CN103787411A - 一种常压下制备疏水性二氧化锆气凝胶的方法 - Google Patents
一种常压下制备疏水性二氧化锆气凝胶的方法 Download PDFInfo
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- CN103787411A CN103787411A CN201310755386.2A CN201310755386A CN103787411A CN 103787411 A CN103787411 A CN 103787411A CN 201310755386 A CN201310755386 A CN 201310755386A CN 103787411 A CN103787411 A CN 103787411A
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- 238000000034 method Methods 0.000 title claims abstract description 38
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- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 title abstract 5
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 title abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 115
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims abstract description 43
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000000499 gel Substances 0.000 claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
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- BSDOQSMQCZQLDV-UHFFFAOYSA-N butan-1-olate;zirconium(4+) Chemical compound [Zr+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] BSDOQSMQCZQLDV-UHFFFAOYSA-N 0.000 claims abstract description 21
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- 238000005406 washing Methods 0.000 claims abstract description 12
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 45
- 235000019441 ethanol Nutrition 0.000 claims description 29
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 12
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- 238000000926 separation method Methods 0.000 claims description 8
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 6
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 6
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 6
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- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract description 5
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- 238000002791 soaking Methods 0.000 abstract description 2
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- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Description
实施例 | V(H2O):V(HAc):V(EtOH) | 密度(kg/m3) |
1 | 1:1:2 | 432 |
2 | 1:3:5 | 430 |
3 | 1:5:8 | 429 |
4 | 1:7:11 | 431 |
5 | 1:10:15 | 433 |
实施例 | 酸催化剂 | 密度(kg/m3) |
6 | 甲酸 | 433 |
7 | 1mol/L硝酸 | 432 |
8 | 苯甲酸 | 434 |
9 | 1mol/L盐酸 | 431 |
10 | 乙酸 | 436 |
实施例 | 乙醇浸泡时间(h) | 密度(kg/m3) |
11 | 6 | 434 |
12 | 11 | 432 |
13 | 15 | 431 |
14 | 19 | 432 |
15 | 24 | 433 |
实施例 | 老化时间(h) | 密度(kg/m3) |
16 | 6 | 434 |
17 | 11 | 432 |
18 | 15 | 433 |
19 | 18 | 435 |
20 | 24 | 436 |
实施例 | 溶剂置换时间(h) | 密度(kg/m3) |
21 | 6 | 433 |
22 | 11 | 431 |
23 | 15 | 429 |
24 | 19 | 431 |
25 | 24 | 432 |
实施例 | V(HMDS):V(正己烷) | 密度(kg/m3) |
26 | 1:100 | 434 |
27 | 5:100 | 432 |
28 | 20:100 | 431 |
29 | 35:100 | 433 |
30 | 50:100 | 435 |
实施例 | 干燥温度(℃) | 密度(kg/m3) |
31 | 30 | 435 |
32 | 50 | 434 |
33 | 100 | 432 |
34 | 150 | 431 |
35 | 250 | 433 |
Claims (10)
Priority Applications (1)
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CN201310755386.2A CN103787411B (zh) | 2013-12-31 | 2013-12-31 | 一种常压下制备疏水性二氧化锆气凝胶的方法 |
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CN201310755386.2A CN103787411B (zh) | 2013-12-31 | 2013-12-31 | 一种常压下制备疏水性二氧化锆气凝胶的方法 |
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Publication Number | Publication Date |
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CN103787411A true CN103787411A (zh) | 2014-05-14 |
CN103787411B CN103787411B (zh) | 2016-04-13 |
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CN201310755386.2A Expired - Fee Related CN103787411B (zh) | 2013-12-31 | 2013-12-31 | 一种常压下制备疏水性二氧化锆气凝胶的方法 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107469741A (zh) * | 2017-08-10 | 2017-12-15 | 浙江大学 | 一种采用阴离子交换法制备硫化铜气凝胶的方法 |
CN110496574A (zh) * | 2019-10-09 | 2019-11-26 | 江苏脒诺甫纳米材料有限公司 | 一种块状氧化锆气凝胶及其制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5409600A (en) * | 1992-04-13 | 1995-04-25 | Texaco Inc. | Hydrodesulfurization and hydrodenitrogenation over a transition metal oxide aerogel catalyst |
CN101503195A (zh) * | 2009-02-05 | 2009-08-12 | 扬州天辰精细化工有限公司 | 一种制备疏水型SiO2气凝胶的方法 |
CN101844771A (zh) * | 2010-06-14 | 2010-09-29 | 大连理工大学 | 一种常压下制备超疏水性二氧化硅气凝胶的方法 |
CN103011280A (zh) * | 2012-11-27 | 2013-04-03 | 天津大学 | 氧化锆气凝胶的制备方法 |
CN103214034A (zh) * | 2013-04-19 | 2013-07-24 | 天津大学 | 氧化锆-氧化硅复合气凝胶的制备方法 |
-
2013
- 2013-12-31 CN CN201310755386.2A patent/CN103787411B/zh not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5409600A (en) * | 1992-04-13 | 1995-04-25 | Texaco Inc. | Hydrodesulfurization and hydrodenitrogenation over a transition metal oxide aerogel catalyst |
CN101503195A (zh) * | 2009-02-05 | 2009-08-12 | 扬州天辰精细化工有限公司 | 一种制备疏水型SiO2气凝胶的方法 |
CN101844771A (zh) * | 2010-06-14 | 2010-09-29 | 大连理工大学 | 一种常压下制备超疏水性二氧化硅气凝胶的方法 |
CN103011280A (zh) * | 2012-11-27 | 2013-04-03 | 天津大学 | 氧化锆气凝胶的制备方法 |
CN103214034A (zh) * | 2013-04-19 | 2013-07-24 | 天津大学 | 氧化锆-氧化硅复合气凝胶的制备方法 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107469741A (zh) * | 2017-08-10 | 2017-12-15 | 浙江大学 | 一种采用阴离子交换法制备硫化铜气凝胶的方法 |
CN110496574A (zh) * | 2019-10-09 | 2019-11-26 | 江苏脒诺甫纳米材料有限公司 | 一种块状氧化锆气凝胶及其制备方法 |
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Effective date of registration: 20191225 Address after: No. 2388, xinqun Road, Pinghu Economic Development Zone, Jiaxing City, Zhejiang Province Patentee after: PINGHU SHENGJIA ELECTRONICS Co.,Ltd. Address before: 510000 unit 2414-2416, building, No. five, No. 371, Tianhe District, Guangdong, China Patentee before: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Effective date of registration: 20191225 Address after: 510000 unit 2414-2416, building, No. five, No. 371, Tianhe District, Guangdong, China Patentee after: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Address before: The city Zhaohui six districts Chao Wang Road Hangzhou City, Zhejiang province 310014 18 Patentee before: Zhejiang University of Technology |
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Effective date of registration: 20210128 Address after: 445000 No.46, group 2, quannongting village, Yesanguan Town, Badong County, Enshi Tujia and Miao Autonomous Prefecture, Hubei Province Patentee after: Deng Aimei Address before: No.2388, xinqun Road, Pinghu Economic Development Zone, Jiaxing City, Zhejiang Province, 314200 Patentee before: PINGHU SHENGJIA ELECTRONICS Co.,Ltd. |
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Effective date of registration: 20210329 Address after: 102600 Room 403, unit 1, 15th floor, changfengyuan, Huangcun Town, Daxing District, Beijing Patentee after: Du Lihong Address before: 445000 No.46, group 2, quannongting village, Yesanguan Town, Badong County, Enshi Tujia and Miao Autonomous Prefecture, Hubei Province Patentee before: Deng Aimei |
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Effective date of registration: 20220524 Address after: 310012 Room 401, unit 1, building 1, No. 20, Huanggushan Road, Xihu District, Hangzhou City, Zhejiang Province Patentee after: Cao Xiaohua Address before: 102600 Room 403, unit 1, 15th floor, changfengyuan, Huangcun Town, Daxing District, Beijing Patentee before: Du Lihong |
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