CN106118497A - A kind of photovoltaic storage battery fluid sealant based on ethyl ester and hydroxypropyl acrylate and manufacture method - Google Patents
A kind of photovoltaic storage battery fluid sealant based on ethyl ester and hydroxypropyl acrylate and manufacture method Download PDFInfo
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- CN106118497A CN106118497A CN201610486385.6A CN201610486385A CN106118497A CN 106118497 A CN106118497 A CN 106118497A CN 201610486385 A CN201610486385 A CN 201610486385A CN 106118497 A CN106118497 A CN 106118497A
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- component
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- ethyl ester
- platinum
- silane
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- 239000000565 sealant Substances 0.000 title claims abstract description 15
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 title claims abstract description 14
- 239000012530 fluid Substances 0.000 title claims abstract description 13
- 125000004494 ethyl ester group Chemical group 0.000 title claims abstract description 12
- 238000003860 storage Methods 0.000 title claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 238000000034 method Methods 0.000 title claims abstract description 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 68
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 51
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 34
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 34
- 229910000077 silane Inorganic materials 0.000 claims abstract description 34
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000003063 flame retardant Substances 0.000 claims abstract description 22
- -1 dimethylaminoethyl ethyl Chemical group 0.000 claims abstract description 21
- 239000013530 defoamer Substances 0.000 claims abstract description 20
- HVCNXQOWACZAFN-UHFFFAOYSA-N 4-ethylmorpholine Chemical compound CCN1CCOCC1 HVCNXQOWACZAFN-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 17
- 229920000570 polyether Polymers 0.000 claims abstract description 17
- 239000011863 silicon-based powder Substances 0.000 claims abstract description 17
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000004971 Cross linker Substances 0.000 claims abstract description 15
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims abstract description 14
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002318 adhesion promoter Substances 0.000 claims abstract description 12
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims description 21
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 12
- 230000018044 dehydration Effects 0.000 claims description 10
- 238000006297 dehydration reaction Methods 0.000 claims description 10
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000005543 nano-size silicon particle Substances 0.000 claims description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 6
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 6
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 6
- 235000019253 formic acid Nutrition 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 229910052582 BN Inorganic materials 0.000 claims description 3
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 3
- 206010008190 Cerebrovascular accident Diseases 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 3
- 208000006011 Stroke Diseases 0.000 claims description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 3
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 claims description 3
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 claims description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 3
- 239000000347 magnesium hydroxide Substances 0.000 claims description 3
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 3
- 239000012188 paraffin wax Substances 0.000 claims description 3
- UOURRHZRLGCVDA-UHFFFAOYSA-D pentazinc;dicarbonate;hexahydroxide Chemical group [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[O-]C([O-])=O.[O-]C([O-])=O UOURRHZRLGCVDA-UHFFFAOYSA-D 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
- 238000005660 chlorination reaction Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 3
- 239000003292 glue Substances 0.000 abstract description 2
- 239000000306 component Substances 0.000 description 45
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 239000003570 air Substances 0.000 description 2
- 239000004567 concrete Substances 0.000 description 2
- 238000004382 potting Methods 0.000 description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000008358 core component Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/183—Sealing members
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Sealing Material Composition (AREA)
Abstract
The invention discloses a kind of photovoltaic storage battery fluid sealant based on ethyl ester and hydroxypropyl acrylate and manufacture method, including component A and B component；Described component A is made up of dimethylaminoethyl ethyl ester, ethyl acetate, dioctyl phthalate, fire retardant, silicon powder, antioxidant 1010, heat filling；B component is made up of Hydroxypropyl methacrylate, polyether rubber, N ethyl morpholine, silane crosslinker, platinum or platinum complex, defoamer, silane adhesion promoters；The present invention, by the material in component A and B component is processed production respectively respectively, is processed into by vacuum kneader and reactor.The present invention passes through good fire retardant and heat filling, other materials are utilized to be mutually mixed, in making glue, air bubble content is little, and have that caking property is excellent, high-temp resisting high-humidity resisting excellent performance and flame-retarded heat-conducting and electrical insulating property good, the advantages such as curing rate is fast, easy to operate.
Description
Technical field
The present invention relates to chemical technology field, particularly to accumulator is played the one of sealing function based on ethyl ester and
The photovoltaic storage battery fluid sealant of hydroxypropyl acrylate and manufacture method.
Background technology
In recent years, country built a conservation-minded society in promotion always, advocated energy-saving and emission-reduction, advocated low-carbon environment-friendly, so
Overall situation under, solar energy industry occur to the inexorable trend developed under a kind of policy.Technology disconnected upgrading not also becomes
For the best support of solar energy industry.Solaode is a kind of new technique in solar energy industry, and it utilizes silicon etc. partly to lead
The quantum effect of body, is directly changed into electric energy the visible ray of the sun.The core component of solaode is silicon wafer.For ensureing
The light electrical efficiency of silicon wafer and life-span, industrial meeting is sealed against inside photovoltaic module, and the aluminum frame of assembly, bus bar and
Rosettees etc. are accomplished by with being bonded and sealed that special sealing cement is carried out, it is to avoid in air, water and oxygen etc. enter.
Being currently used for the One component Sealant of photovoltaic module, curing rate is slow, and the curing time of assembly is long, affects efficiency.
Solar energy overhead accumulator requires that fluid sealant should have good resistance to elevated temperatures and good flame-retarded heat-conducting performance, and keeps good
Good electrical insulation capability, and this type of fluid sealant is narrower in research range, it is impossible to meet the market demand.
Summary of the invention
It is an object of the invention to provide one and have that caking property is excellent, high-temp resisting high-humidity resisting excellent performance and flame-retarded heat-conducting and
Electrical insulating property is good, and a kind of based on ethyl ester and hydroxypropyl acrylate the photovoltaic storage battery of the advantages such as curing rate is fast, easy to operate is close
Sealing and manufacture method, solve the use needs of problems of accumulator sealant.
In order to achieve the above object, the present invention provides following technical scheme:
A kind of photovoltaic storage battery fluid sealant based on ethyl ester and hydroxypropyl acrylate, it is characterised in that: include component A and B component；Described
Component A is by dimethylaminoethyl ethyl ester, ethyl acetate, dioctyl phthalate, fire retardant, silicon powder, antioxygen
Agent 1010, heat filling forms；B component is by Hydroxypropyl methacrylate, polyether rubber, N-ethylmorpholine, silane crosslinker, platinum
Or platinum complex, defoamer, silane adhesion promoters forms；In wherein said component A, including: the dimethylaminoethyl acrylate methyl of 40-60 part
Amido ethyl ester, the ethyl acetate of 25-40 part, the dioctyl phthalate of 5-15 part, the fire retardant of 20-35 part, 2-10 part
Silicon powder, the antioxidant 1010 of 2-10 part, 5-15 part heat filling composition；In described B component, including: the first of 60-80 part
Base Hydroxypropyl acrylate, the polyether rubber of 15-25 part, the N-ethylmorpholine of 5-15 part, the silane crosslinker of 3-15 part, 1-8 part
Platinum or platinum complex, the defoamer of 10-15 part, the silane adhesion promoters of 0.1-6 part.
Described fire retardant be basic zinc carbonate, Firebrake ZB, aluminium hydroxide, magnesium hydroxide, iron oxide red, decabromodiphenyl oxide,
At least one in red phosphorus, chlorinated paraffin；Heat filling is nanometer silicon carbide, nano aluminum nitride, nm-class boron nitride, nano silicon nitride
Silicon, high heat conduction composite powder, at least one in nano silicon carbide aluminum；Described defoamer is silicone and polyacrylate apoplexy due to endogenous wind
Any one in BYK-065, BYK-066N, BYK-354, DEUCHEM2700.
In described component A, including: the dimethylaminoethyl ethyl ester of 50 parts, the ethyl acetate of 35 parts, 10 parts
Dioctyl phthalate, the fire retardant of 25 parts, the silicon powder of 5 parts, the antioxidant 1010 of 6 parts, the heat filling composition of 10 parts；
In described B component, including: the Hydroxypropyl methacrylate of 70 parts, the polyether rubber of 20 parts, the N-ethylmorpholine of 10 parts, 8 parts
Silane crosslinker, the platinum of 4 parts or platinum complex, the defoamer of 12 parts, the silane adhesion promoters of 3 parts.
Concretely comprise the following steps:
Component A includes step: by above-mentioned weight, by dimethylaminoethyl ethyl ester, ethyl acetate, adjacent benzene two
Formic acid dioctyl ester adds in vacuum kneader, and temperature controls at 60～100 DEG C, and vacuum is 0.08～0.12MPa, and dehydration is blended
1～6 hour, then move in reactor, start stirring, then put into fire retardant, and silicon powder, antioxidant 1010, heat filling, mixed
Close uniformly, obtain component A；B component includes step: by above-mentioned weight, by Hydroxypropyl methacrylate, and polyether rubber,
N-ethylmorpholine adds in vacuum kneader, and temperature controls at 60～120 DEG C, and vacuum is 0.08～0.12MPa, and dehydration is blended
1～7 hour, then move in reactor, start stirring, put into silane crosslinker, platinum or platinum complex, defoamer, silane increases
Stick, after mix homogeneously, obtains B component.
The rotating speed of described reactor is 50～1000rpm, and the mix and blend time is 15～120 minutes.
Beneficial effects of the present invention: the present invention passes through good fire retardant and heat filling, utilizes other materials the most mixed
Closing, in making glue, air bubble content is little, and has caking property excellence, high-temp resisting high-humidity resisting excellent performance and flame-retarded heat-conducting and electric insulation
Property good, the advantages such as curing rate is fast, easy to operate.
Detailed description of the invention
Below in conjunction with embodiment, technical scheme is clearly and completely described, it is clear that described
Embodiment is only a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, this area
The every other embodiment that those of ordinary skill is obtained under not making creative work premise, broadly falls into present invention protection
Scope.
Embodiment 1:
A kind of photovoltaic storage battery fluid sealant based on ethyl ester and hydroxypropyl acrylate, it is characterised in that: include component A and B component；Described
Component A is by dimethylaminoethyl ethyl ester, ethyl acetate, dioctyl phthalate, fire retardant, silicon powder, antioxygen
Agent 1010, heat filling forms；B component is by Hydroxypropyl methacrylate, polyether rubber, N-ethylmorpholine, silane crosslinker, platinum
Or platinum complex, defoamer, silane adhesion promoters forms；In wherein said component A, including: the dimethylaminoethyl acrylate methyl of 40-60 part
Amido ethyl ester, the ethyl acetate of 25-40 part, the dioctyl phthalate of 5-15 part, the fire retardant of 20-35 part, 2-10 part
Silicon powder, the antioxidant 1010 of 2-10 part, 5-15 part heat filling composition；In described B component, including: the first of 60-80 part
Base Hydroxypropyl acrylate, the polyether rubber of 15-25 part, the N-ethylmorpholine of 5-15 part, the silane crosslinker of 3-15 part, 1-8 part
Platinum or platinum complex, the defoamer of 10-15 part, the silane adhesion promoters of 0.1-6 part.
Described fire retardant be basic zinc carbonate, Firebrake ZB, aluminium hydroxide, magnesium hydroxide, iron oxide red, decabromodiphenyl oxide,
At least one in red phosphorus, chlorinated paraffin；Heat filling is nanometer silicon carbide, nano aluminum nitride, nm-class boron nitride, nano silicon nitride
Silicon, high heat conduction composite powder, at least one in nano silicon carbide aluminum；Described defoamer is silicone and polyacrylate apoplexy due to endogenous wind
Any one in BYK-065, BYK-066N, BYK-354, DEUCHEM2700.
In described component A, including: the dimethylaminoethyl ethyl ester of 50 parts, the ethyl acetate of 35 parts, 10 parts
Dioctyl phthalate, the fire retardant of 25 parts, the silicon powder of 5 parts, the antioxidant 1010 of 6 parts, the heat filling composition of 10 parts；
In described B component, including: the Hydroxypropyl methacrylate of 70 parts, the polyether rubber of 20 parts, the N-ethylmorpholine of 10 parts, 8 parts
Silane crosslinker, the platinum of 4 parts or platinum complex, the defoamer of 12 parts, the silane adhesion promoters of 3 parts.
Concretely comprise the following steps:
Component A includes step: by above-mentioned weight, by dimethylaminoethyl ethyl ester, ethyl acetate, adjacent benzene two
Formic acid dioctyl ester adds in vacuum kneader, and temperature controls at 60～100 DEG C, and vacuum is 0.08～0.12MPa, and dehydration is blended
1～6 hour, then move in reactor, start stirring, then put into fire retardant, and silicon powder, antioxidant 1010, heat filling, mixed
Close uniformly, obtain component A；B component includes step: by above-mentioned weight, by Hydroxypropyl methacrylate, and polyether rubber,
N-ethylmorpholine adds in vacuum kneader, and temperature controls at 60～120 DEG C, and vacuum is 0.08～0.12MPa, and dehydration is blended
1～7 hour, then move in reactor, start stirring, put into silane crosslinker, platinum or platinum complex, defoamer, silane increases
Stick, after mix homogeneously, obtains B component.
The rotating speed of described reactor is 50～1000rpm, and the mix and blend time is 15～120 minutes.
Embodiment 2:
In described component A, including: the dimethylaminoethyl ethyl ester of 40-60 part, the ethyl acetate of 25-40 part, 5-15
The dioctyl phthalate of part, the fire retardant of 20-35 part, the silicon powder of 2-10 part, the antioxidant 1010 of 2-10 part, 5-15 part
Heat filling composition；In described B component, including: the Hydroxypropyl methacrylate of 60-80 part, the polyether rubber of 15-25 part,
The N-ethylmorpholine of 5-15 part, the silane crosslinker of 3-15 part, the platinum of 1-8 part or platinum complex, the defoamer of 10-15 part,
The silane adhesion promoters of 0.1-6 part.
Concrete production and processing step is:
Component A includes step: by above-mentioned weight, by dimethylaminoethyl ethyl ester, ethyl acetate, adjacent benzene two
Formic acid dioctyl ester adds in vacuum kneader, and temperature controls at 60～100 DEG C, and vacuum is 0.08～0.12MPa, and dehydration is blended
1～6 hour, then move in reactor, start stirring, then put into fire retardant, and silicon powder, antioxidant 1010, heat filling, mixed
Close uniformly, obtain component A；B component includes step: by above-mentioned weight, by Hydroxypropyl methacrylate, and polyether rubber,
N-ethylmorpholine adds in vacuum kneader, and temperature controls at 60～120 DEG C, and vacuum is 0.08～0.12MPa, and dehydration is blended
1～7 hour, then move in reactor, start stirring, put into silane crosslinker, platinum or platinum complex, defoamer, silane increases
Stick, after mix homogeneously, obtains B component.
Component A, B component stand subpackage respectively, during use directly by component A, B component according to weight ratio mix homogeneously after
Potting operation can be carried out.
Embodiment 3:
In described component A, including: the dimethylaminoethyl ethyl ester of 50 parts, the ethyl acetate of 35 parts, the adjacent benzene of 10 parts
Dioctyl phthalate dioctyl ester, the fire retardant of 25 parts, the silicon powder of 5 parts, the antioxidant 1010 of 6 parts, the heat filling composition of 10 parts；Described
In B component, including: the Hydroxypropyl methacrylate of 70 parts, the polyether rubber of 20 parts, the N-ethylmorpholine of 10 parts, the silane of 8 parts
Cross-linking agent, the platinum of 4 parts or platinum complex, the defoamer of 12 parts, the silane adhesion promoters of 3 parts.
Concrete production and processing step is:
Component A includes step: by above-mentioned weight, by dimethylaminoethyl ethyl ester, ethyl acetate, adjacent benzene two
Formic acid dioctyl ester adds in vacuum kneader, and temperature controls at 60～100 DEG C, and vacuum is 0.08～0.12MPa, and dehydration is blended
1～6 hour, then move in reactor, start stirring, then put into fire retardant, and silicon powder, antioxidant 1010, heat filling, mixed
Close uniformly, obtain component A；B component includes step: by above-mentioned weight, by Hydroxypropyl methacrylate, and polyether rubber,
N-ethylmorpholine adds in vacuum kneader, and temperature controls at 60～120 DEG C, and vacuum is 0.08～0.12MPa, and dehydration is blended
1～7 hour, then move in reactor, start stirring, put into silane crosslinker, platinum or platinum complex, defoamer, silane increases
Stick, after mix homogeneously, obtains B component.
Component A, B component stand subpackage respectively, during use directly by component A, B component according to weight ratio mix homogeneously after
Potting operation can be carried out.
The above, the only detailed description of the invention of the present invention, but protection scope of the present invention is not limited thereto, and any
Those familiar with the art, in the technical scope that the invention discloses, can readily occur in change or replace, should contain
Cover within protection scope of the present invention.Therefore, protection scope of the present invention should described be as the criterion with scope of the claims.
Claims (5)
1. a photovoltaic storage battery fluid sealant based on ethyl ester and hydroxypropyl acrylate, it is characterised in that: include component A and B component；Institute
State component A by dimethylaminoethyl ethyl ester, ethyl acetate, dioctyl phthalate, fire retardant, silicon powder, anti-
Oxygen agent 1010, heat filling forms；B component by Hydroxypropyl methacrylate, polyether rubber, N-ethylmorpholine, silane crosslinker,
Platinum or platinum complex, defoamer, silane adhesion promoters forms；In wherein said component A, including: the methacrylic acid two of 40-60 part
Methylamino ethyl ester, the ethyl acetate of 25-40 part, the dioctyl phthalate of 5-15 part, the fire retardant of 20-35 part, 2-10
The silicon powder of part, the antioxidant 1010 of 2-10 part, the heat filling composition of 5-15 part；In described B component, including: 60-80 part
Hydroxypropyl methacrylate, the polyether rubber of 15-25 part, the N-ethylmorpholine of 5-15 part, the silane crosslinker of 3-15 part, 1-8
The platinum of part or platinum complex, the defoamer of 10-15 part, the silane adhesion promoters of 0.1-6 part.
A kind of photovoltaic storage battery fluid sealant based on ethyl ester and hydroxypropyl acrylate the most according to claim 1, it is characterised in that:
Described fire retardant is basic zinc carbonate, Firebrake ZB, aluminium hydroxide, magnesium hydroxide, iron oxide red, decabromodiphenyl oxide, red phosphorus, chlorination
At least one in paraffin；Heat filling is nanometer silicon carbide, nano aluminum nitride, nm-class boron nitride, nano-silicon nitride, high heat conduction
Composite powder, at least one in nano silicon carbide aluminum；Described defoamer be silicone and polyacrylate apoplexy due to endogenous wind BYK-065,
Any one in BYK-066N, BYK-354, DEUCHEM2700.
A kind of photovoltaic storage battery fluid sealant based on ethyl ester and hydroxypropyl acrylate the most according to claim 1, it is characterised in that:
In described component A, including: the dimethylaminoethyl ethyl ester of 50 parts, the ethyl acetate of 35 parts, the O-phthalic of 10 parts
Dioctyl phthalate, the fire retardant of 25 parts, the silicon powder of 5 parts, the antioxidant 1010 of 6 parts, the heat filling composition of 10 parts；Described B group
In Fen, including: the Hydroxypropyl methacrylate of 70 parts, the polyether rubber of 20 parts, the N-ethylmorpholine of 10 parts, the crosslinkable silane of 8 parts
Connection agent, the platinum of 4 parts or platinum complex, the defoamer of 12 parts, the silane adhesion promoters of 3 parts.
4. according to a kind of based on ethyl ester and hydroxypropyl acrylate the photovoltaic storage battery fluid sealant according to any one of claim 1-3
Manufacture method, it is characterised in that: concretely comprise the following steps:
Component A includes step: by above-mentioned weight, by dimethylaminoethyl ethyl ester, ethyl acetate, adjacent benzene two
Formic acid dioctyl ester adds in vacuum kneader, and temperature controls at 60～100 DEG C, and vacuum is 0.08～0.12MPa, and dehydration is blended
1～6 hour, then move in reactor, start stirring, then put into fire retardant, and silicon powder, antioxidant 1010, heat filling, mixed
Close uniformly, obtain component A；B component includes step: by above-mentioned weight, by Hydroxypropyl methacrylate, and polyether rubber,
N-ethylmorpholine adds in vacuum kneader, and temperature controls at 60～120 DEG C, and vacuum is 0.08～0.12MPa, and dehydration is blended
1～7 hour, then move in reactor, start stirring, put into silane crosslinker, platinum or platinum complex, defoamer, silane increases
Stick, after mix homogeneously, obtains B component.
5. according to the making side of a kind of based on ethyl ester and hydroxypropyl acrylate the photovoltaic storage battery fluid sealant described in claim 4
Method, it is characterised in that: the rotating speed of described reactor is 50～1000rpm, and the mix and blend time is 15～120 minutes.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610486385.6A CN106118497A (en) | 2016-06-29 | 2016-06-29 | A kind of photovoltaic storage battery fluid sealant based on ethyl ester and hydroxypropyl acrylate and manufacture method |
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| CN201610486385.6A CN106118497A (en) | 2016-06-29 | 2016-06-29 | A kind of photovoltaic storage battery fluid sealant based on ethyl ester and hydroxypropyl acrylate and manufacture method |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103834330A (en) * | 2012-11-23 | 2014-06-04 | 湖北回天胶业股份有限公司 | Flame retardant acrylate adhesive |
-
2016
- 2016-06-29 CN CN201610486385.6A patent/CN106118497A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103834330A (en) * | 2012-11-23 | 2014-06-04 | 湖北回天胶业股份有限公司 | Flame retardant acrylate adhesive |
Non-Patent Citations (2)
| Title |
|---|
| 李子东: "《现代胶粘技术手册》", 31 January 2002, 新时代出版社 * |
| 王慎敏: "《胶黏剂合成、配方设计与配方实例》", 30 June 2003, 化学工业出版社 * |
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Application publication date: 20161116 |