CN105969213A - Flame-retardant storage battery sealing adhesive based on vinyl toluene and neopentyl glycol dimethacrylate and production method of flame-retardant storage battery sealing adhesive - Google Patents
Flame-retardant storage battery sealing adhesive based on vinyl toluene and neopentyl glycol dimethacrylate and production method of flame-retardant storage battery sealing adhesive Download PDFInfo
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- CN105969213A CN105969213A CN201610487894.0A CN201610487894A CN105969213A CN 105969213 A CN105969213 A CN 105969213A CN 201610487894 A CN201610487894 A CN 201610487894A CN 105969213 A CN105969213 A CN 105969213A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Sealing Material Composition (AREA)
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Abstract
The invention discloses a flame-retardant storage battery sealing adhesive based on vinyl toluene and neopentyl glycol dimethacrylate and a production method of the flame-retardant storage battery sealing adhesive. The flame-retardant storage battery sealing adhesive comprises a component A and a component B, wherein the component A comprises the vinyl toluene, solvent, dioctyl phthalate, iron oxide red, reinforcing filler, Irganox5057 and nitrile butadiene rubber; the component B comprises the neopentyl glycol dimethacrylate, nitrile butadiene rubber, triethylamine, phosphonate type flame-retardant plasticizer, carbon black, solvent, BYK-065 and 1, 2-epoxy ethyoxyl trimethoxy silane. The adhesive of the component A and the adhesive of the component B are respectively prepared by vacuum kneading and mixing in a reaction kettle. The flame-retardant storage battery sealing adhesive has the advantages that by the reasonable proportion of the raw materials of the component A and the component B, the component A and the component B can be well adhered to each other during use, the generation of internal bubbles is reduced, gaps in the adhesive are reduced, good fire resistance and thermal insulation performance are achieved, the original flowability of the adhesive is guaranteed, and the discharge of harmful substances is reduced.
Description
Technical field
The present invention relates to chemical technology field, particularly to a kind of based on vinyltoluene Yu dibasic acid esters the flame-retardant storage battery fluid sealant that accumulator is played sealing function
And manufacture method
。
Background technology
Macromolecular material is increasingly extensive in building material industry application, but macromolecular material itself easily burns, and when fire occurs, burning discharges substantial amounts of toxic gas, such as carbon monoxide, nitric oxide etc., people just can be made in very short time to be poisoned to death.Great mass of data shows, toxic smoke is the first of causing death the big killer in fire.Thus the fire resistance of construction material is directly connected to the people's lives and property safety.And the halogen flame that now flame retardant sealant adds in a large number can generate the toxic gas such as substantial amounts of hydrogen halides in combustion, and bittern-free flame-proof material, magnesium hydroxide, aluminium hydroxide flame retardant effect poor, addition greatly, has a strong impact on material property.Simultaneously because add substantial amounts of fire retardant, cause the mobility of fluid sealant to decline, be difficult to immerse narrow and small filleting, make troubles to construction.
Summary of the invention
It is an object of the invention to provide
One has and decreases glue internal clearance, adds good fire protecting performance and heat-proof quality, it is ensured that the original mobility of adhesive simultaneously, decreases the discharge of harmful substance
A kind of based on vinyltoluene Yu dibasic acid esters flame-retardant storage battery fluid sealant
And manufacture method
, solve the use needs of problems of accumulator sealant.
In order to achieve the above object, the present invention provides following technical scheme:
A kind of flame-retardant storage battery fluid sealant based on vinyltoluene Yu dibasic acid esters, it is characterised in that: include
A
Component and
B
Component；Described
A
Component by vinyltoluene, solvent, dioctyl phthalate, iron oxide red, reinforcing filler,
Irganox5057
, nitrile rubber forms；
B
Component by methacrylic acid neopentyl glycol dibasic acid esters, nitrile rubber, triethylamine, Phosphonate Flame Retardant plasticizer, white carbon black, solvent,
BYK-065
,
1
、
2-
Epoxy ethyoxyl trimethoxy silane forms；Wherein said
A
In component, including:
40-60
The vinyltoluene of part,
20-30
The solvent of part,
4-8
The dioctyl phthalate of part,
10-25
The iron oxide red of part,
5-10
The reinforcing filler of part,
5-10
Part
Irganox5057
,
20-35
The nitrile rubber composition of part；Described
B
In component, including:
60-80
The methacrylic acid neopentyl glycol dibasic acid esters of part,
20-30
The nitrile rubber of part,
5-15
The triethylamine of part,
5-15
The Phosphonate Flame Retardant plasticizer of part,
5-10
The white carbon black of part,
25-40
Part solvent,
10-15
Part
BYK-065
,
4-10
Part
1
、
2-
Epoxy ethyoxyl trimethoxy silane.
Described solvent is one or more in acetone, chloroform, dichloroethanes, nylon acid dimethyl ester, ethyl acetate, toluene or dimethylbenzene；Reinforcing filler is one or more that fume colloidal silica, precipitated silica and surface process in white carbon.
Described
A
In component, including:
40-55
The vinyltoluene of part,
20-28
The solvent of part,
4-7
The dioctyl phthalate of part,
10-22
The iron oxide red of part,
5-8
The reinforcing filler of part,
5-9
Part
Irganox5057
,
20-33
The nitrile rubber composition of part；Described
B
In component, including:
60-78
The methacrylic acid neopentyl glycol dibasic acid esters of part,
20-25
The nitrile rubber of part,
5-12
The triethylamine of part,
5-13
The Phosphonate Flame Retardant plasticizer of part,
5-8
The white carbon black of part,
25-35
The solvent of part,
10-14
Part
BYK-065
,
4-8
Part
1
、
2-
Epoxy ethyoxyl trimethoxy silane.
Described
A
In component, including:
50
The vinyltoluene of part,
25
The solvent of part,
6
The dioctyl phthalate of part,
22
The iron oxide red of part,
8
The reinforcing filler of part,
8
Part
Irganox5057
,
28
The nitrile rubber composition of part；Described
B
In component, including:
70
The methacrylic acid neopentyl glycol dibasic acid esters of part,
25
The nitrile rubber of part,
10
The triethylamine of part,
10
The Phosphonate Flame Retardant plasticizer of part,
8
The white carbon black of part,
35
The solvent of part,
13
Part
BYK-065
,
8
Part
1
、
2-
Epoxy ethyoxyl trimethoxy silane.
Concretely comprise the following steps:
1
, will
A
Component medium vinyl toluene, solvent, dioctyl phthalate, nitrile rubber adds in vacuum kneader, in temperature according to above-mentioned parts by weight proportioning mode
70
~
100
℃
, vacuum is
0.08
~
0.12MPa
, dehydration be blended
60
~
300
Minute, prepare
A
Group compound, moves in high speed dispersion stirred tank, standby；Will
B
Methacrylic acid neopentyl glycol dibasic acid esters in component, nitrile rubber, Phosphonate Flame Retardant plasticizer, solvent adds in vacuum kneader, in temperature according to above-mentioned parts by weight proportioning mode
70
~
100
℃
, vacuum is
0.08
~
0.12MPa
, dehydration be blended
60
~
300
Minute, prepare
B
Group compound, moves in high speed dispersion stirred tank, standby；
2
, at room temperature, by above-mentioned
A
Addition iron oxide red in group compound, reinforcing filler,
Irganox5057
Being placed in stirred tank, vacuum is
0.08
~
0.12MPa
, rotating speed
100
~
600rpm
, it is sufficiently mixed
1
~
5
Hour, prepare
A
Group is thoroughly mixed material；By above-mentioned
B
Addition triethylamine in group compound, white carbon black,
BYK-065
,
1
、
2-
Epoxy ethyoxyl trimethoxy silane is placed in stirred tank, and vacuum is
0.08
~
0.12MPa
, rotating speed
100
~
600rpm
, it is sufficiently mixed
1
~
5
Hour, prepare
B
Group is thoroughly mixed material.
Beneficial effects of the present invention: the present invention
By the raw material in A, B component is carried out rational proportioning, make the bonding that two kinds of components in use can be good, and reduce the generation of air entrapment, decrease glue internal clearance, add good fire protecting performance and heat-proof quality simultaneously, ensure that the original mobility of adhesive, decrease the discharge of harmful substance
。
Detailed description of the invention
Below in conjunction with embodiment, technical scheme is clearly and completely described, it is clear that described embodiment is only a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, the every other embodiment that those of ordinary skill in the art are obtained under not making creative work premise, broadly fall into the scope of protection of the invention.
Embodiment
1
:
A kind of flame-retardant storage battery fluid sealant based on vinyltoluene Yu dibasic acid esters, it is characterised in that: include
A
Component and
B
Component；Described
A
Component by vinyltoluene, solvent, dioctyl phthalate, iron oxide red, reinforcing filler,
Irganox5057
, nitrile rubber forms；
B
Component by methacrylic acid neopentyl glycol dibasic acid esters, nitrile rubber, triethylamine, Phosphonate Flame Retardant plasticizer, white carbon black, solvent,
BYK-065
,
1
、
2-
Epoxy ethyoxyl trimethoxy silane forms；Wherein said
A
In component, including:
40-60
The vinyltoluene of part,
20-30
The solvent of part,
4-8
The dioctyl phthalate of part,
10-25
The iron oxide red of part,
5-10
The reinforcing filler of part,
5-10
Part
Irganox5057
,
20-35
The nitrile rubber composition of part；Described
B
In component, including:
60-80
The methacrylic acid neopentyl glycol dibasic acid esters of part,
20-30
The nitrile rubber of part,
5-15
The triethylamine of part,
5-15
The Phosphonate Flame Retardant plasticizer of part,
5-10
The white carbon black of part,
25-40
Part solvent,
10-15
Part
BYK-065
,
4-10
Part
1
、
2-
Epoxy ethyoxyl trimethoxy silane.
Described solvent is one or more in acetone, chloroform, dichloroethanes, nylon acid dimethyl ester, ethyl acetate, toluene or dimethylbenzene；Reinforcing filler is one or more that fume colloidal silica, precipitated silica and surface process in white carbon.
Described
A
In component, including:
40-55
The vinyltoluene of part,
20-28
The solvent of part,
4-7
The dioctyl phthalate of part,
10-22
The iron oxide red of part,
5-8
The reinforcing filler of part,
5-9
Part
Irganox5057
,
20-33
The nitrile rubber composition of part；Described
B
In component, including:
60-78
The methacrylic acid neopentyl glycol dibasic acid esters of part,
20-25
The nitrile rubber of part,
5-12
The triethylamine of part,
5-13
The Phosphonate Flame Retardant plasticizer of part,
5-8
The white carbon black of part,
25-35
The solvent of part,
10-14
Part
BYK-065
,
4-8
Part
1
、
2-
Epoxy ethyoxyl trimethoxy silane.
Described
A
In component, including:
50
The vinyltoluene of part,
25
The solvent of part,
6
The dioctyl phthalate of part,
22
The iron oxide red of part,
8
The reinforcing filler of part,
8
Part
Irganox5057
,
28
The nitrile rubber composition of part；Described
B
In component, including:
70
The methacrylic acid neopentyl glycol dibasic acid esters of part,
25
The nitrile rubber of part,
10
The triethylamine of part,
10
The Phosphonate Flame Retardant plasticizer of part,
8
The white carbon black of part,
35
The solvent of part,
13
Part
BYK-065
,
8
Part
1
、
2-
Epoxy ethyoxyl trimethoxy silane.
Concretely comprise the following steps:
1
, will
A
Component medium vinyl toluene, solvent, dioctyl phthalate, nitrile rubber adds in vacuum kneader, in temperature according to above-mentioned parts by weight proportioning mode
70
~
100
℃
, vacuum is
0.08
~
0.12MPa
, dehydration be blended
60
~
300
Minute, prepare
A
Group compound, moves in high speed dispersion stirred tank, standby；Will
B
Methacrylic acid neopentyl glycol dibasic acid esters in component, nitrile rubber, Phosphonate Flame Retardant plasticizer, solvent adds in vacuum kneader, in temperature according to above-mentioned parts by weight proportioning mode
70
~
100
℃
, vacuum is
0.08
~
0.12MPa
, dehydration be blended
60
~
300
Minute, prepare
B
Group compound, moves in high speed dispersion stirred tank, standby；
2
, at room temperature, by above-mentioned
A
Addition iron oxide red in group compound, reinforcing filler,
Irganox5057
Being placed in stirred tank, vacuum is
0.08
~
0.12MPa
, rotating speed
100
~
600rpm
, it is sufficiently mixed
1
~
5
Hour, prepare
A
Group is thoroughly mixed material；By above-mentioned
B
Addition triethylamine in group compound, white carbon black,
BYK-065
,
1
、
2-
Epoxy ethyoxyl trimethoxy silane is placed in stirred tank, and vacuum is
0.08
~
0.12MPa
, rotating speed
100
~
600rpm
, it is sufficiently mixed
1
~
5
Hour, prepare
B
Group is thoroughly mixed material.
Embodiment
2
:
A kind of flame-retardant storage battery fluid sealant based on vinyltoluene Yu dibasic acid esters, it is characterised in that: include
A
Component and
B
Component；Described
A
Component by vinyltoluene, solvent, dioctyl phthalate, iron oxide red, reinforcing filler,
Irganox5057
, nitrile rubber forms；
B
Component by methacrylic acid neopentyl glycol dibasic acid esters, nitrile rubber, triethylamine, Phosphonate Flame Retardant plasticizer, white carbon black, solvent,
BYK-065
,
1
、
2-
Epoxy ethyoxyl trimethoxy silane forms；Wherein said
A
In component, including:
40-60
The vinyltoluene of part,
20-30
The solvent of part,
4-8
The dioctyl phthalate of part,
10-25
The iron oxide red of part,
5-10
The reinforcing filler of part,
5-10
Part
Irganox5057
,
20-35
The nitrile rubber composition of part；Described
B
In component, including:
60-80
The methacrylic acid neopentyl glycol dibasic acid esters of part,
20-30
The nitrile rubber of part,
5-15
The triethylamine of part,
5-15
The Phosphonate Flame Retardant plasticizer of part,
5-10
The white carbon black of part,
25-40
Part solvent,
10-15
Part
BYK-065
,
4-10
Part
1
、
2-
Epoxy ethyoxyl trimethoxy silane.
Following manufacture method is utilized to make the proportioning in above-mentioned component:
1
, will
A
Component medium vinyl toluene, solvent, dioctyl phthalate, nitrile rubber adds in vacuum kneader, in temperature according to above-mentioned parts by weight proportioning mode
70
~
100
℃
, vacuum is
0.08
~
0.12MPa
, dehydration be blended
60
~
300
Minute, prepare
A
Group compound, moves in high speed dispersion stirred tank, standby；Will
B
Methacrylic acid neopentyl glycol dibasic acid esters in component, nitrile rubber, Phosphonate Flame Retardant plasticizer, solvent adds in vacuum kneader, in temperature according to above-mentioned parts by weight proportioning mode
70
~
100
℃
, vacuum is
0.08
~
0.12MPa
, dehydration be blended
60
~
300
Minute, prepare
B
Group compound, moves in high speed dispersion stirred tank, standby；
2
, at room temperature, by above-mentioned
A
Addition iron oxide red in group compound, reinforcing filler,
Irganox5057
Being placed in stirred tank, vacuum is
0.08
~
0.12MPa
, rotating speed
100
~
600rpm
, it is sufficiently mixed
1
~
5
Hour, prepare
A
Group is thoroughly mixed material；By above-mentioned
B
Addition triethylamine in group compound, white carbon black,
BYK-065
,
1
、
2-
Epoxy ethyoxyl trimethoxy silane is placed in stirred tank, and vacuum is
0.08
~
0.12MPa
, rotating speed
100
~
600rpm
, it is sufficiently mixed
1
~
5
Hour, prepare
B
Group is thoroughly mixed material.
A
Component
With
B
Component
Respectively
Stand subpackage, directly will during use
A
Component,
B
Component is according to carrying out potting operation after weight ratio mix homogeneously.
Following table is the Data Comparison of the present invention and other series products:
Upper table shows that the properties of the present invention is better than like product, can meet the process requirements that accumulator seals.
Embodiment
3
:
Described
A
In component, including:
40-55
The vinyltoluene of part,
20-28
The solvent of part,
4-7
The dioctyl phthalate of part,
10-22
The iron oxide red of part,
5-8
The reinforcing filler of part,
5-9
Part
Irganox5057
,
20-33
The nitrile rubber composition of part；Described
B
In component, including:
60-78
The methacrylic acid neopentyl glycol dibasic acid esters of part,
20-25
The nitrile rubber of part,
5-12
The triethylamine of part,
5-13
The Phosphonate Flame Retardant plasticizer of part,
5-8
The white carbon black of part,
25-35
The solvent of part,
10-14
Part
BYK-065
,
4-8
Part
1
、
2-
Epoxy ethyoxyl trimethoxy silane.
Following manufacture method is utilized to make the proportioning in above-mentioned component:
1
, will
A
Component medium vinyl toluene, solvent, dioctyl phthalate, nitrile rubber adds in vacuum kneader, in temperature according to above-mentioned parts by weight proportioning mode
100
℃
, vacuum is
0.12MPa
, dehydration be blended
300
Minute, prepare
A
Group compound, moves in high speed dispersion stirred tank, standby；Will
B
Methacrylic acid neopentyl glycol dibasic acid esters in component, nitrile rubber, Phosphonate Flame Retardant plasticizer, solvent adds in vacuum kneader, in temperature according to above-mentioned parts by weight proportioning mode
100
℃
, vacuum is
0.12MPa
, dehydration be blended
300
Minute, prepare
B
Group compound, moves in high speed dispersion stirred tank, standby；
2
, at room temperature, by above-mentioned
A
Addition iron oxide red in group compound, reinforcing filler,
Irganox5057
Being placed in stirred tank, vacuum is
0.12MPa
, rotating speed
600rpm
, it is sufficiently mixed
5
Hour, prepare
A
Group is thoroughly mixed material；By above-mentioned
B
Addition triethylamine in group compound, white carbon black,
BYK-065
,
1
、
2-
Epoxy ethyoxyl trimethoxy silane is placed in stirred tank, and vacuum is
0.12MPa
, rotating speed
600rpm
, it is sufficiently mixed
5
Hour, prepare
B
Group is thoroughly mixed material.
A
Component
With
B
Component
Respectively
Stand subpackage, directly will during use
A
Component,
B
Component is according to carrying out potting operation after weight ratio mix homogeneously.
Embodiment
4
:
Described
A
In component, including:
50
The vinyltoluene of part,
25
The solvent of part,
6
The dioctyl phthalate of part,
22
The iron oxide red of part,
8
The reinforcing filler of part,
8
Part
Irganox5057
,
28
The nitrile rubber composition of part；Described
B
In component, including:
70
The methacrylic acid neopentyl glycol dibasic acid esters of part,
25
The nitrile rubber of part,
10
The triethylamine of part,
10
The Phosphonate Flame Retardant plasticizer of part,
8
The white carbon black of part,
35
The solvent of part,
13
Part
BYK-065
,
8
Part
1
、
2-
Epoxy ethyoxyl trimethoxy silane.
Following manufacture method is utilized to make the proportioning in above-mentioned component:
1
, will
A
Component medium vinyl toluene, solvent, dioctyl phthalate, nitrile rubber adds in vacuum kneader, in temperature according to above-mentioned parts by weight proportioning mode
70
℃
, vacuum is
0.08MPa
, dehydration be blended
60
Minute, prepare
A
Group compound, moves in high speed dispersion stirred tank, standby；Will
B
Methacrylic acid neopentyl glycol dibasic acid esters in component, nitrile rubber, Phosphonate Flame Retardant plasticizer, solvent adds in vacuum kneader, in temperature according to above-mentioned parts by weight proportioning mode
70
℃
, vacuum is
0.08MPa
, dehydration be blended
60
Minute, prepare
B
Group compound, moves in high speed dispersion stirred tank, standby；
2
, at room temperature, by above-mentioned
A
Addition iron oxide red in group compound, reinforcing filler,
Irganox5057
Being placed in stirred tank, vacuum is
0.08MPa
, rotating speed
100rpm
, it is sufficiently mixed
5
Hour, prepare
A
Group is thoroughly mixed material；By above-mentioned
B
Addition triethylamine in group compound, white carbon black,
BYK-065
,
1
、
2-
Epoxy ethyoxyl trimethoxy silane is placed in stirred tank, and vacuum is
0.08MPa
, rotating speed
100rpm
, it is sufficiently mixed
5
Hour, prepare
B
Group is thoroughly mixed material.
A
Component
With
B
Component
Respectively
Stand subpackage, directly will during use
A
Component,
B
Component is according to carrying out potting operation after weight ratio mix homogeneously.
The above; being only the detailed description of the invention of the present invention, but protection scope of the present invention is not limited thereto, any those familiar with the art is in the technical scope that the invention discloses; change can be readily occurred in or replace, all should contain within protection scope of the present invention.Therefore, protection scope of the present invention should described be as the criterion with scope of the claims.
Claims (5)
1. a flame-retardant storage battery fluid sealant based on vinyltoluene Yu dibasic acid esters, it is characterised in that: include component A and B component；Described component A is made up of vinyltoluene, solvent, dioctyl phthalate, iron oxide red, reinforcing filler, Irganox5057, nitrile rubber；B component by methacrylic acid neopentyl glycol dibasic acid esters, nitrile rubber, triethylamine, Phosphonate Flame Retardant plasticizer, white carbon black, solvent, BYK-065,1,2-epoxy ethyoxyl trimethoxy silane composition；In wherein said component A, including: the vinyltoluene of 40-60 part, the solvent of 20-30 part, the dioctyl phthalate of 4-8 part, the iron oxide red of 10-25 part, the reinforcing filler of 5-10 part, the nitrile rubber composition of the Irganox5057 of 5-10 part, 20-35 part；In described B component, including: the methacrylic acid neopentyl glycol dibasic acid esters of 60-80 part, the nitrile rubber of 20-30 part, the triethylamine of 5-15 part, the Phosphonate Flame Retardant plasticizer of 5-15 part, the white carbon black of 5-10 part, 25-40 part solvent, the 1 of the BYK-065 of 10-15 part, 4-10 part, 2-epoxy ethyoxyl trimethoxy silane.
A kind of flame-retardant storage battery fluid sealant based on vinyltoluene Yu dibasic acid esters the most according to claim 1, it is characterised in that: described solvent is one or more in acetone, chloroform, dichloroethanes, nylon acid dimethyl ester, ethyl acetate, toluene or dimethylbenzene；Reinforcing filler is one or more that fume colloidal silica, precipitated silica and surface process in white carbon.
A kind of flame-retardant storage battery fluid sealant based on vinyltoluene Yu dibasic acid esters the most according to claim 1, it is characterized in that: in described component A, including: the vinyltoluene of 40-55 part, the solvent of 20-28 part, the dioctyl phthalate of 4-7 part, the iron oxide red of 10-22 part, the reinforcing filler of 5-8 part, the nitrile rubber composition of the Irganox5057 of 5-9 part, 20-33 part；In described B component, including: the methacrylic acid neopentyl glycol dibasic acid esters of 60-78 part, the nitrile rubber of 20-25 part, the triethylamine of 5-12 part, the Phosphonate Flame Retardant plasticizer of 5-13 part, the white carbon black of 5-8 part, the solvent of 25-35 part, the 1 of the BYK-065 of 10-14 part, 4-8 part, 2-epoxy ethyoxyl trimethoxy silane.
A kind of flame-retardant storage battery fluid sealant based on vinyltoluene Yu dibasic acid esters the most according to claim 1, it is characterized in that: in described component A, including: the vinyltoluene of 50 parts, the solvent of 25 parts, the dioctyl phthalate of 6 parts, the iron oxide red of 22 parts, the reinforcing filler of 8 parts, the Irganox5057 of 8 parts, the nitrile rubber composition of 28 parts；In described B component, including: the methacrylic acid neopentyl glycol dibasic acid esters of 70 parts, the nitrile rubber of 25 parts, the triethylamine of 10 parts, the Phosphonate Flame Retardant plasticizer of 10 parts, the white carbon black of 8 parts, the solvent of 35 parts, the BYK-065 of 13 parts, 8 parts 1,2-epoxy ethyoxyl trimethoxy silane.
5. according to a kind of based on vinyltoluene Yu the flame-retardant storage battery fluid sealant of dibasic acid esters the manufacture method according to any one of claim 1-4, it is characterised in that: concretely comprise the following steps:
1, by component A medium vinyl toluene, solvent, dioctyl phthalate, nitrile rubber adds in vacuum kneader according to above-mentioned parts by weight proportioning mode, in temperature 70～100 DEG C, vacuum is 0.08～0.12MPa, dehydration is blended 60～300 minutes, prepares A group compound, move in high speed dispersion stirred tank, standby；By methacrylic acid neopentyl glycol dibasic acid esters in B component, nitrile rubber, Phosphonate Flame Retardant plasticizer, solvent adds in vacuum kneader according to above-mentioned parts by weight proportioning mode, in temperature 70～100 DEG C, vacuum is 0.08～0.12MPa, dehydration is blended 60～300 minutes, prepares B group compound, move in high speed dispersion stirred tank, standby；
2, at room temperature, will add iron oxide red, reinforcing filler in above-mentioned A group compound, Irganox5057 is placed in stirred tank, and vacuum is 0.08～0.12MPa, rotating speed 100～600rpm, is sufficiently mixed 1～5 hour, prepares A group and is thoroughly mixed material；Will in above-mentioned B group compound add triethylamine, white carbon black, BYK-065,1,2-epoxy ethyoxyl trimethoxy silane be placed in stirred tank, vacuum is 0.08～0.12MPa, rotating speed 100～600rpm, is sufficiently mixed 1～5 hour, prepare B group be thoroughly mixed material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610487894.0A CN105969213A (en) | 2016-06-29 | 2016-06-29 | Flame-retardant storage battery sealing adhesive based on vinyl toluene and neopentyl glycol dimethacrylate and production method of flame-retardant storage battery sealing adhesive |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610487894.0A CN105969213A (en) | 2016-06-29 | 2016-06-29 | Flame-retardant storage battery sealing adhesive based on vinyl toluene and neopentyl glycol dimethacrylate and production method of flame-retardant storage battery sealing adhesive |
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| CN105969213A true CN105969213A (en) | 2016-09-28 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103820035A (en) * | 2014-02-20 | 2014-05-28 | 铜陵祥云消防科技有限责任公司 | Flame retardant adhesive containing modified kaolin |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103820035A (en) * | 2014-02-20 | 2014-05-28 | 铜陵祥云消防科技有限责任公司 | Flame retardant adhesive containing modified kaolin |
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Application publication date: 20160928 |