CN106010306A - Photovoltaic storage battery sealant based on tridecanyl and glyceride and manufacturing method thereof - Google Patents
Photovoltaic storage battery sealant based on tridecanyl and glyceride and manufacturing method thereof Download PDFInfo
- Publication number
- CN106010306A CN106010306A CN201610486487.8A CN201610486487A CN106010306A CN 106010306 A CN106010306 A CN 106010306A CN 201610486487 A CN201610486487 A CN 201610486487A CN 106010306 A CN106010306 A CN 106010306A
- Authority
- CN
- China
- Prior art keywords
- component
- parts
- platinum
- fire retardant
- glyceride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Sealing Material Composition (AREA)
Abstract
The invention discloses a photovoltaic storage battery sealant based on tridecanyl and glyceride. The sealant is manufactured from a component A and a component B, wherein the component A is prepared from methacrylic acid tridecyl ester, trichloromethane, dibutyl phthalate, fire retardant, titanium dioxide, antioxidant 1010 and a thermal conducting filler; the component B is prepared from glycidyl methacrylate, chlorosulfonated polyethylene, triethylenediamine, a silane crosslinking, a platinum or platinum complex, a defoaming agent and a silane tackifier. The materials in the component A and the component B are subjected to processing production respectively, and the sealant is obtained through processing of a vacuum kneading machine and a reaction kettle. Due to the good fire retardant and the thermal conducting filler, by means of mixing of other substances, the content of bubbles inside the sealant is small, and the sealant has the advantages of being excellent in cohesiveness, excellent in high temperature resistance and high humidity resistance, good in flame retardant, heat conduction and electric insulation performance, high in curing speed, convenient to operate and the like.
Description
Technical field
The present invention relates to chemical technology field, particularly to a kind of based on 13 esters and glyceride the photovoltaic storage battery fluid sealant that accumulator is played sealing function
And manufacture method
。
Background technology
In recent years, country builds a conservation-minded society in promotion always, advocates energy-saving and emission-reduction, advocates low-carbon environment-friendly, under such overall situation, and occurring to the inexorable trend developed under a kind of policy of solar energy industry.Technology disconnected upgrading not also becomes the best support of solar energy industry.Solaode is a kind of new technique in solar energy industry, and it utilizes the quantum effect of the quasiconductors such as silicon, directly the visible ray of the sun is changed into electric energy.The core component of solaode is silicon wafer.For ensureing light electrical efficiency and the life-span of silicon wafer, industrial meeting is sealed against inside photovoltaic module, and aluminum frame, bus bar and the rosette etc. of assembly are accomplished by with being bonded and sealed that special sealing cement is carried out, it is to avoid in air, water and oxygen etc. enter.
Being currently used for the One component Sealant of photovoltaic module, curing rate is slow, and the curing time of assembly is long, affects efficiency.Photovoltaic
Accumulator
Require that fluid sealant should have good resistance to elevated temperatures and good flame-retarded heat-conducting performance, and keep good electrical insulation capability
, and this type of fluid sealant is narrower in research range, it is impossible to meet the market demand
。
Summary of the invention
It is an object of the invention to provide
One has
Caking property excellence, high-temp resisting high-humidity resisting excellent performance and flame-retarded heat-conducting and electrical insulating property are good, and curing rate is fast, easy to operate
Etc. advantage
A kind of based on 13 esters and glyceride photovoltaic storage battery fluid sealant
And manufacture method
, solve the use needs of problems of accumulator sealant.
In order to achieve the above object, the present invention provides following technical scheme:
A kind of photovoltaic storage battery fluid sealant based on 13 esters and glyceride, it is characterised in that: include
A
Component and
B
Component；Described
A
Component is by methacrylic acid 13 ester, chloroform, dibutyl phthalate, fire retardant, titanium dioxide, antioxidant
1010
, heat filling forms；
B
Component is made up of glycidyl methacrylate, chlorosulfonated polyethylene, triethylenediamine, silane crosslinker, platinum or platinum complex, defoamer, silane adhesion promoters；Wherein said
A
In component, including:
40-60
Methacrylic acid 13 ester of part,
25-40
The chloroform of part,
5-15
The dibutyl phthalate of part,
20-35
The fire retardant of part,
2-10
The titanium dioxide of part,
2-10
The antioxidant of part
1010
,
5-15
The heat filling composition of part；Described
B
In component, including:
60-80
The glycidyl methacrylate of part,
15-25
The chlorosulfonated polyethylene of part,
5-15
The triethylenediamine of part,
3-15
The silane crosslinker of part,
1-8
The platinum of part or platinum complex,
10-15
The defoamer of part,
0.1-6
The silane adhesion promoters of part.
Described fire retardant is at least one in basic zinc carbonate, Firebrake ZB, aluminium hydroxide, magnesium hydroxide, iron oxide red, decabromodiphenyl oxide, red phosphorus, chlorinated paraffin；Heat filling is nanometer silicon carbide, nano aluminum nitride, nm-class boron nitride, nano-silicon nitride, high heat conduction composite powder, at least one in nano silicon carbide aluminum；Described defoamer is silicone and polyacrylate apoplexy due to endogenous wind
BYK-065
、
BYK-066N
、
BYK-354
、
DEUCHEM2700
In any one.
Described
A
In component, including:
50
Methacrylic acid 13 ester of part,
35
The chloroform of part,
10
The dibutyl phthalate of part,
25
The fire retardant of part,
5
The titanium dioxide of part,
6
The antioxidant of part
1010
,
10
The heat filling composition of part；Described
B
In component, including:
70
The glycidyl methacrylate of part,
20
The chlorosulfonated polyethylene of part,
10
The triethylenediamine of part,
8
The silane crosslinker of part,
4
The platinum of part or platinum complex,
12
The defoamer of part,
3
The silane adhesion promoters of part.
Concretely comprise the following steps:
A
Component includes step: by above-mentioned weight, by methacrylic acid 13 ester, chloroform, dibutyl phthalate adds in vacuum kneader, and temperature controls
60
~
100
℃
, vacuum is
0.08
~
0.12MPa
, dehydration is blended
1
~
6
Hour, then move in reactor, start stirring, then put into fire retardant, and titanium dioxide, antioxidant
1010
, heat filling, mix homogeneously, to obtain final product
A
Component；
B
Component includes step: by above-mentioned weight, by glycidyl methacrylate, chlorosulfonated polyethylene, triethylenediamine adds in vacuum kneader, and temperature controls
60
~
120
℃
, vacuum is
0.08
~
0.12MPa
, dehydration is blended
1
~
7
Hour, then move in reactor, start stirring, put into silane crosslinker, platinum or platinum complex, defoamer, silane adhesion promoters, after mix homogeneously, to obtain final product
B
Component.
The rotating speed of described reactor is
50
~
1000rpm
, the mix and blend time is
15
~
120
Minute.
Beneficial effects of the present invention: the present invention
By good fire retardant and heat filling, utilizing other materials to be mutually mixed, in making glue, air bubble content is little, and has
Caking property excellence, high-temp resisting high-humidity resisting excellent performance and flame-retarded heat-conducting and electrical insulating property are good, and curing rate is fast, easy to operate
Etc. advantage
。
Detailed description of the invention
Below in conjunction with embodiment, technical scheme is clearly and completely described, it is clear that described embodiment is only a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, the every other embodiment that those of ordinary skill in the art are obtained under not making creative work premise, broadly fall into the scope of protection of the invention.
Embodiment
1
:
A kind of photovoltaic storage battery fluid sealant based on 13 esters and glyceride, it is characterised in that: include
A
Component and
B
Component；Described
A
Component is by methacrylic acid 13 ester, chloroform, dibutyl phthalate, fire retardant, titanium dioxide, antioxidant
1010
, heat filling forms；
B
Component is made up of glycidyl methacrylate, chlorosulfonated polyethylene, triethylenediamine, silane crosslinker, platinum or platinum complex, defoamer, silane adhesion promoters；Wherein said
A
In component, including:
40-60
Methacrylic acid 13 ester of part,
25-40
The chloroform of part,
5-15
The dibutyl phthalate of part,
20-35
The fire retardant of part,
2-10
The titanium dioxide of part,
2-10
The antioxidant of part
1010
,
5-15
The heat filling composition of part；Described
B
In component, including:
60-80
The glycidyl methacrylate of part,
15-25
The chlorosulfonated polyethylene of part,
5-15
The triethylenediamine of part,
3-15
The silane crosslinker of part,
1-8
The platinum of part or platinum complex,
10-15
The defoamer of part,
0.1-6
The silane adhesion promoters of part.
Described fire retardant is at least one in basic zinc carbonate, Firebrake ZB, aluminium hydroxide, magnesium hydroxide, iron oxide red, decabromodiphenyl oxide, red phosphorus, chlorinated paraffin；Heat filling is nanometer silicon carbide, nano aluminum nitride, nm-class boron nitride, nano-silicon nitride, high heat conduction composite powder, at least one in nano silicon carbide aluminum；Described defoamer is silicone and polyacrylate apoplexy due to endogenous wind
BYK-065
、
BYK-066N
、
BYK-354
、
DEUCHEM2700
In any one.
Described
A
In component, including:
50
Methacrylic acid 13 ester of part,
35
The chloroform of part,
10
The dibutyl phthalate of part,
25
The fire retardant of part,
5
The titanium dioxide of part,
6
The antioxidant of part
1010
,
10
The heat filling composition of part；Described
B
In component, including:
70
The glycidyl methacrylate of part,
20
The chlorosulfonated polyethylene of part,
10
The triethylenediamine of part,
8
The silane crosslinker of part,
4
The platinum of part or platinum complex,
12
The defoamer of part,
3
The silane adhesion promoters of part.
Concretely comprise the following steps:
A
Component includes step: by above-mentioned weight, by methacrylic acid 13 ester, chloroform, dibutyl phthalate adds in vacuum kneader, and temperature controls
60
~
100
℃
, vacuum is
0.08
~
0.12MPa
, dehydration is blended
1
~
6
Hour, then move in reactor, start stirring, then put into fire retardant, and titanium dioxide, antioxidant
1010
, heat filling, mix homogeneously, to obtain final product
A
Component；
B
Component includes step: by above-mentioned weight, by glycidyl methacrylate, chlorosulfonated polyethylene, triethylenediamine adds in vacuum kneader, and temperature controls
60
~
120
℃
, vacuum is
0.08
~
0.12MPa
, dehydration is blended
1
~
7
Hour, then move in reactor, start stirring, put into silane crosslinker, platinum or platinum complex, defoamer, silane adhesion promoters, after mix homogeneously, to obtain final product
B
Component.
The rotating speed of described reactor is
50
~
1000rpm
, the mix and blend time is
15
~
120
Minute.
Embodiment
2
:
Described
A
In component, including:
40-60
Methacrylic acid 13 ester of part,
25-40
The chloroform of part,
5-15
The dibutyl phthalate of part,
20-35
The fire retardant of part,
2-10
The titanium dioxide of part,
2-10
The antioxidant of part
1010
,
5-15
The heat filling composition of part；Described
B
In component, including:
60-80
The glycidyl methacrylate of part,
15-25
The chlorosulfonated polyethylene of part,
5-15
The triethylenediamine of part,
3-15
The silane crosslinker of part,
1-8
The platinum of part or platinum complex,
10-15
The defoamer of part,
0.1-6
The silane adhesion promoters of part.
Specifically
Production and processing
Step is:
A
Component includes step: by above-mentioned weight, by methacrylic acid 13 ester, chloroform, dibutyl phthalate adds in vacuum kneader, and temperature controls
60
~
100
℃
, vacuum is
0.08
~
0.12MPa
, dehydration is blended
1
~
6
Hour, then move in reactor, start stirring, then put into fire retardant, and titanium dioxide, antioxidant
1010
, heat filling, mix homogeneously, to obtain final product
A
Component；
B
Component includes step: by above-mentioned weight, by glycidyl methacrylate, chlorosulfonated polyethylene, triethylenediamine adds in vacuum kneader, and temperature controls
60
~
120
℃
, vacuum is
0.08
~
0.12MPa
, dehydration is blended
1
~
7
Hour, then move in reactor, start stirring, put into silane crosslinker, platinum or platinum complex, defoamer, silane adhesion promoters, after mix homogeneously, to obtain final product
B
Component.
A
Component,
B
Component
Respectively
Stand subpackage, directly will during use
A
Component,
B
Component is according to carrying out potting operation after weight ratio mix homogeneously.
Embodiment
3
:
Described
A
In component, including:
50
Methacrylic acid 13 ester of part,
35
The chloroform of part,
10
The dibutyl phthalate of part,
25
The fire retardant of part,
5
The titanium dioxide of part,
6
The antioxidant of part
1010
,
10
The heat filling composition of part；Described
B
In component, including:
70
The glycidyl methacrylate of part,
20
The chlorosulfonated polyethylene of part,
10
The triethylenediamine of part,
8
The silane crosslinker of part,
4
The platinum of part or platinum complex,
12
The defoamer of part,
3
The silane adhesion promoters of part.
Specifically
Production and processing
Step is:
A
Component includes step: by above-mentioned weight, by methacrylic acid 13 ester, chloroform, dibutyl phthalate adds in vacuum kneader, and temperature controls
60
~
100
℃
, vacuum is
0.08
~
0.12MPa
, dehydration is blended
1
~
6
Hour, then move in reactor, start stirring, then put into fire retardant, and titanium dioxide, antioxidant
1010
, heat filling, mix homogeneously, to obtain final product
A
Component；
B
Component includes step: by above-mentioned weight, by glycidyl methacrylate, chlorosulfonated polyethylene, triethylenediamine adds in vacuum kneader, and temperature controls
60
~
120
℃
, vacuum is
0.08
~
0.12MPa
, dehydration is blended
1
~
7
Hour, then move in reactor, start stirring, put into silane crosslinker, platinum or platinum complex, defoamer, silane adhesion promoters, after mix homogeneously, to obtain final product
B
Component.
A
Component,
B
Component
Respectively
Stand subpackage, directly will during use
A
Component,
B
Component is according to carrying out potting operation after weight ratio mix homogeneously.
The above; being only the detailed description of the invention of the present invention, but protection scope of the present invention is not limited thereto, any those familiar with the art is in the technical scope that the invention discloses; change can be readily occurred in or replace, all should contain within protection scope of the present invention.Therefore, protection scope of the present invention should described be as the criterion with scope of the claims.
Claims (5)
1. a photovoltaic storage battery fluid sealant based on 13 esters and glyceride, it is characterised in that: include component A and B component；Described component A is made up of methacrylic acid 13 ester, chloroform, dibutyl phthalate, fire retardant, titanium dioxide, antioxidant 1010, heat filling；B component is made up of glycidyl methacrylate, chlorosulfonated polyethylene, triethylenediamine, silane crosslinker, platinum or platinum complex, defoamer, silane adhesion promoters；In wherein said component A, including: methacrylic acid 13 ester of 40-60 part, the chloroform of 25-40 part, the dibutyl phthalate of 5-15 part, the fire retardant of 20-35 part, the titanium dioxide of 2-10 part, the antioxidant 1010 of 2-10 part, the heat filling composition of 5-15 part；In described B component, including: the glycidyl methacrylate of 60-80 part, the chlorosulfonated polyethylene of 15-25 part, the triethylenediamine of 5-15 part, the silane crosslinker of 3-15 part, the platinum of 1-8 part or platinum complex, the defoamer of 10-15 part, the silane adhesion promoters of 0.1-6 part.
A kind of photovoltaic storage battery fluid sealant based on 13 esters and glyceride the most according to claim 1, it is characterised in that: described fire retardant is at least one in basic zinc carbonate, Firebrake ZB, aluminium hydroxide, magnesium hydroxide, iron oxide red, decabromodiphenyl oxide, red phosphorus, chlorinated paraffin；Heat filling is nanometer silicon carbide, nano aluminum nitride, nm-class boron nitride, nano-silicon nitride, high heat conduction composite powder, at least one in nano silicon carbide aluminum；Described defoamer is any one in silicone and polyacrylate apoplexy due to endogenous wind BYK-065, BYK-066N, BYK-354, DEUCHEM2700.
A kind of photovoltaic storage battery fluid sealant based on 13 esters and glyceride the most according to claim 1, it is characterized in that: in described component A, including: methacrylic acid 13 ester of 50 parts, the chloroform of 35 parts, the dibutyl phthalate of 10 parts, the fire retardant of 25 parts, the titanium dioxide of 5 parts, the antioxidant 1010 of 6 parts, the heat filling composition of 10 parts；In described B component, including: the glycidyl methacrylate of 70 parts, the chlorosulfonated polyethylene of 20 parts, the triethylenediamine of 10 parts, the silane crosslinker of 8 parts, the platinum of 4 parts or platinum complex, the defoamer of 12 parts, the silane adhesion promoters of 3 parts.
4. according to the manufacture method of a kind of based on 13 esters and glyceride the photovoltaic storage battery fluid sealant according to any one of claim 1-3, it is characterised in that: concretely comprise the following steps:
Component A includes step: by above-mentioned weight, by methacrylic acid 13 ester, chloroform, dibutyl phthalate adds in vacuum kneader, and temperature controls at 60～100 DEG C, and vacuum is 0.08～0.12MPa, dehydration 1～6 hour is blended, then moves in reactor, start stirring, put into fire retardant again, titanium dioxide, antioxidant 1010, heat filling, mix homogeneously, obtains component A；B component includes step: by above-mentioned weight, by glycidyl methacrylate, chlorosulfonated polyethylene, triethylenediamine adds in vacuum kneader, and temperature controls at 60～120 DEG C, and vacuum is 0.08～0.12MPa, dehydration 1～7 hour is blended, then moves in reactor, start stirring, put into silane crosslinker, platinum or platinum complex, defoamer, silane adhesion promoters, after mix homogeneously, obtain B component.
5. according to the manufacture method of a kind of based on 13 esters and glyceride the photovoltaic storage battery fluid sealant described in claim 4, it is characterised in that: the rotating speed of described reactor is 50～1000rpm, and the mix and blend time is 15～120 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610486487.8A CN106010306A (en) | 2016-06-29 | 2016-06-29 | Photovoltaic storage battery sealant based on tridecanyl and glyceride and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610486487.8A CN106010306A (en) | 2016-06-29 | 2016-06-29 | Photovoltaic storage battery sealant based on tridecanyl and glyceride and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106010306A true CN106010306A (en) | 2016-10-12 |
Family
ID=57084708
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610486487.8A Pending CN106010306A (en) | 2016-06-29 | 2016-06-29 | Photovoltaic storage battery sealant based on tridecanyl and glyceride and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106010306A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103834330A (en) * | 2012-11-23 | 2014-06-04 | 湖北回天胶业股份有限公司 | Flame retardant acrylate adhesive |
-
2016
- 2016-06-29 CN CN201610486487.8A patent/CN106010306A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103834330A (en) * | 2012-11-23 | 2014-06-04 | 湖北回天胶业股份有限公司 | Flame retardant acrylate adhesive |
Non-Patent Citations (2)
| Title |
|---|
| 李子东: "《现代胶粘技术手册》", 31 January 2002, 新时代出版社 * |
| 王慎敏: "《胶黏剂合成、配方设计与配发实例》", 30 June 2003, 化学工业出版社 * |
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Application publication date: 20161012 |
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