CN103772067B - A kind of Humic acid type organic-inorganic medicine fertilizer composition comprising tea saponin utilizing sugar refinery, grain distillery's waste - Google Patents
A kind of Humic acid type organic-inorganic medicine fertilizer composition comprising tea saponin utilizing sugar refinery, grain distillery's waste Download PDFInfo
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- CN103772067B CN103772067B CN201410005949.0A CN201410005949A CN103772067B CN 103772067 B CN103772067 B CN 103772067B CN 201410005949 A CN201410005949 A CN 201410005949A CN 103772067 B CN103772067 B CN 103772067B
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 99
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 title claims abstract description 67
- 239000004021 humic acid Substances 0.000 title claims abstract description 66
- 239000000203 mixture Substances 0.000 title claims abstract description 45
- 239000002699 waste material Substances 0.000 title claims abstract description 33
- 239000001397 quillaja saponaria molina bark Substances 0.000 title claims abstract description 22
- 229930182490 saponin Natural products 0.000 title claims abstract description 22
- 150000007949 saponins Chemical class 0.000 title claims abstract description 22
- 241001122767 Theaceae Species 0.000 title abstract description 20
- 239000003814 drug Substances 0.000 title abstract 2
- 239000011573 trace mineral Substances 0.000 claims abstract description 19
- 235000013619 trace mineral Nutrition 0.000 claims abstract description 19
- 239000007788 liquid Substances 0.000 claims description 34
- 239000000243 solution Substances 0.000 claims description 34
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 28
- 239000003895 organic fertilizer Substances 0.000 claims description 18
- 239000006228 supernatant Substances 0.000 claims description 18
- 238000012216 screening Methods 0.000 claims description 16
- 240000008042 Zea mays Species 0.000 claims description 14
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 14
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 14
- 235000005822 corn Nutrition 0.000 claims description 14
- 238000001704 evaporation Methods 0.000 claims description 13
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 12
- 230000008020 evaporation Effects 0.000 claims description 12
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 11
- 230000003213 activating effect Effects 0.000 claims description 11
- 239000011733 molybdenum Substances 0.000 claims description 11
- 229910052750 molybdenum Inorganic materials 0.000 claims description 11
- 241000736285 Sphagnum Species 0.000 claims description 10
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims description 10
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 9
- 241000196324 Embryophyta Species 0.000 claims description 9
- 229910052796 boron Inorganic materials 0.000 claims description 9
- 235000012343 cottonseed oil Nutrition 0.000 claims description 9
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 9
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 9
- 235000011151 potassium sulphates Nutrition 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 8
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 8
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 8
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 8
- 229910017604 nitric acid Inorganic materials 0.000 claims description 8
- 230000001737 promoting effect Effects 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 6
- 238000005303 weighing Methods 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 5
- MBNMHBAJUNHZRE-UHFFFAOYSA-M thiosultap monosodium Chemical compound [Na+].OS(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O MBNMHBAJUNHZRE-UHFFFAOYSA-M 0.000 claims description 5
- 229910021529 ammonia Inorganic materials 0.000 claims description 4
- 239000012141 concentrate Substances 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 239000011230 binding agent Substances 0.000 claims description 3
- 229910000403 monosodium phosphate Inorganic materials 0.000 claims description 3
- 235000019799 monosodium phosphate Nutrition 0.000 claims description 3
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 210000003608 fece Anatomy 0.000 claims description 2
- 239000010871 livestock manure Substances 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 244000269722 Thea sinensis Species 0.000 claims 5
- 239000000047 product Substances 0.000 description 25
- 230000000052 comparative effect Effects 0.000 description 16
- 230000001965 increasing effect Effects 0.000 description 12
- 239000000575 pesticide Substances 0.000 description 11
- 239000004480 active ingredient Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000000843 powder Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 4
- 229930006000 Sucrose Natural products 0.000 description 4
- 229960004793 sucrose Drugs 0.000 description 4
- CZMRCDWAGMRECN-UHFFFAOYSA-N Rohrzucker Natural products OCC1OC(CO)(OC2OC(CO)C(O)C(O)C2O)C(O)C1O CZMRCDWAGMRECN-UHFFFAOYSA-N 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- DNVLJEWNNDHELH-UHFFFAOYSA-N thiocyclam Chemical compound CN(C)C1CSSSC1 DNVLJEWNNDHELH-UHFFFAOYSA-N 0.000 description 3
- 239000004563 wettable powder Substances 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 239000003630 growth substance Substances 0.000 description 2
- SEOVTRFCIGRIMH-UHFFFAOYSA-N indole-3-acetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CNC2=C1 SEOVTRFCIGRIMH-UHFFFAOYSA-N 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- RMOGWMIKYWRTKW-UONOGXRCSA-N (S,S)-paclobutrazol Chemical compound C([C@@H]([C@@H](O)C(C)(C)C)N1N=CN=C1)C1=CC=C(Cl)C=C1 RMOGWMIKYWRTKW-UONOGXRCSA-N 0.000 description 1
- 239000005472 Bensulfuron methyl Substances 0.000 description 1
- 208000003643 Callosities Diseases 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 206010020649 Hyperkeratosis Diseases 0.000 description 1
- 239000005985 Paclobutrazol Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- XMQFTWRPUQYINF-UHFFFAOYSA-N bensulfuron-methyl Chemical group COC(=O)C1=CC=CC=C1CS(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 XMQFTWRPUQYINF-UHFFFAOYSA-N 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000013270 controlled release Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 239000003617 indole-3-acetic acid Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000013379 molasses Nutrition 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- FFSJPOPLSWBGQY-UHFFFAOYSA-N triazol-4-one Chemical compound O=C1C=NN=N1 FFSJPOPLSWBGQY-UHFFFAOYSA-N 0.000 description 1
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- Fertilizers (AREA)
Abstract
The present invention relates to a kind of Humic acid type organic-inorganic medicine fertilizer composition comprising tea saponin utilizing sugar refinery, grain distillery's waste, described fertilizer comprises activated humic acid, fertilizer, inorganic fertilizer, trace element fertilizer and tea saponin etc., and described product obviously can promote that crop takes root, volume increase.
Description
Technical Field
The invention relates to the field of fertilizers, in particular to a humic acid type organic-inorganic pesticide-fertilizer composition prepared from wastes of sugar mills and alcohol plants.
Background
The waste alcohol liquid from sugar refinery is an acidic waste liquid left after preparing alcohol from residual molasses from sugar refinery such as cane sugar factory, beet sugar factory, etc. the waste liquid contains a large amount of organic matter and beneficial elements. Millions of tons of waste liquid are discharged every year in China at present, and the problem of serious environmental pollution is caused. At present, the main utilization mode of the waste liquid is direct irrigation, and on one hand, the extensive application mode is not beneficial to the effective utilization of nutrition; on the other hand, due to the limitation of transportation and the like, the application mode is limited to the periphery of a factory; in addition, the waste liquid discharged directly is acidic, and soil hardening can be caused after long-term use.
The long-term use of inorganic fertilizer can cause soil hardening, the utilization rate of the fertilizer is reduced, and underground water is polluted.
Document CN1480430A discloses a liquid fertilizer made from molasses alcohol waste liquor and a preparation method thereof.
Patent document CN101632357A discloses a cotton pot seedling raising, root increasing and seedling strengthening composition, which comprises triazolone as a bactericide, and indoleacetic acid and paclobutrazol as growth regulators. This document controls the growth of seedlings mainly by the action of growth regulators or combinations thereof.
At present, no report is found on promoting the yield increase and rooting of crops, particularly corns, by adding other organic fertilizers, inorganic fertilizers, trace element fertilizers, tea saponin, other pesticides and the like after specially treating the alcohol waste liquid of a sugar refinery. The inventor finds that the active humic acid prepared by specially treating alcohol waste liquor of a sugar refinery is matched with the components, so that the crop yield can be remarkably increased, the crop rooting can be promoted, and the crop root-stem ratio can be increased. The present inventors have completed the present invention based on the above findings.
Disclosure of Invention
The invention aims to provide a humic acid type organic-inorganic pesticide-fertilizer composition utilizing wastes of sugar factories and alcohol factories. In order to achieve the above object, the present invention adopts the following technical means.
One object of the present invention relates to a humic acid type organic-inorganic medicinal fertilizer composition containing tea saponin, which utilizes wastes of sugar mills and alcohol plants, and comprises active humic acid, organic fertilizer, inorganic fertilizer, microelement fertilizer, tea saponin and pesticide active ingredients.
Preferably, in the humic acid type organic-inorganic pesticide-fertilizer composition containing tea saponin, which utilizes wastes of sugar mills and alcohol plants, the composition comprises the following components in parts by weight:
the preparation method of the active humic acid comprises the following steps: standing and clarifying the alcohol waste liquid of the sugar refinery to obtain a supernatant, heating the supernatant to 60-90 ℃, preferably 70-80 ℃, carrying out evaporation concentration, concentrating to 1/4-1/6 of the initial weight to obtain a concentrated solution, adding nitric acid or sulfuric acid into the concentrated solution, adjusting the pH of the concentrated solution to 1-4, preferably 2-3, standing and activating at normal temperature for 12-24 hours, preferably 16-20 hours, then adding ammonia water to adjust the pH to 6-8 to obtain an active humic acid liquid, drying, crushing and screening the active humic acid liquid to obtain active humic acid;
the organic fertilizer is selected from one or two of sphagnum, pig manure, cottonseed cakes and tea seed cakes;
the inorganic fertilizer is one or two of potassium sulfate, sodium dihydrogen phosphate and disodium hydrogen phosphate;
the trace elements are selected from one or two of molybdenum fertilizer, boron fertilizer and zinc fertilizer;
the pesticide is one or two of monosultap and thiocyclam.
Preferably, in the humic acid type organic-inorganic pesticide-fertilizer composition containing tea saponin, which utilizes wastes of sugar mills and alcohol plants, the composition comprises the following components in parts by weight:
more preferably, in the humic acid type organic-inorganic pesticide-fertilizer composition containing tea saponin, which utilizes wastes of sugar mills and alcohol plants, the composition comprises the following components in parts by weight:
in the preparation process of the active humic acid, the evaporation concentration temperature is preferably 75 ℃; preferably, the sugar refinery alcohol waste liquid is concentrated to 1/5 of the initial weight; the pH of the concentrate is preferably adjusted to 3; the preferred activating time is 18 hours when the mixture is kept still at normal temperature; preferably, ammonia is added to adjust the pH value to 7;
the organic fertilizer is sphagnum and cottonseed cakes, and the weight ratio of the sphagnum to the cottonseed cakes is 2: 1;
the inorganic fertilizer is potassium sulfate and disodium hydrogen phosphate, and the weight ratio of the potassium sulfate to the disodium hydrogen phosphate is 1.5: 1;
the trace elements are molybdenum fertilizer and boron fertilizer, and the weight ratio of the molybdenum fertilizer to the boron fertilizer is 1: 1;
the pesticide is monosultap.
Another object of the invention relates to a preparation method of the humic acid type organic-inorganic pesticide-fertilizer composition, wherein the specific preparation method comprises the following steps:
step 1: standing and clarifying the alcohol waste liquid of the sugar refinery to obtain a supernatant, heating the supernatant to 60-90 ℃, preferably 70-80 ℃, carrying out evaporation concentration, concentrating to 1/4-1/6 of the initial weight to obtain a concentrated solution, adding nitric acid or sulfuric acid into the concentrated solution, adjusting the pH of the concentrated solution to 1-4, preferably 2-3, standing and activating at normal temperature for 12-24 hours, preferably 16-20 hours, then adding ammonia water to adjust the pH to 6-8 to obtain an active humic acid liquid, drying, crushing and screening the active humic acid liquid to obtain active humic acid;
step 2: respectively crushing and screening the organic fertilizer, the inorganic fertilizer and the trace element fertilizer to obtain a powdery organic fertilizer, a powdery inorganic fertilizer and a powdery trace element fertilizer;
and step 3: respectively weighing the prepared active humic acid, powdery organic fertilizer, powdery inorganic fertilizer, powdery trace element fertilizer, tea saponin and pesticide according to the proportion, and uniformly mixing to obtain a mixture;
and 4, step 4: adding a binder aqueous solution accounting for 1-10% of the total weight of the mixture into the mixture, and granulating;
and 5: and drying and screening the obtained particles to obtain the humic acid type organic-inorganic pesticide-fertilizer composition.
Preferably, during the preparation process of the active humic acid, the evaporation concentration temperature is preferably 75 ℃; the pH of the concentrate is preferably adjusted to 3; the preferred activating time is 18 hours when the mixture is kept still at normal temperature; preferably, ammonia is added to adjust the pH to 7.
Another object of the invention relates to the use of the humic acid type organic-inorganic pesticide fertilizer composition in promoting the yield increase of crops, in particular to promoting the yield increase of corn, for example, the corn can be increased by more than about 5%, preferably more than 15%.
Another object of the invention relates to the use of the humic acid type organic-inorganic pesticide fertilizer composition in promoting crop rooting, in particular in promoting corn rooting. It can significantly increase the rhizome ratio (measured at about 4-leaf stage), for example by 10% or more, preferably by 20% or more.
Another object of the invention relates to the use of the humic acid type organic-inorganic pesticide fertilizer composition in promoting crop rooting and yield increase, in particular to the use in promoting corn rooting and yield increase. For example, the corn yield can be increased by about 5% or more, preferably 15% or more, and the corn rootstock ratio (measured at about 4-leaf stage) can be increased by 10% or more, preferably 20% or more.
The form of the insecticide used in the present invention is not particularly limited, and may be the active ingredient itself or an agriculturally acceptable solid formulation such as a wettable powder or the like. For example, the monosulfuron and the thiocyclam active ingredient can be added directly, or their conventional formulations, such as 20% wettable monosulfuron powder, 50% wettable thiocyclam powder, etc., can be used. The active ingredients are all commercially available, and the formulations, such as wettable powders, are also commercially available or self-made using conventional pesticide type processing methods.
Other various raw materials used in the present application are commercially available. For example, the alcohol waste liquid from sugar refinery may be alcohol waste liquid from cane sugar refinery or alcohol waste liquid from beet sugar refinery, and may be obtained from sugar refinery or alcohol plant. The organic fertilizer, the inorganic fertilizer, the trace element fertilizer and the like are all sold in the market; the tea saponin, the pesticide and the like are all sold in the market. Other materials used in the present application are also readily available on the market.
The invention has the beneficial effects that:
according to the invention, the active humic acid, the organic fertilizer, the inorganic fertilizer, the trace element fertilizer, the tea saponin, the pesticide and the like prepared by a special method are mixed for use, so that the yield of crops can be obviously increased, the root-stem ratio of the crops can be obviously increased, and the lodging resistance is enhanced;
the invention combines and applies a plurality of fertilizers, trace element fertilizers and the like, overcomes the application defect of a single fertilizer, saves labor force, and increases slow release and controlled release effects to a certain extent because each component is respectively diluted and dispersed.
Detailed Description
The invention is further illustrated by the following examples for the understanding of the invention, but is not limited thereto.
Example 1
Taking 1000kg of the alcohol waste liquid of the cane sugar factory, standing for clarification to obtain a supernatant, heating the supernatant to 75 ℃, evaporating and concentrating to obtain 200kg of a concentrated solution, adding nitric acid into the concentrated solution until the pH of the concentrated solution is 3, standing and activating at normal temperature for 18 hours, then adding ammonia water to adjust the pH to 7 to obtain an active humic acid solution, drying, crushing and screening the active humic acid solution to obtain active humic acid, wherein about 100kg of the active humic acid is reserved.
100kg of sphagnum and 50kg of cottonseed cakes, 15kg of potassium sulfate and 5kg of disodium hydrogen phosphate, 0.5kg of molybdenum fertilizer and 0.5kg of boron fertilizer are respectively weighed, crushed and sieved for later use.
Respectively weighing 50g of tea saponin and 125g of 20% wettable monosulfuron powder (25 g of active ingredients);
mixing the active humic acid, sphagnum, cottonseed cake, potassium sulfate, disodium hydrogen phosphate, molybdenum fertilizer, boron fertilizer, tea saponin and wettable powder of monosulfuron, adding 10kg of 10% starch water solution, mixing, and extruding for granulation.
And finally, drying and screening the obtained particles to obtain the humic acid type organic-inorganic pesticide-fertilizer composition.
Example 2
1400kg of alcohol waste liquid of a beet sugar factory is taken, kept stand and clarified to obtain supernatant, then the supernatant is heated to 85 ℃ for evaporation concentration to obtain 300kg of concentrated solution, nitric acid is added into the concentrated solution until the pH value of the concentrated solution is 2, the concentrated solution is kept stand and activated for 24 hours at normal temperature, then ammonia water is added to adjust the pH value to 6.5 to obtain active humic acid solution, and the active humic acid solution is dried, crushed and screened to obtain active humic acid, wherein the active humic acid is about 150kg for later use.
Weighing 175kg of tea seed cake, 15kg of sodium dihydrogen phosphate and 2.5kg of molybdenum fertilizer respectively, crushing and screening for later use.
Respectively weighing 250g of tea saponin and 50g of 20% wettable monosulfuron powder (10 g of active ingredients are reduced);
mixing the active humic acid, sphagnum, cottonseed cake, potassium sulfate, disodium hydrogen phosphate, molybdenum fertilizer, boron fertilizer, tea saponin and wettable powder of monosulfuron, adding 20kg of 10% starch water solution, mixing, and extruding for granulation.
And finally, drying and screening the obtained particles to obtain the humic acid type organic-inorganic pesticide-fertilizer composition.
Comparative example 1
Taking 1000kg of the alcohol waste liquid of the cane sugar factory, standing and clarifying to obtain a supernatant, and then heating the supernatant to 80 ℃ for evaporation and concentration to obtain 300kg of a concentrated solution.
Comparative example 2
100kg of sphagnum, 20kg of disodium hydrogen phosphate and 1kg of molybdenum fertilizer are respectively weighed and uniformly mixed to obtain an organic fertilizer, an inorganic fertilizer and a trace element fertilizer compound fertilizer.
Comparative example 3
The tea saponin and 20% of bensulfuron-methyl are mixed according to the mass ratio of 1: 1 to obtain the product.
Effect example 1 yield increasing effect test
The products 1-2 of the invention and the comparative products 1-3 are respectively used as base fertilizers to be applied to field plots in divided areas, and the specific application method comprises the following steps:
the products 1-2 and the comparative product 2 are directly applied to the field, and the dosage is 45 kg/mu;
the comparative product 1 is sprayed or sprinkled in the field, and the dosage is 100 kg/mu;
the contrast product 3 is diluted by water and sprayed to the field soil, and the dosage per mu is 45 g;
then the land is ploughed, corn (variety: Nongda 108) is planted, the row spacing is controlled to be about 40-50cm, the plant spacing is controlled to be 30-40cm, the crops are watered regularly during the growth period, and no additional fertilizer is applied. Wherein the same treatment is performed for each treatment. After harvesting, the acre yield of each treatment was determined.
The acre yield data of each treatment is as follows:
| treatment of | Mu dosage (kg) of fertilizer | Corn yield per mu (jin) |
| Product 1 according to the invention | 45 | 1305 |
| Inventive product 2 | 45 | 1285 |
| Comparative product 1 | 100 | 1150 |
| Comparative product 2 | 45 | 1190 |
| Comparative product 3 | 45(g) | 1100 |
| Blank (not applying fertilizer) | - | 1095 |
The above data show that under the same conditions, the yield increase effect of the product of the invention relative to the comparative product is significant, for example, the yield of the product 1-2 of the invention is increased by about 100 jin or even more relative to the comparative product 1-2; for example, the products 1-2 of the present invention increased the yield by about 200 jin relative to the comparative product 3 and the blank control.
Effect example 2 rhizome ratio Effect test
For each treatment in effect example 1, when the corn seedlings grow to about 4-leaf stage, each treatment was sampled (five-point sampling method, 3 samples were taken at each point), and the corn seedlings at 4-leaf stage were collected. Then, the seedlings are put into clean water to be cleaned, the overground part and the underground part are cut off by scissors, and the rootstock ratio is measured.
The specific measurement method comprises the following steps: respectively placing the overground part and the underground part in a 60 ℃ oven to be dried to constant weight, and calculating the rhizome ratio by the following formula:
wherein the rhizome ratio data of each treatment is as follows:
| treatment of | Root to rhizome ratio |
| Product 1 according to the invention | 0.73 |
| Inventive product 2 | 0.71 |
| Comparative product 1 | 0.53 |
| Comparative product 2 | 0.52 |
| Comparative product 3 | 0.57 |
| Blank control (not fertilizer) | 0.51 |
It can be seen from the above data that the products of the present invention are also significantly superior to the comparative products 1-3 and the blank control in increasing the corn to root ratio. This contributes to the lodging resistance of the corn.
The above examples are merely illustrative and not restrictive of the present invention, and the solution obtained by simple modification of the above solution is also within the scope of the present application.
Claims (7)
1. A humic acid type organic-inorganic medicinal fertilizer composition containing tea saponin, which utilizes wastes of sugar mills and alcohol plants, comprises active humic acid, organic fertilizer, inorganic fertilizer, microelement fertilizer, tea saponin and monosultap, and comprises the following components in parts by weight:
wherein,
the preparation method of the active humic acid comprises the following steps: standing and clarifying the alcohol waste liquid of the sugar refinery to obtain a supernatant, heating the supernatant to 60-90 ℃, carrying out evaporation concentration, concentrating to 1/4-1/6 of the initial weight to obtain a concentrated solution, adding nitric acid or sulfuric acid into the concentrated solution, adjusting the pH of the concentrated solution to 1-4, standing and activating at normal temperature for 12-24 hours, adding ammonia water to adjust the pH to 6-8 to obtain an active humic acid liquid, drying, crushing and screening the active humic acid liquid to obtain active humic acid;
the organic fertilizer is selected from one or two of sphagnum, pig manure, cottonseed cakes and tea seed cakes;
the inorganic fertilizer is one or two of potassium sulfate, sodium dihydrogen phosphate and disodium hydrogen phosphate;
the trace elements are selected from one or two of molybdenum fertilizer, boron fertilizer and zinc fertilizer.
2. The humic acid type organic-inorganic medicinal fertilizer composition according to claim 1, wherein the active humic acid is prepared by the following steps: standing and clarifying the alcohol waste liquid of the sugar refinery to obtain a supernatant, heating the supernatant to 70-80 ℃, carrying out evaporation concentration, concentrating to 1/4-1/6 of the initial weight to obtain a concentrated solution, adding nitric acid or sulfuric acid into the concentrated solution, adjusting the pH of the concentrated solution to 2-3, standing and activating at normal temperature for 16-20 hours, adding ammonia water to adjust the pH to 6-8 to obtain an active humic acid liquid, drying, crushing and screening the active humic acid liquid to obtain active humic acid.
3. The humic acid type organic-inorganic pesticide-fertilizer composition according to claim 1 or 2, which is characterized by comprising the following components in parts by weight:
in the preparation process of the active humic acid, the evaporation concentration temperature is preferably 75 ℃; preferably, the sugar refinery alcohol waste liquid is concentrated to 1/5 of the initial weight; the pH of the concentrate is preferably adjusted to 3; the preferred activating time is 18 hours when the mixture is kept still at normal temperature; preferably, ammonia is added to adjust the pH value to 7;
the organic fertilizer is sphagnum and cottonseed cakes, and the weight ratio of the sphagnum to the cottonseed cakes is 2: 1;
the inorganic fertilizer is potassium sulfate and disodium hydrogen phosphate, and the weight ratio of the potassium sulfate to the disodium hydrogen phosphate is 1.5: 1;
the trace elements are molybdenum fertilizer and boron fertilizer, and the weight ratio of the molybdenum fertilizer to the boron fertilizer is 1: 1.
4. A process for the preparation of a humic acid type organic-inorganic fertilizer composition of any one of claims 1 to 3 wherein:
step 1: standing and clarifying the alcohol waste liquid of the sugar refinery to obtain a supernatant, heating the supernatant to 60-90 ℃, carrying out evaporation concentration, concentrating to 1/4-1/6 of the initial weight to obtain a concentrated solution, adding nitric acid or sulfuric acid into the concentrated solution, adjusting the pH of the concentrated solution to 1-4, standing and activating at normal temperature for 12-24 hours, adding ammonia water to adjust the pH to 6-8 to obtain an active humic acid liquid, drying, crushing and screening the active humic acid liquid to obtain active humic acid;
step 2: respectively crushing and screening the organic fertilizer, the inorganic fertilizer and the trace element fertilizer to obtain a powdery organic fertilizer, a powdery inorganic fertilizer and a powdery trace element fertilizer;
and step 3: respectively weighing the prepared active humic acid, powdery organic fertilizer, powdery inorganic fertilizer, powdery trace element fertilizer, tea saponin and monosultap according to the proportion, and uniformly mixing to obtain a mixture;
and 4, step 4: adding a binder aqueous solution accounting for 1-10% of the total weight of the mixture into the mixture, and granulating;
and 5: and drying and screening the obtained particles to obtain the humic acid type organic-inorganic pesticide-fertilizer composition.
5. The method for preparing the humic acid type organic-inorganic medicinal fertilizer composition according to claim 4, which is characterized in that:
step 1: standing and clarifying the alcohol waste liquid of the sugar refinery to obtain a supernatant, heating the supernatant to 70-80 ℃, carrying out evaporation concentration, concentrating to 1/4-1/6 of the initial weight to obtain a concentrated solution, adding nitric acid or sulfuric acid into the concentrated solution, adjusting the pH of the concentrated solution to 2-3, standing and activating at normal temperature for 16-20 hours, adding ammonia water to adjust the pH to 6-8 to obtain an active humic acid liquid, drying, crushing and screening the active humic acid liquid to obtain active humic acid;
step 2: respectively crushing and screening the organic fertilizer, the inorganic fertilizer and the trace element fertilizer to obtain a powdery organic fertilizer, a powdery inorganic fertilizer and a powdery trace element fertilizer;
and step 3: respectively weighing the prepared active humic acid, powdery organic fertilizer, powdery inorganic fertilizer, powdery trace element fertilizer, tea saponin and monosultap according to the proportion, and uniformly mixing to obtain a mixture;
and 4, step 4: adding a binder aqueous solution accounting for 1-10% of the total weight of the mixture into the mixture, and granulating;
and 5: and drying and screening the obtained particles to obtain the humic acid type organic-inorganic pesticide-fertilizer composition.
6. The method according to claim 4 or 5, characterized in that in step 1, the concentration temperature by evaporation is preferably 75 ℃; the pH of the concentrate is preferably adjusted to 3; the preferred activating time is 18 hours when the mixture is kept still at normal temperature; preferably, ammonia is added to adjust the pH to 7.
7. Use of the humic acid type organic-inorganic medicinal fertilizer composition of any one of claims 1 to 3 or the humic acid type organic-inorganic medicinal fertilizer composition prepared by any one of claims 4 to 6 for promoting corn rooting.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4541245B2 (en) * | 2005-08-01 | 2010-09-08 | 株式会社 ユーリカ エンジニアリング | Dry methane fermentation |
| CN102382660A (en) * | 2011-01-29 | 2012-03-21 | 曲靖宏程工贸有限公司 | Drought-resistant water retention agent |
| CN102599177A (en) * | 2012-03-05 | 2012-07-25 | 叶长东 | Nereistoxin insecticide containing tea saponin, alkyl glycoside and fulvic acid |
| CN102898204A (en) * | 2011-07-26 | 2013-01-30 | 叶长东 | Novel plant micronutrient manufacturing method |
| CN102992900A (en) * | 2012-11-29 | 2013-03-27 | 叶长东 | Pesticide-fertilizer composition containing nereistoxin and pyrethroid pesticides |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4541245B2 (en) * | 2005-08-01 | 2010-09-08 | 株式会社 ユーリカ エンジニアリング | Dry methane fermentation |
| CN102382660A (en) * | 2011-01-29 | 2012-03-21 | 曲靖宏程工贸有限公司 | Drought-resistant water retention agent |
| CN102898204A (en) * | 2011-07-26 | 2013-01-30 | 叶长东 | Novel plant micronutrient manufacturing method |
| CN102599177A (en) * | 2012-03-05 | 2012-07-25 | 叶长东 | Nereistoxin insecticide containing tea saponin, alkyl glycoside and fulvic acid |
| CN102992900A (en) * | 2012-11-29 | 2013-03-27 | 叶长东 | Pesticide-fertilizer composition containing nereistoxin and pyrethroid pesticides |
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Denomination of invention: The utility model relates to a humic acid type organic-inorganic medicine fertilizer composition containing tea saponin by utilizing the waste of sugar and alcohol factories Effective date of registration: 20200923 Granted publication date: 20160120 Pledgee: Bank of Communications Ltd. the Guangxi Zhuang Autonomous Region branch Pledgor: Ye Changdong Registration number: Y2020450000039 |
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Granted publication date: 20160120 Pledgee: Bank of Communications Ltd. the Guangxi Zhuang Autonomous Region branch Pledgor: Ye Changdong Registration number: Y2020450000039 |