CN103834330A - Flame retardant acrylate adhesive - Google Patents
Flame retardant acrylate adhesive Download PDFInfo
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- CN103834330A CN103834330A CN201210478873.4A CN201210478873A CN103834330A CN 103834330 A CN103834330 A CN 103834330A CN 201210478873 A CN201210478873 A CN 201210478873A CN 103834330 A CN103834330 A CN 103834330A
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- flame retardant
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Abstract
The invention discloses a flame retardant acrylate adhesive, belongs to the technical field of two-component acrylate adhesives, and mainly solves the problem that after curing acrylate adhesives in the prior art may cause adhesive layer combustion when the acrylate adhesives meet spark sputtering. The flame retardant acrylate adhesive is mainly characterized by including a main agent component which comprises 25 to 60 parts of acrylate monomers containing at least one vinyl, 1 to 25 parts of methacrylic acid, 0 to 25 parts of an elastomer, 1 to 25 parts of a fire retardant, 0.5 to 8 parts of an initiator and 0.1 to 5 parts of a stabilizer; and a curing agent component which comprises 25 to 60 parts of the acrylic monomers containing at least 1 vinyl, 1 to 25 parts of the methacrylic acid, 0 to 25 parts of the elastomer, 1 to 25 parts of the fire retardant and 1-10 parts of an accelerant. The flame retardant acrylate adhesive has an improved flashing point, is nonflammable, can achieve the effects of being non-ignitable when meeting a fire or self-extinguishing when being away from the fire, and is mainly used as a flame retardant acrylate adhesive.
Description
Technical field
The invention belongs to bi-component acrylic ester adhesive technical field, be specifically related to a kind of flame retardant type acrylic ester adhesive.
Background technology
Acrylic ester structure adhesive has that room temperature fast-curing, intensity are high, good toughness, can Sealant, the distinguishing feature such as strong adaptability, simple process.Therefore the structure that is widely used in the industries such as aerospace, aviation, automobile, machinery, naval vessel, electronics, electrical equipment, instrument, building, furniture, toy, rail vehicle, civil engineering work, industrial art is bonding.
Along with the continuous expansion of Application Areas, acrylate adhesive relies on its every good performance all to realize industrial applications in a lot of fields.In the manufacturing processed of van container, due to its panel area great Yi bending, so need to use stiffening web to be fixed.The contact area of stiffening web and panel is little, but stressed as weight bearing area, so need high-intensity sqtructural adhesive to bond, therefore acrylate adhesive becomes the first-selection in industrial application, and is widely used.But find in production practice subsequently, when stiffening web and panel bonding after, in the time that face plate edge is carried out electric welding sealing, when spark is splashed on bonding plane, will cause glue-line burning, after need to manually putting out, continue again to produce, man power and material has been caused to certain waste, also produced certain hidden danger of quality simultaneously.And for example the weight bearing area of engineering machinery and large-scale steel is bonding, when flame calcination glue-line makes, if cause glue-line burning, will cause weight bearing area unsticking, causes serious property damage.Therefore, need a kind of flame retardant resistance acrylate adhesive, its cured article chance fire does not fire or certainly puts out from fire, maintains good mechanical property and curing performance simultaneously.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of acrylic ester adhesive of flame retardant type, to improve the flash-point (flash-point of conventional acrylate adhesive is as 10 DEG C) of acrylate adhesive, make its cured article nonflammable, can reach and meet the effect that fire does not fire or certainly put out from fire.
The present invention solves the problems of the technologies described above taked technical solution: a kind of flame retardant type acrylic ester adhesive is two component adhesive, comprises curing agent component and host component, it is characterized in that:
(1) host component: 25 ~ 60 parts at least contain the acrylate monomer of 1 vinyl, 1 ~ 25 part of methacrylic acid, 0 ~ 25 part of elastomerics, 1 ~ 25 part of fire retardant, 0.5 ~ 8 part of initiator, 0.1 ~ 5 part of stablizer;
(2) curing agent component: 25 ~ 60 parts at least contain the acrylate monomer of 1 vinyl, 1 ~ 25 part of methacrylic acid, 0 ~ 25 part of elastomerics, 1 ~ 25 part of fire retardant, 1 ~ 10 part of promotor;
In (3) two components, have at least in a component and contain elastomerics.
In technical solution of the present invention, the said acrylate monomer that at least contains 1 vinyl can be monomethacrylates monomer, dimethacrylate monomer, many methacrylate monomer or its mixture.
In technical solution of the present invention, said monomethacrylates monomer is methyl methacrylate, β-dimethyl-aminoethylmethacrylate, propyl methacrylate, butyl methacrylate, methacrylic acid pentyl ester, N-Hexyl methacrylate, methacrylic heptyl heptylate, Octyl methacrylate, hydroxyethyl methylacrylate, Rocryl 410, methacrylic acid ring pentyl ester, cyclohexyl methacrylate, 2-hydroxyethyl methacrylic acid phosphoric acid ester or its mixture.
In technical solution of the present invention, said initiator is superoxide.
Superoxide described in technical solution of the present invention is benzoyl peroxide, tertbutyl peroxide, isopropyl benzene hydroperoxide, methylethyl ketone peroxide, dicumyl peroxide or its mixture.
In technical solution of the present invention, said elastomerics is rubber-like elastomerics or its mixtures such as chlorosulfonated polyethylene, paracril, chloroprene rubber, acrylic elastomer, polyether rubber, ABS, SBS, MBS.
In technical solution of the present invention, said stablizer is phenolic compound, quinones, oxalic acid, Na salt or its mixture.
In technical solution of the present invention, said promotor is amine, Thiourea, aldehyde-amine condensate or its mixture.
In technical solution of the present invention, said fire retardant is a kind of or its mixture in TCPP, TCEP, TDCPP, IPPP and DMMP.
The acrylic ester adhesive that adopts the technology of the present invention solution to prepare is a kind of flame retardant type acrylic ester adhesive, can be used for the self-adhesion of various material and sticky mutually.It is inflammable that the present invention has overcome common s-generation acrylate adhesive, the shortcoming that flash-point is low, and by adding phosphorus flame retardant, in condensed phase, thermolysis is phosphoric acid or Tripyrophosphoric acid, generates the stickiness top layer protection adhesive substrate of melting, makes it not burn or be oxidized.The present invention has the flash-point that improves acrylate adhesive, makes its cured article nonflammable, can reach the fiery feature of not firing or certainly putting out effect from fire of meeting.The present invention is mainly used in flame retardant type acrylic ester adhesive.
Embodiment
The correlated performance test of flame retardant type acrylic ester adhesive of the present invention, shearing resistance and flame retardant resistance are the detection index of adhesive solidification thing.
The following example will be introduced the present invention more in detail, but the present invention is not limited to these embodiment.
Embodiment 1:
Proportioning curing agent component host component
Methyl methacrylate 26%Wt 21%Wt
Hydroxyethyl methylacrylate 22%Wt 40%Wt
Methacrylic acid 14%Wt 6%Wt
2-hydroxyethyl methacrylic acid phosphoric acid ester 5%Wt-
ABS 5.5％Wt 4.5％Wt
Paracril 12%Wt 12%Wt
Substituting thioureido 3%Wt-
Aminated compounds 2.5%Wt-
Isosorbide-5-Nitrae-Resorcinol-0.2%Wt
Fire retardant 10%Wt 10%Wt
Isopropyl benzene hydroperoxide-4.8%Wt
Benzoyl peroxide-1.5%Wt.
Preparation method:
(1) host: monomethacrylates monomer and methacrylic acid are dropped in reactor, add elastomerics, be stirred to elastomerics and dissolve completely, add epoxy resin, stablizer, stir, add isopropyl benzene hydroperoxide, benzoyl peroxide, stir.
(2) curing agent component: monomethacrylates monomer and methacrylic acid are dropped in reactor, add elastomerics, be stirred to elastomerics and dissolve completely, add substituting thioureido, aminated compounds, stir.
Performance test:
1, flame retardant resistance: test is with reference to GB/T5455-1997 " textile combustion performance test normal beam technique ";
2, flash-point: test is with reference to GB/T 261-2008 " flashing test "
3, shearing resistance: the test piece making was solidified after 24 hours, carry out tensile shear strength by GB/T 7124-1986.
Test result is in table 1.
Embodiment 2:
Proportioning curing agent component host component
Methyl methacrylate 23%Wt 20%Wt
Hydroxyethyl methylacrylate 25%Wt 40%Wt
Methacrylic acid 11%Wt 5%Wt
2-hydroxyethyl methacrylic acid phosphoric acid ester 5%Wt-
ABS 5.5％Wt 4.5％Wt
Paracril 12%Wt 12%Wt
Substituting thioureido 3%Wt-
Aminated compounds 2.5%Wt-
Isosorbide-5-Nitrae-Resorcinol-0.2%Wt
Fire retardant 13%Wt 12%Wt
Isopropyl benzene hydroperoxide-4.8%Wt
Benzoyl peroxide-1.5%Wt.
Preparation method is with embodiment 1.
Performance test is with embodiment 1.
Test result is in table 1.
Embodiment 3:
Proportioning curing agent component host component
Methyl methacrylate 20%Wt 19%Wt
Hydroxyethyl methylacrylate 28%Wt 41%Wt
Methacrylic acid 8%Wt 5%Wt
2-hydroxyethyl methacrylic acid phosphoric acid ester 5%Wt-
ABS 5.5％Wt 4.5％Wt
Paracril 12%Wt 12%Wt
Substituting thioureido 3.5%Wt-
Aminated compounds 3%Wt-
Isosorbide-5-Nitrae-Resorcinol-0.2%Wt
Fire retardant 15%Wt 12%Wt
Isopropyl benzene hydroperoxide-4.8%Wt
Benzoyl peroxide-1.5%Wt.
Preparation method is with embodiment 1.
Performance test is with embodiment 1.
Test result is in table 1.
Embodiment 4:
Proportioning curing agent component host component
Methyl methacrylate 15%Wt 14%Wt
Hydroxyethyl methylacrylate 28%Wt 41%Wt
Methacrylic acid 8%Wt 5%Wt
2-hydroxyethyl methacrylic acid phosphoric acid ester 5%Wt-
ABS 5.5％Wt 4.5％Wt
Paracril 12%Wt 12%Wt
Substituting thioureido 3.5%Wt-
Aminated compounds 3%Wt-
Isosorbide-5-Nitrae-Resorcinol-0.2%Wt
Fire retardant 20%Wt 17%Wt
Isopropyl benzene hydroperoxide-4.8%Wt
Benzoyl peroxide-1.5%Wt.
Preparation method is with embodiment 1.
Performance test is with embodiment 1.
Test result is in table 1.
Claims (9)
1. a flame retardant type acrylic ester adhesive, is two component adhesive, comprises curing agent component and host component, it is characterized in that:
(1) host component: 25 ~ 60 parts at least contain the acrylate monomer of 1 vinyl, 1 ~ 25 part of methacrylic acid, 0 ~ 25 part of elastomerics, 1 ~ 25 part of fire retardant, 0.5 ~ 8 part of initiator, 0.1 ~ 5 part of stablizer;
(2) curing agent component: 25 ~ 60 parts at least contain the acrylate monomer of 1 vinyl, 1 ~ 25 part of methacrylic acid, 0 ~ 25 part of elastomerics, 1 ~ 25 part of fire retardant, 1 ~ 10 part of promotor;
In (3) two components, have at least in a component and contain elastomerics.
2. a kind of flame retardant type acrylic ester adhesive according to claim 1, is characterized in that: the described acrylate monomer that at least contains 1 vinyl is monomethacrylates monomer, dimethacrylate monomer, many methacrylate monomer or its mixture.
3. a kind of flame retardant type acrylic ester adhesive according to claim 2, is characterized in that: described monomethacrylates monomer is methyl methacrylate, β-dimethyl-aminoethylmethacrylate, propyl methacrylate, butyl methacrylate, methacrylic acid pentyl ester, N-Hexyl methacrylate, methacrylic heptyl heptylate, Octyl methacrylate, hydroxyethyl methylacrylate, Rocryl 410, methacrylic acid ring pentyl ester, cyclohexyl methacrylate, 2-hydroxyethyl methacrylic acid phosphoric acid ester or its mixture.
4. a kind of flame retardant type acrylic ester adhesive according to claim 1, is characterized in that: described elastomerics is chlorosulfonated polyethylene, paracril, chloroprene rubber, acrylic elastomer, polyether rubber, ABS, SBS, MBS rubber-like elastomerics or its mixture.
5. a kind of flame retardant type acrylic ester adhesive according to claim 1, is characterized in that: described initiator is superoxide.
6. a kind of flame retardant type acrylic ester adhesive according to claim 5, is characterized in that: described superoxide is benzoyl peroxide, tertbutyl peroxide, isopropyl benzene hydroperoxide, methylethyl ketone peroxide, dicumyl peroxide or its mixture.
7. a kind of flame retardant type acrylic ester adhesive according to claim 1, is characterized in that: described stablizer is phenolic compound, quinones, oxalic acid, Na salt or its mixture.
8. a kind of flame retardant type acrylic ester adhesive according to claim 1, is characterized in that: described promotor is amine, Thiourea, aldehyde-amine condensate or its mixture.
9. a kind of flame retardant type acrylic ester adhesive according to claim 1, is characterized in that: described fire retardant is a kind of or its mixture of TCPP, TCEP, TDCPP, IPPP and DMMP.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210478873.4A CN103834330A (en) | 2012-11-23 | 2012-11-23 | Flame retardant acrylate adhesive |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210478873.4A CN103834330A (en) | 2012-11-23 | 2012-11-23 | Flame retardant acrylate adhesive |
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| CN103834330A true CN103834330A (en) | 2014-06-04 |
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| CN201210478873.4A Pending CN103834330A (en) | 2012-11-23 | 2012-11-23 | Flame retardant acrylate adhesive |
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