CN103554360B - 一种耐温抗盐两亲共聚物及其制备方法 - Google Patents
一种耐温抗盐两亲共聚物及其制备方法 Download PDFInfo
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- CN103554360B CN103554360B CN201310533660.1A CN201310533660A CN103554360B CN 103554360 B CN103554360 B CN 103554360B CN 201310533660 A CN201310533660 A CN 201310533660A CN 103554360 B CN103554360 B CN 103554360B
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- resistant
- salt
- temperature
- acrylamide
- amphiphilic copolymer
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- 150000003839 salts Chemical class 0.000 title claims abstract description 47
- 229920001577 copolymer Polymers 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 239000000178 monomer Substances 0.000 claims abstract description 25
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 16
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 13
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 8
- -1 methacryloyl Chemical group 0.000 claims abstract description 6
- 238000007334 copolymerization reaction Methods 0.000 claims abstract 2
- 150000003254 radicals Chemical class 0.000 claims abstract 2
- 229920000642 polymer Polymers 0.000 claims description 38
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 7
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 239000003999 initiator Substances 0.000 claims description 6
- 235000019270 ammonium chloride Nutrition 0.000 claims description 5
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 2
- 239000012153 distilled water Substances 0.000 claims description 2
- BOLDJAUMGUJJKM-LSDHHAIUSA-N renifolin D Natural products CC(=C)[C@@H]1Cc2c(O)c(O)ccc2[C@H]1CC(=O)c3ccc(O)cc3O BOLDJAUMGUJJKM-LSDHHAIUSA-N 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 230000007774 longterm Effects 0.000 abstract description 14
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract description 6
- 238000010008 shearing Methods 0.000 abstract description 6
- 239000010779 crude oil Substances 0.000 abstract description 4
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract description 3
- 230000007928 solubilization Effects 0.000 abstract description 3
- 238000005063 solubilization Methods 0.000 abstract description 3
- 238000000605 extraction Methods 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 15
- 239000003921 oil Substances 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 238000012512 characterization method Methods 0.000 description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 238000006073 displacement reaction Methods 0.000 description 4
- 239000012452 mother liquor Substances 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000002861 polymer material Substances 0.000 description 2
- IMZGHXHAVUGEMC-UHFFFAOYSA-N C(C=C)(=O)NC(C)(C)[Na] Chemical compound C(C=C)(=O)NC(C)(C)[Na] IMZGHXHAVUGEMC-UHFFFAOYSA-N 0.000 description 1
- 150000003926 acrylamides Chemical class 0.000 description 1
- 238000009412 basement excavation Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 229920001222 biopolymer Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229920005570 flexible polymer Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
- 229920001480 hydrophilic copolymer Polymers 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 230000015784 hyperosmotic salinity response Effects 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 125000001453 quaternary ammonium group Chemical class 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
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CN103554360B true CN103554360B (zh) | 2014-07-30 |
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Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107868179B (zh) * | 2016-09-28 | 2020-04-07 | 中国石油化工股份有限公司 | 一种丙烯酰胺共聚物及其制备方法与应用 |
CN107446563A (zh) * | 2017-08-04 | 2017-12-08 | 中国海洋石油总公司 | 一种稠油活化剂的应用 |
CN107383273B (zh) * | 2017-08-04 | 2019-05-21 | 中国海洋石油集团有限公司 | 一种稠油活化剂及其制备方法 |
CN109536145B (zh) * | 2018-12-03 | 2021-11-19 | 中国石油天然气集团有限公司 | 一种水溶性压裂暂堵剂及其合成方法 |
CN113337265B (zh) * | 2021-07-29 | 2021-11-23 | 山东德仕化工有限公司 | 一种低张力降粘驱油剂及其制备方法和应用 |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4694046A (en) * | 1985-11-25 | 1987-09-15 | Exxon Research And Engineering Company | Hydrophobically associating terpolymers of acrylamide, salts of acrylic acid and alkyl acrylamide |
US4709759A (en) * | 1986-12-29 | 1987-12-01 | Exxon Research And Engineering Company | Enhanced oil recovery with hydrophobically associating polymers containing N-vinyl-pyrrolidone functionality |
JPH02163189A (ja) * | 1988-12-16 | 1990-06-22 | Dai Ichi Kogyo Seiyaku Co Ltd | 石油ボーリング掘削用泥水調整剤 |
CN1405266A (zh) * | 2002-10-28 | 2003-03-26 | 四川大学 | 高增粘疏水缔合聚合物驱油剂的制备方法 |
CN101463116A (zh) * | 2009-01-12 | 2009-06-24 | 成都理工大学 | 非线型缔合水溶性四元共聚物及其制备方法和用途 |
JP2010270170A (ja) * | 2009-05-19 | 2010-12-02 | Toagosei Co Ltd | 石油回収薬剤及びその製造方法、並びに石油回収用圧入液体 |
CN103059217A (zh) * | 2013-01-08 | 2013-04-24 | 西南石油大学 | 一种耐温抗盐疏水缔合聚合物驱油剂及制备方法 |
CN103305204A (zh) * | 2013-05-28 | 2013-09-18 | 西南石油大学 | 一种耐温耐盐丙烯酰胺三元共聚物磺酸盐驱油剂及合成 |
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2013
- 2013-10-31 CN CN201310533660.1A patent/CN103554360B/zh not_active Expired - Fee Related
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4694046A (en) * | 1985-11-25 | 1987-09-15 | Exxon Research And Engineering Company | Hydrophobically associating terpolymers of acrylamide, salts of acrylic acid and alkyl acrylamide |
US4709759A (en) * | 1986-12-29 | 1987-12-01 | Exxon Research And Engineering Company | Enhanced oil recovery with hydrophobically associating polymers containing N-vinyl-pyrrolidone functionality |
JPH02163189A (ja) * | 1988-12-16 | 1990-06-22 | Dai Ichi Kogyo Seiyaku Co Ltd | 石油ボーリング掘削用泥水調整剤 |
CN1405266A (zh) * | 2002-10-28 | 2003-03-26 | 四川大学 | 高增粘疏水缔合聚合物驱油剂的制备方法 |
CN101463116A (zh) * | 2009-01-12 | 2009-06-24 | 成都理工大学 | 非线型缔合水溶性四元共聚物及其制备方法和用途 |
JP2010270170A (ja) * | 2009-05-19 | 2010-12-02 | Toagosei Co Ltd | 石油回収薬剤及びその製造方法、並びに石油回収用圧入液体 |
CN103059217A (zh) * | 2013-01-08 | 2013-04-24 | 西南石油大学 | 一种耐温抗盐疏水缔合聚合物驱油剂及制备方法 |
CN103305204A (zh) * | 2013-05-28 | 2013-09-18 | 西南石油大学 | 一种耐温耐盐丙烯酰胺三元共聚物磺酸盐驱油剂及合成 |
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Application publication date: 20140205 Assignee: LANDY (LANGFANG) PETROCHEMICAL ENVIRONMENTAL PROTECTION EQUIPMENT CO.,LTD. Assignor: Southwest Petroleum University Contract record no.: 2014990000763 Denomination of invention: Temperature-resistant salt-resistant amphiphilic copolymer as well as preparation method thereof Granted publication date: 20140730 License type: Exclusive License Record date: 20140923 |
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