CN103526581A - Environment-friendly printing adhesive as well as preparation method thereof - Google Patents
Environment-friendly printing adhesive as well as preparation method thereof Download PDFInfo
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- CN103526581A CN103526581A CN201310501811.5A CN201310501811A CN103526581A CN 103526581 A CN103526581 A CN 103526581A CN 201310501811 A CN201310501811 A CN 201310501811A CN 103526581 A CN103526581 A CN 103526581A
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Abstract
The invention discloses an environment-friendly printing adhesive. The environment-friendly printing adhesive is prepared from the following materials in parts by weight: 3-4 parts of acrylic acid, 12-15 parts of methyl acrylate, 10-12 parts of ethyl acrylate, 6-8 parts of ethyl trifluoroacetate, 4-5 parts of isobornyl acrylate, 1-2 parts of phenyl glycidyl ether, 20-25 parts of aromatic urethane acrylate, 3-4 parts of acrylic resin, 2-5 parts of allyl heptanoate, 1-2 parts of 4-methylcatechol, 1-2 parts of sodium naphthalene sulfonate, 1-2 parts of ammonium persulfate, 4-5 parts of auxiliaries and 70-80 parts of water. The adhesive disclosed by the invention has characteristics of being high in crocking fastness, watertight, moderate in hardness, good in toughness and moderate in viscosity. Paint adopting the adhesive is simple in printing process, rich and gaudy in color, clear in outline, and not easy to contaminate and corrode silk screens. The adhesive disclosed by the invention contains formaldehyde less than 5 PPM (Parts Per Million) and APEO (Alkylphenol Ethoxylates) less than 5 PPM, and belongs to a green environment-friendly product, so that the pollution is reduced and the development prospect is wide.
Description
Technical field
The invention belongs to textile auxiliary's technical field, relate in particular to a kind of environmental protection printing adhesive and preparation method thereof.
Background technology
So-called COAT PRINTING is the effect by adhesive, by water insoluble, to fabric, do not have compatibility and reactive pigment to anchor on fabric, thereby reach painted object.According to update introduction, the PRINTED FABRIC of nearly half output is COAT PRINTING in the world at present.Pigment printing binding agent is the main component of textile printing pigment, and the quality of COAT PRINTING end product quality is directly subject to the impact of printing adhesive performance.
The quality of printing adhesive differs at present, the stamp defect rate causing because of adhesive quality problems, more than 3%, has caused huge economic loss, and the quality of printing adhesive directly has influence on quality, the fineness of stamp, the class of fabric, therefore, need to research and develop the more adhesive of high-quality.
Summary of the invention
The object of the present invention is to provide a kind of environmental protection printing adhesive and preparation method thereof, this adhesive has the feature of environmental protection, wear-resisting, good toughness.
Technical scheme of the present invention is as follows:
An adhesive, is characterized in that being made by the raw material of following weight portion: acrylic acid 3-4, methyl acrylate 12-15, ethyl acrylate 10-12, Trifluoroacetic Acid Ethyl Ester 6-8, isobornyl acrylate 4-5, phenyl glycidyl ether 1-2, aromatic urethane acrylate 20-25, acrylic resin 3-4, allyl heptanoate 2-5,4-methyl guaiacol and 4 1-2, sodium butylnaphthalenesulfonate 1-2, ammonium persulfate 1-2, auxiliary agent 4-5, water 70-80; Described auxiliary agent is made by the raw material of following weight portion: Silane coupling reagent KH-570 2-3, crosslinking agent TAC1-2, Tea Polyphenols 2-3, styrene 3-4, styrylphenol polyoxyethylene ether 2.5-3.0, lemon 0.1-0.2, morpholine 1-2, glycerin monostearate 4-5, neopentyl glycol 3-4, vinylacetate 2-3, antioxidant 1035 2-3, diethylene glycol (DEG) 7-9, ethanol 12-15; Preparation method mixes crosslinking agent TAC, styrene, vinylacetate, neopentyl glycol, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
The preparation method of described environmental protection printing adhesive, it is characterized in that comprising the following steps: acrylic acid, methyl acrylate, ethyl acrylate, Trifluoroacetic Acid Ethyl Ester, isobornyl acrylate, phenyl glycidyl ether, aromatic urethane acrylate, acrylic resin, allyl heptanoate, 4-methyl guaiacol and 4 are mixed, under 800-1200 rev/min of stirring, with the speed of 7-9 ℃/minute, be heated to 60-70 ℃; Add sodium butylnaphthalenesulfonate, with the speed of 5-7 ℃/minute, be heated to 80-90 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2-3 hour, obtain.
Beneficial effect of the present invention
Adhesive of the present invention has that crock fastness is high, water-fast, neither too hard, nor too soft, the feature of good toughness, modest viscosity; Adopt the COAT PRINTING technique of this adhesive simple, color is rich and gaudy, clear-cut, be difficult for to stain corrosion silk screen, formaldehyde < 5PPM in this adhesive, APEO < 5PPM, belongs to environmental type product, reduces and pollutes, and has wide development prospect.
The specific embodiment
An adhesive, by following weight portion (kilogram) raw material make: acrylic acid 3.5, methyl acrylate 13, ethyl acrylate 11, Trifluoroacetic Acid Ethyl Ester 7, isobornyl acrylate 4.5, phenyl glycidyl ether 1.5, aromatic urethane acrylate 23, acrylic resin 3.5, allyl heptanoate 4,4-methyl guaiacol and 4 1.5, sodium butylnaphthalenesulfonate 1.5, ammonium persulfate 1.5, auxiliary agent 4.5, water 75; Described auxiliary agent by following weight portion (kilogram) raw material make: Silane coupling reagent KH-570 2, crosslinking agent TAC1, Tea Polyphenols 3, styrene 3, styrylphenol polyoxyethylene ether 2.5, lemon 0.1, morpholine 1, glycerin monostearate 4, neopentyl glycol 3, vinylacetate 2, antioxidant 1,035 2, diethylene glycol (DEG) 7, ethanol 15; Preparation method mixes crosslinking agent TAC, styrene, vinylacetate, neopentyl glycol, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
The preparation method of described environmental protection printing adhesive, it is characterized in that comprising the following steps: acrylic acid, methyl acrylate, ethyl acrylate, Trifluoroacetic Acid Ethyl Ester, isobornyl acrylate, phenyl glycidyl ether, aromatic urethane acrylate, acrylic resin, allyl heptanoate, 4-methyl guaiacol and 4 are mixed, under 1000 revs/min of stirrings, with the speed of 8 ℃/minute, be heated to 65 ℃; Add sodium butylnaphthalenesulfonate, with the speed of 6 ℃/minute, be heated to 85 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2.5 hours, obtain.
This environmental protection printing adhesive, for PRINTED FABRIC, is pressed GB standard detection, dry fastness 3-4 level, and fastness to wet rubbing is at 3 grades, and brushing fastness 3-4 level, glues 4 grades of COLOR FASTNESS, the fastness of fading after soaping 3-4 level.
Claims (2)
1. an environmental protection printing adhesive, is characterized in that being made by the raw material of following weight portion: acrylic acid 3-4, methyl acrylate 12-15, ethyl acrylate 10-12, Trifluoroacetic Acid Ethyl Ester 6-8, isobornyl acrylate 4-5, phenyl glycidyl ether 1-2, aromatic urethane acrylate 20-25, acrylic resin 3-4, allyl heptanoate 2-5,4-methyl guaiacol and 4 1-2, sodium butylnaphthalenesulfonate 1-2, ammonium persulfate 1-2, auxiliary agent 4-5, water 70-80; Described auxiliary agent is made by the raw material of following weight portion: Silane coupling reagent KH-570 2-3, crosslinking agent TAC1-2, Tea Polyphenols 2-3, styrene 3-4, styrylphenol polyoxyethylene ether 2.5-3.0, lemon 0.1-0.2, morpholine 1-2, glycerin monostearate 4-5, neopentyl glycol 3-4, vinylacetate 2-3, antioxidant 1035 2-3, diethylene glycol (DEG) 7-9, ethanol 12-15; Preparation method mixes crosslinking agent TAC, styrene, vinylacetate, neopentyl glycol, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
2. the preparation method of environmental protection printing adhesive according to claim 1, it is characterized in that comprising the following steps: acrylic acid, methyl acrylate, ethyl acrylate, Trifluoroacetic Acid Ethyl Ester, isobornyl acrylate, phenyl glycidyl ether, aromatic urethane acrylate, acrylic resin, allyl heptanoate, 4-methyl guaiacol and 4 are mixed, under 800-1200 rev/min of stirring, with the speed of 7-9 ℃/minute, be heated to 60-70 ℃; Add sodium butylnaphthalenesulfonate, with the speed of 5-7 ℃/minute, be heated to 80-90 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2-3 hour, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310501811.5A CN103526581A (en) | 2013-10-23 | 2013-10-23 | Environment-friendly printing adhesive as well as preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310501811.5A CN103526581A (en) | 2013-10-23 | 2013-10-23 | Environment-friendly printing adhesive as well as preparation method thereof |
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| CN103526581A true CN103526581A (en) | 2014-01-22 |
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| CN201310501811.5A Pending CN103526581A (en) | 2013-10-23 | 2013-10-23 | Environment-friendly printing adhesive as well as preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111024688A (en) * | 2019-12-23 | 2020-04-17 | 江西省药品检验检测研究院 | Method for rapidly identifying aromatic polyurethane adhesive in medicinal composite film |
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| US20060252329A1 (en) * | 2005-05-04 | 2006-11-09 | Shawmut Corporation | Halogen and plasticizer free permeable laminate |
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| CN102605648A (en) * | 2012-03-12 | 2012-07-25 | 辽宁恒星精细化工有限公司 | Textile water-based pigment printing binding agent and preparation method |
| CN103214992A (en) * | 2013-05-04 | 2013-07-24 | 辽宁恒星精细化工有限公司 | Binding agent for conductive carbon black slurry and preparation method thereof |
| CN103233375A (en) * | 2013-05-04 | 2013-08-07 | 辽宁恒星精细化工有限公司 | Stereo printing paste for suede and preparation method thereof |
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- 2013-10-23 CN CN201310501811.5A patent/CN103526581A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1526772A (en) * | 2003-03-03 | 2004-09-08 | 珠海东诚化工有限公司 | Visible light cured woodenware paint |
| US20060252329A1 (en) * | 2005-05-04 | 2006-11-09 | Shawmut Corporation | Halogen and plasticizer free permeable laminate |
| CN102206462A (en) * | 2010-03-31 | 2011-10-05 | 东莞市佩琦涂料有限公司 | Metal UV (Ultraviolet) coating |
| CN101948555A (en) * | 2010-09-30 | 2011-01-19 | 东莞长联新材料科技有限公司 | Acrylate-containing elastic emulsion, preparation method thereof and compounded printing binder |
| CN102605648A (en) * | 2012-03-12 | 2012-07-25 | 辽宁恒星精细化工有限公司 | Textile water-based pigment printing binding agent and preparation method |
| CN103214992A (en) * | 2013-05-04 | 2013-07-24 | 辽宁恒星精细化工有限公司 | Binding agent for conductive carbon black slurry and preparation method thereof |
| CN103233375A (en) * | 2013-05-04 | 2013-08-07 | 辽宁恒星精细化工有限公司 | Stereo printing paste for suede and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111024688A (en) * | 2019-12-23 | 2020-04-17 | 江西省药品检验检测研究院 | Method for rapidly identifying aromatic polyurethane adhesive in medicinal composite film |
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Application publication date: 20140122 |
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| RJ01 | Rejection of invention patent application after publication |