CN103664420B - Humic acid water-retention sustained and controlled release organic-inorganic fertilizer made from waste of sugar refineries and alcohol plants - Google Patents
Humic acid water-retention sustained and controlled release organic-inorganic fertilizer made from waste of sugar refineries and alcohol plants Download PDFInfo
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 97
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 title claims abstract description 83
- 239000004021 humic acid Substances 0.000 title claims abstract description 27
- 239000002699 waste material Substances 0.000 title claims abstract description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 238000013270 controlled release Methods 0.000 title claims description 26
- 206010016807 Fluid retention Diseases 0.000 title abstract 3
- 230000002459 sustained effect Effects 0.000 title abstract 2
- 238000013268 sustained release Methods 0.000 title 1
- 239000007788 liquid Substances 0.000 claims description 30
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 28
- 238000012216 screening Methods 0.000 claims description 25
- 238000000034 method Methods 0.000 claims description 19
- 239000006228 supernatant Substances 0.000 claims description 19
- 229920002401 polyacrylamide Polymers 0.000 claims description 18
- 240000008042 Zea mays Species 0.000 claims description 16
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 16
- 240000002791 Brassica napus Species 0.000 claims description 14
- 235000004977 Brassica sinapistrum Nutrition 0.000 claims description 14
- -1 alkene oxime amine Chemical class 0.000 claims description 14
- 238000001035 drying Methods 0.000 claims description 14
- 235000010333 potassium nitrate Nutrition 0.000 claims description 14
- 239000004323 potassium nitrate Substances 0.000 claims description 14
- 235000013339 cereals Nutrition 0.000 claims description 13
- 239000004563 wettable powder Substances 0.000 claims description 13
- 241000736285 Sphagnum Species 0.000 claims description 10
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 claims description 10
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 10
- 238000005352 clarification Methods 0.000 claims description 10
- 235000019691 monocalcium phosphate Nutrition 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 10
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 9
- 230000004913 activation Effects 0.000 claims description 9
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 9
- 238000001704 evaporation Methods 0.000 claims description 9
- 230000008020 evaporation Effects 0.000 claims description 9
- 229910017604 nitric acid Inorganic materials 0.000 claims description 9
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 claims description 7
- 235000009973 maize Nutrition 0.000 claims description 7
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 6
- 229930006000 Sucrose Natural products 0.000 claims description 6
- 238000005469 granulation Methods 0.000 claims description 6
- 230000003179 granulation Effects 0.000 claims description 6
- 238000010298 pulverizing process Methods 0.000 claims description 6
- 229960004793 sucrose Drugs 0.000 claims description 6
- CZMRCDWAGMRECN-UHFFFAOYSA-N Rohrzucker Natural products OCC1OC(CO)(OC2OC(CO)C(O)C(O)C2O)C(O)C1O CZMRCDWAGMRECN-UHFFFAOYSA-N 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 230000001737 promoting effect Effects 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 abstract description 29
- 239000000203 mixture Substances 0.000 abstract description 18
- 239000003895 organic fertilizer Substances 0.000 abstract description 2
- 239000003206 sterilizing agent Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 28
- 238000002360 preparation method Methods 0.000 description 16
- 230000000855 fungicidal effect Effects 0.000 description 10
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 9
- 235000005822 corn Nutrition 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 239000000126 substance Substances 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 210000003608 fece Anatomy 0.000 description 6
- 239000010871 livestock manure Substances 0.000 description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- 229920002125 Sokalan® Polymers 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- 229920000578 graft copolymer Polymers 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000004584 polyacrylic acid Substances 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 244000269722 Thea sinensis Species 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 235000013877 carbamide Nutrition 0.000 description 3
- 235000012343 cottonseed oil Nutrition 0.000 description 3
- 238000005457 optimization Methods 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000005056 compaction Methods 0.000 description 2
- 239000003630 growth substance Substances 0.000 description 2
- 230000003641 microbiacidal effect Effects 0.000 description 2
- 235000016709 nutrition Nutrition 0.000 description 2
- 230000035764 nutrition Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- RMOGWMIKYWRTKW-UONOGXRCSA-N (S,S)-paclobutrazol Chemical compound C([C@@H]([C@@H](O)C(C)(C)C)N1N=CN=C1)C1=CC=C(Cl)C=C1 RMOGWMIKYWRTKW-UONOGXRCSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000005985 Paclobutrazol Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- SEOVTRFCIGRIMH-UHFFFAOYSA-N indole-3-acetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CNC2=C1 SEOVTRFCIGRIMH-UHFFFAOYSA-N 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 235000013379 molasses Nutrition 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000009923 sugaring Methods 0.000 description 1
- FFSJPOPLSWBGQY-UHFFFAOYSA-N triazol-4-one Chemical compound O=C1C=NN=N1 FFSJPOPLSWBGQY-UHFFFAOYSA-N 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
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- Fertilizers (AREA)
Abstract
The invention relates to a humic acid water-retention sustained and controlled organic-inorganic fertilizer made from waste of sugar refineries and alcohol plants. The fertilizer comprises active humic acid, a water retention agent, an organic fertilizer and an inorganic fertilizer. Moreover, a fertilizer composition can contain a sterilizing agent. The fertilizer composition disclosed by the invention can effectively promote rooting of crops and increase the yield.
Description
Technical field
The present invention relates to fertilizer field, be specifically related to a kind of humic acid type water-holding slow-release controlled release organic-inorganic fertilizer utilizing sugar refinery, grain distillery's waste.
Background technology
Alcohol waste liquid for sugar refinery is a kind of with remaining the acid waste liquid be left after molasses prepare alcohol from the sugaring such as cane sugar factory, beet-sugar factory factory, containing a large amount of organic matters and beneficial element in such waste liquid.China discharges this waste liquid ton up to a million at present every year, has caused serious problem of environmental pollution.The main Land use systems of current this waste liquid remains direct irrigation, and on the one hand, the method for application of this extensive style is unfavorable for effective utilization of nutrition; On the other hand, due to the restriction of the aspects such as transport, this method of application is only limitted to factory's periphery; Moreover the waste liquid of directly discharge is in acid, and life-time service can cause soil compaction.
Life-time service inorganic fertilizer can cause soil compaction, and utilization rate of fertilizer reduces, polluted underground water etc.
Patent documentation CN101632357A discloses a kind of cotton nutrition nursery extraneous root composition in strong sprout, and it comprises sterilant triazolone, and growth regulator indolylacetic acid, paclobutrazol.The document mainly by growth regulator or its combination be used for control the growth of seedling.
At present, about being equipped with other fertilizers, inorganic fertilizer and water-holding agent to promote that the volume increase of crop, especially corn has no report after carrying out special processing to alcohol waste liquid for sugar refinery.And in above-mentioned Ru 2006101161, add appropriate sterilant to promote that crop takes root, volume increase also has no report.The present inventor finds alcohol waste liquid for sugar refinery to carry out the obtained activated humic acid of special processing and is equipped with fertilizer, inorganic fertilizer and water-holding agent and significantly can increases crop yield, and in above-mentioned Ru 2006101161, add appropriate sterilant, while promotion crop yield, can also promote that crop takes root, just based on above-mentioned discovery, contriver completes the present invention.
Summary of the invention
An object of the present invention is to provide a kind of humic acid type water-holding slow-release controlled release organic-inorganic fertilizer utilizing sugar refinery, grain distillery's waste.In order to achieve the above object, the present invention adopts following technical scheme.
One aspect of the present invention relates to a kind of humic acid type water-holding slow-release controlled release organic-inorganic fertilizer comprising sugar refinery, grain distillery's waste, described fertilizer comprises activated humic acid, water-holding agent, fertilizer and inorganic fertilizer, tool weight ratio is activated humic acid: water-holding agent: fertilizer: inorganic fertilizer=7 ~ 12: 1 ~ 4: 15 ~ 30: 2 ~ 6, preferred activated humic acid: water-holding agent: fertilizer: inorganic fertilizer=8: 2: 20: 4;
The preparation method of wherein said activated humic acid is: alcohol waste liquid for sugar refinery is left standstill clarification, obtain supernatant liquor, then described supernatant liquor is heated to 60 ~ 90 DEG C, preferably 70 ~ 80 DEG C, more preferably 75 DEG C are carried out evaporation concentration, be concentrated into 1/4 ~ 1/6 of initial weight, obtain concentrated solution, nitric acid or sulfuric acid is added in concentrated solution, the pH regulating concentrated solution is 1 ~ 4, preferably 2 ~ 3, more preferably 3, normal temperature leaves standstill activation 12 ~ 24 hours, preferably 16 ~ 20 hours, more preferably 18 hours, then adding ammoniacal liquor regulates pH to be 6 ~ 8, preferably 7, obtain activated humic acid liquid, activated humic acid liquid is dry, pulverize, screening, obtain activated humic acid,
Described water-holding agent be selected from polyacrylamide, Mierocrystalline cellulose-acrylic acid graft copolymer, polyacrylic acid potassium one or both, optimization polypropylene acid amides;
Described fertilizer be selected from sphagnum moss, hog manure, rapeseed cake, cottonseed cake, tea seed cake one or both, preferred rapeseed cake;
Described inorganic fertilizer be selected from urea, saltpetre, calcium superphosphate one or both, preferred saltpetre;
The humic acid type water-holding slow-release controlled release organic-inorganic fertilizer that such scheme of the present invention obtains, apply due to the activated humic acid obtained is mixed with other fertilizer etc., therefore, it is possible to significantly increase crop yield, such as, can make corn yield increasing about more than 10%, preferably more than 20%.
Another aspect of the present invention relates to a kind of humic acid type water-holding slow-release controlled release organic-inorganic fertilizer comprising sugar refinery, grain distillery's waste, described fertilizer comprises activated humic acid, water-holding agent, fertilizer, inorganic fertilizer and fungicidal activity composition, its weight ratio is activated humic acid: water-holding agent: fertilizer: inorganic fertilizer: fungicidal activity composition=7 ~ 12: 1 ~ 4: 15 ~ 30: 2 ~ 6: 0.001 ~ 0.5, preferred activated humic acid: water-holding agent: fertilizer: inorganic fertilizer: fungicidal activity composition=8: 2: 20: 4: 0.005;
The preparation method of wherein said activated humic acid is: alcohol waste liquid for sugar refinery is left standstill clarification, obtain supernatant liquor, then described supernatant liquor is heated to 60 ~ 90 DEG C, preferably 70 ~ 80 DEG C, more preferably 75 DEG C are carried out evaporation concentration, be concentrated into 1/4 ~ 1/6 of initial weight, obtain concentrated solution, nitric acid or sulfuric acid is added in concentrated solution, the pH regulating concentrated solution is 1 ~ 4, preferably 2 ~ 3, more preferably 3, normal temperature leaves standstill activation 12 ~ 24 hours, preferably 16 ~ 20 hours, more preferably 18 hours, then adding ammoniacal liquor regulates pH to be 6 ~ 8, preferably 7, obtain activated humic acid liquid, activated humic acid liquid is dry, pulverize, screening, obtain activated humic acid,
Described water-holding agent be selected from polyacrylamide, Mierocrystalline cellulose-acrylic acid graft copolymer, polyacrylic acid potassium one or both, optimization polypropylene acid amides;
Described fertilizer be selected from sphagnum moss, hog manure, rapeseed cake, cottonseed cake, tea seed cake one or both, preferred rapeseed cake;
Described inorganic fertilizer be selected from urea, saltpetre, calcium superphosphate one or both, preferred saltpetre;
Described sterilant is selected from enostroburin or alkene oxime amine, preferred alkene oxime amine.Described sterilant can be former medicine or its preparation, preferably its wettable powder; Wherein, when sterilant used is preparation, its used in amounts amounts to the amount of active components, i.e. the add-on of fungicidal activity composition in preparation.
The humic acid type water-holding slow-release controlled release organic-inorganic fertilizer of what such scheme of the present invention obtained comprise microbiocidal composition, significantly can increase crop yield, such as, can make corn yield increasing about more than 10%, and preferably more than 20%.In addition, the fertilizer that what technique scheme of the present invention obtained comprise microbiocidal composition can also promote maize rooting, significantly increases its rhizome ratio (measuring during about 4 leaf phase), such as, increase by more than 10%, preferably increases by more than 20%.
Another object of the present invention relates to the preparation method of above-mentioned humic acid type water-holding slow-release controlled release organic-inorganic fertilizer, and concrete steps are:
Step 1: alcohol waste liquid for sugar refinery is left standstill clarification, obtain supernatant liquor, then described supernatant liquor is heated to 60 ~ 90 DEG C, preferably 70 ~ 80 DEG C, more preferably 75 DEG C are carried out evaporation concentration, be concentrated into 1/4 ~ 1/6 of initial weight, obtain concentrated solution, nitric acid or sulfuric acid is added in concentrated solution, the pH regulating concentrated solution is 1 ~ 4, preferably 2 ~ 3, more preferably 3, normal temperature leaves standstill activation 12 ~ 24 hours, preferably 16 ~ 20 hours, more preferably 18 hours, then adding ammoniacal liquor regulates pH to be 6 ~ 8, preferably 7, obtain activated humic acid liquid, activated humic acid liquid is dry, pulverize, screening, obtain activated humic acid,
Step 2: respectively described water-holding agent, fertilizer and inorganic fertilizer are pulverized, screening, obtains powdery water-holding agent, powdery fertilizer and powdery inorganic fertile;
Step 3: take the above-mentioned activated humic acid, powdery water-holding agent, powdery fertilizer, powdery inorganic fertilizer and the optional fungicidal activity composition that prepare respectively in described ratio;
Wherein, when not comprising fungicidal activity composition, the weight ratio activated humic acid of each component: water-holding agent: fertilizer: inorganic fertilizer=7 ~ 12: 1 ~ 4: 15 ~ 30: 2 ~ 6, preferred activated humic acid: water-holding agent: fertilizer: inorganic fertilizer=8: 2: 20: 4;
When comprising fungicidal activity composition, the weight ratio of each component is activated humic acid: water-holding agent: fertilizer: inorganic fertilizer: fungicidal activity composition=7 ~ 12: 1 ~ 4: 15 ~ 30: 2 ~ 6: 0.001 ~ 0.5, preferred activated humic acid: water-holding agent: fertilizer: inorganic fertilizer: fungicidal activity composition=8: 2: 20: 4: 0.005;
And above-mentioned each component is mixed, obtain mixture;
Step 4: the adhesive solution accounting for mixture total weight amount and be about 1-10% is added in said mixture, carries out granulation; Concrete prilling process can use the method for this area routine, such as extruder grain, rotary table granulation etc.Described binding agent can use the binding agent of this area routine, such as starch, carboxymethyl cellulose etc.; The concentration of described binding agent can control according to actual needs, such as 10-20%.
Step 5: the particle obtained is carried out drying, screening, obtains described humic acid type water-holding slow-release controlled release organic-inorganic fertilizer.The particle diameter of final particle can adjust as required, such as 1-8mm, preferred 2-5mm.
Wherein, described water-holding agent be selected from polyacrylamide, Mierocrystalline cellulose-acrylic acid graft copolymer, polyacrylic acid potassium one or both, optimization polypropylene acid amides;
Wherein, described fertilizer be selected from sphagnum moss, hog manure, rapeseed cake, cottonseed cake, tea seed cake one or both, preferred rapeseed cake;
Wherein, described inorganic fertilizer be selected from urea, saltpetre, calcium superphosphate one or both, preferred saltpetre;
Wherein, described sterilant is selected from enostroburin or alkene oxime amine, preferred alkene oxime amine.Described sterilant can be former medicine or its preparation, preferably its wettable powder; Wherein, when sterilant used is preparation, its used in amounts amounts to the amount of active components, i.e. the add-on of fungicidal activity composition in preparation.
Another object of the present invention relates to humic acid type water-holding slow-release controlled release organic-inorganic fertilizer of the present invention in the purposes promoting crop, especially corn yield increasing, and wherein said fertilizer is used as base manure, and mu consumption is 20-50kg, preferably 40kg.Wherein can increase production about more than 10%, preferably more than 20%.
Another object of the present invention relates to humic acid type water-holding slow-release controlled release organic-inorganic fertilizer of the present invention in the purposes promoting crop, especially maize rooting, volume increase, and wherein said fertilizer is used as base manure, and mu consumption is 20-50kg, preferably 40kg.Wherein can increase production about more than 10%, preferably more than 20%.The rhizome of Maize Seedling is than increasing by about more than 10%, preferably more than 20% (measuring during about 4 leaf phase).
Various raw materials used by the application are all available on market.Such as alcohol waste liquid for sugar refinery can be cane sugar factory alcohol slops or beet-sugar factory alcohol slops, can obtain from sugar refinery or grain distillery.Water-holding agent such as polyacrylamide, Mierocrystalline cellulose-acrylic acid graft copolymer, polyacrylic acid potassium are all available on market, water-intake rate such as about 1: 500-1000, such as, purchased from Hangzhou Xu Mei Chemical Co., Ltd., Renqiu City Zheng Hao Chemicals company limited.The former medicine of enostroburin, the former medicine of alkene oxime amine, 30% enostroburin wettable powder and 20% alkene oxime amine wettable powder are also commercially available, such as, purchased from Shenyang Sciencreat Chemicals Co., Ltd., also can make by oneself according to the Conventional processing methods of wettable powder.Other raw materials such as the fertilizer used by the application, inorganic fertilizer and tackiness agent also can be buied easily from the market.
Beneficial effect of the present invention is:
Used in combination by by activated humic acid and water-holding agent, fertilizer and inorganic fertilizer etc., obviously can promote crop yield, especially corn yield increasing;
Used in combination by by activated humic acid, water-holding agent, fertilizer, inorganic fertilizer and sterilant etc., while obviously promoting crop yield, obviously can also increase the rhizome ratio of crop, strengthen lodging resistance;
The present invention, by Combination application such as multiple fertilizer and water-holding agents, overcomes the applied defect of single fertilizer, saves labor force, and will dilute each other respectively, disperse due to each component, scolds to a certain extent and has added slowly-releasing, controlled-release effect.
Embodiment
In order to understand the present invention, further illustrate the present invention with embodiment below, but do not limit the present invention.
The preparation of embodiment 1 product 1 of the present invention
Get cane sugar factory alcohol slops 900kg, leave standstill clarification, obtain supernatant liquor, then described supernatant liquor is heated to 75 DEG C and carries out evaporation concentration, obtain concentrated solution 150kg, in concentrated solution, add nitric acid until the pH of concentrated solution is 3, normal temperature leaves standstill activation 18 hours, then adds ammoniacal liquor and regulates pH to be 7, obtain activated humic acid liquid, by the drying of activated humic acid liquid, pulverizing, screening, obtain activated humic acid, about 80kg is for subsequent use.
Take 20kg polyacrylamide (purchased from Renqiu City Zheng Hao Chemicals company limited), 200kg rapeseed cake, 40kg saltpetre respectively, and pulverize, screening, for subsequent use.
Activated humic acid obtained above and polyacrylamide, rapeseed cake, saltpetre are mixed, add the amidin of 10kg10%, mixing, then carries out extruder grain.
Finally, the particle obtained is carried out drying, screening, obtain described humic acid type water-holding slow-release controlled release organic-inorganic fertilizer.Wherein, the weight ratio of activated humic acid, water-holding agent, fertilizer, inorganic fertilizer is 8: 2: 20: 4.
The preparation of embodiment 2 product 2 of the present invention
Get beet-sugar factory alcohol slops 1200kg, leave standstill clarification, obtain supernatant liquor, then described supernatant liquor is heated to 85 DEG C and carries out evaporation concentration, obtain concentrated solution 240kg, in concentrated solution, add nitric acid until the pH of concentrated solution is 2, normal temperature leaves standstill activation 24 hours, then adds ammoniacal liquor and regulates pH to be 6.5, obtain activated humic acid liquid, by the drying of activated humic acid liquid, pulverizing, screening, obtain activated humic acid, about 110kg is for subsequent use.
Take 30kg polyacrylamide (purchased from Renqiu City Zheng Hao Chemicals company limited), 300kg sphagnum moss, 50kg calcium superphosphate respectively, and pulverize, screening, for subsequent use.
Activated humic acid obtained above and polyacrylamide, sphagnum moss, calcium superphosphate are mixed, the amidin adding 20kg12% carries out rotary table granulation.
Finally, the particle obtained is carried out drying, screening, obtain described humic acid type water-holding slow-release controlled release organic-inorganic fertilizer.Wherein, the weight ratio of activated humic acid, water-holding agent, fertilizer, inorganic fertilizer is 11: 3: 30: 5.
The preparation of embodiment 3 product 3 of the present invention
Get cane sugar factory alcohol slops 900kg, leave standstill clarification, obtain supernatant liquor, then described supernatant liquor is heated to 75 DEG C and carries out evaporation concentration, obtain concentrated solution 150kg, in concentrated solution, add nitric acid until the pH of concentrated solution is 3, normal temperature leaves standstill activation 18 hours, then adds ammoniacal liquor and regulates pH to be 7, obtain activated humic acid liquid, by the drying of activated humic acid liquid, pulverizing, screening, obtain activated humic acid, about 80kg is for subsequent use.
Take 20kg polyacrylamide (purchased from Renqiu City Zheng Hao Chemicals company limited), 200kg rapeseed cake, 40kg saltpetre respectively, and pulverize, screening, for subsequent use.
Take the alkene oxime amine wettable powder (self-control) for subsequent use (amounting to activeconstituents is 50g) of 250g20%;
Activated humic acid obtained above and polyacrylamide, rapeseed cake, saltpetre, alkene oxime amine wettable powder are mixed, add the amidin of 10kg10%, mixing, then carries out extruder grain.
Finally, the particle obtained is carried out drying, screening, obtain described humic acid type water-holding slow-release controlled release organic-inorganic fertilizer.Wherein the weight ratio of activated humic acid, water-holding agent, fertilizer, inorganic fertilizer, sterilant is 8: 2: 20: 4: 0.005.
The preparation of embodiment 4 product 4 of the present invention
Get beet-sugar factory alcohol slops 1200kg, leave standstill clarification, obtain supernatant liquor, then described supernatant liquor is heated to 85 DEG C and carries out evaporation concentration, obtain concentrated solution 240kg, in concentrated solution, add nitric acid until the pH of concentrated solution is 2, normal temperature leaves standstill activation 24 hours, then adds ammoniacal liquor and regulates pH to be 6.5, obtain activated humic acid liquid, by the drying of activated humic acid liquid, pulverizing, screening, obtain activated humic acid, about 110kg is for subsequent use.
Take 30kg polyacrylamide (purchased from Renqiu City Zheng Hao Chemicals company limited), 300kg sphagnum moss, 50kg calcium superphosphate respectively, and pulverize, screening, for subsequent use.
Take enostroburin wettable powder (purchased from Danyang, Jiangsu Province pesticide chemical factory) for subsequent use (amounting to activeconstituents is 100g) of 334g30%;
Activated humic acid obtained above and polyacrylamide, sphagnum moss, calcium superphosphate, enostroburin wettable powder are mixed, the amidin adding 20kg12% carries out rotary table granulation.
Finally, the particle obtained is carried out drying, screening, obtain described humic acid type water-holding slow-release controlled release organic-inorganic fertilizer.Wherein the weight ratio of activated humic acid, water-holding agent, fertilizer, inorganic fertilizer, sterilant is 11: 3: 30: 5: 0.01.
The preparation of comparative example 1 contrast product 1
This contrast product is for replacing the fertilizer obtained by the fertilizer of the activated humic acid equivalent in embodiment 1 product (product 1 of the present invention).Be specially:
Take 20kg polyacrylamide (purchased from Renqiu City Zheng Hao Chemicals company limited), 2800kg (200kg+80kg) rapeseed cake, 40kg saltpetre respectively, and pulverize, screening, for subsequent use.
Polyacrylamide obtained above, rapeseed cake, saltpetre are mixed, add the amidin of 10kg10%, mixing, then carries out extruder grain.
Finally, the particle obtained is carried out drying, screening, obtain described humic acid type water-holding slow-release controlled release organic-inorganic fertilizer.
The preparation of comparative example 2 contrast product 2
By the fertilizer product that sphagnum moss and calcium superphosphate obtain according to granulation after the ratio mixing of 30: 5.
The preparation of comparative example 3 contrast product 3
After cane sugar factory alcohol slops of the present invention is left standstill clarification, get supernatant liquor and directly use, without any process.
Effect example 1 Effects of Increasing Yield
Spread fertilizer over the fields the field to having divided region respectively using the invention described above product 1-4 and contrast product 1-2 as base manure, its consumption is 40kg/ mu, comparative example 3 product is evenly sprayed or drenched impose on field, and its mu of consumption is 300kg/ mu; Turn over to soil afterwards, maize planting (kind: Nongda108), control lines, apart from about 40-50cm, spacing in the rows 30-40cm, is regularly watered during plant growth, is not topdressed.Wherein identical process is carried out to each process.After results, measure the per mu yield of each process.
Wherein the per mu yield data of each process are as follows:
Above-mentioned data are not difficult to find out, under the same conditions, the effect of increasing production relative to contrast product of product of the present invention is obvious, visible the present invention by activated humic acid and water-holding agent and other organic and inorganic fertilizer with the use of, achieve obvious effect of increasing production.Further, when other conditions are identical, adding sterilant also can increase crop yield to a certain extent.
Effect example 2 rhizome compares effect test
For each process in effect example 1, wherein when corn seedling grew to about 4 leaf phases, each process is sampled (five point sampling methods, every point sampling 3) respectively, gather the corn seedling of the 4 leaf phases that were in.Afterwards seedling being placed in clear water to clean, over-ground part and underground part scissors are cut off, carrying out rhizome than measuring.
Concrete measuring method is: respectively over-ground part and underground part are placed in 60 DEG C of baking ovens and dry to constant weight, by following formulae discovery rhizome ratio:
Wherein the rhizome of each process is as follows than data:
| Process | Rhizome ratio |
| Product 1 of the present invention | 0.58 |
| Product 2 of the present invention | 0.56 |
| Product 3 of the present invention | 0.73 |
| Product 4 of the present invention | 0.70 |
| Contrast product 1 | 0.52 |
| Contrast product 2 | 0.51 |
| Contrast product 3 | 0.50 |
| Blank (fertilising) | 0.51 |
Be not difficult to find out by above-mentioned data, wherein with the addition of the fertilizer product of sterilant as alkene oxime amine and enostroburin of the present invention, relative to the fertilizer product not adding described sterilant, significantly increase the rhizome ratio of Maize Seedling, rhizome ratio such as through the corn of product 3 and 4 process of the present invention is 0.73 and 0.70, and this numerical value is obviously greater than product 1-2 and contrast product 1-3 of the present invention.This is conducive to the lodging resistance of corn.
Above-mentioned example is only to further explanation of the present invention, is not limitation of the invention, by the scheme simply adjusted by such scheme and then obtain, equally within the protection domain of the application.
Claims (2)
1. comprise sugar refinery, grain distillery's waste humic acid type water-holding slow-release controlled release organic-inorganic fertilizer for promoting a purposes for maize rooting, it is characterized in that, described humic acid type water-holding slow-release controlled release fertilizer is prepared by the following method:
Get cane sugar factory alcohol slops 900kg, leave standstill clarification, obtain supernatant liquor, then described supernatant liquor is heated to 75 DEG C and carries out evaporation concentration, obtain concentrated solution 150kg, nitric acid is added until the pH of concentrated solution is 3 in concentrated solution, normal temperature leaves standstill activation 18 hours, then adds ammoniacal liquor and regulates pH to be 7, obtain activated humic acid liquid, by the drying of activated humic acid liquid, pulverizing, screening, obtain activated humic acid 80kg;
Take polyacrylamide 20kg, rapeseed cake 200kg, saltpetre 40kg, and pulverize, screening;
Take the alkene oxime amine wettable powder 250g of 20%;
Activated humic acid obtained above and polyacrylamide, rapeseed cake, saltpetre, alkene oxime amine wettable powder are mixed, add the amidin 10kg of 10%, mixing, then carries out extruder grain;
The particle obtained is carried out drying, screening, obtains described humic acid type water-holding slow-release controlled release organic-inorganic fertilizer;
The mu consumption of described humic acid type water-holding slow-release controlled release organic-inorganic fertilizer is 40kg.
2. comprise sugar refinery, grain distillery's waste humic acid type water-holding slow-release controlled release organic-inorganic fertilizer for promoting a purposes for maize rooting, it is characterized in that, described humic acid type water-holding slow-release controlled release fertilizer is prepared by the following method:
Get beet-sugar factory alcohol slops 1200kg, leave standstill clarification, obtain supernatant liquor, then described supernatant liquor is heated to 85 DEG C and carries out evaporation concentration, obtain concentrated solution 240kg, nitric acid is added until the pH of concentrated solution is 2 in concentrated solution, normal temperature leaves standstill activation 24 hours, then adds ammoniacal liquor and regulates pH to be 6.5, obtain activated humic acid liquid, by the drying of activated humic acid liquid, pulverizing, screening, obtain activated humic acid 110kg;
Take polyacrylamide 30kg, sphagnum moss 300kg, calcium superphosphate 50kg, and pulverize, screening;
Take the enostroburin wettable powder 334g of 30%;
Activated humic acid obtained above and polyacrylamide, sphagnum moss, calcium superphosphate, enostroburin wettable powder are mixed, adds the amidin 20kg of 12%, carry out rotary table granulation;
The particle obtained is carried out drying, screening, obtains described humic acid type water-holding slow-release controlled release organic-inorganic fertilizer;
The mu consumption of described humic acid type water-holding slow-release controlled release organic-inorganic fertilizer is 40kg.
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| CN104030819B (en) * | 2014-06-17 | 2016-03-30 | 山东宝源生物科技股份有限公司 | A kind of water keeping fertilizer and preparation method thereof |
| CN104311342A (en) * | 2014-10-21 | 2015-01-28 | 中山市巴斯德农业科技有限公司 | Liquid fertilizer containing humic acid |
| CN104478552B (en) * | 2014-11-17 | 2017-01-11 | 砀山县沃福农业发展有限公司 | Garlic special-purpose organic inorganic compound fertilizer and preparation method thereof |
| CN104557306A (en) * | 2014-12-31 | 2015-04-29 | 山东海森现代农业专业合作联合社 | Droughty thin soil cultivation-oriented organic fertilizer, preparation method and application |
| CN106892778B (en) * | 2017-03-13 | 2021-07-09 | 叶长东 | Water-retaining fertilizer |
| CN109796250A (en) * | 2017-11-16 | 2019-05-24 | 丹阳市珥陵镇小潘园茭白专业合作社 | A kind of vegetable fertilizer of the mud containing beer |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19605256C1 (en) * | 1994-08-12 | 1997-09-25 | Kanne Brottrunk Gmbh & Betrieb | Cleaning and disinfecting agents |
| CN101054317A (en) * | 2006-04-13 | 2007-10-17 | 孙明 | Process of producing plant water keeping organic fertilizer |
| CN103102226A (en) * | 2013-03-11 | 2013-05-15 | 叶长东 | Soil conditioner containing sugar refinery alcohol waste liquor, filter mud and peat |
| CN103351869A (en) * | 2013-06-08 | 2013-10-16 | 中国矿业大学(北京) | Snow-melting-agent-resistant soil-modification composite water-retention fertilizer |
| CN103420738A (en) * | 2012-05-25 | 2013-12-04 | 王勇 | Fertilizer |
-
2013
- 2013-12-13 CN CN201310676455.0A patent/CN103664420B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19605256C1 (en) * | 1994-08-12 | 1997-09-25 | Kanne Brottrunk Gmbh & Betrieb | Cleaning and disinfecting agents |
| CN101054317A (en) * | 2006-04-13 | 2007-10-17 | 孙明 | Process of producing plant water keeping organic fertilizer |
| CN103420738A (en) * | 2012-05-25 | 2013-12-04 | 王勇 | Fertilizer |
| CN103102226A (en) * | 2013-03-11 | 2013-05-15 | 叶长东 | Soil conditioner containing sugar refinery alcohol waste liquor, filter mud and peat |
| CN103351869A (en) * | 2013-06-08 | 2013-10-16 | 中国矿业大学(北京) | Snow-melting-agent-resistant soil-modification composite water-retention fertilizer |
Non-Patent Citations (5)
| Title |
|---|
| 姚素梅.广义有机肥.《新型肥料施用指南》.化学工业出版社,2011,(第1版), * |
| 崔毅.化学节水技术.《农业节水灌溉技术及应用实例》.化学工业出版社,2005,(第1版), * |
| 杨凤军,等.园林树木施肥.《园林树木栽培养护学》.哈尔滨地图出版社,2009,(第1版), * |
| 纪明山,等.杀菌剂.《新编农药使用技术》.辽宁大学出版社,2010,(第3版), * |
| 郝应其.功能高分子材料.《材料改变着世界》.科学普及出版社,1986,(第1版), * |
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