CN105542780A - Novel water-retaining agent by using edible vinegar factory waste liquid and preparation method thereof - Google Patents
Novel water-retaining agent by using edible vinegar factory waste liquid and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
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- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
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Abstract
The invention discloses a novel water-retaining agent by using edible vinegar factory waste liquid and a preparation method thereof, and belongs to the field of water-retaining agent preparation technology. The novel water-retaining agent comprises the following raw materials in parts by weight: 30-40 parts of a water-retaining agent, 25-35 parts of humic acid, 6-10 parts of distilled water, 0.05-0.08 parts of a mildew inhibitor, and 0.02-0.04 parts of an insecticidal composition; the novel water-retaining agent is prepared by the following steps: preparation of humic acid, preparation of the insecticidal composition, mixing, granulation, drying, etc. The novel water-retaining agent can effectively prevent insect diseases, improve lodging resistance of crops, and increase yields; the edible vinegar factory waste liquid is used for preparing humic acid, so that recycling of wastes is realized, and cost is reduced; the novel water-retaining agent has good application effect and is good for promotion and application.
Description
Technical field
The invention belongs to water-holding agent preparing technical field, be specifically related to a kind ofly utilize novel water-retaining agent of vinegar factory waste liquid and preparation method thereof.
Background technology
Containing a large amount of organic matters and beneficial element in vinegar factory waste liquid, China discharges this waste liquid more than 1,000,000 tons at present every year, has caused serious problem of environmental pollution.The main Land use systems of current this waste liquid remains direct irrigation, and on the one hand, the method for application of this extensive style is unfavorable for effective utilization of nutrition; On the other hand, due to the restriction of the aspects such as transport, this method of application is only limitted to factory's periphery; Moreover the waste liquid of directly discharge is in acid, and life-time service can cause soil compaction.
Farm crop, at Growing season, if there is weather of blowing, are easy to lodge, and farm crop are once lodging, greatly will reduce output.
Facts have proved, conventional water-holding agent is functional single, is used alone and easily causes soil compaction, and therefore, studying a kind of multi-functional novel water-retaining agent becomes developing direction.
Summary of the invention
The invention provides and a kind ofly utilize novel water-retaining agent of vinegar factory waste liquid and preparation method thereof, to solve the functional problem such as single of conventional water-holding agent, novel water-retaining agent of the present invention can not only preventing disease and pest effectively, and can strengthen the lodging resistance of farm crop, improves output; Water-holding agent preparation cost of the present invention is low, effect good, is conducive to applying.
For solving above technical problem, the present invention by the following technical solutions:
Utilize a novel water-retaining agent for vinegar factory waste liquid, in units of weight part, comprise following raw material: water-holding agent 30-40 part, humic acids 25-35 part, distilled water 6-10 part, mould inhibitor 0.05-0.08 part, insect-killing composition 0.02-0.04 part.
Preferably, described water-holding agent comprises one or both in starch-acrylate graft copolymer, Mierocrystalline cellulose-acrylic acid graft copolymer.
Preferably, described humic acids is made up of vinegar factory waste liquid.
Preferably, described mould inhibitor comprises one or both in quinoxyfen, triazolone.
Preferably, described insect-killing composition is extracted made by tobacco, trypterygine, capsicum, the rhizome of Chinese monkshood, pyrethrum, print chinaberry, leaf of tea tree, Herba Patriniae, bitter dish, absinth, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, Root or stem of Hairypetal Millettia, Chinese prickly ash, purslane, thorn apple, Herba Anabasis aphyllae, weeping willow leaf, leaf of Pterocarya Stenoptera.
The present invention also provides a kind of preparation method utilizing the novel water-retaining agent of vinegar factory waste liquid, comprises the following steps:
S1: vinegar factory waste liquid is left standstill clarification, obtain supernatant liquor, then described supernatant liquor is heated to 70-80 DEG C and carries out evaporation concentration, being concentrated into pH value is 2.5-3.5, stops heating, left at room temperature activation 13-15h, then add volatile salt adjust ph to 6.2-7.6, obtain humic acid solution, humic acid solution is dried to water content≤6% at 85-105 DEG C, 100-300 mesh sieve is crossed, obtained humic acids after pulverizing;
S2: by tobacco, trypterygine, capsicum, the rhizome of Chinese monkshood, pyrethrum, print chinaberry, leaf of tea tree, Herba Patriniae, bitter dish, absinth, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, Root or stem of Hairypetal Millettia, Chinese prickly ash, purslane, thorn apple, Herba Anabasis aphyllae, weeping willow leaf, leaf of Pterocarya Stenoptera co-grinding, liquid is extracted under ultrasonic assistant ethanol extraction method, gained medical filtration, to be concentrated into after water content≤20% to obtain mixture A, gained mixture A is dried to water content≤6% at 90-100 DEG C, 100-300 mesh sieve is crossed, obtained insect-killing composition after pulverizing;
S3: take humic acids that step S1 obtains, step S2 obtained insect-killing composition, water-holding agent, mould inhibitor and distilled water respectively in described ratio, mix to obtain mixture B, described mixture B is carried out making 1.5-2.5mm particle and be dried to water content≤6% at 90-100 DEG C, obtained novel water-retaining agent.
Preferably, the condition of the ethanol extraction method of ultrasonic assistant described in step S2 extraction liquid is: solid-liquid ratio is 1:8-16, and ultrasonic power is 140-180W, and alcohol concn is 50%-80%, and Extracting temperature is 50-70 DEG C, and extraction time is 60-90min.
The effect that instant component has is as follows:
The humic acids utilizing vinegar factory waste liquid to make contains a large amount of organic matters and beneficial element, is conducive to growing up healthy and sound of farm crop, shortens growth cycle.
Mould inhibitor, refers to and can prevent microorganism from causing mouldy medicament, has very strong suppression, killing action to bacterium, fungi.
Tobacco has the effects such as promoting the circulation of QI to relieve pain, eliminating dampness, detumescence, removing toxic substances desinsection.
Trypterygine can be dispeled the wind, removing toxic substances, desinsection.External application treating rheumatic arthritis, skin is itched, and kills maggot, wriggler, water-snail eradication, malicious mouse.
Capsicum can alleviate chest abdomen crymodynia, prevents dysentery, kills and presses down stomach abdomen entozoa, controls heart trouble and coronary sclerosis, the function such as have sterilization, anticorrosion, seasoning, nutrition, dispel cold.
The napelline of aconite extract has suppression or killing action to streptococcus aureus, dysentery bacterium, Corynebacterium diphtheriae, Pseudomonas aeruginosa.
Pyrethrum containing 4 kinds of insecticidal constituents, pyrethrin (pyrethrin) I, II and cinerin (cinerin) I, II, pyrethrum to various insects as mosquito, fly, bedbug and cockroach etc. have toxic action.
Print Melia, in Meliaceae, comes from South East Asia, and containing print chinaberry, solannin etc., have good disinsection efficiency, insect is once contact, and growth will be suppressed.
The extract of leaf of tea tree has potent germicidal action, and tea tree can effectively tackle for various fungal infection, can kill streptococcus aureus, diphtheria corynebacterium.
Herba Patriniae, with root stock and root, all herbal medicine, belongs to antipyretic and antidotal type medicine in Chinese medicine, cool in nature, taste is pungent, bitter.Return liver, stomach, large intestine channel, have effect that is clearing heat and detoxicating, removing blood stasis and expelling pus.Modern pharmacy is thought, it is containing volatile oil, Patrinia scaniosaefolia saponin and β-sterol glucose formula, have anti-inflammatory, antibacterial, calm, protect the liver the effect with cardiac stimulant diuresis.Herba Patriniae has suppression or killing action to streptococcus aureus, dysentery bacterium, Corynebacterium diphtheriae, Pseudomonas aeruginosa.
Containing the composition such as taraxasterol, choline in bitter dish, stronger germicidal action is had to staphylococcus aureus resistance bacterial strain, Hemolytic streptococcus, also there is certain lethal effect to pneumococcus, meningococcus, diphtheria corynebacterium, Pseudomonas aeruginosa, dysentery bacterium etc., therefore all have certain curative effect to icterohepatitis, pharyngolaryngitis, bacillary dysentery, cold, fever and chronic tracheitis, tonsillitis etc.
Absinth bitter, cold in nature, poisonous, there is heat-clearing and damp-drying drug, drive ascarid, stomach invigorating, the effect such as antibacterial desinsection, all have suppression and killing action to multiple coccus, bacillus, fungi and virus etc.
The bark of ash has antibacterial insecticidal action, has obvious restraining effect, be usually used in controlling bacillary dysentery clinically to streptococcus aureus, subtilis, intestinal bacteria, cereuisiae fermentum, bacterium wine yeast etc., enteritis, leukorrhea, chronic tracheitis, conjunctival congestion with pain and swelling of the eye etc.
Kuh-seng belongs to per nnial herb; Be taken as the substitute of monkshood and radix aconiti agrestis at the Northwest's kuh-seng and use, simultaneously the traditional medicine of the ethnic minority such as Ye Shi kazakh, the Hui ethnic group, is mainly used in pain relieving, dehumidifying, cold-dispelling.
Roots of Euphorbia soongarica is per nnial herb, main product in Gansu, the ground such as Xinjiang and Russia, the substitute in new thick area as the root of Beijing euphorbia uses, and has effect of removing fluid-retention by purgation, dispersing swelling and dissipating binds.
Root or stem of Hairypetal Millettia dicotyledons medicine leguminous plants, extract bitter, very toxic, there is killing parasites to relieve itching, by effects such as arthritis with fixed pain caused by dampness.
Chinese prickly ash can alleviate chest abdomen crymodynia, prevents dysentery, kills and presses down stomach abdomen entozoa, controls heart trouble and coronary sclerosis, the function such as have sterilization, anticorrosion, seasoning, nutrition, dispel cold.
Purslane is cold in nature, the sweet acid of taste, and have clearing heat and detoxicating, Li Shui dries, and loose blood detumescence, dust-collection sterilization, anti-inflammatory analgetic, effects such as cool blood of stopping blooding, have stronger restraining effect to dysentery bacterium, Corynebacterium diphtheriae and intestinal bacteria.
Thorn apple is botanical pesticide, has extremely strong sterilization, insecticidal action.
Herba Anabasis aphyllae belongs to chenopod, is dicotyledons, has the effects such as clearing heat and detoxicating, antisepsis and anti-inflammation, pain relieving desinsection, can be used for rural area preparation agricultural chemicals of eliminating the four pests--rats, bedbugs, flies and mosquitoes, the use of disinfestation and deratization.
Weeping willow leaf has the effect such as clearing heat and detoxicating, expelling wind and removing dampness, antisepsis and anti-inflammation, maggot of going out, infanticide Jue.
Chinese ash has the effects such as antibacterial, desinsection, removing toxic substances, and leaf is poisonous, can used as pesticides sterilant.
The present invention has following beneficial effect:
(1) novel water-retaining agent of the present invention can obviously promote that farm crop take root, and increases the rhizome ratio of farm crop, strengthens lodging resistance;
(2) the present invention is by combinations such as water-holding agent, humic acids, mould inhibitor, insect-killing compositions, adds the function of water-holding agent;
(3) the present invention utilizes vinegar factory waste liquid to prepare humic acids, is conducive to the resource utilization of waste, reduces cost of the present invention;
(4) novel water-retaining agent of the present invention can not only preventing disease and pest effectively, and can improve edatope;
(5) novel water-retaining agent composition degradable of the present invention, can not bring environmental pollution;
(6) novel water-retaining agent effect of the present invention is good, is conducive to applying.
Embodiment
Be specifically described below in conjunction with specific embodiment.
Embodiment 1
Utilize a novel water-retaining agent for vinegar factory waste liquid, in units of weight part, comprise following raw material: starch-acrylate graft copolymer 30 parts, humic acids 25 parts, distilled water 6 parts, mould inhibitor 0.05 part, insect-killing composition 0.02 part.
The described preparation method utilizing the novel water-retaining agent of vinegar factory waste liquid, comprises the following steps:
S1: vinegar factory waste liquid is left standstill clarification, obtain supernatant liquor, then described supernatant liquor is heated to 70 DEG C and carries out evaporation concentration, being concentrated into pH value is 3.5, stops heating, left at room temperature activation 13h, then add volatile salt adjust ph to 6.2, obtain humic acid solution, humic acid solution being dried at 105 DEG C water content is 6%, 100 mesh sieve are crossed, obtained humic acids after pulverizing;
S2: by tobacco, trypterygine, capsicum, the rhizome of Chinese monkshood, pyrethrum, print chinaberry, leaf of tea tree, Herba Patriniae, bitter dish, absinth, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, Root or stem of Hairypetal Millettia, Chinese prickly ash, purslane, thorn apple, Herba Anabasis aphyllae, weeping willow leaf, leaf of Pterocarya Stenoptera co-grinding, liquid is extracted under ultrasonic assistant ethanol extraction method, condition is: solid-liquid ratio is 1:8, ultrasonic power is 140W, alcohol concn is 50%, Extracting temperature is 50 DEG C, extraction time is 90min, gained medical filtration, be concentrated into water content be after 20% mixture A, it is 6% that gained mixture A is dried to water content at 90 DEG C, 100 mesh sieve are crossed after pulverizing, obtained insect-killing composition,
S3: take humic acids that step S1 obtains, step S2 obtained insect-killing composition, water-holding agent, mould inhibitor and distilled water respectively in described ratio, mix to obtain mixture B, being carried out making 1.5-2.5mm particle and at 90 DEG C, be dried to water content by described mixture B is 6%, obtained novel water-retaining agent.
Embodiment 2
Utilize a novel water-retaining agent for vinegar factory waste liquid, in units of weight part, comprise following raw material: starch-acrylate graft copolymer 40 parts, humic acids 35 parts, distilled water 10 parts, mould inhibitor 0.08 part, insect-killing composition 0.04 part.
The described preparation method utilizing the novel water-retaining agent of vinegar factory waste liquid, comprises the following steps:
S1: vinegar factory waste liquid is left standstill clarification, obtain supernatant liquor, then described supernatant liquor is heated to 80 DEG C and carries out evaporation concentration, being concentrated into pH value is 2.5, stops heating, left at room temperature activation 15h, then add volatile salt adjust ph to 7.6, obtain humic acid solution, humic acid solution being dried at 100 DEG C water content is 5%, 300 mesh sieve are crossed, obtained humic acids after pulverizing;
S2: by tobacco, trypterygine, capsicum, the rhizome of Chinese monkshood, pyrethrum, print chinaberry, leaf of tea tree, Herba Patriniae, bitter dish, absinth, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, Root or stem of Hairypetal Millettia, Chinese prickly ash, purslane, thorn apple, Herba Anabasis aphyllae, weeping willow leaf, leaf of Pterocarya Stenoptera co-grinding, liquid is extracted under ultrasonic assistant ethanol extraction method, condition is: solid-liquid ratio is 1:16, ultrasonic power is 180W, alcohol concn is 80%, Extracting temperature is 70 DEG C, extraction time is 60min, gained medical filtration, be concentrated into water content be after 16% mixture A, it is 5% that gained mixture A is dried to water content at 100 DEG C, 300 mesh sieve are crossed after pulverizing, obtained insect-killing composition,
S3: take humic acids that step S1 obtains, step S2 obtained insect-killing composition, water-holding agent, mould inhibitor and distilled water respectively in described ratio, mix to obtain mixture B, being carried out making 1.5-2.5mm particle and at 100 DEG C, be dried to water content by described mixture B is 5%, obtained novel water-retaining agent.
Embodiment 3
Utilize a novel water-retaining agent for vinegar factory waste liquid, in units of weight part, comprise following raw material: starch-acrylate graft copolymer 35 parts, humic acids 30 parts, distilled water 8 parts, mould inhibitor 0.07 part, insect-killing composition 0.03 part.
The described preparation method utilizing the novel water-retaining agent of vinegar factory waste liquid, comprises the following steps:
S1: vinegar factory waste liquid is left standstill clarification, obtain supernatant liquor, then described supernatant liquor is heated to 75 DEG C and carries out evaporation concentration, being concentrated into pH value is 3, stops heating, left at room temperature activation 14h, then add volatile salt adjust ph to 7, obtain humic acid solution, humic acid solution being dried at 95 DEG C water content is 4%, 200 mesh sieve are crossed, obtained humic acids after pulverizing;
S2: by tobacco, trypterygine, capsicum, the rhizome of Chinese monkshood, pyrethrum, print chinaberry, leaf of tea tree, Herba Patriniae, bitter dish, absinth, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, Root or stem of Hairypetal Millettia, Chinese prickly ash, purslane, thorn apple, Herba Anabasis aphyllae, weeping willow leaf, leaf of Pterocarya Stenoptera co-grinding, liquid is extracted under ultrasonic assistant ethanol extraction method, condition is: solid-liquid ratio is 1:12, ultrasonic power is 160W, alcohol concn is 65%, Extracting temperature is 60 DEG C, extraction time is 75min, gained medical filtration, be concentrated into water content be after 16% mixture A, it is 4% that gained mixture A is dried to water content at 95 DEG C, 200 mesh sieve are crossed after pulverizing, obtained insect-killing composition,
S3: take humic acids that step S1 obtains, step S2 obtained insect-killing composition, water-holding agent, mould inhibitor and distilled water respectively in described ratio, mix to obtain mixture B, being carried out making 1.5-2.5mm particle and at 95 DEG C, be dried to water content by described mixture B is 4%, obtained novel water-retaining agent.
Embodiment 4
A kind of novel water-retaining agent utilizing vinegar factory waste liquid, in units of weight part, comprise following raw material: starch-acrylate graft copolymer 16 parts, Mierocrystalline cellulose-acrylic acid graft copolymer 16 parts, humic acids 28 parts, distilled water 7 parts, mould inhibitor 0.06 part, insect-killing composition 0.03 part.
The described preparation method utilizing the novel water-retaining agent of vinegar factory waste liquid, comprises the following steps:
S1: vinegar factory waste liquid is left standstill clarification, obtain supernatant liquor, then described supernatant liquor is heated to 80 DEG C and carries out evaporation concentration, being concentrated into pH value is 2.8, stops heating, left at room temperature activation 15h, then add volatile salt adjust ph to 6.8, obtain humic acid solution, humic acid solution being dried at 85 DEG C water content is 6%, 200 mesh sieve are crossed, obtained humic acids after pulverizing;
S2: by tobacco, trypterygine, capsicum, the rhizome of Chinese monkshood, pyrethrum, print chinaberry, leaf of tea tree, Herba Patriniae, bitter dish, absinth, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, Root or stem of Hairypetal Millettia, Chinese prickly ash, purslane, thorn apple, Herba Anabasis aphyllae, weeping willow leaf, leaf of Pterocarya Stenoptera co-grinding, liquid is extracted under ultrasonic assistant ethanol extraction method, condition is: solid-liquid ratio is 1:10, ultrasonic power is 150W, alcohol concn is 60%, Extracting temperature is 70 DEG C, extraction time is 80min, gained medical filtration, be concentrated into water content be after 20% mixture A, it is 6% that gained mixture A is dried to water content at 100 DEG C, 200 mesh sieve are crossed after pulverizing, obtained insect-killing composition,
S3: take humic acids that step S1 obtains, step S2 obtained insect-killing composition, water-holding agent, mould inhibitor and distilled water respectively in described ratio, mix to obtain mixture B, being carried out making 1.5-2.5mm particle and at 100 DEG C, be dried to water content by described mixture B is 6%, obtained novel water-retaining agent.
Embodiment 5
Utilize a novel water-retaining agent for vinegar factory waste liquid, in units of weight part, comprise following raw material: Mierocrystalline cellulose-acrylic acid graft copolymer 38 parts, humic acids 32 parts, distilled water 9 parts, mould inhibitor 0.07 part, insect-killing composition 0.04 part.
The described preparation method utilizing the novel water-retaining agent of vinegar factory waste liquid, comprises the following steps:
S1: vinegar factory waste liquid is left standstill clarification, obtain supernatant liquor, then described supernatant liquor is heated to 75 DEG C and carries out evaporation concentration, being concentrated into pH value is 3.5, stops heating, left at room temperature activation 13h, then add volatile salt adjust ph to 7.2, obtain humic acid solution, humic acid solution being dried at 90 DEG C water content is 5%, 300 mesh sieve are crossed, obtained humic acids after pulverizing;
S2: by tobacco, trypterygine, capsicum, the rhizome of Chinese monkshood, pyrethrum, print chinaberry, leaf of tea tree, Herba Patriniae, bitter dish, absinth, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, Root or stem of Hairypetal Millettia, Chinese prickly ash, purslane, thorn apple, Herba Anabasis aphyllae, weeping willow leaf, leaf of Pterocarya Stenoptera co-grinding, liquid is extracted under ultrasonic assistant ethanol extraction method, condition is: solid-liquid ratio is 1:14, ultrasonic power is 170W, alcohol concn is 70%, Extracting temperature is 70 DEG C, extraction time is 70min, gained medical filtration, be concentrated into water content be after 18% mixture A, it is 5% that gained mixture A is dried to water content at 95 DEG C, 300 mesh sieve are crossed after pulverizing, obtained insect-killing composition,
S3: take humic acids that step S1 obtains, step S2 obtained insect-killing composition, water-holding agent, mould inhibitor and distilled water respectively in described ratio, mix to obtain mixture B, being carried out making 1.5-2.5mm particle and at 95 DEG C, be dried to water content by described mixture B is 5%, obtained novel water-retaining agent.
For checking novel water-retaining agent of the present invention is to the effect of farm crop, for corn, by following experimental verification.
(1) rhizome compares effect test
Choose one piece of smooth plot, mark off 8 regions, every region area about 0.6 mu, respectively to the material of each region Yield-increasing Baallus In Maize following table as base manure, it is 7.5kg/ mu that its amount of application amounts to into mu consumption, and other planting conditions is basically identical.
| Sequence number | Application of substances | Consumption (kg) |
| 1 | The embodiment of the present invention 1 product | 4.5 |
| 2 | The embodiment of the present invention 2 product | 4.5 |
| 3 | The embodiment of the present invention 3 product | 4.5 |
| 4 | Starch-acrylate graft copolymer | 4.5 |
| 5 | The humic acids of embodiment 1 | 4.5 |
| 6 | Quinoxyfen | 4.5 |
| 7 | The insect-killing composition of embodiment 1 | 4.5 |
| 8 | Distilled water | 4.5 |
| 9 | Blank (not using any material) | 4.5 |
Wherein when maize seedling grew to about 6 leaf phases, each process is sampled (five point sampling methods, every point sampling 3) respectively, gather the maize seedling of the 6 leaf phases that were in.Afterwards maize seedling being placed in clear water to clean, over-ground part and underground part scissors are cut off, carrying out rhizome than measuring.
Concrete measuring method is: respectively over-ground part and underground part are placed in 65 DEG C of baking ovens and dry to constant weight, calculates rhizome ratio (ratio of underground part dry weight and over-ground part dry weight), as shown in the table.
| Sequence number | Application of substances | Rhizome ratio |
| 1 | The embodiment of the present invention 1 product | 0.82 |
| 2 | The embodiment of the present invention 2 product | 0.82 |
| 3 | The embodiment of the present invention 3 product | 0.83 |
| 4 | Starch-acrylate graft copolymer | 0.55 |
| 5 | The humic acids of embodiment 1 | 0.57 |
| 6 | Quinoxyfen | 0.56 |
| 7 | The insect-killing composition of embodiment 1 | 0.59 |
| 8 | Distilled water | 0.52 |
| 9 | Blank (not using any material) | 0.52 |
As can be seen from upper table data, novel water-retaining agent of the present invention, relative to using separately starch-acrylate graft copolymer, humic acids, mould inhibitor, insect-killing composition, distilled water and blank, all significantly increase the rhizome ratio of Maize Seedling, describe and use novel water-retaining agent of the present invention, be conducive to the lodging resistance strengthening corn.
(2) product preventing disease and pest effect experimental of the present invention
Choose the corn field that six block specifications are basically identical, be set to corn field a, corn field b, corn field c, corn field d, corn field e, corn field f, corn is planted on six pieces of ground, wherein corn field a, corn field b, corn field c use starch-acrylate graft copolymer, corn field d, corn field e, corn field f use the novel water-retaining agent of embodiment 1,2,3 respectively, execute 7.5kg with every mu to calculate, observe the corn growth situation of six plots of corn fields.Result shows: corn gloss difference, plant that corn field a, corn field b, corn field c kind are planted are unhealthy, and the speed of growth is slow, and plant is little, yields poorly, and has volt to fall phenomenon; And the corn good luster that corn field d, corn field e, corn field f kind are planted, plant is healthy, leaf dark green is plump, output is high, without volt phenomenon, compared with not using the corn field of product of the present invention, every mu of volume increase 215.1-222.3kg, and use the disease and pest in the corn field of product of the present invention substantially not have, visible novel water-retaining agent of the present invention can not only preventing disease and pest effectively, and can lodging resistance be strengthened, improve corn yield.
Above content can not assert that the present invention specifically implements to be confined to these explanations; for general technical staff of the technical field of the invention; do not departing under concept thereof of the present invention; some simple deduction or replace can also be made, all should be considered as belonging to the scope of patent protection that the present invention is determined by submitted to claims.
Claims (7)
1. utilize a novel water-retaining agent for vinegar factory waste liquid, it is characterized in that, in units of weight part, comprise following raw material: water-holding agent 30-40 part, humic acids 25-35 part, distilled water 6-10 part, mould inhibitor 0.05-0.08 part, insect-killing composition 0.02-0.04 part.
2. the novel water-retaining agent utilizing vinegar factory waste liquid according to claim 1, is characterized in that, described water-holding agent comprise in starch-acrylate graft copolymer, Mierocrystalline cellulose-acrylic acid graft copolymer one or both.
3. the novel water-retaining agent utilizing vinegar factory waste liquid according to claim 1, is characterized in that, described humic acids is made up of vinegar factory waste liquid.
4. the novel water-retaining agent utilizing vinegar factory waste liquid according to claim 1, is characterized in that, described mould inhibitor comprise in quinoxyfen, triazolone one or both.
5. the novel water-retaining agent utilizing vinegar factory waste liquid according to claim 1, it is characterized in that, described insect-killing composition is extracted made by tobacco, trypterygine, capsicum, the rhizome of Chinese monkshood, pyrethrum, print chinaberry, leaf of tea tree, Herba Patriniae, bitter dish, absinth, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, Root or stem of Hairypetal Millettia, Chinese prickly ash, purslane, thorn apple, Herba Anabasis aphyllae, weeping willow leaf, leaf of Pterocarya Stenoptera.
6. the preparation method utilizing the novel water-retaining agent of vinegar factory waste liquid according to any one of claim 1-5, is characterized in that, comprise the following steps:
S1: vinegar factory waste liquid is left standstill clarification, obtain supernatant liquor, then described supernatant liquor is heated to 70-80 DEG C and carries out evaporation concentration, being concentrated into pH value is 2.5-3.5, stops heating, left at room temperature activation 13-15h, then add volatile salt adjust ph to 6.2-7.6, obtain humic acid solution, humic acid solution is dried to water content≤6% at 85-105 DEG C, 100-300 mesh sieve is crossed, obtained humic acids after pulverizing;
S2: by tobacco, trypterygine, capsicum, the rhizome of Chinese monkshood, pyrethrum, print chinaberry, leaf of tea tree, Herba Patriniae, bitter dish, absinth, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, Root or stem of Hairypetal Millettia, Chinese prickly ash, purslane, thorn apple, Herba Anabasis aphyllae, weeping willow leaf, leaf of Pterocarya Stenoptera co-grinding, liquid is extracted under ultrasonic assistant ethanol extraction method, gained medical filtration, to be concentrated into after water content≤20% to obtain mixture A, gained mixture A is dried to water content≤6% at 90-100 DEG C, 100-300 mesh sieve is crossed, obtained insect-killing composition after pulverizing;
S3: take humic acids that step S1 obtains, step S2 obtained insect-killing composition, water-holding agent, mould inhibitor and distilled water respectively in described ratio, mix to obtain mixture B, described mixture B is carried out making 1.5-2.5mm particle and be dried to water content≤6% at 90-100 DEG C, obtained novel water-retaining agent.
7. the preparation method utilizing the novel water-retaining agent of vinegar factory waste liquid according to claim 6, it is characterized in that, the condition that the ethanol extraction method of ultrasonic assistant described in step S2 extracts liquid is: solid-liquid ratio is 1:8-16, ultrasonic power is 140-180W, alcohol concn is 50%-80%, Extracting temperature is 50-70 DEG C, and extraction time is 60-90min.
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