CN103664384A - Humid acid type organic water-retaining agent containing wastes in sugar refinery and alcohol plant - Google Patents
Humid acid type organic water-retaining agent containing wastes in sugar refinery and alcohol plant Download PDFInfo
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- CN103664384A CN103664384A CN201310676519.7A CN201310676519A CN103664384A CN 103664384 A CN103664384 A CN 103664384A CN 201310676519 A CN201310676519 A CN 201310676519A CN 103664384 A CN103664384 A CN 103664384A
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Abstract
The invention relates to a humid acid type organic water-retaining agent containing wastes in sugar refinery and alcohol plant. The humid acid type organic water-retaining agent contains active humic acid, a water-retaining agent and bactericide; the composition can effectively promote crop rooting.
Description
Technical field
The present invention relates to fertilizer field, be specifically related to a kind of organic water-holding agent of humic acid type that utilizes sugar refinery, grain distillery's waste.
Background technology
Alcohol waste liquid for sugar refinery is that a kind of using from the sugaring factory such as cane sugar factory, beet-sugar factory residue molasses prepared remaining acid waste liquid after alcohol, contains a large amount of organic matters and beneficial element in such waste liquid.China is this waste liquid of annual discharge tons up to a million at present, have caused serious problem of environmental pollution.The main mode of utilizing of current this waste liquid remains direct irrigation, and on the one hand, the method for application of this extensive style is unfavorable for effective utilization of nutrition; On the other hand, due to the restriction of the aspects such as transportation, this method of application only limits to factory's periphery; Moreover directly the waste liquid of discharge is acid, life-time service can cause soil compaction.
Facts have proved list, single use chemistry water-holding agent effect is not ideal, and easily causes soil compaction.
Corn, in growth season, if there is the weather of blowing, is easy to lodge, once and corn lodging will reduce output greatly.
At present, about being equipped with after alcohol waste liquid for sugar refinery is carried out to special processing, water-holding agent and sterilant are realized water conservation effect and promotion crop, especially taking root of corn has no report.The present inventor finds that alcohol waste liquid for sugar refinery is carried out to the activated humic acid that special processing makes is equipped with sterilant and water-holding agent, can also promote that crop takes root realizing on the basis of water retaining function, reduce the generation of lodging phenomenon, based on above-mentioned discovery, contriver has completed the present invention just.
Summary of the invention
An object of the present invention is to provide a kind of organic water-holding agent of humic acid type that utilizes sugar refinery, grain distillery's waste.In order to achieve the above object, the present invention adopts following technical scheme.
One aspect of the present invention relates to a kind of organic water-holding agent of humic acid type that comprises sugar refinery, grain distillery's waste, the organic water-holding agent of described humic acid type comprises activated humic acid, water-holding agent and sterilant, and each components by weight is activated humic acid: water-holding agent: fungicidal activity composition=10~20:10~20:0.001~0.01;
The preparation method of wherein said activated humic acid is: by the standing clarification of alcohol waste liquid for sugar refinery, obtain supernatant liquor, then described supernatant liquor is heated to 60~90 ℃, preferably 70~80 ℃ are carried out evaporation concentration, be concentrated into 1/4~1/6 of initial weight, obtain concentrated solution, in concentrated solution, add nitric acid or sulfuric acid, regulating the pH of concentrated solution is 1~4, preferably 2~3, the standing activation of normal temperature 12~24 hours, preferably 16~20 hours, then adding ammoniacal liquor to regulate pH is 6~8, obtain activated humic acid liquid, activated humic acid liquid is dry, pulverize, screening, obtain activated humic acid,
Described water-holding agent is selected from one or both in sodium polyacrylate, starch-acrylate graft copolymer, Mierocrystalline cellulose-acrylic acid graft copolymer, polyacrylic acid potassium, polyacrylamide;
Described sterilant is selected from tricyclazole or tertraconazole.
Preferred:
The weight ratio of described activated humic acid, water-holding agent and fungicidal activity composition is 15:15:0.005;
In described activated humic acid preparation process, preferably 75 ℃ of evaporation concentration temperature; The pH of concentrated solution is preferably adjusted to 3; The standing soak time of normal temperature preferably 18 hours; Preferably adding ammoniacal liquor to regulate pH is 7;
Described water-holding agent optimization polypropylene acid sodium;
The preferred tertraconazole of described sterilant;
The organic water-holding agent of the humic acid type that comprises microbiocidal composition of the present invention, can promote maize rooting, significantly increases its rhizome than (approximately 4 leaves were measured during the phase), for example, increase more than 10%, preferably increases more than 20%.
Another object of the present invention relates to the preparation method of the organic water-holding agent of above-mentioned humic acid type, and concrete steps are:
Step 1: by the standing clarification of alcohol waste liquid for sugar refinery, obtain supernatant liquor, then described supernatant liquor is heated to 60~90 ℃, preferably 70~80 ℃ carry out evaporation concentration, be concentrated into 1/4~1/6 of initial weight, obtain concentrated solution, in concentrated solution, add nitric acid or sulfuric acid, regulating the pH of concentrated solution is 1~4, preferably 2~3, the standing activation of normal temperature 12~24 hours, preferably 16~20 hours, then adding ammoniacal liquor to regulate pH is 6~8, obtain activated humic acid liquid, activated humic acid liquid is dried, pulverizes, is sieved, obtain activated humic acid;
Step 2: take respectively the above-mentioned activated humic acid preparing, water-holding agent and sterilant in described ratio, and mix, obtain mixture; Wherein, the ratio of each component is activated humic acid: water-holding agent: fungicidal activity composition=10~20:10~20:0.001~0.01;
Step 3: the adhesive solution that accounts for said mixture gross weight 2-6% is added in said mixture, carry out granulation; Concrete prilling process can be used the method for this area routine, for example extruder grain, rotary table granulation etc.Described binding agent can be used the binding agent of this area routine, such as starch, carboxymethyl cellulose etc.; The concentration of described binding agent can be controlled according to actual needs, for example 10-20%.
Step 4: the particle obtaining is dried, is sieved, obtain the organic water-holding agent of described humic acid type.The particle diameter of final particle can be adjusted as required, for example 1-8mm, preferably 2-5mm.
Wherein, described water-holding agent is selected from one or both in sodium polyacrylate, starch-acrylate graft copolymer, Mierocrystalline cellulose-acrylic acid graft copolymer, polyacrylic acid potassium, polyacrylamide;
Wherein, described sterilant is selected from tricyclazole or tertraconazole.Described sterilant can be former medicine or its preparation, preferably its wettable powder; Wherein, when sterilant used is preparation, the amount of its used in amounts folding composite reactive composition, the i.e. add-on of fungicidal activity composition in preparation.
Preferred:
In described activated humic acid preparation process, preferably 75 ℃ of evaporation concentration temperature; The pH of concentrated solution is preferably adjusted to 3; The standing soak time of normal temperature preferably 18 hours; Preferably adding ammoniacal liquor to regulate pH is 7;
Described water-holding agent optimization polypropylene acid sodium;
The preferred tertraconazole of described sterilant;
The preferred 15:15:0.005 of weight ratio of described activated humic acid, water-holding agent and fungicidal activity composition.
Another object of the present invention relates to the organic water-holding agent of humic acid type of the present invention and is promoting crop, the purposes in maize rooting especially, and wherein the organic water-holding agent of humic acid type is used as base manure, and a mu consumption is 5-20kg, preferred 8kg.Wherein the rhizome of Maize Seedling than increasing more than approximately 10%, preferably more than 20% (approximately 4 leaves were measured during the phase).
The application's various raw materials used are all available on market.For example alcohol waste liquid for sugar refinery can be cane sugar factory alcohol slops or beet-sugar factory alcohol slops, can be from sugar refinery or grain distillery obtain.Water-holding agent as sodium polyacrylate, starch-acrylate graft copolymer, Mierocrystalline cellulose-acrylic acid graft copolymer, polyacrylic acid potassium, polyacrylamide be all available on market, water-intake rate is about 1:500-1000 for example, for example, purchased from Hangzhou Xu Mei Chemical Co., Ltd., Renqiu City Zheng Hao Chemicals company limited.Mensurating Tricyclazole Technical, the former medicine of tertraconazole, 20% tricyclazole wettable powder and 25% tertraconazole wettable powder are also commercially available, for example, purchased from Danyang, Jiangsu Province pesticide chemical factory, and also can be according to the conventional machining method self-control of wettable powder.The application's other raw materials used also can be buied easily from the market.
Beneficial effect of the present invention is:
By the mixing of activated humic acid, water-holding agent and sterilant etc. is used, can obviously promote crop to take root, increase the rhizome ratio of crop, strengthen lodging resistance;
The present invention, by applied in any combination such as activated humic acid, water-holding agents, overcomes the applied defect of single fertilizer, has saved labor force.
Embodiment
In order to understand the present invention, with embodiment, further illustrate the present invention below, but do not limit the present invention.
The preparation of embodiment 1 product 1 of the present invention
Get cane sugar factory alcohol slops 160kg, standing clarification, obtains supernatant liquor, then described supernatant liquor is heated to 75 ℃ and carries out evaporation concentration, obtain concentrated solution 32kg, in concentrated solution, add nitric acid until the pH of concentrated solution is 3, the standing activation of normal temperature 18 hours, then adding ammoniacal liquor to regulate pH is 7, obtain activated humic acid liquid, activated humic acid liquid is dried, pulverizes, is sieved, obtain activated humic acid, about 15kg is standby.
Take 15kg sodium polyacrylate (purchased from Renqiu City Zheng Hao Chemicals company limited), standby.
Take the tertraconazole wettable powder standby (purchased from Danyang, Jiangsu Province pesticide chemical factory) (amounting to activeconstituents is 5g) of 20g25%;
Activated humic acid obtained above and sodium polyacrylate, tertraconazole wettable powder are mixed, add the amidin of 1kg10%, mix, then carry out extruder grain.
Finally, the particle obtaining is dried, is sieved, obtain the organic water-holding agent of described humic acid type.Wherein, the weight ratio of activated humic acid, water-holding agent, sterilant is 15:15:0.005.
The preparation of embodiment 2 product 2 of the present invention
Get beet-sugar factory alcohol slops 100kg, standing clarification, obtains supernatant liquor, then described supernatant liquor is heated to 85 ℃ and carries out evaporation concentration, obtain concentrated solution 22kg, in concentrated solution, add nitric acid until the pH of concentrated solution is 2, the standing activation of normal temperature 24 hours, then adding ammoniacal liquor to regulate pH is 6.5, obtain activated humic acid liquid, activated humic acid liquid is dried, pulverizes, is sieved, obtain activated humic acid, about 10kg is standby.
Take 20kg polyacrylamide (purchased from Renqiu City Zheng Hao Chemicals company limited), standby.
Take the tricyclazole wettable powder standby (purchased from Danyang, Jiangsu Province pesticide chemical factory) (amounting to activeconstituents is 10g) of 50g20%;
Activated humic acid obtained above and polyacrylamide, tricyclazole wettable powder are mixed, add the amidin of 1kg12% to carry out rotary table granulation.
Finally, the particle obtaining is dried, is sieved, obtain the organic water-holding agent of described humic acid type.Wherein, the weight ratio of activated humic acid, water-holding agent, sterilant is 10:20:0.01.
Comparative example 1
Get cane sugar factory alcohol slops 100kg, standing clarification, obtains supernatant liquor, then described supernatant liquor is heated to 75 ℃ and carries out evaporation concentration to concentrated solution 20kg.
Comparative example 2
By water-holding agent sodium polyacrylate (purchased from Renqiu City Zheng Hao Chemicals company limited) and 25% tertraconazole wettable powder according to sodium polyacrylate: the product that the ratio that tertraconazole activeconstituents is 3:0.001 is mixed to get
Test example 1 rhizome compares effect test
Choose a smooth plot, mark off five regions, approximately 0.5 mu of every region area, respectively to each Zoned application as the material described in the table 1 of base manure, it is 8kg/ mu (wherein the mu consumption of comparative example 1 is about 20kg) that its amount of application is amounted to into mu consumption, and each processes random alignment.Turned in soil afterwards, maize planting (kind: Nongda108), control the about 40-50cm of line-spacing, spacing in the rows 30-40cm.
Table 1 is respectively processed application of substances and amount of application
Sequence number | Application of substances | Mu consumption (kg) | Remarks |
1 | Product 1 of the present invention | 8 | The about 4kg of water conservation dosage |
2 | Product 2 of the present invention | 8 | The about 5.3kg of water conservation dosage |
3 | Comparative example 1 | 20 | - |
4 | Comparative example 2 | 8 | ? |
5 | Water-holding agent sodium polyacrylate | 8 | - |
6 | Blank (not using any material) | - | ? |
Wherein until corn seedling, grow to 4 leaves about the phase time, each processing is sampled respectively (five point sampling methods, 3 of every point samplings), gather the corn seedling in 4 leaf phases.Afterwards seedling is placed in to clear water and cleans, over-ground part and underground part are cut off with scissors, carry out rhizome than measuring.
Concrete measuring method is: respectively over-ground part and underground part are placed in to 60 ℃ of baking ovens and dry to constant weight, by following formula, calculate rhizome ratio:
Wherein each rhizome of processing than data as table 2:
Table 2 is respectively processed rhizome and is compared result
Sequence number | Process | Rhizome ratio |
1 | Product 1 of the present invention | 0.78 |
2 | Product 2 of the present invention | 0.76 |
3 | Comparative example 1 | 0.53 |
4 | Comparative example 2 | 0.62 |
5 | Water-holding agent sodium polyacrylate | 0.52 |
6 | Blank (not using any material) | 0.50 |
By above-mentioned data, be not difficult to find out, wherein at product of the present invention, with respect to using separately conventional alcohol waste liquid for sugar refinery concentrated solution, use sodium polyacrylate water-holding agent separately, use mixture and the blank of water-holding agent and sterilant, the rhizome ratio that has all obviously increased Maize Seedling, this is conducive to the resistant to lodging of corn.
Above-mentioned example is only to further explanation of the present invention, is not limitation of the invention, by the scheme that such scheme is simply adjusted and then obtained, same within the application's protection domain.
Claims (7)
1. the organic water-holding agent of humic acid type that comprises sugar refinery, grain distillery's waste, the organic water-holding agent of described humic acid type comprises activated humic acid, water-holding agent and sterilant.
2. the organic water-holding agent of humic acid type that comprises sugar refinery, grain distillery's waste according to claim 1, wherein each components by weight is activated humic acid: water-holding agent: fungicidal activity composition=10~20:10~20:0.001~0.01.
3. the organic water-holding agent of humic acid type that comprises sugar refinery, grain distillery's waste according to claim 1, wherein each components by weight is activated humic acid: water-holding agent: fungicidal activity composition=10~20:10~20:0.001~0.01;
The preparation method of wherein said activated humic acid is: by the standing clarification of alcohol waste liquid for sugar refinery, obtain supernatant liquor, then described supernatant liquor is heated to 60~90 ℃, preferably 70~80 ℃ are carried out evaporation concentration, be concentrated into 1/4~1/6 of initial weight, obtain concentrated solution, in concentrated solution, add nitric acid or sulfuric acid, regulating the pH of concentrated solution is 1~4, preferably 2~3, the standing activation of normal temperature 12~24 hours, preferably 16~20 hours, then adding ammoniacal liquor to regulate pH is 6~8, obtain activated humic acid liquid, activated humic acid liquid is dry, pulverize, screening, obtain activated humic acid,
Described water-holding agent is selected from one or both in sodium polyacrylate, starch-acrylate graft copolymer, Mierocrystalline cellulose-acrylic acid graft copolymer, polyacrylic acid potassium, polyacrylamide;
Described sterilant is selected from tricyclazole or tertraconazole.
4. the organic water-holding agent of humic acid type according to claim 3, is characterized in that,
Described living in raw humic acids preparation process, preferably 75 ℃ of evaporation concentration temperature; The pH of concentrated solution is preferably adjusted to 3; The standing soak time of normal temperature preferably 18 hours; Preferably adding ammoniacal liquor to regulate pH is 7;
Described water-holding agent optimization polypropylene acid sodium;
The preferred tertraconazole of described sterilant;
And the preferred 15:15:0.005 of weight ratio of described activated humic acid, water-holding agent and fungicidal activity composition.
5. the preparation method of the organic water-holding agent of humic acid type described in claim 1-3, is characterized in that:
Step 1: by the standing clarification of alcohol waste liquid for sugar refinery, obtain supernatant liquor, then described supernatant liquor is heated to 60~90 ℃, preferably 70~80 ℃ carry out evaporation concentration, be concentrated into 1/4~1/6 of initial weight, obtain concentrated solution, in concentrated solution, add nitric acid or sulfuric acid, regulating the pH of concentrated solution is 1~4, preferably 2~3, the standing activation of normal temperature 12~24 hours, preferably 16~20 hours, then adding ammoniacal liquor to regulate pH is 6~8, obtain activated humic acid liquid, activated humic acid liquid is dried, pulverizes, is sieved, obtain activated humic acid;
Step 2: take respectively the above-mentioned activated humic acid preparing, water-holding agent and sterilant in described ratio, and mix, obtain mixture;
Step 3: the adhesive solution that accounts for said mixture gross weight 2-6% is added in said mixture, carry out granulation;
Step 4: the particle obtaining is dried, is sieved, obtain the organic water-holding agent of described humic acid type.
6. method according to claim 5, is characterized in that,
In described activated humic acid preparation process, preferably 75 ℃ of evaporation concentration temperature; Excellent the stating of pH of concentrated solution is adjusted to 3; The standing soak time of normal temperature preferably 18 hours; Preferably adding ammoniacal liquor to regulate pH is 7;
Described water-holding agent optimization polypropylene acid sodium;
The preferred tertraconazole of described sterilant;
And the preferred 15:15:0.005 of weight ratio of described activated humic acid, water-holding agent and fungicidal activity composition.
7. the purposes of the organic water-holding agent of humic acid type that the organic water-holding agent of described humic acid type described in claim 1-4 or claim 5-6 prepare in promoting maize rooting.
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Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1102944A (en) * | 1993-11-24 | 1995-05-31 | 化学工业部沈阳化工研究院 | Seed processing agent for paddy rice direct seeding |
CN101113122A (en) * | 2007-07-02 | 2008-01-30 | 王树禹 | Rice nursery sock growing seedling strengthen agent and method for using |
CN101209053A (en) * | 2006-12-30 | 2008-07-02 | 江苏里下河地区农业科学研究所 | Forest tree water-preserving promoting agent |
CN101462899A (en) * | 2008-11-14 | 2009-06-24 | 林晓山 | Technique for producing humic acid organic compound fertilizer from sugar refinery waste slag and wastewater |
CN102627775A (en) * | 2012-04-12 | 2012-08-08 | 叶长东 | Method for extracting fulvic acid from sugar cane deep processing alcohol slops |
CN102643117A (en) * | 2012-04-10 | 2012-08-22 | 福建省诏安县绿洲生化有限公司 | Method for producing organic liquid fertilizer base solution with high physiological activity from high-concentration organic wastewater |
CN102731174A (en) * | 2011-04-13 | 2012-10-17 | 叶长东 | Fulvic acid fertilizer and preparation method thereof |
CN103102226A (en) * | 2013-03-11 | 2013-05-15 | 叶长东 | Soil conditioner containing sugar refinery alcohol waste liquor, filter mud and peat |
-
2013
- 2013-12-13 CN CN201310676519.7A patent/CN103664384B/en active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1102944A (en) * | 1993-11-24 | 1995-05-31 | 化学工业部沈阳化工研究院 | Seed processing agent for paddy rice direct seeding |
CN101209053A (en) * | 2006-12-30 | 2008-07-02 | 江苏里下河地区农业科学研究所 | Forest tree water-preserving promoting agent |
CN101113122A (en) * | 2007-07-02 | 2008-01-30 | 王树禹 | Rice nursery sock growing seedling strengthen agent and method for using |
CN101462899A (en) * | 2008-11-14 | 2009-06-24 | 林晓山 | Technique for producing humic acid organic compound fertilizer from sugar refinery waste slag and wastewater |
CN102731174A (en) * | 2011-04-13 | 2012-10-17 | 叶长东 | Fulvic acid fertilizer and preparation method thereof |
CN102643117A (en) * | 2012-04-10 | 2012-08-22 | 福建省诏安县绿洲生化有限公司 | Method for producing organic liquid fertilizer base solution with high physiological activity from high-concentration organic wastewater |
CN102627775A (en) * | 2012-04-12 | 2012-08-08 | 叶长东 | Method for extracting fulvic acid from sugar cane deep processing alcohol slops |
CN103102226A (en) * | 2013-03-11 | 2013-05-15 | 叶长东 | Soil conditioner containing sugar refinery alcohol waste liquor, filter mud and peat |
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CN105542783A (en) * | 2015-12-16 | 2016-05-04 | 罗永城 | Humic acid type inorganic water-retaining agent by using edible vinegar factory waste liquid and preparation method thereof |
CN105542778A (en) * | 2015-12-16 | 2016-05-04 | 罗永城 | Humic acid type organic water-retaining agent and preparation method thereof |
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Effective date of registration: 20191230 Address after: 530007, B-2 building, headquarter of China ASEAN enterprise, No. 1, headquarters Road, Nanning hi tech Zone, the Guangxi Zhuang Autonomous Region Patentee after: Guangxi Qin Tak Polytron Technologies Inc Address before: 530007, B-2 building, headquarter of China ASEAN enterprise, No. 1, headquarters Road, Nanning hi tech Zone, the Guangxi Zhuang Autonomous Region Patentee before: Ye Changdong |