CN1036276C - 韧化聚酯组合物 - Google Patents
韧化聚酯组合物 Download PDFInfo
- Publication number
- CN1036276C CN1036276C CN93121486A CN93121486A CN1036276C CN 1036276 C CN1036276 C CN 1036276C CN 93121486 A CN93121486 A CN 93121486A CN 93121486 A CN93121486 A CN 93121486A CN 1036276 C CN1036276 C CN 1036276C
- Authority
- CN
- China
- Prior art keywords
- composition
- weight
- conjugated diene
- polyester
- diene polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920000728 polyester Polymers 0.000 title claims abstract description 36
- 239000000203 mixture Substances 0.000 title claims abstract description 35
- 229920000642 polymer Polymers 0.000 claims abstract description 40
- 150000001993 dienes Chemical class 0.000 claims abstract description 20
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 claims abstract description 14
- 150000001875 compounds Chemical class 0.000 claims abstract description 9
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 16
- 239000004793 Polystyrene Substances 0.000 claims description 4
- 125000003700 epoxy group Chemical group 0.000 claims description 4
- 238000005984 hydrogenation reaction Methods 0.000 claims description 4
- -1 polybutylene terephthalate Polymers 0.000 claims description 4
- 229920002223 polystyrene Polymers 0.000 claims description 4
- 229920001195 polyisoprene Polymers 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims 2
- XZKRXPZXQLARHH-UHFFFAOYSA-N buta-1,3-dienylbenzene Chemical compound C=CC=CC1=CC=CC=C1 XZKRXPZXQLARHH-UHFFFAOYSA-N 0.000 claims 1
- 230000004048 modification Effects 0.000 claims 1
- 238000012986 modification Methods 0.000 claims 1
- 230000035939 shock Effects 0.000 claims 1
- 229920001169 thermoplastic Polymers 0.000 abstract description 4
- 239000004416 thermosoftening plastic Substances 0.000 abstract description 4
- 239000004593 Epoxy Substances 0.000 abstract description 3
- 229920001400 block copolymer Polymers 0.000 description 19
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 8
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 238000002347 injection Methods 0.000 description 6
- 239000007924 injection Substances 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- SYJPAKDNFZLSMV-HYXAFXHYSA-N (Z)-2-methylpropanal oxime Chemical compound CC(C)\C=N/O SYJPAKDNFZLSMV-HYXAFXHYSA-N 0.000 description 5
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 5
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 239000000806 elastomer Substances 0.000 description 4
- 238000001746 injection moulding Methods 0.000 description 4
- 239000008188 pellet Substances 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 description 3
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 239000005062 Polybutadiene Substances 0.000 description 2
- 239000002174 Styrene-butadiene Substances 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 229920005601 base polymer Polymers 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 2
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000011115 styrene butadiene Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- JLYXXMFPNIAWKQ-UHFFFAOYSA-N γ Benzene hexachloride Chemical compound ClC1C(Cl)C(Cl)C(Cl)C(Cl)C1Cl JLYXXMFPNIAWKQ-UHFFFAOYSA-N 0.000 description 2
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 description 1
- 229920013683 Celanese Polymers 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- 229920001283 Polyalkylene terephthalate Polymers 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 229920003247 engineering thermoplastic Polymers 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 229940095102 methyl benzoate Drugs 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
- Epoxy Resins (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/998,206 US5300567A (en) | 1992-12-30 | 1992-12-30 | Low temperature toughening of polyesters with a modified block copolymer |
| US998,206 | 1992-12-30 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1089282A CN1089282A (zh) | 1994-07-13 |
| CN1036276C true CN1036276C (zh) | 1997-10-29 |
Family
ID=25544921
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN93121486A Expired - Fee Related CN1036276C (zh) | 1992-12-30 | 1993-12-28 | 韧化聚酯组合物 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5300567A (enExample) |
| EP (1) | EP0677084B1 (enExample) |
| JP (1) | JPH08505179A (enExample) |
| CN (1) | CN1036276C (enExample) |
| AT (1) | ATE163668T1 (enExample) |
| AU (1) | AU5815794A (enExample) |
| DE (1) | DE69317307T2 (enExample) |
| ES (1) | ES2113638T3 (enExample) |
| TW (1) | TW252139B (enExample) |
| WO (1) | WO1994016013A1 (enExample) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5598069A (en) * | 1993-09-30 | 1997-01-28 | Diablo Research Corporation | Amalgam system for electrodeless discharge lamp |
| CN1209829A (zh) * | 1996-11-22 | 1999-03-03 | 大瑟路化学工业株式会社 | 热熔性组合物及含有由此组合物而成的层之复层成型体 |
| CN105133084B (zh) * | 2015-09-10 | 2017-12-26 | 孝感市元达新材料科技有限公司 | 用于发光织物的聚合物光纤、发光织物及其制造方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4172859A (en) * | 1975-05-23 | 1979-10-30 | E. I. Du Pont De Nemours And Company | Tough thermoplastic polyester compositions |
| DE3280421T2 (de) * | 1981-08-13 | 1993-07-01 | Asahi Chemical Ind | Modifiziertes block-copolymer. |
| US4647619A (en) * | 1984-07-30 | 1987-03-03 | Atlantic Richfield Company | Impact modified polybutylene terephthalate resin molding compositions |
| US4578429A (en) * | 1984-08-31 | 1986-03-25 | Shell Oil Company | Selectively hydrogenated block copolymers modified with acid compounds or derivatives |
| JPS61126164A (ja) * | 1984-11-21 | 1986-06-13 | Toray Ind Inc | ポリエステル樹脂組成物 |
| CA1289686C (en) * | 1985-07-31 | 1991-09-24 | Richard Gelles | Impact resistant polymeric compositions |
| JP2676525B2 (ja) * | 1988-04-07 | 1997-11-17 | 旭化成工業株式会社 | 主鎖にエステル結合及び／又はカーボネート結合を有する熱可塑性樹脂組成物 |
| US5216074A (en) * | 1989-07-17 | 1993-06-01 | Japan Synthetic Rubber Co., Ltd. | Thermoplastic elastomer composition |
| US5066726A (en) * | 1990-04-23 | 1991-11-19 | Shell Oil Company | Process for melt grafting epoxy compounds to polymers |
-
1992
- 1992-12-30 US US07/998,206 patent/US5300567A/en not_active Expired - Lifetime
-
1993
- 1993-12-09 TW TW082110447A patent/TW252139B/zh active
- 1993-12-28 AU AU58157/94A patent/AU5815794A/en not_active Abandoned
- 1993-12-28 WO PCT/EP1993/003728 patent/WO1994016013A1/en not_active Ceased
- 1993-12-28 CN CN93121486A patent/CN1036276C/zh not_active Expired - Fee Related
- 1993-12-28 AT AT94903887T patent/ATE163668T1/de not_active IP Right Cessation
- 1993-12-28 JP JP6515660A patent/JPH08505179A/ja active Pending
- 1993-12-28 ES ES94903887T patent/ES2113638T3/es not_active Expired - Lifetime
- 1993-12-28 DE DE69317307T patent/DE69317307T2/de not_active Expired - Fee Related
- 1993-12-28 EP EP94903887A patent/EP0677084B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0677084B1 (en) | 1998-03-04 |
| DE69317307D1 (de) | 1998-04-09 |
| DE69317307T2 (de) | 1998-07-09 |
| US5300567A (en) | 1994-04-05 |
| EP0677084A1 (en) | 1995-10-18 |
| ES2113638T3 (es) | 1998-05-01 |
| ATE163668T1 (de) | 1998-03-15 |
| WO1994016013A1 (en) | 1994-07-21 |
| JPH08505179A (ja) | 1996-06-04 |
| AU5815794A (en) | 1994-08-15 |
| CN1089282A (zh) | 1994-07-13 |
| TW252139B (enExample) | 1995-07-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |