassyringae pv.Lecrymans)；
番茄：灰霉病(Botrytis cinerea)、叶霉病(Cladosporium fulvum)、致病疫霉病(Phytophthora infestans)；
茄子：灰霉病(Botrytis cinerea)、黑腐病(Corynespora melongenae)、白粉病(Erysiphe cichoracearum)、绒菌斑病(Mycovellosiella nattrassii)；
草莓：灰霉病(Botrytis cinerea)、白粉病(Sohaerotheca humuli)、炭疽病(Colletotrichum acutatum、Colletotrichum fragariae)、疫霉病(Phytophthoracactorum)；
洋葱：颈腐病(Botrytis allii)、灰霉病(Botrytis cinerea)、白斑叶枯病(Botrytis squamosa)、霜霉病(Peronospora destructor)；
卷心菜：根瘤病(Plasmodiophora brassicae)、软腐病(Erwinia carotovora)、霜霉病(Peronospora parasitica)；
扁豆：菌核病(Sclerotinia sclerotiorum)、灰霉病(Botrytis cinerea)；
苹果：白粉病(Podosphaera leucotricha)、黑星病(Venturia inaequalis)、花腐病(Monilinia mali)、黑点病(Mycosphaerella pomi)、腐烂病(Valsa mali)、斑点落叶病(Alternaria mali)、赤星病(Gymnosporangium yamadae)、轮纹病(Botryosphaeriaberengeriana)、炭疽病(Glomerella cingulata、Colletotrichum acutatum)、褐斑病(Diplocarpon mali)、蝇粪病(Zygophiala jamaicensis)、煤污病(Gloeodes pomigena)；
柿子：白粉病(Phyllactinia kakicola)、炭疽病(Gloeosporium kaki)、角斑落叶病(Cercospora kaki)；
桃：褐腐病(Monilinia fructicola)、黑星病(Cladosporium carpophilum)、拟茎点霉病(Phomopsis sp.)；
樱桃：褐腐病(Monilinia fructicola)；
葡萄：灰霉病(Botrytis cinerea)、白粉病(Uncinula necator)、晚腐病(Glomerella cingulata、Colletotrichum acutatum)、霜霉病(Plasmopara viticola)、黑豆病(Elsinoe ampelina)、褐斑病(Pseudocercospora vitis)、黑腐病(Guignardiabidwellii)；
梨：黑星病(Venturia nashicola)、赤星病(Gymnosporangium asiaticum)、黑斑病(Alternaria kikuchiana)、轮纹病(Botryosphaeria berengeriana)、白粉病(Phyllactinia mali)；
茶：轮斑病(Pestalotia theae)、炭疽病(Colletotrichum theae-sinensis)；
柑桔：疮痂病(Elsinoe fawcetti)、青霉病(Penicillium italicum)、绿霉病(Penicillium digitatum)、灰霉病(Botrytis cinerea)、黑点病(Diaporthe citri)、溃疡病(Xanthomonas campestris pv.Citri)；
小麦：白粉病(Erysiphegraminis f.sp.tritici)、赤霉病(Gibberella zeae)、叶锈病(Puccinia recondita)、褐色雪腐病(Pythium iwayamai)、红色雪腐病(Monographella nivalis)、小麦基腐病(Pseudocercosporella herpotrichoides)、叶枯病(Septoria tritici)、颖枯病(Leptosphaeria nodorum)、雪腐小粒菌核病(Typhulaincarnata)、雪腐大粒菌核病(Myriosclerotinia borealis)、小麦全蚀病(Gaeumanomycesgraminis)；
大麦：条纹病(Pyrenophora graminea)、云斑病(Rhynchosporium secalis)、散黑穗病(Ustilago tritici、U.nuda)；
稻：稻瘟病(Pyricularia oryzae)、纹枯病(Rhizoctonia solani)、恶苗病(Gibberella fujikuroi)、胡麻叶斑病(Cochliobolus niyabeanus)、禾草腐霉病(Pythiumgraminicolum)、白叶枯病(Xanthomonas oryzae)、稻苗细菌性立枯病(Burkholderiaplantarii)、褐条病(Acidovorax avenae)、细菌性谷枯病(Burkholderia glumae)；
烟草：菌核病(Sclerotinia sclerotiorum)、白粉病(Erysiphe cichoracearum)；
郁金香：灰霉病(Botrytis cinerea)；
西洋结缕草：雪腐大粒菌核病(Sclerotinia borealis)、猝倒病(Pythiumaphanidermatum)；
野茅：白粉病(Erysiphe graminis)；
大豆：紫斑病(Cercospora kikuchii)、霜霉病(Peronospora Manshurica)、大豆疫霉病(Phytophthora sojae)；
马铃薯·番茄：致病疫霉病(Phytophthora infestans)等。
另外，本发明的杀菌剂组合物对耐药菌也具有优异的杀菌效果。并且以极低药量的施用就能显示效果，因此有预防新的耐药菌出现的效果。
作为应用本发明的杀菌剂组合物更优选的病害，可以举出苹果的黑星病、黄瓜的灰霉病、小麦的白粉病、番茄的致病疫霉病、小麦的叶锈病、水稻的稻瘟病、黄瓜的枯萎病等。
实施例
接下来，举出实施例进一步对本发明进行详细说明。但是，本发明不受以下实施例任何限定。
实施例1和比较例1
按表1～5所示的浓度，使药剂I和药剂II分别溶解于二甲基亚砜。混合所得溶液，制备杀菌剂组合物。
应予说明，以下的各表中，表示药剂I的符号A表示式(A)所示的含氮杂环化合物，表示药剂I的符号B表示式(B)所示的含氮杂环化合物，表示药剂I的符号C表示式(C)所示的含氮杂环化合物。另外，表中，表示药剂II的数字表示下述的[1]～[61]的化合物。应予说明，表中的“-”表示不使用该药剂。
[1]环氟菌胺
[2]氟菌唑
[3]甲基硫菌灵
[4]双胍辛胺乙酸盐
[5]双胍辛胺烷苯磺酸盐
[6]甲霜灵
[7]霜脲氰
[8]苯噻菌胺
[9]唑菌酮
[10]唑嘧菌胺
[11]氟吡菌胺
[12]苯酰菌胺
[13]三乙膦酸
[14]氰霜唑
[15]丙氧喹啉
[16]苯菌酮
[17]喹氧灵
[18]氟酰胺
[19]哒菌清
[20]咯菌腈
[21]苯醚甲环唑
[22]戊唑醇
[23]萎锈灵
[24]福美双
[25]百菌清
[26]肟菌酯
[27]嘧菌酯
[28]醚菌酯
[29]吡菌苯威
[30]氟吡菌酰胺
[31]氟啶胺
[32]代森锰锌
[33]克菌丹
[34]嘧菌环胺
[35]甲基立枯磷
[36]异菌脲
[37]灭菌丹
[38]式(20)表示的化合物
[39]式(21)表示的化合物
[40]肟醚菌胺
[41]稻瘟灵
[42]啶虫脒
[43]噻螨酮
[44]虫酰肼
[45]吡虫啉
[46]噻虫嗪
[47]噻虫胺
[48]氯吡硫磷
[49]硫双威
[50]多杀菌素
[51]呋虫胺
[52]醚菊酯
[53]氟虫腈
[54]乙虫腈
[55]吡蚜酮
[56]噻呋酰胺
[57]噻嗪酮
[58]啶酰菌胺
[59]溴虫腈
[60]乙嘧酚磺酸酯
[61]式(22)表示的化合物
(杀菌试验)
在马铃薯葡萄糖培养基中添加灰霉病菌(Botrytis cinerea)的分生胞子并使其分散。向其中添加杀菌剂组合物并混合。将其分注到96孔的微孔板中，在暗处在20℃培养3天。其后，用酶标仪测定在波长405nm处的浊度。与无处理(不添加杀菌剂组合物)的情形下的浊度的测定值进行比较，算出灰霉病菌的生长抑制率(％)。试验以两列进行。另外，基于Colby公式算出生长抑制率的期待值。将这些结果示于表1～5。
应予说明，Colby公式为E＝M+N－MN/100。在此，E表示生长抑制率的期待值(％)，M表示由单独使用药剂I时的测定算出的生长抑制率(％)，N表示由单独使用药剂II时的测定算出的生长抑制率(％)。应予说明，表中，单独使用药剂时的期待值因与由测定算出的值相同所以不示出。
[表1]
表1
[表2]
表2
[表3]
表3
[表4]
表4
[表5]
表5
实施例2和比较例2
按表6～8所示的浓度，使药剂I和药剂II分别溶解于二甲基亚砜。混合所得溶液，制备杀菌剂组合物。
用与实施例1和比较例1相同的方法进行杀菌试验。将这些结果示于表6～8。应予说明，表中，单独使用药剂时的期待值因与由测定算出的值相同所以不示出。
[表6]
表6
[表7]
表7
[表8]
表8
由这些结果可知使用本发明涉及的杀菌剂组合物时测定的生长抑制率的值超过了根据上述Colby公式算出的生长抑制率的期待值，均显示协同的杀菌效果。
(黄瓜灰霉病防除试验)
将使药剂I和药剂II溶解于有机溶剂和表面活性剂而制成的混合乳剂用水稀释到规定浓度并散布于在瓦盆中栽培的黄瓜幼苗(品种“相模半白”，子叶期)。应予说明，表中，表示药剂I的符号A表示式(A)所示的含氮杂环化合物，表示药剂I的符号B表示式(B)所示的含氮杂环化合物，表示药剂I的符号C表示式(C)所示的含氮杂环化合物。另外，表中，表示药剂II的数字表示用上述的相同编号记载的各化合物。应予说明，表中的“-”表示不使用该药剂。
在室温下自然干燥后，滴加接种黄瓜灰霉病菌(Botrytis cinerea)的分生胞子悬浮液，在暗处、20℃、高湿度的室内保持3天、4天或者5天。将叶上出现的病斑状态与无处理的情形进行比较调查，求出防除效果。试验以两列进行。另外，基于Colby公式算出防除效果的期待值。
同时，作为比较例，对仅使用药剂I的情形和仅使用药剂II的情形，也用与上述相同的方法进行试验。
将这些结果示于表9～14。
应予说明，Colby公式为E＝M+N－MN/100。在此，E表示防除效果的期待值(％)，M表示由单独使用药剂I时的测定算出的防除效果(％)，N表示由单独使用药剂II时的测定算出的防除效果(％)。应予说明，表中，单独使用药剂时的期待值因与由测定算出的值相同所以不示出。
[表9]
表9(接种4天后)
[表10]
表10(接种5天后)
[表11]
表11(接种4天后)
[表12]
表12(接种5天后)
[表13]
表13(接种4天后)
[表14]
表14(接种3天后)
(黄瓜白粉病防除试验)
将使药剂I和药剂II溶解于有机溶剂和表面活性剂而制成的混合乳剂用水稀释到规定浓度并散布于在瓦盆中栽培的黄瓜幼苗(品种“相模半白”，子叶期)。应予说明，表中，表示药剂I的符号A表示式(A)所示的含氮杂环化合物，表示药剂I的符号B表示式(B)所示的含氮杂环化合物，表示药剂I的符号C表示式(C)所示的含氮杂环化合物。另外，表中，表示药剂II的数字表示用上述相同编号记载的各化合物。应予说明，表中的“-”表示不使用该药剂。
在室温下自然干燥后，抖落黄瓜白粉病菌(Sphaerotheca fuliginea)的分生胞子进行接种，在温室内保持7天。将叶上出现的病斑状态与无处理的情形进行比较调查，求出防除效果。试验以两列进行。另外，基于Colby公式算出防除效果的期待值。
同时，作为比较例，对仅使用药剂I的情形和仅使用药剂II的情形，也用与上述相同的方法进行试验。
将这些结果示于表15。
应予说明，Colby公式为E＝M+N－MN/100。在此，E表示防除效果的期待值(％)，M表示由单独使用药剂I时的测定算出的防除效果(％)，N表示由单独使用药剂II时的测定算出的防除效果(％)。应予说明，表中，单独使用药剂时的期待值因与由测定算出的值相同所以不示出。
[表15]
表15
由这些结果可知，使用本发明涉及的杀菌剂组合物时测定的防除效果的值超过了基于上述Colby公式算出的防除效果的期待值，均显示协同的杀菌效果。
产业上的可利用性
本发明的农园艺用杀菌剂组合物用极低药量就能对植物病害显示优异的防除效果，并且不用担心对有用植物产生药害。因此，本发明可适用于农园艺用杀菌剂组合物。所以本发明在产业上极其有用。

Claims (1)

1.一种农园艺用杀菌剂组合物，其特征在于，含有成分A和成分B，
所述成分A是式(C)表示的含氮杂环化合物，
所述成分B是选自下述化合物中的至少一种化合物，即，SBI剂、苯并咪唑类剂、酸酰胺类杀菌剂、二羧基酰亚胺类杀菌剂、苯基吡咯类杀菌剂、有机(硫代)磷酸酯类剂、胍类杀菌剂、线粒体电子传递链复合体II抑制剂、线粒体电子传递链复合体III抑制剂、苯胺基嘧啶类剂、新烟碱类剂、SH抑制剂、环氟菌胺、霜脲氰、丙氧喹啉、苯菌酮、喹氧灵、哒菌清、稻瘟灵、乙嘧酚磺酸酯、噻螨酮、虫酰肼、硫双威、多杀菌素、醚菊酯、氟虫腈、乙虫腈、吡蚜酮、噻嗪酮、溴虫腈、式(7)表示的化合物、式(8)或(9)表示的化合物以及它们的盐，
所述SBI剂是选自氟菌唑、苯醚甲环唑以及戊唑醇中的1种以上，
所述苯并咪唑类剂是甲基硫菌灵，
所述酸酰胺类杀菌剂是选自甲霜灵、苯噻菌胺、氟吡菌胺、氟吡菌酰胺、苯酰菌胺、氟酰胺、萎锈灵、噻呋酰胺以及啶酰菌胺中的1种以上，
所述二羧基酰亚胺类杀菌剂是异菌脲，
所述苯基吡咯类杀菌剂是咯菌腈，
所述有机(硫代)磷酸酯类剂是选自三乙膦酸、甲基立枯磷以及氯吡硫磷中的1种以上，
所述胍类杀菌剂是双胍辛胺，
所述线粒体电子传递链复合体II抑制剂是由酰苯胺类杀菌剂构成的1种以上，
所述线粒体电子传递链复合体III抑制剂是选自QoI剂、QiI剂以及唑嘧菌胺中的1种以上，
所述QoI剂是选自肟菌酯、嘧菌酯、醚菌酯、肟醚菌胺、唑菌酮以及吡菌苯威中的1种以上，
所述QiI剂是氰霜唑，
所述苯胺基嘧啶类剂是嘧菌环胺，
所述新烟碱类剂是选自啶虫脒、吡虫啉、噻虫嗪、噻虫胺以及呋虫胺中的1种以上，
所述SH抑制剂是选自代森锰锌、福美双、百菌清、克菌丹、灭菌丹以及氟啶胺中的1种以上，
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