CN105969268A - Flame-retardant storage battery sealing adhesive based on iso-Octyl methacrylate and dimethylamino ethyl methacrylate and production method of flame-retardant storage battery sealing adhesive - Google Patents
Flame-retardant storage battery sealing adhesive based on iso-Octyl methacrylate and dimethylamino ethyl methacrylate and production method of flame-retardant storage battery sealing adhesive Download PDFInfo
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- CN105969268A CN105969268A CN201610487924.8A CN201610487924A CN105969268A CN 105969268 A CN105969268 A CN 105969268A CN 201610487924 A CN201610487924 A CN 201610487924A CN 105969268 A CN105969268 A CN 105969268A
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- storage battery
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 43
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 238000003860 storage Methods 0.000 title claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 239000012945 sealing adhesive Substances 0.000 title abstract 6
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 title abstract 3
- NQSLZEHVGKWKAY-UHFFFAOYSA-N 6-methylheptyl 2-methylprop-2-enoate Chemical compound CC(C)CCCCCOC(=O)C(C)=C NQSLZEHVGKWKAY-UHFFFAOYSA-N 0.000 title abstract 3
- 239000002904 solvent Substances 0.000 claims abstract description 48
- -1 polyethylene Polymers 0.000 claims abstract description 34
- 239000012763 reinforcing filler Substances 0.000 claims abstract description 26
- 229920001971 elastomer Polymers 0.000 claims abstract description 23
- 239000010445 mica Substances 0.000 claims abstract description 23
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 23
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims abstract description 23
- 239000004014 plasticizer Substances 0.000 claims abstract description 23
- 239000000843 powder Substances 0.000 claims abstract description 23
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 22
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229920000570 polyether Polymers 0.000 claims abstract description 22
- MFWFDRBPQDXFRC-LNTINUHCSA-N (z)-4-hydroxypent-3-en-2-one;vanadium Chemical compound [V].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O MFWFDRBPQDXFRC-LNTINUHCSA-N 0.000 claims abstract description 18
- 238000004898 kneading Methods 0.000 claims abstract description 5
- 239000004698 Polyethylene Substances 0.000 claims abstract description 4
- 229920000573 polyethylene Polymers 0.000 claims abstract description 4
- 150000002148 esters Chemical class 0.000 claims description 35
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 22
- 150000001875 compounds Chemical class 0.000 claims description 22
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 claims description 22
- 229920002681 hypalon Polymers 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 18
- SIXWIUJQBBANGK-UHFFFAOYSA-N 4-(4-fluorophenyl)-1h-pyrazol-5-amine Chemical compound N1N=CC(C=2C=CC(F)=CC=2)=C1N SIXWIUJQBBANGK-UHFFFAOYSA-N 0.000 claims description 15
- 125000004494 ethyl ester group Chemical group 0.000 claims description 15
- 239000000565 sealant Substances 0.000 claims description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 230000018044 dehydration Effects 0.000 claims description 12
- 238000006297 dehydration reaction Methods 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 12
- 239000012530 fluid Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- MJKYCJBIICJHRD-UHFFFAOYSA-N pentane-2,4-dione;vanadium Chemical compound [V].CC(=O)CC(C)=O MJKYCJBIICJHRD-UHFFFAOYSA-N 0.000 claims description 4
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical class CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 claims description 3
- 239000004677 Nylon Substances 0.000 claims description 3
- 239000008119 colloidal silica Substances 0.000 claims description 3
- 239000003517 fume Substances 0.000 claims description 3
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 claims description 3
- 229920001778 nylon Polymers 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000000853 adhesive Substances 0.000 abstract description 6
- 230000001070 adhesive effect Effects 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 2
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 abstract 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 abstract 1
- 238000009413 insulation Methods 0.000 abstract 1
- 230000007423 decrease Effects 0.000 description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 4
- 238000004382 potting Methods 0.000 description 3
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 239000002341 toxic gas Substances 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/06—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/08—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/183—Sealing members
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a flame-retardant storage battery sealing adhesive based on iso-Octyl methacrylate and dimethylamino ethyl methacrylate and a production method of the flame-retardant storage battery sealing adhesive. The flame-retardant storage battery sealing adhesive comprises a component A and a component B, wherein the component A comprises the iso-Octyl methacrylate, solvent, di-iso-decylphthalate, deca-brominated diphenyl ether, reinforcing filler, IrgastabPUR68 and polyether rubber; the component B comprises the dimethylamino ethyl methacrylate, chlorosulphonated polyethylene, vanadium acetylacetonate, phosphonate type flame-retardant plasticizer, mica powder, solvent, BYK-065 and butyl titanate. The adhesive of the component A and the adhesive of the component B are respectively prepared by vacuum kneading and mixing in a reaction kettle. The flame-retardant storage battery sealing adhesive has the advantages that by the reasonable proportion of the raw materials of the component A and the component B, the component A and the component B can be well adhered to each other during use, the generation of internal bubbles is reduced, gaps in the adhesive are reduced, good fire resistance and thermal insulation performance are achieved, the original flowability of the adhesive is guaranteed, and the discharge of harmful substances is reduced.
Description
Technical field
The present invention relates to chemical technology field, particularly to accumulator is played the one of sealing function based on different monooctyl ester with
The flame-retardant storage battery fluid sealant of ethyl ester and manufacture method.
Background technology
Macromolecular material is increasingly extensive in building material industry application, but macromolecular material itself easily burns, when fire is sent out
Time raw, burning discharges substantial amounts of toxic gas, such as carbon monoxide, nitric oxide etc., people just can be made in very short time to be poisoned
Dead.Great mass of data shows, toxic smoke is the first of causing death the big killer in fire.Thus the fire resistance of construction material is direct
It is related to the people's lives and property safety.And the halogen flame that flame retardant sealant adds in a large number now can be given birth in combustion
Become the toxic gas such as substantial amounts of hydrogen halides, and bittern-free flame-proof material, magnesium hydroxide, aluminium hydroxide flame retardant effect poor, addition
Greatly, material property is had a strong impact on.Simultaneously because add substantial amounts of fire retardant, cause the mobility of fluid sealant to decline, be difficult to immerse
Narrow and small filleting, makes troubles to construction.
Summary of the invention
It is an object of the invention to provide one to have and decrease glue internal clearance, add simultaneously good fire protecting performance and every
Hot property, it is ensured that the original mobility of adhesive, decreases the one of discharge of harmful substance based on different monooctyl ester and ethyl ester
Flame-retardant storage battery fluid sealant and manufacture method, solve accumulator sealant use needs of problems.
In order to achieve the above object, the present invention provides following technical scheme:
A kind of flame-retardant storage battery fluid sealant based on different monooctyl ester Yu ethyl ester, it is characterised in that: include component A and B component；Described
Component A by the different monooctyl ester of methylacrylic acid, solvent, diisooctyl phthalate, decabromodiphenyl oxide, reinforcing filler,
IrgastabPUR68, polyether rubber forms；B component is by dimethylaminoethyl ethyl ester, chlorosulfonated polyethylene, acetyl
Acetone vanadium, Phosphonate Flame Retardant plasticizer, mica powder, solvent, BYK-065, butyl titanate forms；In wherein said component A, bag
Include: the different monooctyl ester of methylacrylic acid of 40-60 part, the solvent of 20-30 part, the diisooctyl phthalate of 4-8 part, 10-25 part
Decabromodiphenyl oxide, the reinforcing filler of 5-10 part, the IrgastabPUR68 of 5-10 part, 20-35 part polyether rubber composition；
In described B component, including: the dimethylaminoethyl ethyl ester of 60-80 part, the chlorosulfonated polyethylene of 20-30 part, 5-15
The vanadium acetylacetonate of part, the Phosphonate Flame Retardant plasticizer of 5-15 part, the mica powder of 5-10 part, 25-40 part solvent, 10-15 part
The butyl titanate of BYK-065,4-10 part.
Described solvent is in acetone, chloroform, dichloroethanes, nylon acid dimethyl ester, ethyl acetate, toluene or dimethylbenzene
One or more；Reinforcing filler be fume colloidal silica, precipitated silica and surface process the one in white carbon or
Several.
In described component A, including: the different monooctyl ester of methylacrylic acid of 40-55 part, the solvent of 20-28 part, the adjacent benzene of 4-7 part
Dioctyl phthalate two isodecyl ester, the decabromodiphenyl oxide of 10-22 part, the reinforcing filler of 5-8 part, the IrgastabPUR68 of 5-9 part, 20-
The polyether rubber composition of 33 parts；In described B component, including: the dimethylaminoethyl ethyl ester of 60-78 part, 20-25 part
Chlorosulfonated polyethylene, the vanadium acetylacetonate of 5-12 part, the Phosphonate Flame Retardant plasticizer of 5-13 part, the mica powder of 5-8 part, 25-
The solvent of 35 parts, the butyl titanate of the BYK-065 of 10-14 part, 4-8 part.
In described component A, including: the different monooctyl ester of methylacrylic acid of 50 parts, the solvent of 25 parts, the phthalic acid two of 6 parts
Isodecyl ester, the decabromodiphenyl oxide of 22 parts, the reinforcing filler of 8 parts, the IrgastabPUR68 of 8 parts, the polyether rubber group of 28 parts
Become；In described B component, including: the dimethylaminoethyl ethyl ester of 70 parts, the chlorosulfonated polyethylene of 25 parts, 10 parts
Vanadium acetylacetonate, the Phosphonate Flame Retardant plasticizer of 10 parts, the mica powder of 8 parts, the solvent of 35 parts, the BYK-065 of 13 parts, 8 parts
Butyl titanate.
Concretely comprise the following steps:
1, by different for methylacrylic acid in component A monooctyl ester, solvent, diisooctyl phthalate, polyether rubber is according to above-mentioned weight
Number proportioning mode adds in vacuum kneader, and in temperature 70～100 DEG C, vacuum is 0.08～0.12MPa, dehydration is blended 60
～300 minutes, prepare A group compound, move in high speed dispersion stirred tank, standby；By dimethylaminoethyl in B component
Ethyl ester, chlorosulfonated polyethylene, Phosphonate Flame Retardant plasticizer, solvent adds vacuum kneading according to above-mentioned parts by weight proportioning mode
In machine, in temperature 70～100 DEG C, vacuum is 0.08～0.12MPa, dehydration is blended 60～300 minutes, prepares B group compound,
Move in high speed dispersion stirred tank, standby；
2, at room temperature, will add decabromodiphenyl oxide in above-mentioned A group compound, reinforcing filler, IrgastabPUR68 is placed in and stirs
Mixing in still, vacuum is 0.08～0.12MPa, rotating speed 100～600rpm, is sufficiently mixed 1～5 hour, prepares A group and is thoroughly mixed
Material；To add vanadium acetylacetonate in above-mentioned B group compound, mica powder, BYK-065, butyl titanate is placed in stirred tank, vacuum
Be 0.08～0.12MPa, rotating speed 100～600rpm, be sufficiently mixed 1～5 hour, prepare B group be thoroughly mixed material.
Beneficial effects of the present invention: the present invention, by the raw material in A, B component is carried out rational proportioning, makes two kinds of components
Bonding that in use can be good, and reduce the generation of air entrapment, decrease glue internal clearance, add simultaneously
Good fire protecting performance and heat-proof quality, it is ensured that the original mobility of adhesive, decrease the discharge of harmful substance.
Detailed description of the invention
Below in conjunction with embodiment, technical scheme is clearly and completely described, it is clear that described
Embodiment is only a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, this area
The every other embodiment that those of ordinary skill is obtained under not making creative work premise, broadly falls into present invention protection
Scope.
Embodiment 1:
A kind of flame-retardant storage battery fluid sealant based on different monooctyl ester Yu ethyl ester, it is characterised in that: include component A and B component；Described
Component A by the different monooctyl ester of methylacrylic acid, solvent, diisooctyl phthalate, decabromodiphenyl oxide, reinforcing filler,
IrgastabPUR68, polyether rubber forms；B component is by dimethylaminoethyl ethyl ester, chlorosulfonated polyethylene, acetyl
Acetone vanadium, Phosphonate Flame Retardant plasticizer, mica powder, solvent, BYK-065, butyl titanate forms；In wherein said component A, bag
Include: the different monooctyl ester of methylacrylic acid of 40-60 part, the solvent of 20-30 part, the diisooctyl phthalate of 4-8 part, 10-25 part
Decabromodiphenyl oxide, the reinforcing filler of 5-10 part, the IrgastabPUR68 of 5-10 part, 20-35 part polyether rubber composition；
In described B component, including: the dimethylaminoethyl ethyl ester of 60-80 part, the chlorosulfonated polyethylene of 20-30 part, 5-15
The vanadium acetylacetonate of part, the Phosphonate Flame Retardant plasticizer of 5-15 part, the mica powder of 5-10 part, 25-40 part solvent, 10-15 part
The butyl titanate of BYK-065,4-10 part.
Described solvent is in acetone, chloroform, dichloroethanes, nylon acid dimethyl ester, ethyl acetate, toluene or dimethylbenzene
One or more；Reinforcing filler be fume colloidal silica, precipitated silica and surface process the one in white carbon or
Several.
In described component A, including: the different monooctyl ester of methylacrylic acid of 40-55 part, the solvent of 20-28 part, the adjacent benzene of 4-7 part
Dioctyl phthalate two isodecyl ester, the decabromodiphenyl oxide of 10-22 part, the reinforcing filler of 5-8 part, the IrgastabPUR68 of 5-9 part, 20-
The polyether rubber composition of 33 parts；In described B component, including: the dimethylaminoethyl ethyl ester of 60-78 part, 20-25 part
Chlorosulfonated polyethylene, the vanadium acetylacetonate of 5-12 part, the Phosphonate Flame Retardant plasticizer of 5-13 part, the mica powder of 5-8 part, 25-
The solvent of 35 parts, the butyl titanate of the BYK-065 of 10-14 part, 4-8 part.
In described component A, including: the different monooctyl ester of methylacrylic acid of 50 parts, the solvent of 25 parts, the phthalic acid two of 6 parts
Isodecyl ester, the decabromodiphenyl oxide of 22 parts, the reinforcing filler of 8 parts, the IrgastabPUR68 of 8 parts, the polyether rubber group of 28 parts
Become；In described B component, including: the dimethylaminoethyl ethyl ester of 70 parts, the chlorosulfonated polyethylene of 25 parts, 10 parts
Vanadium acetylacetonate, the Phosphonate Flame Retardant plasticizer of 10 parts, the mica powder of 8 parts, the solvent of 35 parts, the BYK-065 of 13 parts, 8 parts
Butyl titanate.
Concretely comprise the following steps:
1, by different for methylacrylic acid in component A monooctyl ester, solvent, diisooctyl phthalate, polyether rubber is according to above-mentioned weight
Number proportioning mode adds in vacuum kneader, and in temperature 70～100 DEG C, vacuum is 0.08～0.12MPa, dehydration is blended 60
～300 minutes, prepare A group compound, move in high speed dispersion stirred tank, standby；By dimethylaminoethyl in B component
Ethyl ester, chlorosulfonated polyethylene, Phosphonate Flame Retardant plasticizer, solvent adds vacuum kneading according to above-mentioned parts by weight proportioning mode
In machine, in temperature 70～100 DEG C, vacuum is 0.08～0.12MPa, dehydration is blended 60～300 minutes, prepares B group compound,
Move in high speed dispersion stirred tank, standby；
2, at room temperature, will add decabromodiphenyl oxide in above-mentioned A group compound, reinforcing filler, IrgastabPUR68 is placed in and stirs
Mixing in still, vacuum is 0.08～0.12MPa, rotating speed 100～600rpm, is sufficiently mixed 1～5 hour, prepares A group and is thoroughly mixed
Material；To add vanadium acetylacetonate in above-mentioned B group compound, mica powder, BYK-065, butyl titanate is placed in stirred tank, vacuum
Be 0.08～0.12MPa, rotating speed 100～600rpm, be sufficiently mixed 1～5 hour, prepare B group be thoroughly mixed material.
Embodiment 2:
A kind of flame-retardant storage battery fluid sealant based on different monooctyl ester Yu ethyl ester, it is characterised in that: include component A and B component；Described
Component A by the different monooctyl ester of methylacrylic acid, solvent, diisooctyl phthalate, decabromodiphenyl oxide, reinforcing filler,
IrgastabPUR68, polyether rubber forms；B component is by dimethylaminoethyl ethyl ester, chlorosulfonated polyethylene, acetyl
Acetone vanadium, Phosphonate Flame Retardant plasticizer, mica powder, solvent, BYK-065, butyl titanate forms；In wherein said component A, bag
Include: the different monooctyl ester of methylacrylic acid of 40-60 part, the solvent of 20-30 part, the diisooctyl phthalate of 4-8 part, 10-25 part
Decabromodiphenyl oxide, the reinforcing filler of 5-10 part, the IrgastabPUR68 of 5-10 part, 20-35 part polyether rubber composition；
In described B component, including: the dimethylaminoethyl ethyl ester of 60-80 part, the chlorosulfonated polyethylene of 20-30 part, 5-15
The vanadium acetylacetonate of part, the Phosphonate Flame Retardant plasticizer of 5-15 part, the mica powder of 5-10 part, 25-40 part solvent, 10-15 part
The butyl titanate of BYK-065,4-10 part.
Following manufacture method is utilized to make the proportioning in above-mentioned component:
1, by different for methylacrylic acid in component A monooctyl ester, solvent, diisooctyl phthalate, polyether rubber is according to above-mentioned weight
Number proportioning mode adds in vacuum kneader, and in temperature 70～100 DEG C, vacuum is 0.08～0.12MPa, dehydration is blended 60
～300 minutes, prepare A group compound, move in high speed dispersion stirred tank, standby；By dimethylaminoethyl in B component
Ethyl ester, chlorosulfonated polyethylene, Phosphonate Flame Retardant plasticizer, solvent adds vacuum kneading according to above-mentioned parts by weight proportioning mode
In machine, in temperature 70～100 DEG C, vacuum is 0.08～0.12MPa, dehydration is blended 60～300 minutes, prepares B group compound,
Move in high speed dispersion stirred tank, standby；
2, at room temperature, will add decabromodiphenyl oxide in above-mentioned A group compound, reinforcing filler, IrgastabPUR68 is placed in and stirs
Mixing in still, vacuum is 0.08～0.12MPa, rotating speed 100～600rpm, is sufficiently mixed 1～5 hour, prepares A group and is thoroughly mixed
Material；To add vanadium acetylacetonate in above-mentioned B group compound, mica powder, BYK-065, butyl titanate is placed in stirred tank, vacuum
Be 0.08～0.12MPa, rotating speed 100～600rpm, be sufficiently mixed 1～5 hour, prepare B group be thoroughly mixed material.
Component A and B component stand subpackage respectively, during use directly by component A, B component according to weight ratio mix homogeneously after
Potting operation can be carried out.
Following table is the Data Comparison of the present invention and other series products:
Upper table shows that the properties of the present invention is better than like product, can meet the process requirements that accumulator seals.
Embodiment 3:
In described component A, including: the different monooctyl ester of methylacrylic acid of 40-55 part, the solvent of 20-28 part, the O-phthalic of 4-7 part
Acid two isodecyl esters, the decabromodiphenyl oxide of 10-22 part, the reinforcing filler of 5-8 part, the IrgastabPUR68 of 5-9 part, 20-33 part
Polyether rubber composition；In described B component, including: the dimethylaminoethyl ethyl ester of 60-78 part, the chlorine of 20-25 part
Sulfonated polyethylene, the vanadium acetylacetonate of 5-12 part, the Phosphonate Flame Retardant plasticizer of 5-13 part, the mica powder of 5-8 part, 25-35 part
Solvent, the butyl titanate of the BYK-065 of 10-14 part, 4-8 part.
Following manufacture method is utilized to make the proportioning in above-mentioned component:
1, by different for methylacrylic acid in component A monooctyl ester, solvent, diisooctyl phthalate, polyether rubber is according to above-mentioned weight
Number proportioning mode adds in vacuum kneader, and in temperature 100 DEG C, vacuum is 0.12MPa, dehydration is blended 300 minutes, prepares
A group compound, moves in high speed dispersion stirred tank, standby；By dimethylaminoethyl ethyl ester in B component, chlorosulfonation
Polyethylene, Phosphonate Flame Retardant plasticizer, solvent adds in vacuum kneader, in temperature according to above-mentioned parts by weight proportioning mode
100 DEG C, vacuum is 0.12MPa, dehydration is blended 300 minutes, prepares B group compound, moves in high speed dispersion stirred tank, standby
With；
2, at room temperature, will add decabromodiphenyl oxide in above-mentioned A group compound, reinforcing filler, IrgastabPUR68 is placed in and stirs
Mixing in still, vacuum is 0.12MPa, rotating speed 600rpm, is sufficiently mixed 5 hours, prepares A group and is thoroughly mixed material；Above-mentioned B group is mixed
Closing and add vanadium acetylacetonate in material, mica powder, BYK-065, butyl titanate is placed in stirred tank, and vacuum is 0.12MPa, rotating speed
600rpm, is sufficiently mixed 5 hours, prepares B group and is thoroughly mixed material.
Component A and B component stand subpackage respectively, during use directly by component A, B component according to weight ratio mix homogeneously after
Potting operation can be carried out.
Embodiment 4:
In described component A, including: the different monooctyl ester of methylacrylic acid of 50 parts, the solvent of 25 parts, phthalic acid two isodecyl of 6 parts
Ester, the decabromodiphenyl oxide of 22 parts, the reinforcing filler of 8 parts, the IrgastabPUR68 of 8 parts, the polyether rubber composition of 28 parts；Institute
State in B component, including: the dimethylaminoethyl ethyl ester of 70 parts, the chlorosulfonated polyethylene of 25 parts, the levulinic of 10 parts
Ketone vanadium, the Phosphonate Flame Retardant plasticizer of 10 parts, the mica powder of 8 parts, the solvent of 35 parts, the BYK-065 of 13 parts, the metatitanic acid fourth of 8 parts
Ester.
Following manufacture method is utilized to make the proportioning in above-mentioned component:
1, by different for methylacrylic acid in component A monooctyl ester, solvent, diisooctyl phthalate, polyether rubber is according to above-mentioned weight
Number proportioning mode adds in vacuum kneader, and in temperature 70 C, vacuum is 0.08MPa, dehydration is blended 60 minutes, prepares A
Group compound, moves in high speed dispersion stirred tank, standby；By dimethylaminoethyl ethyl ester in B component, chlorosulfonation is gathered
Ethylene, Phosphonate Flame Retardant plasticizer, solvent adds in vacuum kneader, in temperature 70 according to above-mentioned parts by weight proportioning mode
DEG C, vacuum is 0.08MPa, dehydration is blended 60 minutes, prepares B group compound, moves in high speed dispersion stirred tank, standby；
2, at room temperature, will add decabromodiphenyl oxide in above-mentioned A group compound, reinforcing filler, IrgastabPUR68 is placed in and stirs
Mixing in still, vacuum is 0.08MPa, rotating speed 100rpm, is sufficiently mixed 5 hours, prepares A group and is thoroughly mixed material；Above-mentioned B group is mixed
Closing and add vanadium acetylacetonate in material, mica powder, BYK-065, butyl titanate is placed in stirred tank, and vacuum is 0.08MPa, rotating speed
100rpm, is sufficiently mixed 5 hours, prepares B group and is thoroughly mixed material.
Component A and B component stand subpackage respectively, during use directly by component A, B component according to weight ratio mix homogeneously after
Potting operation can be carried out.
The above, the only detailed description of the invention of the present invention, but protection scope of the present invention is not limited thereto, and any
Those familiar with the art, in the technical scope that the invention discloses, can readily occur in change or replace, should contain
Cover within protection scope of the present invention.Therefore, protection scope of the present invention should described be as the criterion with scope of the claims.
Claims (5)
1. a flame-retardant storage battery fluid sealant based on different monooctyl ester Yu ethyl ester, it is characterised in that: include component A and B component；Institute
State component A by the different monooctyl ester of methylacrylic acid, solvent, diisooctyl phthalate, decabromodiphenyl oxide, reinforcing filler,
IrgastabPUR68, polyether rubber forms；B component is by dimethylaminoethyl ethyl ester, chlorosulfonated polyethylene, acetyl
Acetone vanadium, Phosphonate Flame Retardant plasticizer, mica powder, solvent, BYK-065, butyl titanate forms；In wherein said component A, bag
Include: the different monooctyl ester of methylacrylic acid of 40-60 part, the solvent of 20-30 part, the diisooctyl phthalate of 4-8 part, 10-25 part
Decabromodiphenyl oxide, the reinforcing filler of 5-10 part, the IrgastabPUR68 of 5-10 part, 20-35 part polyether rubber composition；
In described B component, including: the dimethylaminoethyl ethyl ester of 60-80 part, the chlorosulfonated polyethylene of 20-30 part, 5-15
The vanadium acetylacetonate of part, the Phosphonate Flame Retardant plasticizer of 5-15 part, the mica powder of 5-10 part, 25-40 part solvent, 10-15 part
The butyl titanate of BYK-065,4-10 part.
A kind of flame-retardant storage battery fluid sealant based on different monooctyl ester Yu ethyl ester the most according to claim 1, it is characterised in that:
Described solvent be the one in acetone, chloroform, dichloroethanes, nylon acid dimethyl ester, ethyl acetate, toluene or dimethylbenzene or
Several；Reinforcing filler is one or more that fume colloidal silica, precipitated silica and surface process in white carbon.
A kind of flame-retardant storage battery fluid sealant based on different monooctyl ester Yu ethyl ester the most according to claim 1, it is characterised in that:
In described component A, including: the different monooctyl ester of methylacrylic acid of 40-55 part, the solvent of 20-28 part, the phthalic acid two of 4-7 part
Isodecyl ester, the decabromodiphenyl oxide of 10-22 part, the reinforcing filler of 5-8 part, gathering of the IrgastabPUR68 of 5-9 part, 20-33 part
Ether rubber forms；In described B component, including: the dimethylaminoethyl ethyl ester of 60-78 part, the chlorosulfonation of 20-25 part
Polyethylene, the vanadium acetylacetonate of 5-12 part, the Phosphonate Flame Retardant plasticizer of 5-13 part, the mica powder of 5-8 part, 25-35 part molten
Agent, the butyl titanate of the BYK-065 of 10-14 part, 4-8 part.
A kind of flame-retardant storage battery fluid sealant based on different monooctyl ester Yu ethyl ester the most according to claim 1, it is characterised in that:
In described component A, including: the different monooctyl ester of methylacrylic acid of 50 parts, the solvent of 25 parts, the diisooctyl phthalate of 6 parts, 22
The decabromodiphenyl oxide of part, the reinforcing filler of 8 parts, the IrgastabPUR68 of 8 parts, the polyether rubber composition of 28 parts；Described B group
In Fen, including: the dimethylaminoethyl ethyl ester of 70 parts, the chlorosulfonated polyethylene of 25 parts, the vanadium acetylacetonate of 10 parts,
The Phosphonate Flame Retardant plasticizer of 10 parts, the mica powder of 8 parts, the solvent of 35 parts, the BYK-065 of 13 parts, the butyl titanate of 8 parts.
5. according to a kind of based on different monooctyl ester and ethyl ester the flame-retardant storage battery fluid sealant according to any one of claim 1-4
Manufacture method, it is characterised in that: concretely comprise the following steps:
1, by different for methylacrylic acid in component A monooctyl ester, solvent, diisooctyl phthalate, polyether rubber is according to above-mentioned weight
Number proportioning mode adds in vacuum kneader, and in temperature 70～100 DEG C, vacuum is 0.08～0.12MPa, dehydration is blended 60
～300 minutes, prepare A group compound, move in high speed dispersion stirred tank, standby；By dimethylaminoethyl in B component
Ethyl ester, chlorosulfonated polyethylene, Phosphonate Flame Retardant plasticizer, solvent adds vacuum kneading according to above-mentioned parts by weight proportioning mode
In machine, in temperature 70～100 DEG C, vacuum is 0.08～0.12MPa, dehydration is blended 60～300 minutes, prepares B group compound,
Move in high speed dispersion stirred tank, standby；
2, at room temperature, will add decabromodiphenyl oxide in above-mentioned A group compound, reinforcing filler, IrgastabPUR68 is placed in and stirs
Mixing in still, vacuum is 0.08～0.12MPa, rotating speed 100～600rpm, is sufficiently mixed 1～5 hour, prepares A group and is thoroughly mixed
Material；To add vanadium acetylacetonate in above-mentioned B group compound, mica powder, BYK-065, butyl titanate is placed in stirred tank, vacuum
Be 0.08～0.12MPa, rotating speed 100～600rpm, be sufficiently mixed 1～5 hour, prepare B group be thoroughly mixed material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610487924.8A CN105969268A (en) | 2016-06-29 | 2016-06-29 | Flame-retardant storage battery sealing adhesive based on iso-Octyl methacrylate and dimethylamino ethyl methacrylate and production method of flame-retardant storage battery sealing adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610487924.8A CN105969268A (en) | 2016-06-29 | 2016-06-29 | Flame-retardant storage battery sealing adhesive based on iso-Octyl methacrylate and dimethylamino ethyl methacrylate and production method of flame-retardant storage battery sealing adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105969268A true CN105969268A (en) | 2016-09-28 |
Family
ID=57019408
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610487924.8A Pending CN105969268A (en) | 2016-06-29 | 2016-06-29 | Flame-retardant storage battery sealing adhesive based on iso-Octyl methacrylate and dimethylamino ethyl methacrylate and production method of flame-retardant storage battery sealing adhesive |
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| Country | Link |
|---|---|
| CN (1) | CN105969268A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103834330A (en) * | 2012-11-23 | 2014-06-04 | 湖北回天胶业股份有限公司 | Flame retardant acrylate adhesive |
-
2016
- 2016-06-29 CN CN201610487924.8A patent/CN105969268A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103834330A (en) * | 2012-11-23 | 2014-06-04 | 湖北回天胶业股份有限公司 | Flame retardant acrylate adhesive |
Non-Patent Citations (2)
| Title |
|---|
| 李子东: "《现代胶粘技术手册》", 31 January 2002, 新时代出版社 * |
| 王慎敏: "《胶黏剂合成、配方设计与配方实例》", 30 June 2003, 化学工业出版社 * |
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