CN105969210A - Flame-retardant storage battery sealing adhesive based on isobornyl methacrylate and tetrahydrofurfuryl alcohol methacrylate and production method of flame-retardant storage battery sealing adhesive - Google Patents
Flame-retardant storage battery sealing adhesive based on isobornyl methacrylate and tetrahydrofurfuryl alcohol methacrylate and production method of flame-retardant storage battery sealing adhesive Download PDFInfo
- Publication number
- CN105969210A CN105969210A CN201610487845.7A CN201610487845A CN105969210A CN 105969210 A CN105969210 A CN 105969210A CN 201610487845 A CN201610487845 A CN 201610487845A CN 105969210 A CN105969210 A CN 105969210A
- Authority
- CN
- China
- Prior art keywords
- component
- solvent
- parts
- flame
- storage battery
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a flame-retardant storage battery sealing adhesive based on isobornyl methacrylate and tetrahydrofurfuryl alcohol methacrylate and a production method of the flame-retardant storage battery sealing adhesive. The flame-retardant storage battery sealing adhesive comprises a component A and a component B, wherein the component A comprises the isobornyl methacrylate, solvent, dioctyl adipate, zinc borate, reinforcing filler, IrgastabPUR68 and SBS resin; the component B comprises the tetrahydrofurfuryl alcohol methacrylate, acrylate rubber, cobalt naphthenate, phosphonate type flame-retardant plasticizer, kaolin, solvent, BYK-354 and 1, 2-epoxy ethyoxyl trimethoxy silane. The adhesive of the component A and the adhesive of the component B are respectively prepared by vacuum kneading and mixing in a reaction kettle. The flame-retardant storage battery sealing adhesive has the advantages that by the reasonable proportion of the raw materials of the component A and the component B, the component A and the component B can be well adhered to each other during use, the generation of internal bubbles is reduced, gaps in the adhesive are reduced, good fire resistance and thermal insulation performance are achieved, the original flowability of the adhesive is guaranteed, and the discharge of harmful substances is reduced.
Description
Technical field
The present invention relates to chemical technology field, particularly to a kind of based on isobornyl thiocyanoacetate Yu furfuryl alcohol ester the flame-retardant storage battery fluid sealant that accumulator is played sealing function
And manufacture method
。
Background technology
Macromolecular material is increasingly extensive in building material industry application, but macromolecular material itself easily burns, and when fire occurs, burning discharges substantial amounts of toxic gas, such as carbon monoxide, nitric oxide etc., people just can be made in very short time to be poisoned to death.Great mass of data shows, toxic smoke is the first of causing death the big killer in fire.Thus the fire resistance of construction material is directly connected to the people's lives and property safety.And the halogen flame that now flame retardant sealant adds in a large number can generate the toxic gas such as substantial amounts of hydrogen halides in combustion, and bittern-free flame-proof material, magnesium hydroxide, aluminium hydroxide flame retardant effect poor, addition greatly, has a strong impact on material property.Simultaneously because add substantial amounts of fire retardant, cause the mobility of fluid sealant to decline, be difficult to immerse narrow and small filleting, make troubles to construction.
Summary of the invention
It is an object of the invention to provide
One has and decreases glue internal clearance, adds good fire protecting performance and heat-proof quality, it is ensured that the original mobility of adhesive simultaneously, decreases the discharge of harmful substance
A kind of based on isobornyl thiocyanoacetate Yu furfuryl alcohol ester flame-retardant storage battery fluid sealant
And manufacture method
, solve the use needs of problems of accumulator sealant.
In order to achieve the above object, the present invention provides following technical scheme:
A kind of flame-retardant storage battery fluid sealant based on isobornyl thiocyanoacetate Yu furfuryl alcohol ester, it is characterised in that: include
A
Component and
B
Component；Described
A
Component by isobornyl methacrylate, solvent, adipic acid dibutyl ester, Firebrake ZB, reinforcing filler,
IrgastabPUR68
,
SBS
Resin forms；
B
Component by metering system tetrahydrofurfuryl alcohol ester, acrylate rubber, cobalt naphthenate, Phosphonate Flame Retardant plasticizer, Kaolin, solvent,
BYK-354
,
1
、
2-
Epoxy ethyoxyl trimethoxy silane forms；Wherein said
A
In component, including:
40-60
The isobornyl methacrylate of part,
20-30
The solvent of part,
4-8
The adipic acid dibutyl ester of part,
10-25
The Firebrake ZB of part,
5-10
The reinforcing filler of part,
5-10
Part
IrgastabPUR68
,
20-35
Part
SBS
Resin forms；Described
B
In component, including:
60-80
The metering system tetrahydrofurfuryl alcohol ester of part,
20-30
The acrylate rubber of part,
5-15
The cobalt naphthenate of part,
5-15
The Phosphonate Flame Retardant plasticizer of part,
5-10
The Kaolin of part,
25-40
Part solvent,
10-15
Part
BYK-354
,
4-10
Part
1
、
2-
Epoxy ethyoxyl trimethoxy silane.
Described solvent is one or more in acetone, chloroform, dichloroethanes, nylon acid dimethyl ester, ethyl acetate, toluene or dimethylbenzene；Reinforcing filler is one or more that fume colloidal silica, precipitated silica and surface process in white carbon.
Described
A
In component, including:
40-55
The isobornyl methacrylate of part,
20-28
The solvent of part,
4-7
The adipic acid dibutyl ester of part,
10-22
The Firebrake ZB of part,
5-8
The reinforcing filler of part,
5-9
Part
IrgastabPUR68
,
20-33
Part
SBS
Resin forms；Described
B
In component, including:
60-78
The metering system tetrahydrofurfuryl alcohol ester of part,
20-25
The acrylate rubber of part,
5-12
The cobalt naphthenate of part,
5-13
The Phosphonate Flame Retardant plasticizer of part,
5-8
The Kaolin of part,
25-35
The solvent of part,
10-14
Part
BYK-354
,
4-8
Part
1
、
2-
Epoxy ethyoxyl trimethoxy silane.
Described
A
In component, including:
50
The isobornyl methacrylate of part,
25
The solvent of part,
6
The adipic acid dibutyl ester of part,
22
The Firebrake ZB of part,
8
The reinforcing filler of part,
8
Part
IrgastabPUR68
,
28
Part
SBS
Resin forms；Described
B
In component, including:
70
The metering system tetrahydrofurfuryl alcohol ester of part,
25
The acrylate rubber of part,
10
The cobalt naphthenate of part,
10
The Phosphonate Flame Retardant plasticizer of part,
8
The Kaolin of part,
35
The solvent of part,
13
Part
BYK-354
,
8
Part
1
、
2-
Epoxy ethyoxyl trimethoxy silane.
Concretely comprise the following steps:
1
, will
A
Isobornyl methacrylate in component, solvent, adipic acid dibutyl ester,
SBS
Resin adds in vacuum kneader, in temperature according to above-mentioned parts by weight proportioning mode
70
~
100
℃
, vacuum is
0.08
~
0.12MPa
, dehydration be blended
60
~
300
Minute, prepare
A
Group compound, moves in high speed dispersion stirred tank, standby；Will
B
Metering system tetrahydrofurfuryl alcohol ester in component, acrylate rubber, Phosphonate Flame Retardant plasticizer, solvent adds in vacuum kneader, in temperature according to above-mentioned parts by weight proportioning mode
70
~
100
℃
, vacuum is
0.08
~
0.12MPa
, dehydration be blended
60
~
300
Minute, prepare
B
Group compound, moves in high speed dispersion stirred tank, standby；
2
, at room temperature, by above-mentioned
A
Addition Firebrake ZB in group compound, reinforcing filler,
IrgastabPUR68
Being placed in stirred tank, vacuum is
0.08
~
0.12MPa
, rotating speed
100
~
600rpm
, it is sufficiently mixed
1
~
5
Hour, prepare
A
Group is thoroughly mixed material；By above-mentioned
B
Addition cobalt naphthenate in group compound, Kaolin,
BYK-354
,
1
、
2-
Epoxy ethyoxyl trimethoxy silane is placed in stirred tank, and vacuum is
0.08
~
0.12MPa
, rotating speed
100
~
600rpm
, it is sufficiently mixed
1
~
5
Hour, prepare
B
Group is thoroughly mixed material.
Beneficial effects of the present invention: the present invention
By the raw material in A, B component is carried out rational proportioning, make the bonding that two kinds of components in use can be good, and reduce the generation of air entrapment, decrease glue internal clearance, add good fire protecting performance and heat-proof quality simultaneously, ensure that the original mobility of adhesive, decrease the discharge of harmful substance
。
Detailed description of the invention
Below in conjunction with embodiment, technical scheme is clearly and completely described, it is clear that described embodiment is only a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, the every other embodiment that those of ordinary skill in the art are obtained under not making creative work premise, broadly fall into the scope of protection of the invention.
Embodiment
1
:
A kind of flame-retardant storage battery fluid sealant based on isobornyl thiocyanoacetate Yu furfuryl alcohol ester, it is characterised in that: include
A
Component and
B
Component；Described
A
Component by isobornyl methacrylate, solvent, adipic acid dibutyl ester, Firebrake ZB, reinforcing filler,
IrgastabPUR68
,
SBS
Resin forms；
B
Component by metering system tetrahydrofurfuryl alcohol ester, acrylate rubber, cobalt naphthenate, Phosphonate Flame Retardant plasticizer, Kaolin, solvent,
BYK-354
,
1
、
2-
Epoxy ethyoxyl trimethoxy silane forms；Wherein said
A
In component, including:
40-60
The isobornyl methacrylate of part,
20-30
The solvent of part,
4-8
The adipic acid dibutyl ester of part,
10-25
The Firebrake ZB of part,
5-10
The reinforcing filler of part,
5-10
Part
IrgastabPUR68
,
20-35
Part
SBS
Resin forms；Described
B
In component, including:
60-80
The metering system tetrahydrofurfuryl alcohol ester of part,
20-30
The acrylate rubber of part,
5-15
The cobalt naphthenate of part,
5-15
The Phosphonate Flame Retardant plasticizer of part,
5-10
The Kaolin of part,
25-40
Part solvent,
10-15
Part
BYK-354
,
4-10
Part
1
、
2-
Epoxy ethyoxyl trimethoxy silane.
Described solvent is one or more in acetone, chloroform, dichloroethanes, nylon acid dimethyl ester, ethyl acetate, toluene or dimethylbenzene；Reinforcing filler is one or more that fume colloidal silica, precipitated silica and surface process in white carbon.
Described
A
In component, including:
40-55
The isobornyl methacrylate of part,
20-28
The solvent of part,
4-7
The adipic acid dibutyl ester of part,
10-22
The Firebrake ZB of part,
5-8
The reinforcing filler of part,
5-9
Part
IrgastabPUR68
,
20-33
Part
SBS
Resin forms；Described
B
In component, including:
60-78
The metering system tetrahydrofurfuryl alcohol ester of part,
20-25
The acrylate rubber of part,
5-12
The cobalt naphthenate of part,
5-13
The Phosphonate Flame Retardant plasticizer of part,
5-8
The Kaolin of part,
25-35
The solvent of part,
10-14
Part
BYK-354
,
4-8
Part
1
、
2-
Epoxy ethyoxyl trimethoxy silane.
Described
A
In component, including:
50
The isobornyl methacrylate of part,
25
The solvent of part,
6
The adipic acid dibutyl ester of part,
22
The Firebrake ZB of part,
8
The reinforcing filler of part,
8
Part
IrgastabPUR68
,
28
Part
SBS
Resin forms；Described
B
In component, including:
70
The metering system tetrahydrofurfuryl alcohol ester of part,
25
The acrylate rubber of part,
10
The cobalt naphthenate of part,
10
The Phosphonate Flame Retardant plasticizer of part,
8
The Kaolin of part,
35
The solvent of part,
13
Part
BYK-354
,
8
Part
1
、
2-
Epoxy ethyoxyl trimethoxy silane.
Concretely comprise the following steps:
1
, will
A
Isobornyl methacrylate in component, solvent, adipic acid dibutyl ester,
SBS
Resin adds in vacuum kneader, in temperature according to above-mentioned parts by weight proportioning mode
70
~
100
℃
, vacuum is
0.08
~
0.12MPa
, dehydration be blended
60
~
300
Minute, prepare
A
Group compound, moves in high speed dispersion stirred tank, standby；Will
B
Metering system tetrahydrofurfuryl alcohol ester in component, acrylate rubber, Phosphonate Flame Retardant plasticizer, solvent adds in vacuum kneader, in temperature according to above-mentioned parts by weight proportioning mode
70
~
100
℃
, vacuum is
0.08
~
0.12MPa
, dehydration be blended
60
~
300
Minute, prepare
B
Group compound, moves in high speed dispersion stirred tank, standby；
2
, at room temperature, by above-mentioned
A
Addition Firebrake ZB in group compound, reinforcing filler,
IrgastabPUR68
Being placed in stirred tank, vacuum is
0.08
~
0.12MPa
, rotating speed
100
~
600rpm
, it is sufficiently mixed
1
~
5
Hour, prepare
A
Group is thoroughly mixed material；By above-mentioned
B
Addition cobalt naphthenate in group compound, Kaolin,
BYK-354
,
1
、
2-
Epoxy ethyoxyl trimethoxy silane is placed in stirred tank, and vacuum is
0.08
~
0.12MPa
, rotating speed
100
~
600rpm
, it is sufficiently mixed
1
~
5
Hour, prepare
B
Group is thoroughly mixed material.
Embodiment
2
:
A kind of flame-retardant storage battery fluid sealant based on isobornyl thiocyanoacetate Yu furfuryl alcohol ester, it is characterised in that: include
A
Component and
B
Component；Described
A
Component by isobornyl methacrylate, solvent, adipic acid dibutyl ester, Firebrake ZB, reinforcing filler,
IrgastabPUR68
,
SBS
Resin forms；
B
Component by metering system tetrahydrofurfuryl alcohol ester, acrylate rubber, cobalt naphthenate, Phosphonate Flame Retardant plasticizer, Kaolin, solvent,
BYK-354
,
1
、
2-
Epoxy ethyoxyl trimethoxy silane forms；Wherein said
A
In component, including:
40-60
The isobornyl methacrylate of part,
20-30
The solvent of part,
4-8
The adipic acid dibutyl ester of part,
10-25
The Firebrake ZB of part,
5-10
The reinforcing filler of part,
5-10
Part
IrgastabPUR68
,
20-35
Part
SBS
Resin forms；Described
B
In component, including:
60-80
The metering system tetrahydrofurfuryl alcohol ester of part,
20-30
The acrylate rubber of part,
5-15
The cobalt naphthenate of part,
5-15
The Phosphonate Flame Retardant plasticizer of part,
5-10
The Kaolin of part,
25-40
Part solvent,
10-15
Part
BYK-354
,
4-10
Part
1
、
2-
Epoxy ethyoxyl trimethoxy silane.
Following manufacture method is utilized to make the proportioning in above-mentioned component:
1
, will
A
Isobornyl methacrylate in component, solvent, adipic acid dibutyl ester,
SBS
Resin adds in vacuum kneader, in temperature according to above-mentioned parts by weight proportioning mode
70
~
100
℃
, vacuum is
0.08
~
0.12MPa
, dehydration be blended
60
~
300
Minute, prepare
A
Group compound, moves in high speed dispersion stirred tank, standby；Will
B
Metering system tetrahydrofurfuryl alcohol ester in component, acrylate rubber, Phosphonate Flame Retardant plasticizer, solvent adds in vacuum kneader, in temperature according to above-mentioned parts by weight proportioning mode
70
~
100
℃
, vacuum is
0.08
~
0.12MPa
, dehydration be blended
60
~
300
Minute, prepare
B
Group compound, moves in high speed dispersion stirred tank, standby；
2
, at room temperature, by above-mentioned
A
Addition Firebrake ZB in group compound, reinforcing filler,
IrgastabPUR68
Being placed in stirred tank, vacuum is
0.08
~
0.12MPa
, rotating speed
100
~
600rpm
, it is sufficiently mixed
1
~
5
Hour, prepare
A
Group is thoroughly mixed material；By above-mentioned
B
Addition cobalt naphthenate in group compound, Kaolin,
BYK-354
,
1
、
2-
Epoxy ethyoxyl trimethoxy silane is placed in stirred tank, and vacuum is
0.08
~
0.12MPa
, rotating speed
100
~
600rpm
, it is sufficiently mixed
1
~
5
Hour, prepare
B
Group is thoroughly mixed material.
A
Component
With
B
Component
Respectively
Stand subpackage, directly will during use
A
Component,
B
Component is according to carrying out potting operation after weight ratio mix homogeneously.
Following table is the Data Comparison of the present invention and other series products:
Upper table shows that the properties of the present invention is better than like product, can meet the process requirements that accumulator seals.
Embodiment
3
:
Described
A
In component, including:
40-55
The isobornyl methacrylate of part,
20-28
The solvent of part,
4-7
The adipic acid dibutyl ester of part,
10-22
The Firebrake ZB of part,
5-8
The reinforcing filler of part,
5-9
Part
IrgastabPUR68
,
20-33
Part
SBS
Resin forms；Described
B
In component, including:
60-78
The metering system tetrahydrofurfuryl alcohol ester of part,
20-25
The acrylate rubber of part,
5-12
The cobalt naphthenate of part,
5-13
The Phosphonate Flame Retardant plasticizer of part,
5-8
The Kaolin of part,
25-35
The solvent of part,
10-14
Part
BYK-354
,
4-8
Part
1
、
2-
Epoxy ethyoxyl trimethoxy silane.
Following manufacture method is utilized to make the proportioning in above-mentioned component:
1
, will
A
Isobornyl methacrylate in component, solvent, adipic acid dibutyl ester,
SBS
Resin adds in vacuum kneader, in temperature according to above-mentioned parts by weight proportioning mode
100
℃
, vacuum is
0.12MPa
, dehydration be blended
300
Minute, prepare
A
Group compound, moves in high speed dispersion stirred tank, standby；Will
B
Metering system tetrahydrofurfuryl alcohol ester in component, acrylate rubber, Phosphonate Flame Retardant plasticizer, solvent adds in vacuum kneader, in temperature according to above-mentioned parts by weight proportioning mode
100
℃
, vacuum is
0.12MPa
, dehydration be blended
300
Minute, prepare
B
Group compound, moves in high speed dispersion stirred tank, standby；
2
, at room temperature, by above-mentioned
A
Addition Firebrake ZB in group compound, reinforcing filler,
IrgastabPUR68
Being placed in stirred tank, vacuum is
0.12MPa
, rotating speed
600rpm
, it is sufficiently mixed
5
Hour, prepare
A
Group is thoroughly mixed material；By above-mentioned
B
Addition cobalt naphthenate in group compound, Kaolin,
BYK-354
,
1
、
2-
Epoxy ethyoxyl trimethoxy silane is placed in stirred tank, and vacuum is
0.12MPa
, rotating speed
600rpm
, it is sufficiently mixed
5
Hour, prepare
B
Group is thoroughly mixed material.
A
Component
With
B
Component
Respectively
Stand subpackage, directly will during use
A
Component,
B
Component is according to carrying out potting operation after weight ratio mix homogeneously.
Embodiment
4
:
Described
A
In component, including:
50
The isobornyl methacrylate of part,
25
The solvent of part,
6
The adipic acid dibutyl ester of part,
22
The Firebrake ZB of part,
8
The reinforcing filler of part,
8
Part
IrgastabPUR68
,
28
Part
SBS
Resin forms；Described
B
In component, including:
70
The metering system tetrahydrofurfuryl alcohol ester of part,
25
The acrylate rubber of part,
10
The cobalt naphthenate of part,
10
The Phosphonate Flame Retardant plasticizer of part,
8
The Kaolin of part,
35
The solvent of part,
13
Part
BYK-354
,
8
Part
1
、
2-
Epoxy ethyoxyl trimethoxy silane.
Following manufacture method is utilized to make the proportioning in above-mentioned component:
1
, will
A
Isobornyl methacrylate in component, solvent, adipic acid dibutyl ester,
SBS
Resin adds in vacuum kneader, in temperature according to above-mentioned parts by weight proportioning mode
70
℃
, vacuum is
0.08MPa
, dehydration be blended
60
Minute, prepare
A
Group compound, moves in high speed dispersion stirred tank, standby；Will
B
Metering system tetrahydrofurfuryl alcohol ester in component, acrylate rubber, Phosphonate Flame Retardant plasticizer, solvent adds in vacuum kneader, in temperature according to above-mentioned parts by weight proportioning mode
70
℃
, vacuum is
0.08MPa
, dehydration be blended
60
Minute, prepare
B
Group compound, moves in high speed dispersion stirred tank, standby；
2
, at room temperature, by above-mentioned
A
Addition Firebrake ZB in group compound, reinforcing filler,
IrgastabPUR68
Being placed in stirred tank, vacuum is
0.08MPa
, rotating speed
100rpm
, it is sufficiently mixed
5
Hour, prepare
A
Group is thoroughly mixed material；By above-mentioned
B
Addition cobalt naphthenate in group compound, Kaolin,
BYK-354
,
1
、
2-
Epoxy ethyoxyl trimethoxy silane is placed in stirred tank, and vacuum is
0.08MPa
, rotating speed
100rpm
, it is sufficiently mixed
5
Hour, prepare
B
Group is thoroughly mixed material.
A
Component
With
B
Component
Respectively
Stand subpackage, directly will during use
A
Component,
B
Component is according to carrying out potting operation after weight ratio mix homogeneously.
The above; being only the detailed description of the invention of the present invention, but protection scope of the present invention is not limited thereto, any those familiar with the art is in the technical scope that the invention discloses; change can be readily occurred in or replace, all should contain within protection scope of the present invention.Therefore, protection scope of the present invention should described be as the criterion with scope of the claims.
Claims (5)
1. a flame-retardant storage battery fluid sealant based on isobornyl thiocyanoacetate Yu furfuryl alcohol ester, it is characterised in that: include component A and B component；Described component A is made up of isobornyl methacrylate, solvent, adipic acid dibutyl ester, Firebrake ZB, reinforcing filler, IrgastabPUR68, SBS resin；B component by metering system tetrahydrofurfuryl alcohol ester, acrylate rubber, cobalt naphthenate, Phosphonate Flame Retardant plasticizer, Kaolin, solvent, BYK-354,1,2-epoxy ethyoxyl trimethoxy silane composition；In wherein said component A, including: the isobornyl methacrylate of 40-60 part, the solvent of 20-30 part, the adipic acid dibutyl ester of 4-8 part, the Firebrake ZB of 10-25 part, the reinforcing filler of 5-10 part, the SBS resin composition of the IrgastabPUR68 of 5-10 part, 20-35 part；In described B component, including: the metering system tetrahydrofurfuryl alcohol ester of 60-80 part, the acrylate rubber of 20-30 part, the cobalt naphthenate of 5-15 part, the Phosphonate Flame Retardant plasticizer of 5-15 part, the Kaolin of 5-10 part, 25-40 part solvent, the 1 of the BYK-354 of 10-15 part, 4-10 part, 2-epoxy ethyoxyl trimethoxy silane.
A kind of flame-retardant storage battery fluid sealant based on isobornyl thiocyanoacetate Yu furfuryl alcohol ester the most according to claim 1, it is characterised in that: described solvent is one or more in acetone, chloroform, dichloroethanes, nylon acid dimethyl ester, ethyl acetate, toluene or dimethylbenzene；Reinforcing filler is one or more that fume colloidal silica, precipitated silica and surface process in white carbon.
A kind of flame-retardant storage battery fluid sealant based on isobornyl thiocyanoacetate Yu furfuryl alcohol ester the most according to claim 1, it is characterized in that: in described component A, including: the isobornyl methacrylate of 40-55 part, the solvent of 20-28 part, the adipic acid dibutyl ester of 4-7 part, the Firebrake ZB of 10-22 part, the reinforcing filler of 5-8 part, the SBS resin composition of the IrgastabPUR68 of 5-9 part, 20-33 part；In described B component, including: the metering system tetrahydrofurfuryl alcohol ester of 60-78 part, the acrylate rubber of 20-25 part, the cobalt naphthenate of 5-12 part, the Phosphonate Flame Retardant plasticizer of 5-13 part, the Kaolin of 5-8 part, the solvent of 25-35 part, the 1 of the BYK-354 of 10-14 part, 4-8 part, 2-epoxy ethyoxyl trimethoxy silane.
A kind of flame-retardant storage battery fluid sealant based on isobornyl thiocyanoacetate Yu furfuryl alcohol ester the most according to claim 1, it is characterized in that: in described component A, including: the isobornyl methacrylate of 50 parts, the solvent of 25 parts, the adipic acid dibutyl ester of 6 parts, the Firebrake ZB of 22 parts, the reinforcing filler of 8 parts, the IrgastabPUR68 of 8 parts, the SBS resin composition of 28 parts；In described B component, including: the metering system tetrahydrofurfuryl alcohol ester of 70 parts, the acrylate rubber of 25 parts, the cobalt naphthenate of 10 parts, the Phosphonate Flame Retardant plasticizer of 10 parts, the Kaolin of 8 parts, the solvent of 35 parts, the BYK-354 of 13 parts, 8 parts 1,2-epoxy ethyoxyl trimethoxy silane.
5. according to a kind of based on isobornyl thiocyanoacetate Yu the flame-retardant storage battery fluid sealant of furfuryl alcohol ester the manufacture method according to any one of claim 1-4, it is characterised in that: concretely comprise the following steps:
1, by isobornyl methacrylate in component A, solvent, adipic acid dibutyl ester, SBS resin adds in vacuum kneader according to above-mentioned parts by weight proportioning mode, in temperature 70～100 DEG C, vacuum is 0.08～0.12MPa, dehydration is blended 60～300 minutes, prepares A group compound, move in high speed dispersion stirred tank, standby；By metering system tetrahydrofurfuryl alcohol ester in B component, acrylate rubber, Phosphonate Flame Retardant plasticizer, solvent adds in vacuum kneader according to above-mentioned parts by weight proportioning mode, in temperature 70～100 DEG C, vacuum is 0.08～0.12MPa, dehydration is blended 60～300 minutes, prepares B group compound, move in high speed dispersion stirred tank, standby；
2, at room temperature, will add Firebrake ZB, reinforcing filler in above-mentioned A group compound, IrgastabPUR68 is placed in stirred tank, and vacuum is 0.08～0.12MPa, rotating speed 100～600rpm, is sufficiently mixed 1～5 hour, prepares A group and is thoroughly mixed material；Will in above-mentioned B group compound add cobalt naphthenate, Kaolin, BYK-354,1,2-epoxy ethyoxyl trimethoxy silane be placed in stirred tank, vacuum is 0.08～0.12MPa, rotating speed 100～600rpm, is sufficiently mixed 1～5 hour, prepare B group be thoroughly mixed material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610487845.7A CN105969210A (en) | 2016-06-29 | 2016-06-29 | Flame-retardant storage battery sealing adhesive based on isobornyl methacrylate and tetrahydrofurfuryl alcohol methacrylate and production method of flame-retardant storage battery sealing adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610487845.7A CN105969210A (en) | 2016-06-29 | 2016-06-29 | Flame-retardant storage battery sealing adhesive based on isobornyl methacrylate and tetrahydrofurfuryl alcohol methacrylate and production method of flame-retardant storage battery sealing adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105969210A true CN105969210A (en) | 2016-09-28 |
Family
ID=57019440
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610487845.7A Pending CN105969210A (en) | 2016-06-29 | 2016-06-29 | Flame-retardant storage battery sealing adhesive based on isobornyl methacrylate and tetrahydrofurfuryl alcohol methacrylate and production method of flame-retardant storage battery sealing adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105969210A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103834330A (en) * | 2012-11-23 | 2014-06-04 | 湖北回天胶业股份有限公司 | Flame retardant acrylate adhesive |
-
2016
- 2016-06-29 CN CN201610487845.7A patent/CN105969210A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103834330A (en) * | 2012-11-23 | 2014-06-04 | 湖北回天胶业股份有限公司 | Flame retardant acrylate adhesive |
Non-Patent Citations (2)
| Title |
|---|
| 李子东等: "《现代胶粘技术手册》", 31 January 2002 * |
| 王慎敏: "《胶黏剂合成、配方设计与配方实例》", 30 June 2003 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101985550A (en) | One-component room temperature vulcanizing silicone fireproof sealant and preparation method thereof | |
| CN101575493B (en) | Bi-component polysulfide fireproofing flame retardant sealant and preparation method thereof | |
| CN109666446A (en) | A kind of flame-retardant modified silicone sealant and preparation method thereof | |
| CN104927362A (en) | Flame-retardant ceramization silicon rubber and preparation method | |
| CN103396759B (en) | A kind of desulfuration chimney inner wall anti-corrosive organic silicon adhesive and method for formulating thereof | |
| CN103497431B (en) | Oversheath of flame retardant cable and preparation method thereof | |
| CN103333653A (en) | Antiflaming one-component modified silane polyether sealant and preparation method thereof | |
| CN102277125B (en) | Flame-retardant polysulfide sealant and preparation method thereof | |
| CN104109504A (en) | Deeply-cured ketoxime type single-component room-temperature vulcanized silicon rubber and preparation method thereof | |
| CN1333035C (en) | Single component mildew-proof flame retarded organic silicon sealing agent for machinery and preparation process thereof | |
| CN110577708A (en) | Modified floating bead/graphene oxide flame-retardant runway particle material | |
| CN102432405B (en) | Low density explosive and preparation method thereof | |
| CN105969210A (en) | Flame-retardant storage battery sealing adhesive based on isobornyl methacrylate and tetrahydrofurfuryl alcohol methacrylate and production method of flame-retardant storage battery sealing adhesive | |
| CN105969213A (en) | Flame-retardant storage battery sealing adhesive based on vinyl toluene and neopentyl glycol dimethacrylate and production method of flame-retardant storage battery sealing adhesive | |
| CN105950086A (en) | Flame-retardant storage battery sealant based on diester and cyclohexyl and making method of flame-retardant storage battery sealant | |
| CN105969212A (en) | Glycol diester and cyclohexyl ester based flame-retardant sealant for storage batteries and manufacturing method of glycol diester and cyclohexyl ester based flame-retardant sealant | |
| CN105969214A (en) | Vinyltoluene and ethyl ester based flame-retardant sealant for storage batteries and manufacturing method of vinyltoluene and ethyl ester based flame-retardant sealant | |
| CN105969211A (en) | Flame-retardant storage battery sealing adhesive based on lauryl methacrylate and tridecyl methacrylate and production method of flame-retardant storage battery sealing adhesive | |
| CN102838799A (en) | Special cable material | |
| CN106085258A (en) | A kind of flame-retardant storage battery fluid sealant based on acrylic acid methyl ester. and acrylamide and manufacture method | |
| CN105969209A (en) | Hydroxypropyl ester and ethyl ester based flame-retardant sealant for storage batteries and manufacturing method of hydroxypropyl and ethyl ester based flame-retardant sealant | |
| CN106047189A (en) | Flame retardant accumulator sealant based on glyceride and tridecyl ester and preparation method | |
| CN106497457A (en) | A kind of polystyrene gluing agent and preparation method thereof | |
| CN105969268A (en) | Flame-retardant storage battery sealing adhesive based on iso-Octyl methacrylate and dimethylamino ethyl methacrylate and production method of flame-retardant storage battery sealing adhesive | |
| CN106047188A (en) | Flame-retardant storage battery sealant based on propane triester and glyceride and manufacturing method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160928 |
|
| WD01 | Invention patent application deemed withdrawn after publication |