CN103636616A - Ultra-low volume liquid containing boscalid and morpholine bactericide - Google Patents
Ultra-low volume liquid containing boscalid and morpholine bactericide Download PDFInfo
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Abstract
The invention belongs to the technical field of pesticide, and relates to an ultra-low volume liquid containing boscalid and a morpholine bactericide, wherein the morpholine bactericide is one selected from dimethomorph, fenpropidin, fenpropimorph, spiroxamine and tridemorph, and boscalid and the morpholine bactericide are mixed so as to obtain a binary active ingredient. The ultra-low volume liquid comprises following ingredients, by weight, 0.5 to 10% of boscalid, 2 to 20% of the morpholine bactericide, 1 to 15% of an accessory ingredient, and the balance a solvent and a cosolvent. The binary active ingredient is composed of boscalid and the morpholine bactericide via mixing; and the morpholine bactericide is one randomly selected from dimethomorph, fenpropidin, fenpropimorph, spiroxamine and tridemorph. The ultra-low volume liquid is suitable for ultra-low volume spraying, low volume spraying and electrostatic spraying; and can be used for preventing and controlling diseases of paddies, fruit trees and vegetables. The ultra-low volume liquid possesses advantages such as quick effect realization, long lasting period, rain wash resistance, low water consumption, and low labor consumption.
Description
Technical field
The invention belongs to technical field of pesticide, relate to containing composite one of in Boscalid and morpholine series bactericidal agent dimethomorph, fenpropidin, butadiene morpholine, volution bacterium amine, tridemorph be the ultra low volume liquids of binary active ingredient, be specially the ultra low volume liquids containing Boscalid and morpholine series bactericidal agent.
Background technology
At present for easily producing the control of insect of resistance in agricultural, what main way was exploitation and existing kind without between the new composition of cross resistance or existing pesticide species is composite, the former is because required development cost is high, the cycle is long, and the speed that development rate produces less than pest resistance to insecticide far away at present.Therefore, for the different existing pesticide species of the mechanism of action, being mixed is a kind of selection of the best.If reasonable mixture ratio, can produce significant synergistic effect, make field control effect significantly be better than the effect of each single dose.On agricultural insect pests control, usually there is certain defect in the insecticide that contains single-activity composition, continuous several times is used and is not only made insect easily develop immunity to drugs, and easily cause the pollution to food and environment, by rational mixture between pesticide active ingredient, can overcome above shortcoming.The reasonably composite synergistic effect that active ingredient is produced simultaneously, can improve preventive effect, reduce effective ingredient consumption, cost-saving, delay the drug-fast generation of insect, closely can alleviate and even avoid the pollution of agricultural chemicals to food and environment, and the efficient novel pesticide of the low toxicity that the present invention researchs and develops, not only target drug effect is significantly strengthened, and very low on the impact of people, crop, non-target and environment.
Boscalid belongs to Novel tobacco acid amide fungicides; English name is Cantus; chemical name is the chloro-N-of 2-(4 '-chlorodiphenyl-2-yl) vitamin PP; by blade face, permeate in plant and shift, suppress mitochondrial succinate ester dehydrase, hinder tricarbonic acid cycle; amino acid, sugar shortage, energy are reduced; the division of interference cell and growth, have neural activity to disease, has protection and therapeutic action.Suppress the Main Stage that spore germination, the extension of bacterium pipe, mycelial growth and spore mother cell form conk and breeding, bactericidal action is directly caused there is no corresponding metabolic activity by parent active substance.With carbendazim, Sukeling etc. without cross resistance.Be mainly used in preventing and treating powdery mildew, gray mold, various rot, brown rot and root rot.
Dimethomorph, chemical name: (E, Z)-4-[3-(4-chlorphenyl) 3-(3,4-Dimethoxyphenyl) acryloyl] morpholine is efficient, interior absorption azoles fungicide.The mechanism of action is demethylation sterol inhibitor, has the multiple actions such as prevention, protection and treatment.It is single-minded ovicidal Gammaproteobacteria fungi bactericide, its effect feature is to destroy the formation of cell envelope, there is effect in each stage to oomycetes history of life, and particularly responsive at the formation stages of sporangiophore and egg spore, under extremely low concentration, (<0.25 μ g/ml) is suppressed.With phenylamide medicament without cross resistance.Be widely used in vegetables downy mildew, epidemic disease, seedling stage damping off, black shank etc. by the fungus-caused disease control of Mastigomycotina Oomycete, tool systemic activity.Do not considering under the drug-fast prerequisite of disease fungus, the more now widely used metalaxyl of drug effect, white urea cyanogen, aliette, Wakil etc. are high.
Fenpropidin, chemical name: (RS)-1-[3-(4-t-butyl-phenyl)-2-methyl-propyl] piperidines, belong to piperidines systemic fungicide.Sterol decomposing inhibitor, effective especially to Erysiphaceae, especially standing grain powdery mildew, rye spore and handle rest fungus, cereal crop Application 750g/ha.As prevented and treated barley powdery mildew, rust with 500～700g (a.i.)/ha, there is therapeutic action, about 28d of lasting period.
Butadiene morpholine, chemical name: (±) cis-4-3-(4-t-butyl-phenyl)-2-methyl-propyl)-2,6-thebaine, morpholines.It is sterol reduction inhibitor agent.With 750g (a.i.)/ha spraying, can prevent and treat the important true Seedling Diseases being caused by the raw tail spore of beet, the standing grain powdery mildew of Erysiphe, rye beak spore, beet monospore rest fungus, Puccinia on cereal crop, pulse family and beet.This product has protection and therapeutic action, and can, to top conduction, to the protection of Newborn Leaves, reach 3～4 weeks.
Volution bacterium amine, chemical name: the N-ethyl-N-propyl group-8-tert-butyl group-Isosorbide-5-Nitrae-dioxo spiro [4.5] decane-2-methylamine, belong to sterol biosynthesis inhibitor, mainly suppress the synthetic of C-14 demethylation enzyme.Be suitable for Wheat and barley.Under recommended dose to crop safety, without poisoning.Controlling object wheat powdery mildew and various rust, barley leaf blotch and stripe disease.Volution bacterium amine is a kind of blade face bactericide of novel, interior absorption, effective especially to powdery mildew.Speed of action is fast and the lasting period is long, has protection and therapeutic action concurrently.Both can use separately, again can be with other fungicide compoundings to expand fungicidal spectrum.Using dosage is 375～750g (a.i.)/hm
2.
Tridemorph, chemical name: 2,6-dimethyl-4-tridecyl morpholine, tridemorph is mainly used in preventing and treating powdery mildem of cereals and sigatoka, to other fungal disease, as white, red, the brown root rot of: bamboo grows, powdery mildew, coffee eye spot; The cake disease that tealeaves is right; Melon powdery mildew and the electricity such as powdery mildew of flowers and trees have good preventive effect.Applicable crops is wheat, barley, cucumber, potato, pea, banana, tea tree, rubber etc.Main controlling object is Wheat and barley powdery mildew, leaf rust and yellow rust, cucumber, potato, powdery mildew of pea, rubber tree powdery mildew, sigatoka.
Ultra low volume liquids is to be applicable to the pesticidal preparations that ultra low volume spraying is used, ultra low volume spraying is to follow the appearance of ultra low volume sprayer tool and an advanced applications of pesticide new technology producing, because its droplet is the uniform oiliness droplet of fineness, easily stick on crops, the elegant loss of droplet is little, so agricultural chemicals utilization ratio is high.Compare with the pesticidal preparations of conventional spray application, it has following characteristic:
1. spray amount is low, and work efficiency is high, ultra low volume liquids spray amount 60～330 mL/ mus, be conventional spraying consumption hundreds of/mono-, the high decades of times of work efficiency.
2. droplet is thin, ultra low volume liquids mist droplet particle size scope 20～100 μ m, and conventional fogdrop diameter 200～600 μ m, and the coverage rate of liquid is high, good penetrability, drug effect is high.
3. liquor strength is high, and ultra low volume liquids is Direct spraying dispenser, and the conventional spraying of spray liquor concentration ratio is high tens of to hundreds of times.
Lasting period long, conventional spray liquor is made carrier with water, and ultra low volume is made carrier in order to high boiling point oil solvent, resistance of rainwater washing against more, the drug effect phase is long.
5. safe, ultra low volume finish is to crop safety, and its active ingredient does not adopt severe toxicity and high-toxic pesticide, to person poultry safety.
The inventor's formerly patent 201110269638.1 has been reported Flusilazole and the composite ultra low volume liquids of Boscalid, has coordination synergistic effect, and is not reported with the composite ultra low volume liquids of morpholine class.So the composite ultra low volume of exploitation Boscalid and morpholine class has certain prospect.
Summary of the invention
The object of this invention is to provide a kind of safely, ultra low volume finish is to crop safety, and its active ingredient does not adopt severe toxicity and high-toxic pesticide, the ultra low volume liquids containing Boscalid and morpholine series bactericidal agent to person poultry safety.
The present invention solves the technical scheme that its technical problem takes:
Containing the ultra low volume liquids of Boscalid and morpholine series bactericidal agent, be that one of containing in Boscalid and morpholine series bactericidal agent dimethomorph, fenpropidin, butadiene morpholine, volution bacterium amine, tridemorph composite is the ultra low volume liquids of binary active ingredient.
Containing the ultra low volume liquids of Boscalid and morpholine series bactericidal agent, by the raw material of following percentage by weight, formed:
Boscalid 0.5～10%
Morpholine series bactericidal agent 2～20%
Auxiliary agent 1～15%
Solvent and cosolvent surplus complement to 100%.
Wherein, morpholine series bactericidal agent is any one in dimethomorph, fenpropidin, butadiene morpholine, volution bacterium amine, tridemorph.
Described auxiliary agent is one or more composition in alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, castor oil polyoxyethylene ether, alkyl benzene calcium sulfonate, phenethyl phenol polyethenoxy ether, alkyl phenol formaldehyde resin polyoxyethylene ether.
Described solvent is one or more the mixture in polar solvent DMF, methyl-sulfoxide, sulfolane, 1-METHYLPYRROLIDONE.
Described cosolvent is one or more the mixture in vegetable oil methyl oleate kind solvent or other kind solvents; Vegetable oil methyl oleate kind solvent comprises soybean oil, cottonseed oil, palm oil, castor oil, turpentine oil, corn oil; Aromatic solvent trimethylbenzene, dimethylbenzene, two wires oil and butylbenzene; Other kind solvents comprise terpineol, tripropylene glycol butyl ether, n-octyl alcohol, 2-methyl naphthalene, diesel oil or repefral.
The preparation method who contains the ultra low volume liquids of Boscalid and morpholine series bactericidal agent is: first take the proportioning raw material that formula requires, first solvent is dropped in reactor, open reactor agitator, under stirring condition, drop into Boscalid and the former medicine of morpholine series bactericidal agent, (approximately 10 minutes) until completely dissolved, drop into cosolvent, auxiliary agent, material adds rear continuation and stirs 15-60 minute, obtains the oily product of homogeneous transparent.
Ultra low volume liquids containing Boscalid and morpholine series bactericidal agent is applied to the crops such as paddy rice, wheat, fruit tree, vegetables, is used for preventing and treating powdery mildew, banded sclerotial blight, rice blast, downy mildew, gray mold, various rot, brown rot, root rot and anthracnose.
Good effect of the present invention is embodied in:
(1) spray amount is low, and work efficiency is high, and droplet is thin, and the coverage rate of liquid is high, good penetrability, and drug effect is high.
(2) liquor strength is high, and ultra low volume liquids is Direct spraying dispenser, and the conventional spraying of spray liquor concentration ratio is high tens of to hundreds of times.
(3) lasting period long, conventional spray liquor is made carrier with water, and ultra low volume is made carrier in order to high boiling point oil solvent, resistance of rainwater washing against more, the drug effect phase is long.
(4) safe, ultra low volume finish is to crop safety, and its active ingredient does not adopt severe toxicity and high-toxic pesticide, to person poultry safety.
(5) applied range, generalization is strong.
Embodiment
Essence for a better understanding of the present invention, describes the technology contents of invention below in detail with example.
Embodiment 1:
Configuration quality percentage composition is 16% Boscalid dimethomorph ultra low volume liquids, and its composition and each content are:
Boscalid 0.5kg
Dimethomorph 15.0kg
Fatty alcohol-polyoxyethylene ether 3.0 kg
Alkylphenol polyoxyethylene 6.0 kg
DMF 5.0 kg
Methyl oleate 30.0kg
Diesel oil complements to 100 kg.
Embodiment 2:
Configuration quality percentage composition is 12% Boscalid dimethomorph ultra low volume liquids, and its composition and each content are:
Boscalid 10.0 kg
Dimethomorph 2.0kg
Alkyl benzene calcium sulfonate 3.0 kg
Alkylphenol polyoxyethylene 4.0 kg
Sulfolane 20.0 kg
Two wires oil 30.0kg
Cottonseed oil complements to 100 kg.
Embodiment 3:
Configuration quality percentage composition is 8% Boscalid dimethomorph ultra low volume liquids, and its composition and each content are:
Boscalid 5.0 kg
Dimethomorph 3.0kg
Phenethyl phenol polyethenoxy ether 0.5 kg
Alkylphenol polyoxyethylene 0.5 kg
1-METHYLPYRROLIDONE 35.0 kg
Butylbenzene 30.0kg
Palm oil complements to 100 kg.
Embodiment 4:
Configuration quality percentage composition is 15% Boscalid fenpropidin ultra low volume liquids, and its composition and each content are:
Boscalid 10.0 kg
Fenpropidin 5.0kg
Castor oil polyoxyethylene ether 4.0 kg
Phenethyl phenol polyethenoxy ether 11 kg
Methyl-sulfoxide 14.0 kg
Trimethylbenzene 5.0 kg
1-METHYLPYRROLIDONE 25.0 kg
Methyl oleate 12 kg
Terpineol complements to 100 kg.
Embodiment 5:
Configuration quality percentage composition is 23% Boscalid fenpropidin ultra low volume liquids, and its composition and each content are:
Boscalid 3.0 kg
Fenpropidin 20.0 kg
Phenethyl phenol polyethenoxy ether 5.0 kg
Fatty alcohol-polyoxyethylene ether 3.5 kg
Methyl-sulfoxide 20.0 kg
N-octyl alcohol 12 kg
Methyl oleate complements to 100 kg.
Embodiment 6:
Configuration quality percentage composition is 15% Boscalid fenpropidin ultra low volume liquids, and its composition and each content are:
Boscalid 8.0 kg
Fenpropidin 7.0 kg
Alkyl phenol formaldehyde resin polyoxyethylene ether 6.5 kg
1-METHYLPYRROLIDONE 25.0 kg
Methyl oleate 12 kg
Repefral complements to 100 kg.
Embodiment 7:
Configuration quality percentage composition is 5% Boscalid butadiene morpholine ultra low volume liquids, and its composition and each content are:
Boscalid 2.0 kg
Butadiene morpholine 3.0 kg
Fatty alcohol-polyoxyethylene ether 4.0 kg
1-METHYLPYRROLIDONE 25.0 kg
Methyl oleate 20.0kg
Corn oil complements to 100 kg.
Embodiment 8:
Configuration quality percentage composition is 11% Boscalid butadiene morpholine azoles ultra low volume liquids, and its composition and each content are:
Boscalid 9.0 kg
Butadiene morpholine 2.0 kg
Phenethyl phenol polyethenoxy ether 4.5 kg
DMF 30.0 kg
Dimethylbenzene 5.0 kg
Terpineol complements to 100 kg.
Embodiment 9:
Configuration quality percentage composition is 18% Boscalid butadiene morpholine ultra low volume liquids, and its composition and each content are:
Boscalid 3.0 kg
Butadiene morpholine 15.0 kg
Alkyl phenol formaldehyde resin polyoxyethylene ether 8.0 kg
Phenethyl phenol polyethenoxy ether 6.5 kg
Methyl-sulfoxide 25.0 kg
N-octyl alcohol 12 kg
Castor oil complements to 100 kg.
Embodiment 10:
Configuration quality percentage composition is 10% Boscalid volution bacterium amine ultra low volume liquids, and its composition and each content are:
Boscalid 5.0 kg
Volution bacterium amine 5.0 kg
Alkyl benzene calcium sulfonate 4.0 kg
1-METHYLPYRROLIDONE 25.0 kg
Tripropylene glycol butyl ether 20.0 kg
Repefral complements to 100 kg.
Embodiment 11:
Configuration quality percentage composition is 12% Boscalid volution bacterium amine ultra low volume liquids, and its composition and each content are:
Boscalid 9.0 kg
Volution bacterium amine 3.0 kg
Alkyl phenol formaldehyde resin polyoxyethylene ether 4.0 kg
Phenethyl phenol polyethenoxy ether 5.0 kg
1-METHYLPYRROLIDONE 30.0 kg
Turpentine oil 5.0 kg
Cottonseed oil complements to 100 kg.
Embodiment 12:
Configuration quality percentage composition is 20% Boscalid volution bacterium amine ultra low volume liquids, and its composition and each content are:
Boscalid 5.0 kg
Volution bacterium amine 15.0 kg
Alkylphenol polyoxyethylene 4.0 kg
Alkyl benzene calcium sulfonate 4.0 kg
1-METHYLPYRROLIDONE 30.0 kg
Two wires oil complements to 100 kg.
Embodiment 13:
Configuration quality percentage composition is 5% Boscalid tridemorph ultra low volume liquids, and its composition and each content are:
Boscalid 2.0 kg
Tridemorph 3.0 kg
Fatty alcohol-polyoxyethylene ether 4.0 kg
Alkylaryl polyoxyethylene polyoxypropylene ether 4.0 kg
1-METHYLPYRROLIDONE 25.0 kg
Methyl oleate 20.0kg
Soybean oil complements to 100 kg.
Embodiment 14:
Configuration quality percentage composition is 11% Boscalid tridemorph azoles ultra low volume liquids, and its composition and each content are:
Boscalid 9.0 kg
Tridemorph 2.0 kg
Phenethyl phenol polyethenoxy ether 4.5 kg
Sulfolane 30.0 kg
Castor oil complements to 100 kg.
Embodiment 15:
Configuration quality percentage composition is 23% Boscalid tridemorph ultra low volume liquids, and its composition and each content are:
Boscalid 3.0 kg
Tridemorph 20.0 kg
Alkyl phenol formaldehyde resin polyoxyethylene ether 8.0 kg
Phenethyl phenol polyethenoxy ether 6.5 kg
Methyl-sulfoxide 25.0 kg
N-octyl alcohol 12 kg
2-methyl naphthalene complements to 100 kg.
The preparation method of each example ultra low volume liquids is above: first by formula requirement, take proportioning raw material, first solvent is dropped in reactor, open reactor agitator, under stirring condition, drop into former medicine, (approximately 10 minutes) until completely dissolved, drop into cosolvent, surfactant, material adds rear continuation and stirs 20-30 minute, obtains the oily product of homogeneous transparent.
Test example 1: the ultra low volume liquids of Boscalid and morpholine series bactericidal agent is prevented and treated the field trial of rice sheath blight disease.
The mixture that the embodiment of the present invention is obtained and 24% Boscalid SC, morpholine series bactericidal agent conventional dose are carried out field control effectiveness test, and establishing each community area is rice area 60m
2, repeat 3 times; 7 days, 14 days investigation preventive effects after medicine, the method for investigation drug effect is: 5 pockets are investigated in each community, and every pocket is got a point by east, south, west, north, middle direction, every some investigation 2 strains, record total strain number and diseased plant number at different levels, check the occurrence degree of banded sclerotial blight.Result of the test is as table 1:
The control efficiency of table 1 pair rice sheath blight disease.
Field test results shows, containing the ultra low volume liquids of Boscalid and morpholine series bactericidal agent, can effectively prevent and treat rice sheath blight disease, and effect be better than Boscalid single dose and own azoles alcohol control efficiency.
Claims (8)
1. the ultra low volume liquids containing Boscalid and morpholine series bactericidal agent, contain active component, auxiliary agent, solvent, it is characterized in that: the active component of this ultra low volume liquids is by Boscalid and morpholine series bactericidal agent is composite forms, and in formula, each percentage by weight is composed as follows:
Boscalid 0.5～10%
Morpholine series bactericidal agent 2～20%
Auxiliary agent 1～15%
Solvent and cosolvent surplus complement to 100%.
2. ultra low volume liquids according to claim 1, is characterized in that: described morpholine series bactericidal agent is any one in dimethomorph, fenpropidin, butadiene morpholine, volution bacterium amine, tridemorph.
3. ultra low volume liquids according to claim 1, is characterized in that: described auxiliary agent is one or more mixture in alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, castor oil polyoxyethylene ether, alkyl benzene calcium sulfonate, phenethyl phenol polyethenoxy ether, alkyl phenol formaldehyde resin polyoxyethylene ether.
4. ultra low volume liquids according to claim 1, is characterized in that: described solvent is one or more the mixture in polar solvent DMF, methyl-sulfoxide, sulfolane, 1-METHYLPYRROLIDONE.
5. ultra low volume liquids according to claim 1, is characterized in that: described cosolvent is one or more the mixture in vegetable oil methyl oleate kind solvent or other kind solvents.
6. ultra low volume liquids according to claim 5, is characterized in that: described vegetable oil methyl oleate kind solvent comprises soybean oil, cottonseed oil, palm oil, castor oil, turpentine oil, corn oil.
7. ultra low volume liquids according to claim 5, is characterized in that: described aromatic solvent trimethylbenzene, dimethylbenzene, two wires oil and butylbenzene.
8. ultra low volume liquids according to claim 5, is characterized in that: other described kind solvents comprise terpineol, tripropylene glycol butyl ether, n-octyl alcohol, 2-methyl naphthalene, diesel oil or repefral.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103719109A (en) * | 2013-12-25 | 2014-04-16 | 江苏龙灯化学有限公司 | Fungicidal composition |
| CN104855413A (en) * | 2015-05-12 | 2015-08-26 | 柳州市耕青科技有限公司 | Special rot resistant agent for succulent stone flower |
| CN105941404A (en) * | 2016-05-20 | 2016-09-21 | 南京华洲药业有限公司 | Bactericidal composition containing spiroxamine and metominostrobin and application of bactericidal composition |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005104847A1 (en) * | 2004-04-30 | 2005-11-10 | Basf Aktiengesellschaft | Fungicidal mixtures |
| CN101808521A (en) * | 2007-09-26 | 2010-08-18 | 巴斯夫欧洲公司 | ternary fungicidal compositions comprising boscalid and chlorothalonil |
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2013
- 2013-11-19 CN CN201310577558.1A patent/CN103636616B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005104847A1 (en) * | 2004-04-30 | 2005-11-10 | Basf Aktiengesellschaft | Fungicidal mixtures |
| CN101808521A (en) * | 2007-09-26 | 2010-08-18 | 巴斯夫欧洲公司 | ternary fungicidal compositions comprising boscalid and chlorothalonil |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103719109A (en) * | 2013-12-25 | 2014-04-16 | 江苏龙灯化学有限公司 | Fungicidal composition |
| CN104855413A (en) * | 2015-05-12 | 2015-08-26 | 柳州市耕青科技有限公司 | Special rot resistant agent for succulent stone flower |
| CN105941404A (en) * | 2016-05-20 | 2016-09-21 | 南京华洲药业有限公司 | Bactericidal composition containing spiroxamine and metominostrobin and application of bactericidal composition |
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