CN103526587A - Digital printing adhesive and preparation method thereof - Google Patents
Digital printing adhesive and preparation method thereof Download PDFInfo
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- CN103526587A CN103526587A CN201310501979.6A CN201310501979A CN103526587A CN 103526587 A CN103526587 A CN 103526587A CN 201310501979 A CN201310501979 A CN 201310501979A CN 103526587 A CN103526587 A CN 103526587A
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Abstract
The invention relates to a digital printing adhesive. The digital printing adhesive is prepared from the following raw materials in parts by weight: 30-35 parts of bisphenol A epoxy acrylate, 2-3 parts of sodium dodecyl benzene sulfonate, 5-6 parts of glycerinum, 6-8 parts of trimethylolethane, 3-4 parts of xylitol, 10-12 parts of tris(2-butoxyethyl) phosphate, 5-8 parts of butyl methacrylate, 14-16 parts of 1,6 hexanediol diacrylate, 10-15 parts of trimethylolpropane triacrylate, 2-3 parts of nonyl phenol, 3-4 parts of polyvinyl butyral, 1-2 parts of ammonium persulfate, 4-5 parts of addition agent, and 70-80 parts of water. The digital printing adhesive does not contain APEO (alkylphenol ethoxylates), formaldehyde, degradable compounds and the like, is environment-friendly and pollution-free, has good stability and dispersing property, can prevent pigment particles from coagulation, can be baked to form a film through crosslinking at lower temperature, greatly reduces the energy consumption and sewage discharge, and has the characteristics of strong adhesive force, high curing speed, good toughness, and good waterproof, hot water resistant and drug resistant properties.
Description
Technical field
The invention belongs to textile auxiliary's technical field, relate in particular to a kind of digit printing adhesive and preparation method thereof.
Background technology
So-called COAT PRINTING is the effect by adhesive, by water insoluble, to fabric, do not have compatibility and reactive pigment to anchor on fabric, thereby reach painted object.According to update introduction, the PRINTED FABRIC of nearly half output is COAT PRINTING in the world at present.Pigment printing binding agent is the main component of textile printing pigment, and the quality of COAT PRINTING end product quality is directly subject to the impact of printing adhesive performance.
The quality of printing adhesive differs at present, the stamp defect rate causing because of adhesive quality problems, more than 3%, has caused huge economic loss, and the quality of printing adhesive directly has influence on quality, the fineness of stamp, the class of fabric, therefore, need to research and develop the more adhesive of high-quality.
Summary of the invention
The object of the present invention is to provide a kind of digit printing adhesive and preparation method thereof, this adhesive has that adhesion strength is strong, quick solidifying, good toughness, water-fast feature.
Technical scheme of the present invention is as follows:
A kind of digit printing adhesive, it is characterized in that being made by the raw material of following weight portion: bisphenol A epoxy acrylate 30-35, neopelex 2-3, glycerine 5-6, trimethylolethane 6-8, xylitol 3-4, butoxy ethyl phosphate 10-12, butyl methacrylate 5-8,1,6 hexanediyl ester 14-16, trimethylolpropane triacrylate 10-15, nonyl phenol 2-3, polyvinyl butyral resin 3-4, ammonium persulfate 1-2, auxiliary agent 4-5, water 70-80; Described auxiliary agent is made by the raw material of following weight portion: Silane coupling reagent KH-570 2-3, crosslinking agent TAC1-2, styrene 3-4, maleic anhydride 2-3, Tween-81 2-3, acrylonitrile 2-3, antioxidant 1035 1-2, diethylene glycol (DEG) 7-9, ethanol 12-15; Preparation method mixes crosslinking agent TAC, styrene, maleic anhydride, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
The preparation method of described digit printing adhesive, it is characterized in that comprising the following steps: bisphenol A epoxy acrylate, glycerine, trimethylolethane, xylitol, butoxy ethyl phosphate, butyl methacrylate, 1,6 hexanediyl esters, trimethylolpropane triacrylate, nonyl phenol, polyvinyl butyral resin mix, under 1000-1400 rev/min of stirring, with the speed of 8-10 ℃/minute, be heated to 60-70 ℃; Add neopelex, with the speed of 6-8 ℃/minute, be heated to 80-90 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2.5-3 hour, obtain.
Beneficial effect of the present invention
Digit printing adhesive of the present invention, not containing APEO, formaldehyde and difficult degradation compound etc., environment friendly and pollution-free, there is good stability and dispersive property, can prevent pigment particles coagulation, below lower temperature, bake film forming crosslinked, greatly degree reduces energy consumption and sewage discharge, has that adhesion strength is strong, a feature of quick solidifying, good toughness, water-fast, heat-resisting water, resistance physical property.
The specific embodiment
A kind of digit printing adhesive, by following weight portion (kilogram) raw material make: bisphenol A epoxy acrylate 33, neopelex 2.5, glycerine 5.5, trimethylolethane 7, xylitol 3.5, butoxy ethyl phosphate 11, butyl methacrylate 6,1,6 hexanediyl ester 15, trimethylolpropane triacrylate 13, nonyl phenol 2.5, polyvinyl butyral resin 3.5, ammonium persulfate 1.5, auxiliary agent 4.5, water 75; Described auxiliary agent by following weight portion (kilogram) raw material make: Silane coupling reagent KH-570 2, crosslinking agent TAC1, styrene 4, maleic anhydride 3, Tween-81 2, acrylonitrile 2, antioxidant 1,035 2, diethylene glycol (DEG) 7, ethanol 12; Preparation method mixes crosslinking agent TAC, styrene, maleic anhydride, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
The preparation method of described digit printing adhesive, comprise the following steps: bisphenol A epoxy acrylate, glycerine, trimethylolethane, xylitol, butoxy ethyl phosphate, butyl methacrylate, 1,6 hexanediyl esters, trimethylolpropane triacrylate, nonyl phenol, polyvinyl butyral resin mix, under 1200 revs/min of stirrings, with the speed of 9 ℃/minute, be heated to 65 ℃; Add neopelex, with the speed of 7 ℃/minute, be heated to 85 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2.7 hours, obtain.
This knitted fabric for stamp, is pressed GB standard detection with printing adhesive, dry fastness 3-4 level, and fastness to wet rubbing is at 3 grades, and 4 grades of brushing fastnesses, glue 4 grades of COLOR FASTNESS, the fastness of fading after soaping 3-4 level.
Claims (2)
1. a digit printing adhesive, it is characterized in that being made by the raw material of following weight portion: bisphenol A epoxy acrylate 30-35, neopelex 2-3, glycerine 5-6, trimethylolethane 6-8, xylitol 3-4, butoxy ethyl phosphate 10-12, butyl methacrylate 5-8,1,6 hexanediyl ester 14-16, trimethylolpropane triacrylate 10-15, nonyl phenol 2-3, polyvinyl butyral resin 3-4, ammonium persulfate 1-2, auxiliary agent 4-5, water 70-80; Described auxiliary agent is made by the raw material of following weight portion: Silane coupling reagent KH-570 2-3, crosslinking agent TAC1-2, styrene 3-4, maleic anhydride 2-3, Tween-81 2-3, acrylonitrile 2-3, antioxidant 1035 1-2, diethylene glycol (DEG) 7-9, ethanol 12-15; Preparation method mixes crosslinking agent TAC, styrene, maleic anhydride, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
2. the preparation method of digit printing adhesive according to claim 1, it is characterized in that comprising the following steps: by bisphenol A epoxy acrylate, glycerine, trimethylolethane, xylitol, butoxy ethyl phosphate, butyl methacrylate, 1,6 hexanediyl esters, trimethylolpropane triacrylate, nonyl phenol, polyvinyl butyral resin mix, under 1000-1400 rev/min of stirring, with the speed of 8-10 ℃/minute, be heated to 60-70 ℃; Add neopelex, with the speed of 6-8 ℃/minute, be heated to 80-90 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2.5-3 hour, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310501979.6A CN103526587A (en) | 2013-10-23 | 2013-10-23 | Digital printing adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310501979.6A CN103526587A (en) | 2013-10-23 | 2013-10-23 | Digital printing adhesive and preparation method thereof |
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| CN103526587A true CN103526587A (en) | 2014-01-22 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310501979.6A Pending CN103526587A (en) | 2013-10-23 | 2013-10-23 | Digital printing adhesive and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105544247A (en) * | 2016-01-25 | 2016-05-04 | 苏州印丝特纺织数码科技有限公司 | Printing adhesive for digital printing and preparation method thereof |
| CN106867457A (en) * | 2016-12-22 | 2017-06-20 | 新疆德蓝股份有限公司 | A kind of compound dust suppressant and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101508759A (en) * | 2009-03-13 | 2009-08-19 | 上海金山隆捷实业有限公司 | Method of preparing epoxy modified acrylic resin emulsion |
| CN102619103A (en) * | 2012-04-07 | 2012-08-01 | 辽宁恒星精细化工有限公司 | Pigment printing imitated reactive printing adhesive and preparation method thereof |
| CN102899927A (en) * | 2012-10-24 | 2013-01-30 | 绍兴中纺院江南分院有限公司 | Digital printing binding agent, preparation method and applications of digital printing binding agent |
-
2013
- 2013-10-23 CN CN201310501979.6A patent/CN103526587A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101508759A (en) * | 2009-03-13 | 2009-08-19 | 上海金山隆捷实业有限公司 | Method of preparing epoxy modified acrylic resin emulsion |
| CN102619103A (en) * | 2012-04-07 | 2012-08-01 | 辽宁恒星精细化工有限公司 | Pigment printing imitated reactive printing adhesive and preparation method thereof |
| CN102899927A (en) * | 2012-10-24 | 2013-01-30 | 绍兴中纺院江南分院有限公司 | Digital printing binding agent, preparation method and applications of digital printing binding agent |
Non-Patent Citations (2)
| Title |
|---|
| 卢杰宏等: ""涂料印花用粘合剂研究进展"", 《热固性树脂》 * |
| 谭正德等: ""改性PVB印花粘合剂的研究"", 《中国胶粘剂》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105544247A (en) * | 2016-01-25 | 2016-05-04 | 苏州印丝特纺织数码科技有限公司 | Printing adhesive for digital printing and preparation method thereof |
| CN105544247B (en) * | 2016-01-25 | 2018-10-12 | 吴雨潞 | A kind of printing adhesive and preparation method thereof for digit printing |
| CN106867457A (en) * | 2016-12-22 | 2017-06-20 | 新疆德蓝股份有限公司 | A kind of compound dust suppressant and preparation method thereof |
| CN106867457B (en) * | 2016-12-22 | 2019-05-17 | 德蓝水技术股份有限公司 | A kind of compound dust suppressant and preparation method thereof |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140122 |
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| RJ01 | Rejection of invention patent application after publication |