CN103526588A - Soap-washing-endurance pigment printing binding agent and preparation method thereof - Google Patents
Soap-washing-endurance pigment printing binding agent and preparation method thereof Download PDFInfo
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- CN103526588A CN103526588A CN201310502006.4A CN201310502006A CN103526588A CN 103526588 A CN103526588 A CN 103526588A CN 201310502006 A CN201310502006 A CN 201310502006A CN 103526588 A CN103526588 A CN 103526588A
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Abstract
The invention provides a soap-washing-endurance pigment printing binding agent. The binding agent is prepared from the following raw materials in parts by weight: 20-24 parts of poly(ethylene glycol) methacrylate, 1-2 parts of lauryl sodium sulfate, 8-10 parts of acrylic acid, 5-7 parts of styrene, 3-4 parts of butyl acrylate, 16-19 parts of dipentaerythritol hexaacrylate, 12-14 parts of trifluoroacetic acid ethyl ester, 5-7 parts of glycidyl methacrylate, 8-10 parts of ethylene glycol dimethacrylate, 20-24 parts of carbamate vinyl ether, 2-3 parts of methyl triethoxysilane, 2-3 parts of polyborosiloxane, 1-2 parts of ammonium persulfate, 4-5 parts of auxiliaries, and 80-90 parts of water. The binding agent has the characteristics of high transparency, good glossiness, water endurance, soap washing endurance and proper hardness, is proper in viscosity, simple in pigment printing process, strong and rich in color and clear in profile, and has the environment-friendly and healthy effects, and hot melt or high-efficiency suppress washing equipment can not be needed.
Description
Technical field
The invention belongs to textile auxiliary's technical field, relate in particular to a kind of resistance to printing adhesive and preparation method thereof of soaping.
Background technology
So-called COAT PRINTING is the effect by adhesive, by water insoluble, to fabric, do not have compatibility and reactive pigment to anchor on fabric, thereby reach painted object.According to update introduction, the PRINTED FABRIC of nearly half output is COAT PRINTING in the world at present.Pigment printing binding agent is the main component of textile printing pigment, and the quality of COAT PRINTING end product quality is directly subject to the impact of printing adhesive performance.
The quality of printing adhesive differs at present, the stamp defect rate causing because of adhesive quality problems, more than 3%, has caused huge economic loss, and the quality of printing adhesive directly has influence on quality, the fineness of stamp, the class of fabric, therefore, need to research and develop the more adhesive of high-quality.
Summary of the invention
The object of the present invention is to provide a kind of resistance to printing adhesive and preparation method thereof of soaping, this adhesive have resistance toly soap, the feature of environmental protection.
Technical scheme of the present invention is as follows:
The printing adhesive of soaping, is characterized in that being made by the raw material of following weight portion: polyethylene glycol methacrylate-styrene polymer 20-24, lauryl sodium sulfate 1-2, acrylic acid 8-10, styrene 5-7, butyl acrylate 3-4, dipentaerythritol acrylate 16-19, Trifluoroacetic Acid Ethyl Ester 12-14, glycidyl methacrylate 5-7, ethylene glycol dimethacrylate 8-10, carbamate vinyl ethers 20-24, MTES 2-3, polyborosiloxane 2-3, ammonium persulfate 1-2, auxiliary agent 4-5, water 80-90; Described auxiliary agent is made by the raw material of following weight portion: Silane coupling reagent KH-570 2-3, crosslinking agent TAC1-2, Tea Polyphenols 2-3, styrene 3-4, styrylphenol polyoxyethylene ether 2.5-3.0, lemon 0.1-0.2, morpholine 1-2, glycerin monostearate 4-5, neopentyl glycol 3-4, vinylacetate 2-3, antioxidant 1035 2-3, diethylene glycol (DEG) 7-9, ethanol 12-15; Preparation method mixes crosslinking agent TAC, styrene, vinylacetate, neopentyl glycol, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
The preparation method of the described resistance to printing adhesive of soaping, it is characterized in that comprising the following steps: polyethylene glycol methacrylate-styrene polymer, acrylic acid, styrene, butyl acrylate, dipentaerythritol acrylate, Trifluoroacetic Acid Ethyl Ester, glycidyl methacrylate, ethylene glycol dimethacrylate, carbamate vinyl ethers, MTES, polyborosiloxane are mixed, under 800-1200 rev/min of stirring, with the speed of 6-8 ℃/minute, be heated to 60-70 ℃; Add lauryl sodium sulfate, with the speed of 4-6 ℃/minute, be heated to 80-90 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2-3 hour, obtain.
Beneficial effect of the present invention
Adhesive of the present invention has that transparency is high, glossiness good, water-fast, resistance toly soap, neither too hard, nor too soft feature; This adhesive viscosities is moderate, printing technology is simple, color is rich and gaudy, color and luster is full, clear-cut, do not need hot melt and efficient open washing equipment, environment protection health.
The specific embodiment
The printing adhesive of soaping, by following weight portion (kilogram) raw material make: polyethylene glycol methacrylate-styrene polymer 23, lauryl sodium sulfate 1.5, acrylic acid 9, styrene 6, butyl acrylate 3.5, dipentaerythritol acrylate 17, Trifluoroacetic Acid Ethyl Ester 13, glycidyl methacrylate 6, ethylene glycol dimethacrylate 9, carbamate vinyl ethers 23, MTES 2.5, polyborosiloxane 2.5, ammonium persulfate 1.5, auxiliary agent 4.5, water 85; Described auxiliary agent by following weight portion (kilogram) raw material make: Silane coupling reagent KH-570 2, crosslinking agent TAC1, Tea Polyphenols 3, styrene 3, styrylphenol polyoxyethylene ether 2.5, lemon 0.1, morpholine 1, glycerin monostearate 4, neopentyl glycol 3, vinylacetate 2, antioxidant 1,035 2, diethylene glycol (DEG) 7, ethanol 15; Preparation method mixes crosslinking agent TAC, styrene, vinylacetate, neopentyl glycol, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
The preparation method of the described resistance to printing adhesive of soaping, comprise the following steps: polyethylene glycol methacrylate-styrene polymer, acrylic acid, styrene, butyl acrylate, dipentaerythritol acrylate, Trifluoroacetic Acid Ethyl Ester, glycidyl methacrylate, ethylene glycol dimethacrylate, carbamate vinyl ethers, MTES, polyborosiloxane are mixed, under 1000 revs/min of stirrings, with the speed of 7 ℃/minute, be heated to 65 ℃; Add lauryl sodium sulfate, with the speed of 5 ℃/minute, be heated to 85 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2.5 hours, obtain.
This resistance to printing adhesive of soaping, for PRINTED FABRIC, is pressed GB standard detection, 3 grades of dry fastnesses, and fastness to wet rubbing is in 2-3 level, and 4 grades of brushing fastnesses, glue 4 grades of COLOR FASTNESS, 4 grades of the fastness of fading after soaping.
Claims (2)
1. the resistance to printing adhesive of soaping, is characterized in that being made by the raw material of following weight portion: polyethylene glycol methacrylate-styrene polymer 20-24, lauryl sodium sulfate 1-2, acrylic acid 8-10, styrene 5-7, butyl acrylate 3-4, dipentaerythritol acrylate 16-19, Trifluoroacetic Acid Ethyl Ester 12-14, glycidyl methacrylate 5-7, ethylene glycol dimethacrylate 8-10, carbamate vinyl ethers 20-24, MTES 2-3, polyborosiloxane 2-3, ammonium persulfate 1-2, auxiliary agent 4-5, water 80-90; Described auxiliary agent is made by the raw material of following weight portion: Silane coupling reagent KH-570 2-3, crosslinking agent TAC1-2, Tea Polyphenols 2-3, styrene 3-4, styrylphenol polyoxyethylene ether 2.5-3.0, lemon 0.1-0.2, morpholine 1-2, glycerin monostearate 4-5, neopentyl glycol 3-4, vinylacetate 2-3, antioxidant 1035 2-3, diethylene glycol (DEG) 7-9, ethanol 12-15; Preparation method mixes crosslinking agent TAC, styrene, vinylacetate, neopentyl glycol, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
2. the preparation method of the resistance to printing adhesive of soaping according to claim 1, it is characterized in that comprising the following steps: polyethylene glycol methacrylate-styrene polymer, acrylic acid, styrene, butyl acrylate, dipentaerythritol acrylate, Trifluoroacetic Acid Ethyl Ester, glycidyl methacrylate, ethylene glycol dimethacrylate, carbamate vinyl ethers, MTES, polyborosiloxane are mixed, under 800-1200 rev/min of stirring, with the speed of 6-8 ℃/minute, be heated to 60-70 ℃; Add lauryl sodium sulfate, with the speed of 4-6 ℃/minute, be heated to 80-90 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2-3 hour, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310502006.4A CN103526588A (en) | 2013-10-23 | 2013-10-23 | Soap-washing-endurance pigment printing binding agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310502006.4A CN103526588A (en) | 2013-10-23 | 2013-10-23 | Soap-washing-endurance pigment printing binding agent and preparation method thereof |
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| CN103526588A true CN103526588A (en) | 2014-01-22 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310502006.4A Pending CN103526588A (en) | 2013-10-23 | 2013-10-23 | Soap-washing-endurance pigment printing binding agent and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106749863A (en) * | 2016-11-23 | 2017-05-31 | 苏州联胜化学有限公司 | A kind of imitative reactive coating printing adhesive and preparation method thereof, application process |
| CN110591018A (en) * | 2019-01-28 | 2019-12-20 | 四川益欣科技有限责任公司 | V-type polydimethylsiloxane hydrophobic association emulsion polymerization printing thickener, preparation method and application |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101423735A (en) * | 2008-12-05 | 2009-05-06 | 武汉科技学院 | Method for preparing environment-friendly type organosilicon modified acrylic ester binding agent |
| CN101942772A (en) * | 2010-08-17 | 2011-01-12 | 辽宁恒星精细化工有限公司 | Low-formaldehyde soaping-resistant adhesive for textile pigment printing and preparation method thereof |
| CN102504090A (en) * | 2011-10-12 | 2012-06-20 | 辽宁恒星精细化工有限公司 | Binder used for pigment printing of textiles and preparation method thereof |
| WO2012097186A1 (en) * | 2011-01-16 | 2012-07-19 | Simpson Strong-Tie Company, Inc. | Low temperature curable adhesive compositions |
-
2013
- 2013-10-23 CN CN201310502006.4A patent/CN103526588A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101423735A (en) * | 2008-12-05 | 2009-05-06 | 武汉科技学院 | Method for preparing environment-friendly type organosilicon modified acrylic ester binding agent |
| CN101942772A (en) * | 2010-08-17 | 2011-01-12 | 辽宁恒星精细化工有限公司 | Low-formaldehyde soaping-resistant adhesive for textile pigment printing and preparation method thereof |
| WO2012097186A1 (en) * | 2011-01-16 | 2012-07-19 | Simpson Strong-Tie Company, Inc. | Low temperature curable adhesive compositions |
| CN102504090A (en) * | 2011-10-12 | 2012-06-20 | 辽宁恒星精细化工有限公司 | Binder used for pigment printing of textiles and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106749863A (en) * | 2016-11-23 | 2017-05-31 | 苏州联胜化学有限公司 | A kind of imitative reactive coating printing adhesive and preparation method thereof, application process |
| CN110591018A (en) * | 2019-01-28 | 2019-12-20 | 四川益欣科技有限责任公司 | V-type polydimethylsiloxane hydrophobic association emulsion polymerization printing thickener, preparation method and application |
| CN110591018B (en) * | 2019-01-28 | 2021-10-22 | 四川益欣科技有限责任公司 | V-type polydimethylsiloxane hydrophobic association emulsion polymerization printing thickener, preparation method and application |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140122 |