CN103556503A - Anti-stain dustproof printing adhesive and preparation method thereof - Google Patents
Anti-stain dustproof printing adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN103556503A CN103556503A CN201310502054.3A CN201310502054A CN103556503A CN 103556503 A CN103556503 A CN 103556503A CN 201310502054 A CN201310502054 A CN 201310502054A CN 103556503 A CN103556503 A CN 103556503A
- Authority
- CN
- China
- Prior art keywords
- parts
- adhesive
- minute
- preparation
- heated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses an anti-stain dustproof printing adhesive which is prepared from the following raw materials in parts by weight: 2-3 parts of sodium hydrogen carbonate, 1-2 parts of dispersing agent MF, 6-8 parts of polyvinyl alcohol, 2-3 parts of itaconic acid, 14-16 parts of trimethylolpropane trimethacrylate, 40-45 parts of bisphenol A epoxy acrylate, 10-12 parts of tripropylene glycol diacrylate, 12-14 parts of propylene carbonate, 4-5 parts of silica sol, 5-7 parts of methylacrylic acid, 9-12 parts of isooctyl methacrylate, 1-2 parts of ammonium persulfate, 4-5 parts of auxiliaries and 70-75 parts of water. By being added with the silica sol, the adhesive disclosed by the invention has an excellent dustproof anti-stain effect as well as the characteristics of high transparency, hot water resistance, weather resistance, drug resistance, softness, good toughness and high fastness; the application range of the adhesive disclosed by the invention is wide, and the advantage of good fastness can be highlighted when the adhesive is applied to a seriously-worn fabric.
Description
Technical field
The invention belongs to textile auxiliary's technical field, relate in particular to a kind of dirt-resisting dustproof printing adhesive and preparation method thereof.
Background technology
So-called COAT PRINTING is the effect by adhesive, by water insoluble, to fabric, do not have compatibility and reactive pigment to anchor on fabric, thereby reach painted object.According to update introduction, the PRINTED FABRIC of nearly half output is COAT PRINTING in the world at present.Pigment printing binding agent is the main component of textile printing pigment, and the quality of COAT PRINTING end product quality is directly subject to the impact of printing adhesive performance.
The quality of printing adhesive differs at present, the stamp defect rate causing because of adhesive quality problems, more than 3%, has caused huge economic loss, and the quality of printing adhesive directly has influence on quality, the fineness of stamp, the class of fabric, therefore, need to research and develop the more adhesive of high-quality.
Summary of the invention
The object of the present invention is to provide a kind of dirt-resisting dustproof printing adhesive and preparation method thereof, this adhesive has that dirt-resisting dustproof, fastness are high, the feature of weatherability.
Technical scheme of the present invention is as follows:
A printing adhesive, is characterized in that being made by the raw material of following weight portion: sodium bicarbonate 2-3, dispersing agent MF 1-2, polyvinyl alcohol 6-8, itaconic acid 2-3, trimethylol-propane trimethacrylate 14-16, bisphenol A epoxy acrylate 40-45, tri (propylene glycol) diacrylate 10-12, propene carbonate 12-14, Ludox 4-5, methacrylic acid 5-7, EHMA 9-12, ammonium persulfate 1-2, auxiliary agent 4-5, water 70-75; Described auxiliary agent is made by the raw material of following weight portion: Silane coupling reagent KH-570 2-3, crosslinking agent TAC1-2, Tea Polyphenols 2-3, styrene 3-4, styrylphenol polyoxyethylene ether 2.5-3.0, lemon 0.1-0.2, morpholine 1-2, glycerin monostearate 4-5, neopentyl glycol 3-4, vinylacetate 2-3, antioxidant 1035 2-3, diethylene glycol (DEG) 7-9, ethanol 12-15; Preparation method mixes crosslinking agent TAC, styrene, vinylacetate, neopentyl glycol, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
The preparation method of described dirt-resisting dustproof printing adhesive, it is characterized in that comprising the following steps: polyvinyl alcohol, itaconic acid, trimethylol-propane trimethacrylate, bisphenol A epoxy acrylate, tri (propylene glycol) diacrylate, propene carbonate, Ludox, methacrylic acid, EHMA are mixed, under 1200-1500 rev/min of stirring, with the speed of 7-9 ℃/minute, be heated to 60-70 ℃; Add sodium bicarbonate, dispersing agent MF, with the speed of 5-7 ℃/minute, be heated to 80-90 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2-3 hour, obtain.
Beneficial effect of the present invention
Adhesive of the present invention adds Ludox, has excellent dustproof anti-soil effect, also has high, the heat-resisting water of transparency, drug resistance, softness, good toughness, weatherability, feature that fastness is high; Adhesive of the present invention is applied widely, for the fabric of serious wear, more can highlight the advantage that its fastness is good.
The specific embodiment
A printing adhesive, by following weight portion (kilogram) raw material make: sodium bicarbonate 2.5, dispersing agent MF 1.5, polyvinyl alcohol 7, itaconic acid 2.5, trimethylol-propane trimethacrylate 15, bisphenol A epoxy acrylate 43, tri (propylene glycol) diacrylate 11, propene carbonate 13, Ludox 4.5, methacrylic acid 6, EHMA 11, ammonium persulfate 1.5, auxiliary agent 4.5, water 73; Described auxiliary agent by following weight portion (kilogram) raw material make: Silane coupling reagent KH-570 2, crosslinking agent TAC1, Tea Polyphenols 3, styrene 3, styrylphenol polyoxyethylene ether 2.5, lemon 0.1, morpholine 1, glycerin monostearate 4, neopentyl glycol 3, vinylacetate 2, antioxidant 1,035 2, diethylene glycol (DEG) 7, ethanol 15; Preparation method mixes crosslinking agent TAC, styrene, vinylacetate, neopentyl glycol, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
The preparation method of described dirt-resisting dustproof printing adhesive, comprise the following steps: polyvinyl alcohol, itaconic acid, trimethylol-propane trimethacrylate, bisphenol A epoxy acrylate, tri (propylene glycol) diacrylate, propene carbonate, Ludox, methacrylic acid, EHMA are mixed, under 1300 revs/min of stirrings, with the speed of 8 ℃/minute, be heated to 65 ℃; Add sodium bicarbonate, dispersing agent MF, with the speed of 6 ℃/minute, be heated to 85 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2.5 hours, obtain.
This dirt-resisting dustproof printing adhesive, for PRINTED FABRIC, is pressed GB standard detection, dry fastness 3-4 level, and fastness to wet rubbing is at 3 grades, and 4 grades of brushing fastnesses, glue 4 grades of COLOR FASTNESS, the fastness of fading after soaping 3-4 level.
Claims (2)
1. a dirt-resisting dustproof printing adhesive, is characterized in that being made by the raw material of following weight portion: sodium bicarbonate 2-3, dispersing agent MF 1-2, polyvinyl alcohol 6-8, itaconic acid 2-3, trimethylol-propane trimethacrylate 14-16, bisphenol A epoxy acrylate 40-45, tri (propylene glycol) diacrylate 10-12, propene carbonate 12-14, Ludox 4-5, methacrylic acid 5-7, EHMA 9-12, ammonium persulfate 1-2, auxiliary agent 4-5, water 70-75; Described auxiliary agent is made by the raw material of following weight portion: Silane coupling reagent KH-570 2-3, crosslinking agent TAC1-2, Tea Polyphenols 2-3, styrene 3-4, styrylphenol polyoxyethylene ether 2.5-3.0, lemon 0.1-0.2, morpholine 1-2, glycerin monostearate 4-5, neopentyl glycol 3-4, vinylacetate 2-3, antioxidant 1035 2-3, diethylene glycol (DEG) 7-9, ethanol 12-15; Preparation method mixes crosslinking agent TAC, styrene, vinylacetate, neopentyl glycol, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
2. the preparation method of dirt-resisting dustproof printing adhesive according to claim 1, it is characterized in that comprising the following steps: polyvinyl alcohol, itaconic acid, trimethylol-propane trimethacrylate, bisphenol A epoxy acrylate, tri (propylene glycol) diacrylate, propene carbonate, Ludox, methacrylic acid, EHMA are mixed, under 1200-1500 rev/min of stirring, with the speed of 7-9 ℃/minute, be heated to 60-70 ℃; Add sodium bicarbonate, dispersing agent MF, with the speed of 5-7 ℃/minute, be heated to 80-90 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2-3 hour, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310502054.3A CN103556503A (en) | 2013-10-23 | 2013-10-23 | Anti-stain dustproof printing adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310502054.3A CN103556503A (en) | 2013-10-23 | 2013-10-23 | Anti-stain dustproof printing adhesive and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103556503A true CN103556503A (en) | 2014-02-05 |
Family
ID=50010840
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310502054.3A Pending CN103556503A (en) | 2013-10-23 | 2013-10-23 | Anti-stain dustproof printing adhesive and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103556503A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103556466A (en) * | 2013-11-04 | 2014-02-05 | 吴江市祥盛纺织品有限公司 | Composite anti-fouling flannelette |
| CN106867457A (en) * | 2016-12-22 | 2017-06-20 | 新疆德蓝股份有限公司 | A kind of compound dust suppressant and preparation method thereof |
| CN112574702A (en) * | 2020-12-30 | 2021-03-30 | 江苏卡欧化工股份有限公司 | Film-coated cobalt boroacylate adhesive and preparation method thereof |
| CN116922495A (en) * | 2023-09-06 | 2023-10-24 | 深圳江浩电子有限公司 | Air exhaust device of capacitor aluminum foil cutting machine |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060252329A1 (en) * | 2005-05-04 | 2006-11-09 | Shawmut Corporation | Halogen and plasticizer free permeable laminate |
| CN101467075A (en) * | 2006-06-13 | 2009-06-24 | 3M创新有限公司 | Fluoro(meth)acrylate polymer composition suitable for low index layer of antireflective film |
| CN101544869A (en) * | 2008-03-27 | 2009-09-30 | 上海富臣化工有限公司 | Packless ultraviolet curing transparent priming lacquer for woodenware |
| CN102344522A (en) * | 2011-06-25 | 2012-02-08 | 百利合化工（中山）有限公司 | Environment-friendly printing platen adhesive emulsion and preparation method thereof |
| CN102505526A (en) * | 2011-11-04 | 2012-06-20 | 常熟市凯力达蜂窝包装材料有限公司 | Organic silicon-modified adhesive for printing |
| CN103088674A (en) * | 2012-12-26 | 2013-05-08 | 辽宁恒星精细化工有限公司 | Bright film printing paste and preparation method thereof |
| CN103214992A (en) * | 2013-05-04 | 2013-07-24 | 辽宁恒星精细化工有限公司 | Binding agent for conductive carbon black slurry and preparation method thereof |
-
2013
- 2013-10-23 CN CN201310502054.3A patent/CN103556503A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060252329A1 (en) * | 2005-05-04 | 2006-11-09 | Shawmut Corporation | Halogen and plasticizer free permeable laminate |
| CN101467075A (en) * | 2006-06-13 | 2009-06-24 | 3M创新有限公司 | Fluoro(meth)acrylate polymer composition suitable for low index layer of antireflective film |
| CN101544869A (en) * | 2008-03-27 | 2009-09-30 | 上海富臣化工有限公司 | Packless ultraviolet curing transparent priming lacquer for woodenware |
| CN102344522A (en) * | 2011-06-25 | 2012-02-08 | 百利合化工（中山）有限公司 | Environment-friendly printing platen adhesive emulsion and preparation method thereof |
| CN102505526A (en) * | 2011-11-04 | 2012-06-20 | 常熟市凯力达蜂窝包装材料有限公司 | Organic silicon-modified adhesive for printing |
| CN103088674A (en) * | 2012-12-26 | 2013-05-08 | 辽宁恒星精细化工有限公司 | Bright film printing paste and preparation method thereof |
| CN103214992A (en) * | 2013-05-04 | 2013-07-24 | 辽宁恒星精细化工有限公司 | Binding agent for conductive carbon black slurry and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 卢杰宏 等: "涂料印花用粘合剂研究进展", 《热固性树脂》 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103556466A (en) * | 2013-11-04 | 2014-02-05 | 吴江市祥盛纺织品有限公司 | Composite anti-fouling flannelette |
| CN106867457A (en) * | 2016-12-22 | 2017-06-20 | 新疆德蓝股份有限公司 | A kind of compound dust suppressant and preparation method thereof |
| CN106867457B (en) * | 2016-12-22 | 2019-05-17 | 德蓝水技术股份有限公司 | A kind of compound dust suppressant and preparation method thereof |
| CN112574702A (en) * | 2020-12-30 | 2021-03-30 | 江苏卡欧化工股份有限公司 | Film-coated cobalt boroacylate adhesive and preparation method thereof |
| CN116922495A (en) * | 2023-09-06 | 2023-10-24 | 深圳江浩电子有限公司 | Air exhaust device of capacitor aluminum foil cutting machine |
| CN116922495B (en) * | 2023-09-06 | 2023-12-12 | 深圳江浩电子有限公司 | Air exhaust device of capacitor aluminum foil cutting machine |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103556503A (en) | Anti-stain dustproof printing adhesive and preparation method thereof | |
| CN103911885A (en) | Printing and dyeing paste | |
| CN103526589A (en) | Aromatic polyurethane pigment printing binding agent and preparation method thereof | |
| CN102864658A (en) | Pigment printing binder | |
| CN103526586A (en) | Flame-retardant soft printing adhesive and preparation method thereof | |
| CN103541235A (en) | Water emulsion type polyester acrylate printing adhesive and preparation method thereof | |
| CN103526597A (en) | Flame-retardant printing adhesive and preparation method thereof | |
| CN103526584A (en) | Corrosion-resistance pigment printing adhesive and preparation method thereof | |
| CN103556504A (en) | Super soft printing adhesive and preparation method thereof | |
| CN103526588A (en) | Soap-washing-endurance pigment printing binding agent and preparation method thereof | |
| CN103526582A (en) | Waterborne pigment printing adhesive and preparation method thereof | |
| CN103541239A (en) | Waterproof printing adhesive and preparation method thereof | |
| CN103526595A (en) | Active pigment resin printing imitation binder and preparation method for same | |
| CN103526587A (en) | Digital printing adhesive and preparation method thereof | |
| CN103541236A (en) | Soft corrosion-resistant printing adhesive and preparation method | |
| CN101392029B (en) | Novel acrylic ester polymerization oxidation crosslinking modified starch and preparation method thereof | |
| CN103526591A (en) | Flame-retardant soft printing adhesive and preparation method thereof | |
| CN103541237A (en) | Quickly-solidified pigment printing adhesive and preparation method thereof | |
| CN103541233A (en) | Waterproof flexible printing adhesive and preparation method thereof | |
| CN103541242A (en) | Low-shrinking percentage bright printing adhesive and preparation method thereof | |
| CN103541238A (en) | Low-temperature adhesive for pigment printing and preparation method thereof | |
| CN103526593A (en) | Rigid printing adhesive and preparation method thereof | |
| CN104179042A (en) | Dye fixing agent and preparation method of dye fixing agent | |
| CN103666094B (en) | A kind of printing-ink and its preparation method | |
| CN103526580A (en) | Printing adhesive for knitted fabrics and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140205 |
|
| RJ01 | Rejection of invention patent application after publication |