CN103541237A - Quickly-solidified pigment printing adhesive and preparation method thereof - Google Patents
Quickly-solidified pigment printing adhesive and preparation method thereof Download PDFInfo
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- CN103541237A CN103541237A CN201310502018.7A CN201310502018A CN103541237A CN 103541237 A CN103541237 A CN 103541237A CN 201310502018 A CN201310502018 A CN 201310502018A CN 103541237 A CN103541237 A CN 103541237A
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Abstract
The invention discloses a quickly-solidified pigment printing adhesive, which is prepared from the following raw materials in parts by weight: 40-45 parts of epoxy acrylate, 20-23 parts of methyl acrylate, 12-14 parts of pentaerythritol, 4-5 parts of acrylonitrile, 5-7 parts of ethyl acrylate, 1-2 parts of mandarin oil, 1-2 parts of benzotriazole, 4-5 parts of melamine, 4-5 parts of 12-hydroxystearic acid, 1-2 parts of stilbene-phenol polyoxyethylene ether, 1-2 parts of ammonium persulfate, 4-5 parts of an assistant, and 70-80 parts of water. The quickly-solidified pigment printing adhesive is applied to pigment printing; the fabric is soft in touch, bright in color, high in wear resistance and washing-resistance fastness, good in water resistance and drug resistance, free of a cross-linking agent and free of demands on compatibility order. The modulated mill base is good in stability, free of formaldehyde and free of alkylphenol ethoxylates (APEO), has the advantages of no environmental pollution or poison, complete color spectrum, easy color matching, vivid color and luster and the like, and can be widely applied to a printing and dyeing industry.
Description
Technical field
The invention belongs to textile auxiliary's technical field, relate in particular to a kind of fast-curing paint printing adhesive and preparation method thereof.
Background technology
So-called COAT PRINTING is the effect by adhesive, by water insoluble, to fabric, do not have compatibility and reactive pigment to anchor on fabric, thereby reach painted object.According to update introduction, the PRINTED FABRIC of nearly half output is COAT PRINTING in the world at present.Pigment printing binding agent is the main component of textile printing pigment, and the quality of COAT PRINTING end product quality is directly subject to the impact of printing adhesive performance.
The quality of printing adhesive differs at present, the stamp defect rate causing because of adhesive quality problems, more than 3%, has caused huge economic loss, and the quality of printing adhesive directly has influence on quality, the fineness of stamp, the class of fabric, therefore, need to research and develop the more adhesive of high-quality.
Summary of the invention
The object of the present invention is to provide a kind of fast-curing paint printing adhesive and preparation method thereof, this adhesive has quick solidifying, environmental protection, the feature that look bright, fastness is high.
Technical scheme of the present invention is as follows:
A printing adhesive, is characterized in that being made by the raw material of following weight portion: epoxy acrylate 40-45, methyl acrylate 20-23, pentaerythrite 12-14, acrylonitrile 4-5, ethyl acrylate 5-7, mandarin oil 1-2, BTA 1-2, melamine 4-5,12-hydroxy stearic acid 4-5, diphenylethyllene phenol polyoxyethylene ether 1-2, ammonium persulfate 1-2, auxiliary agent 4-5, water 70-80; Described auxiliary agent is made by the raw material of following weight portion: Silane coupling reagent KH-570 2-3, crosslinking agent TAC1-2, styrene 3-4, maleic anhydride 2-3, Tween-81 2-3, acrylonitrile 2-3, antioxidant 1035 1-2, diethylene glycol (DEG) 7-9, ethanol 12-15; Preparation method mixes crosslinking agent TAC, styrene, maleic anhydride, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
The preparation method of described fast-curing paint printing adhesive, it is characterized in that comprising the following steps: epoxy acrylate, methyl acrylate, pentaerythrite, acrylonitrile, ethyl acrylate, mandarin oil, melamine, diphenylethyllene phenol polyoxyethylene ether are mixed, under 1200-1400 rev/min of stirring, with the speed of 7-9 ℃/minute, be heated to 60-70 ℃; Add 12-hydroxy stearic acid, BTA, with the speed of 4-7 ℃/minute, be heated to 80-90 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2-3 hour, obtain.
Beneficial effect of the present invention
The present invention is for COAT PRINTING, fabric soft, look bright, wear resistance and fastness to washing is high, water-fast, resistance physical property is good; Without additional crosslink agent, without compatibility sequence requirement, the stability of pigment paste after modulation is good; Formaldehydeless, without APEO, there is non-environmental-pollution, nonhazardous, chromatogram is complete, colorant match is easy, the advantage such as bright in colour, can in printing and dyeing industry, be used widely.
The specific embodiment
A printing adhesive, by following weight portion (kilogram) raw material make: epoxy acrylate 43, methyl acrylate 22, pentaerythrite 13, acrylonitrile 4.5, ethyl acrylate 6, mandarin oil 1.5, BTA 1.5, melamine 4.5,12-hydroxy stearic acid 4.5, diphenylethyllene phenol polyoxyethylene ether 1.5, ammonium persulfate 1.5, auxiliary agent 4.5, water 75; Described auxiliary agent by following weight portion (kilogram) raw material make: Silane coupling reagent KH-570 2, crosslinking agent TAC1, styrene 4, maleic anhydride 3, Tween-81 2, acrylonitrile 2, antioxidant 1,035 2, diethylene glycol (DEG) 7, ethanol 12; Preparation method mixes crosslinking agent TAC, styrene, maleic anhydride, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
The preparation method of described fast-curing paint printing adhesive, comprise the following steps: epoxy acrylate, methyl acrylate, pentaerythrite, acrylonitrile, ethyl acrylate, mandarin oil, melamine, diphenylethyllene phenol polyoxyethylene ether are mixed, under 1300 revs/min of stirrings, with the speed of 8 ℃/minute, be heated to 65 ℃; Add 12-hydroxy stearic acid, BTA, with the speed of 6 ℃/minute, be heated to 85 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2.5 hours, obtain.
This knitted fabric for stamp, is pressed GB standard detection with printing adhesive, dry fastness 3-4 level, and fastness to wet rubbing is at 3 grades, and brushing fastness 3-4 level, glues 4 grades of COLOR FASTNESS, the fastness of fading after soaping 3-4 level.
Claims (2)
1. a fast-curing paint printing adhesive, is characterized in that being made by the raw material of following weight portion: epoxy acrylate 40-45, methyl acrylate 20-23, pentaerythrite 12-14, acrylonitrile 4-5, ethyl acrylate 5-7, mandarin oil 1-2, BTA 1-2, melamine 4-5,12-hydroxy stearic acid 4-5, diphenylethyllene phenol polyoxyethylene ether 1-2, ammonium persulfate 1-2, auxiliary agent 4-5, water 70-80; Described auxiliary agent is made by the raw material of following weight portion: Silane coupling reagent KH-570 2-3, crosslinking agent TAC1-2, styrene 3-4, maleic anhydride 2-3, Tween-81 2-3, acrylonitrile 2-3, antioxidant 1035 1-2, diethylene glycol (DEG) 7-9, ethanol 12-15; Preparation method mixes crosslinking agent TAC, styrene, maleic anhydride, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
2. the preparation method of fast-curing paint printing adhesive according to claim 1, it is characterized in that comprising the following steps: epoxy acrylate, methyl acrylate, pentaerythrite, acrylonitrile, ethyl acrylate, mandarin oil, melamine, diphenylethyllene phenol polyoxyethylene ether are mixed, under 1200-1400 rev/min of stirring, with the speed of 7-9 ℃/minute, be heated to 60-70 ℃; Add 12-hydroxy stearic acid, BTA, with the speed of 4-7 ℃/minute, be heated to 80-90 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2-3 hour, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310502018.7A CN103541237A (en) | 2013-10-23 | 2013-10-23 | Quickly-solidified pigment printing adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310502018.7A CN103541237A (en) | 2013-10-23 | 2013-10-23 | Quickly-solidified pigment printing adhesive and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103541237A true CN103541237A (en) | 2014-01-29 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310502018.7A Pending CN103541237A (en) | 2013-10-23 | 2013-10-23 | Quickly-solidified pigment printing adhesive and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103924458A (en) * | 2014-03-26 | 2014-07-16 | 东至绿洲环保化工有限公司 | Silicon acrylic emulsion printing adhesive |
| CN106749863A (en) * | 2016-11-23 | 2017-05-31 | 苏州联胜化学有限公司 | A kind of imitative reactive coating printing adhesive and preparation method thereof, application process |
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| CN1453321A (en) * | 2002-04-28 | 2003-11-05 | 王学谦 | Multifunctional aqueous adhesive and its prepn |
| CN1566244A (en) * | 2003-07-01 | 2005-01-19 | 中国乐凯胶片集团公司 | UV photo-curing adhesive for lamination of polarizer sheet protective membrane |
| CN102190989A (en) * | 2010-03-08 | 2011-09-21 | 上海奇想青晨新材料科技股份有限公司 | Water-based pigment printing adhesive and preparation method thereof |
| CN102433094A (en) * | 2011-10-19 | 2012-05-02 | 常州市宝丽胶粘剂有限公司 | Preparation of novel adhesive for low-surface-energy substrate |
| WO2012097186A1 (en) * | 2011-01-16 | 2012-07-19 | Simpson Strong-Tie Company, Inc. | Low temperature curable adhesive compositions |
| CN102732192A (en) * | 2011-12-29 | 2012-10-17 | 湖北航天化学技术研究所 | Emulsion acrylate pressure-sensitive adhesive, preparation method and application thereof |
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2013
- 2013-10-23 CN CN201310502018.7A patent/CN103541237A/en active Pending
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| CN1453321A (en) * | 2002-04-28 | 2003-11-05 | 王学谦 | Multifunctional aqueous adhesive and its prepn |
| CN1566244A (en) * | 2003-07-01 | 2005-01-19 | 中国乐凯胶片集团公司 | UV photo-curing adhesive for lamination of polarizer sheet protective membrane |
| CN102190989A (en) * | 2010-03-08 | 2011-09-21 | 上海奇想青晨新材料科技股份有限公司 | Water-based pigment printing adhesive and preparation method thereof |
| WO2012097186A1 (en) * | 2011-01-16 | 2012-07-19 | Simpson Strong-Tie Company, Inc. | Low temperature curable adhesive compositions |
| CN102433094A (en) * | 2011-10-19 | 2012-05-02 | 常州市宝丽胶粘剂有限公司 | Preparation of novel adhesive for low-surface-energy substrate |
| CN102732192A (en) * | 2011-12-29 | 2012-10-17 | 湖北航天化学技术研究所 | Emulsion acrylate pressure-sensitive adhesive, preparation method and application thereof |
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| 徐金龙等: ""聚丙烯酸酯类乳液的合成与应用开发"", 《江西科学》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103924458A (en) * | 2014-03-26 | 2014-07-16 | 东至绿洲环保化工有限公司 | Silicon acrylic emulsion printing adhesive |
| CN106749863A (en) * | 2016-11-23 | 2017-05-31 | 苏州联胜化学有限公司 | A kind of imitative reactive coating printing adhesive and preparation method thereof, application process |
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Application publication date: 20140129 |