CN106118503A - A kind of flame-retardant storage battery fluid sealant based on propane three ester and isobornyl thiocyanoacetate and manufacture method - Google Patents
A kind of flame-retardant storage battery fluid sealant based on propane three ester and isobornyl thiocyanoacetate and manufacture method Download PDFInfo
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- CN106118503A CN106118503A CN201610487912.5A CN201610487912A CN106118503A CN 106118503 A CN106118503 A CN 106118503A CN 201610487912 A CN201610487912 A CN 201610487912A CN 106118503 A CN106118503 A CN 106118503A
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 36
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 35
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 title claims abstract description 26
- GNEPLYVYORHREW-UHFFFAOYSA-N 1,1,3,3,6-pentamethyl-7-nitro-2h-inden-5-amine Chemical compound CC1=C(N)C=C2C(C)(C)CC(C)(C)C2=C1[N+]([O-])=O GNEPLYVYORHREW-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 150000002148 esters Chemical class 0.000 title claims abstract description 16
- 239000000565 sealant Substances 0.000 title claims abstract description 15
- 239000012530 fluid Substances 0.000 title claims abstract description 13
- 238000000034 method Methods 0.000 title claims abstract description 13
- 239000001294 propane Substances 0.000 title claims abstract description 13
- 238000003860 storage Methods 0.000 title claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 8
- 239000002904 solvent Substances 0.000 claims abstract description 49
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 46
- -1 methacrylic acid trimethylolpropane triester Chemical class 0.000 claims abstract description 29
- 239000012763 reinforcing filler Substances 0.000 claims abstract description 25
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 23
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229920001971 elastomer Polymers 0.000 claims abstract description 23
- 229920001084 poly(chloroprene) Polymers 0.000 claims abstract description 23
- 229920000570 polyether Polymers 0.000 claims abstract description 23
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 21
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims abstract description 21
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims abstract description 21
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims abstract description 20
- 239000004014 plasticizer Substances 0.000 claims abstract description 20
- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 claims abstract description 19
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229940119545 isobornyl methacrylate Drugs 0.000 claims abstract description 19
- JAEZSIYNWDWMMN-UHFFFAOYSA-N 1,1,3-trimethylthiourea Chemical compound CNC(=S)N(C)C JAEZSIYNWDWMMN-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003292 glue Substances 0.000 claims abstract description 7
- 150000001875 compounds Chemical class 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 10
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- 230000018044 dehydration Effects 0.000 claims description 8
- 238000006297 dehydration reaction Methods 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical class CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 claims description 3
- 239000004677 Nylon Substances 0.000 claims description 3
- 239000008119 colloidal silica Substances 0.000 claims description 3
- 239000003517 fume Substances 0.000 claims description 3
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 claims description 3
- 229920001778 nylon Polymers 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 235000019253 formic acid Nutrition 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- KQJQICVXLJTWQD-UHFFFAOYSA-N N-Methylthiourea Chemical compound CNC(N)=S KQJQICVXLJTWQD-UHFFFAOYSA-N 0.000 claims 1
- HKGIIRAXAUXNPR-UHFFFAOYSA-N NC(=O)N.C[S](C)C Chemical compound NC(=O)N.C[S](C)C HKGIIRAXAUXNPR-UHFFFAOYSA-N 0.000 claims 1
- 239000000945 filler Substances 0.000 claims 1
- 230000007423 decrease Effects 0.000 abstract description 7
- 239000000853 adhesive Substances 0.000 abstract description 5
- 230000001070 adhesive effect Effects 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 2
- 238000004898 kneading Methods 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 8
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 4
- YRDGEBQKBARXFW-UHFFFAOYSA-N (dimethyl-$l^{3}-sulfanyl)methane Chemical compound C[S](C)C YRDGEBQKBARXFW-UHFFFAOYSA-N 0.000 description 3
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Natural products P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 3
- 238000004382 potting Methods 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000002341 toxic gas Substances 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/183—Sealing members
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of flame-retardant storage battery fluid sealant based on propane three ester and isobornyl thiocyanoacetate and manufacture method, including component A and B component；Described component A is made up of methacrylic acid trimethylolpropane triester, solvent, dioctyl phthalate, decabromodiphenyl oxide, reinforcing filler, antioxidant 1010, neoprene；B component is made up of isobornyl methacrylate, polyether rubber, trimethyl thiourea, Phosphonate Flame Retardant plasticizer, calcium carbonate, solvent, DEUCHEM2700, butyl titanate；The present invention by by the adhesive of two components of A, B by mixing in respectively vacuum kneading and reactor, make the adhesive of two different components.The present invention is by carrying out rational proportioning by the raw material in A, B component, make the bonding that two kinds of components in use can be good, and reduce the generation of air entrapment, decrease glue internal clearance, add good fire protecting performance and heat-proof quality simultaneously, ensure that the original mobility of adhesive, decrease the discharge of harmful substance.
Description
Technical field
The present invention relates to chemical technology field, particularly to accumulator being played the one of sealing function based on propane three ester
Flame-retardant storage battery fluid sealant and manufacture method with isobornyl thiocyanoacetate.
Background technology
Macromolecular material is increasingly extensive in building material industry application, but macromolecular material itself easily burns, when fire is sent out
Time raw, burning discharges substantial amounts of toxic gas, such as carbon monoxide, nitric oxide etc., people just can be made in very short time to be poisoned
Dead.Great mass of data shows, toxic smoke is the first of causing death the big killer in fire.Thus the fire resistance of construction material is direct
It is related to the people's lives and property safety.And the halogen flame that flame retardant sealant adds in a large number now can be given birth in combustion
Become the toxic gas such as substantial amounts of hydrogen halides, and bittern-free flame-proof material, magnesium hydroxide, aluminium hydroxide flame retardant effect poor, addition
Greatly, material property is had a strong impact on.Simultaneously because add substantial amounts of fire retardant, cause the mobility of fluid sealant to decline, be difficult to immerse
Narrow and small filleting, makes troubles to construction.
Summary of the invention
It is an object of the invention to provide one to have and decrease glue internal clearance, add simultaneously good fire protecting performance and every
Hot property, it is ensured that the original mobility of adhesive, decreases the one of discharge of harmful substance based on propane three ester and different ice
The flame-retardant storage battery fluid sealant of sheet ester and manufacture method, solve the use needs of problems of accumulator sealant.
In order to achieve the above object, the present invention provides following technical scheme:
A kind of flame-retardant storage battery fluid sealant based on propane three ester Yu isobornyl thiocyanoacetate, it is characterised in that: include component A and B component；
Described component A by methacrylic acid trimethylolpropane triester, solvent, dioctyl phthalate, decabromodiphenyl oxide, reinforcing
Filler, antioxidant 1010, neoprene forms；B component is by isobornyl methacrylate, polyether rubber, trimethyl thiourea, phosphine
Ester flame-proof plasticizing agent, calcium carbonate, solvent, DEUCHEM2700, butyl titanate forms；In wherein said component A, including: 40-
The methacrylic acid trimethylolpropane triester of 60 parts, the solvent of 20-30 part, the dioctyl phthalate of 4-8 part, 10-25
The decabromodiphenyl oxide of part, the reinforcing filler of 5-10 part, the antioxidant 1010 of 5-10 part, the neoprene composition of 20-35 part；Institute
State in B component, including: the isobornyl methacrylate of 60-80 part, the polyether rubber of 20-30 part, the trimethyl sulfur of 5-15 part
Urea, the Phosphonate Flame Retardant plasticizer of 5-15 part, the calcium carbonate of 5-10 part, 25-40 part solvent, the DEUCHEM2700 of 10-15 part,
The butyl titanate of 4-10 part.
Described solvent is in acetone, chloroform, dichloroethanes, nylon acid dimethyl ester, ethyl acetate, toluene or dimethylbenzene
One or more；Reinforcing filler be fume colloidal silica, precipitated silica and surface process the one in white carbon or
Several.
In described component A, including: the methacrylic acid trimethylolpropane triester of 40-55 part, the solvent of 20-28 part, 4-
The dioctyl phthalate of 7 parts, the decabromodiphenyl oxide of 10-22 part, the reinforcing filler of 5-8 part, the antioxidant of 5-9 part
The neoprene composition of 1010,20-33 parts；In described B component, including: the isobornyl methacrylate of 60-78 part, 20-25
The polyether rubber of part, the trimethyl thiourea of 5-12 part, the Phosphonate Flame Retardant plasticizer of 5-13 part, the calcium carbonate of 5-8 part, 25-35
The solvent of part, the butyl titanate of the DEUCHEM2700 of 10-14 part, 4-8 part.
In described component A, including: the methacrylic acid trimethylolpropane triester of 50 parts, the solvent of 25 parts, the neighbour of 6 parts
Dioctyl phthalate, the decabromodiphenyl oxide of 22 parts, the reinforcing filler of 8 parts, the antioxidant 1010 of 8 parts, the neoprene rubber of 28 parts
Glue forms；In described B component, including: the isobornyl methacrylate of 70 parts, the polyether rubber of 25 parts, the trimethyl of 10 parts
Thiourea, the Phosphonate Flame Retardant plasticizer of 10 parts, the calcium carbonate of 8 parts, the solvent of 35 parts, the DEUCHEM2700 of 13 parts, the titanium of 8 parts
Acid butyl ester.
Concretely comprise the following steps:
1, by methacrylic acid trimethylolpropane triester in component A, solvent, dioctyl phthalate, neoprene according to
Above-mentioned parts by weight proportioning mode adds in vacuum kneader, and in temperature 70～100 DEG C, vacuum is 0.08～0.12MPa, de-
Water is blended 60～300 minutes, prepares A group compound, moves in high speed dispersion stirred tank, standby；By methacrylic acid in B component
Isobornyl thiocyanoacetate, polyether rubber, Phosphonate Flame Retardant plasticizer, solvent adds vacuum kneader according to above-mentioned parts by weight proportioning mode
In, in temperature 70～100 DEG C, vacuum is 0.08～0.12MPa, dehydration is blended 60～300 minutes, prepares B group compound, shifting
Enter in high speed dispersion stirred tank, standby；
2, at room temperature, will add decabromodiphenyl oxide in above-mentioned A group compound, reinforcing filler, antioxidant 1010 is placed in stirring
In still, vacuum is 0.08～0.12MPa, rotating speed 100～600rpm, is sufficiently mixed 1～5 hour, prepares A group and is thoroughly mixed
Material；To add trimethyl thiourea in above-mentioned B group compound, calcium carbonate, DEUCHEM2700, butyl titanate is placed in stirred tank, very
Reciprocal of duty cycle is 0.08～0.12MPa, rotating speed 100～600rpm, is sufficiently mixed 1～5 hour, prepares B group and is thoroughly mixed material.
Beneficial effects of the present invention: the present invention, by the raw material in A, B component is carried out rational proportioning, makes two kinds of components
Bonding that in use can be good, and reduce the generation of air entrapment, decrease glue internal clearance, add simultaneously
Good fire protecting performance and heat-proof quality, it is ensured that the original mobility of adhesive, decrease the discharge of harmful substance.
Detailed description of the invention
Below in conjunction with embodiment, technical scheme is clearly and completely described, it is clear that described
Embodiment is only a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, this area
The every other embodiment that those of ordinary skill is obtained under not making creative work premise, broadly falls into present invention protection
Scope.
Embodiment 1:
A kind of flame-retardant storage battery fluid sealant based on propane three ester Yu isobornyl thiocyanoacetate, it is characterised in that: include component A and B component；
Described component A by methacrylic acid trimethylolpropane triester, solvent, dioctyl phthalate, decabromodiphenyl oxide, reinforcing
Filler, antioxidant 1010, neoprene forms；B component is by isobornyl methacrylate, polyether rubber, trimethyl thiourea, phosphine
Ester flame-proof plasticizing agent, calcium carbonate, solvent, DEUCHEM2700, butyl titanate forms；In wherein said component A, including: 40-
The methacrylic acid trimethylolpropane triester of 60 parts, the solvent of 20-30 part, the dioctyl phthalate of 4-8 part, 10-25
The decabromodiphenyl oxide of part, the reinforcing filler of 5-10 part, the antioxidant 1010 of 5-10 part, the neoprene composition of 20-35 part；Institute
State in B component, including: the isobornyl methacrylate of 60-80 part, the polyether rubber of 20-30 part, the trimethyl sulfur of 5-15 part
Urea, the Phosphonate Flame Retardant plasticizer of 5-15 part, the calcium carbonate of 5-10 part, 25-40 part solvent, the DEUCHEM2700 of 10-15 part,
The butyl titanate of 4-10 part.
Described solvent is in acetone, chloroform, dichloroethanes, nylon acid dimethyl ester, ethyl acetate, toluene or dimethylbenzene
One or more；Reinforcing filler be fume colloidal silica, precipitated silica and surface process the one in white carbon or
Several.
In described component A, including: the methacrylic acid trimethylolpropane triester of 40-55 part, the solvent of 20-28 part, 4-
The dioctyl phthalate of 7 parts, the decabromodiphenyl oxide of 10-22 part, the reinforcing filler of 5-8 part, the antioxidant of 5-9 part
The neoprene composition of 1010,20-33 parts；In described B component, including: the isobornyl methacrylate of 60-78 part, 20-25
The polyether rubber of part, the trimethyl thiourea of 5-12 part, the Phosphonate Flame Retardant plasticizer of 5-13 part, the calcium carbonate of 5-8 part, 25-35
The solvent of part, the butyl titanate of the DEUCHEM2700 of 10-14 part, 4-8 part.
In described component A, including: the methacrylic acid trimethylolpropane triester of 50 parts, the solvent of 25 parts, the neighbour of 6 parts
Dioctyl phthalate, the decabromodiphenyl oxide of 22 parts, the reinforcing filler of 8 parts, the antioxidant 1010 of 8 parts, the neoprene rubber of 28 parts
Glue forms；In described B component, including: the isobornyl methacrylate of 70 parts, the polyether rubber of 25 parts, the trimethyl of 10 parts
Thiourea, the Phosphonate Flame Retardant plasticizer of 10 parts, the calcium carbonate of 8 parts, the solvent of 35 parts, the DEUCHEM2700 of 13 parts, the titanium of 8 parts
Acid butyl ester.
Concretely comprise the following steps:
1, by methacrylic acid trimethylolpropane triester in component A, solvent, dioctyl phthalate, neoprene according to
Above-mentioned parts by weight proportioning mode adds in vacuum kneader, and in temperature 70～100 DEG C, vacuum is 0.08～0.12MPa, de-
Water is blended 60～300 minutes, prepares A group compound, moves in high speed dispersion stirred tank, standby；By methacrylic acid in B component
Isobornyl thiocyanoacetate, polyether rubber, Phosphonate Flame Retardant plasticizer, solvent adds vacuum kneader according to above-mentioned parts by weight proportioning mode
In, in temperature 70～100 DEG C, vacuum is 0.08～0.12MPa, dehydration is blended 60～300 minutes, prepares B group compound, shifting
Enter in high speed dispersion stirred tank, standby；
2, at room temperature, will add decabromodiphenyl oxide in above-mentioned A group compound, reinforcing filler, antioxidant 1010 is placed in stirring
In still, vacuum is 0.08～0.12MPa, rotating speed 100～600rpm, is sufficiently mixed 1～5 hour, prepares A group and is thoroughly mixed
Material；To add trimethyl thiourea in above-mentioned B group compound, calcium carbonate, DEUCHEM2700, butyl titanate is placed in stirred tank, very
Reciprocal of duty cycle is 0.08～0.12MPa, rotating speed 100～600rpm, is sufficiently mixed 1～5 hour, prepares B group and is thoroughly mixed material.
Embodiment 2:
A kind of flame-retardant storage battery fluid sealant based on propane three ester Yu isobornyl thiocyanoacetate, it is characterised in that: include component A and B component；
Described component A by methacrylic acid trimethylolpropane triester, solvent, dioctyl phthalate, decabromodiphenyl oxide, reinforcing
Filler, antioxidant 1010, neoprene forms；B component is by isobornyl methacrylate, polyether rubber, trimethyl thiourea, phosphine
Ester flame-proof plasticizing agent, calcium carbonate, solvent, DEUCHEM2700, butyl titanate forms；In wherein said component A, including: 40-
The methacrylic acid trimethylolpropane triester of 60 parts, the solvent of 20-30 part, the dioctyl phthalate of 4-8 part, 10-25
The decabromodiphenyl oxide of part, the reinforcing filler of 5-10 part, the antioxidant 1010 of 5-10 part, the neoprene composition of 20-35 part；Institute
State in B component, including: the isobornyl methacrylate of 60-80 part, the polyether rubber of 20-30 part, the trimethyl sulfur of 5-15 part
Urea, the Phosphonate Flame Retardant plasticizer of 5-15 part, the calcium carbonate of 5-10 part, 25-40 part solvent, the DEUCHEM2700 of 10-15 part,
The butyl titanate of 4-10 part.
Following manufacture method is utilized to make the proportioning in above-mentioned component:
1, by methacrylic acid trimethylolpropane triester in component A, solvent, dioctyl phthalate, neoprene according to
Above-mentioned parts by weight proportioning mode adds in vacuum kneader, and in temperature 70～100 DEG C, vacuum is 0.08～0.12MPa, de-
Water is blended 60～300 minutes, prepares A group compound, moves in high speed dispersion stirred tank, standby；By methacrylic acid in B component
Isobornyl thiocyanoacetate, polyether rubber, Phosphonate Flame Retardant plasticizer, solvent adds vacuum kneader according to above-mentioned parts by weight proportioning mode
In, in temperature 70～100 DEG C, vacuum is 0.08～0.12MPa, dehydration is blended 60～300 minutes, prepares B group compound, shifting
Enter in high speed dispersion stirred tank, standby；
2, at room temperature, will add decabromodiphenyl oxide in above-mentioned A group compound, reinforcing filler, antioxidant 1010 is placed in stirring
In still, vacuum is 0.08～0.12MPa, rotating speed 100～600rpm, is sufficiently mixed 1～5 hour, prepares A group and is thoroughly mixed
Material；To add trimethyl thiourea in above-mentioned B group compound, calcium carbonate, DEUCHEM2700, butyl titanate is placed in stirred tank, very
Reciprocal of duty cycle is 0.08～0.12MPa, rotating speed 100～600rpm, is sufficiently mixed 1～5 hour, prepares B group and is thoroughly mixed material.
Component A and B component stand subpackage respectively, during use directly by component A, B component according to weight ratio mix homogeneously after
Potting operation can be carried out.
Following table is the Data Comparison of the present invention and other series products:
Upper table shows that the properties of the present invention is better than like product, can meet the process requirements that accumulator seals.
Embodiment 3:
In described component A, including: the methacrylic acid trimethylolpropane triester of 40-55 part, the solvent of 20-28 part, 4-7 part
Dioctyl phthalate, the decabromodiphenyl oxide of 10-22 part, the reinforcing filler of 5-8 part, the antioxidant 1010 of 5-9 part,
The neoprene composition of 20-33 part；In described B component, including: the isobornyl methacrylate of 60-78 part, 20-25 part
Polyether rubber, the trimethyl thiourea of 5-12 part, the Phosphonate Flame Retardant plasticizer of 5-13 part, the calcium carbonate of 5-8 part, 25-35 part
Solvent, the butyl titanate of the DEUCHEM2700 of 10-14 part, 4-8 part.
Following manufacture method is utilized to make the proportioning in above-mentioned component:
1, by methacrylic acid trimethylolpropane triester in component A, solvent, dioctyl phthalate, neoprene according to
Above-mentioned parts by weight proportioning mode adds in vacuum kneader, and in temperature 100 DEG C, vacuum is 0.12MPa, dehydration is blended 300
Minute, prepare A group compound, move in high speed dispersion stirred tank, standby；By isobornyl methacrylate in B component, polyethers
Rubber, Phosphonate Flame Retardant plasticizer, solvent adds in vacuum kneader, in temperature 100 according to above-mentioned parts by weight proportioning mode
DEG C, vacuum is 0.12MPa, dehydration is blended 300 minutes, prepares B group compound, moves in high speed dispersion stirred tank, standby；
2, at room temperature, will add decabromodiphenyl oxide in above-mentioned A group compound, reinforcing filler, antioxidant 1010 is placed in stirring
In still, vacuum is 0.12MPa, rotating speed 600rpm, is sufficiently mixed 5 hours, prepares A group and is thoroughly mixed material；Above-mentioned B group is mixed
Adding trimethyl thiourea, calcium carbonate, DEUCHEM2700 in material, butyl titanate is placed in stirred tank, and vacuum is 0.12MPa, turns
Speed 600rpm, is sufficiently mixed 5 hours, prepares B group and is thoroughly mixed material.
Component A and B component stand subpackage respectively, during use directly by component A, B component according to weight ratio mix homogeneously after
Potting operation can be carried out.
Embodiment 4:
In described component A, including: the methacrylic acid trimethylolpropane triester of 50 parts, the solvent of 25 parts, the adjacent benzene two of 6 parts
Formic acid dioctyl ester, the decabromodiphenyl oxide of 22 parts, the reinforcing filler of 8 parts, the antioxidant 1010 of 8 parts, the neoprene group of 28 parts
Become；In described B component, including: the isobornyl methacrylate of 70 parts, the polyether rubber of 25 parts, the trimethyl thiourea of 10 parts,
The Phosphonate Flame Retardant plasticizer of 10 parts, the calcium carbonate of 8 parts, the solvent of 35 parts, the DEUCHEM2700 of 13 parts, the metatitanic acid fourth of 8 parts
Ester.
Following manufacture method is utilized to make the proportioning in above-mentioned component:
1, by methacrylic acid trimethylolpropane triester in component A, solvent, dioctyl phthalate, neoprene according to
Above-mentioned parts by weight proportioning mode adds in vacuum kneader, and in temperature 70 C, vacuum is 0.08MPa, dehydration is blended 60 points
Clock, prepares A group compound, moves in high speed dispersion stirred tank, standby；By isobornyl methacrylate in B component, polyethers rubber
Glue, Phosphonate Flame Retardant plasticizer, solvent adds in vacuum kneader according to above-mentioned parts by weight proportioning mode, in temperature 70 C,
Vacuum is 0.08MPa, dehydration is blended 60 minutes, prepares B group compound, moves in high speed dispersion stirred tank, standby；
2, at room temperature, will add decabromodiphenyl oxide in above-mentioned A group compound, reinforcing filler, antioxidant 1010 is placed in stirring
In still, vacuum is 0.08MPa, rotating speed 100rpm, is sufficiently mixed 5 hours, prepares A group and is thoroughly mixed material；Above-mentioned B group is mixed
Adding trimethyl thiourea, calcium carbonate, DEUCHEM2700 in material, butyl titanate is placed in stirred tank, and vacuum is 0.08MPa, turns
Speed 100rpm, is sufficiently mixed 5 hours, prepares B group and is thoroughly mixed material.
Component A and B component stand subpackage respectively, during use directly by component A, B component according to weight ratio mix homogeneously after
Potting operation can be carried out.
The above, the only detailed description of the invention of the present invention, but protection scope of the present invention is not limited thereto, and any
Those familiar with the art, in the technical scope that the invention discloses, can readily occur in change or replace, should contain
Cover within protection scope of the present invention.Therefore, protection scope of the present invention should described be as the criterion with scope of the claims.
Claims (5)
1. a flame-retardant storage battery fluid sealant based on propane three ester Yu isobornyl thiocyanoacetate, it is characterised in that: include component A and B group
Point；Described component A, by methacrylic acid trimethylolpropane triester, solvent, dioctyl phthalate, decabromodiphenyl oxide, is mended
Epistasis filler, antioxidant 1010, neoprene forms；B component is by isobornyl methacrylate, polyether rubber, trimethyl sulfur
Urea, Phosphonate Flame Retardant plasticizer, calcium carbonate, solvent, DEUCHEM2700, butyl titanate forms；In wherein said component A, bag
Include: the methacrylic acid trimethylolpropane triester of 40-60 part, the solvent of 20-30 part, the dioctyl phthalate of 4-8 part,
The decabromodiphenyl oxide of 10-25 part, the reinforcing filler of 5-10 part, the antioxidant 1010 of 5-10 part, the neoprene group of 20-35 part
Become；In described B component, including: the isobornyl methacrylate of 60-80 part, the polyether rubber of 20-30 part, the three of 5-15 part
Methylthiourea, the Phosphonate Flame Retardant plasticizer of 5-15 part, the calcium carbonate of 5-10 part, 25-40 part solvent, 10-15 part
The butyl titanate of DEUCHEM2700,4-10 part.
A kind of flame-retardant storage battery fluid sealant based on propane three ester Yu isobornyl thiocyanoacetate the most according to claim 1, its feature
It is: described solvent is in acetone, chloroform, dichloroethanes, nylon acid dimethyl ester, ethyl acetate, toluene or dimethylbenzene
One or more；Reinforcing filler is the one or several that fume colloidal silica, precipitated silica and surface process in white carbon
Kind.
A kind of flame-retardant storage battery fluid sealant based on propane three ester Yu isobornyl thiocyanoacetate the most according to claim 1, its feature
It is: in described component A, including: the methacrylic acid trimethylolpropane triester of 40-55 part, the solvent of 20-28 part, 4-7 part
Dioctyl phthalate, the decabromodiphenyl oxide of 10-22 part, the reinforcing filler of 5-8 part, the antioxidant 1010 of 5-9 part,
The neoprene composition of 20-33 part；In described B component, including: the isobornyl methacrylate of 60-78 part, 20-25 part
Polyether rubber, the trimethyl thiourea of 5-12 part, the Phosphonate Flame Retardant plasticizer of 5-13 part, the calcium carbonate of 5-8 part, 25-35 part
Solvent, the butyl titanate of the DEUCHEM2700 of 10-14 part, 4-8 part.
A kind of flame-retardant storage battery fluid sealant based on propane three ester Yu isobornyl thiocyanoacetate the most according to claim 1, its feature
It is: in described component A, including: the methacrylic acid trimethylolpropane triester of 50 parts, the solvent of 25 parts, the adjacent benzene two of 6 parts
Formic acid dioctyl ester, the decabromodiphenyl oxide of 22 parts, the reinforcing filler of 8 parts, the antioxidant 1010 of 8 parts, the neoprene group of 28 parts
Become；In described B component, including: the isobornyl methacrylate of 70 parts, the polyether rubber of 25 parts, the trimethyl thiourea of 10 parts,
The Phosphonate Flame Retardant plasticizer of 10 parts, the calcium carbonate of 8 parts, the solvent of 35 parts, the DEUCHEM2700 of 13 parts, the metatitanic acid fourth of 8 parts
Ester.
5. seal according to a kind of based on propane three ester with isobornyl thiocyanoacetate the flame-retardant storage battery according to any one of claim 1-4
The manufacture method of glue, it is characterised in that: concretely comprise the following steps:
1, by methacrylic acid trimethylolpropane triester in component A, solvent, dioctyl phthalate, neoprene according to
Above-mentioned parts by weight proportioning mode adds in vacuum kneader, and in temperature 70～100 DEG C, vacuum is 0.08～0.12MPa, de-
Water is blended 60～300 minutes, prepares A group compound, moves in high speed dispersion stirred tank, standby；By methacrylic acid in B component
Isobornyl thiocyanoacetate, polyether rubber, Phosphonate Flame Retardant plasticizer, solvent adds vacuum kneader according to above-mentioned parts by weight proportioning mode
In, in temperature 70～100 DEG C, vacuum is 0.08～0.12MPa, dehydration is blended 60～300 minutes, prepares B group compound, shifting
Enter in high speed dispersion stirred tank, standby；
2, at room temperature, will add decabromodiphenyl oxide in above-mentioned A group compound, reinforcing filler, antioxidant 1010 is placed in stirring
In still, vacuum is 0.08～0.12MPa, rotating speed 100～600rpm, is sufficiently mixed 1～5 hour, prepares A group and is thoroughly mixed
Material；To add trimethyl thiourea in above-mentioned B group compound, calcium carbonate, DEUCHEM2700, butyl titanate is placed in stirred tank, very
Reciprocal of duty cycle is 0.08～0.12MPa, rotating speed 100～600rpm, is sufficiently mixed 1～5 hour, prepares B group and is thoroughly mixed material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610487912.5A CN106118503A (en) | 2016-06-29 | 2016-06-29 | A kind of flame-retardant storage battery fluid sealant based on propane three ester and isobornyl thiocyanoacetate and manufacture method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610487912.5A CN106118503A (en) | 2016-06-29 | 2016-06-29 | A kind of flame-retardant storage battery fluid sealant based on propane three ester and isobornyl thiocyanoacetate and manufacture method |
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| CN106118503A true CN106118503A (en) | 2016-11-16 |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103834330A (en) * | 2012-11-23 | 2014-06-04 | 湖北回天胶业股份有限公司 | Flame retardant acrylate adhesive |
-
2016
- 2016-06-29 CN CN201610487912.5A patent/CN106118503A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103834330A (en) * | 2012-11-23 | 2014-06-04 | 湖北回天胶业股份有限公司 | Flame retardant acrylate adhesive |
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Application publication date: 20161116 |