CN103526586A - Flame-retardant soft printing adhesive and preparation method thereof - Google Patents
Flame-retardant soft printing adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN103526586A CN103526586A CN201310501978.1A CN201310501978A CN103526586A CN 103526586 A CN103526586 A CN 103526586A CN 201310501978 A CN201310501978 A CN 201310501978A CN 103526586 A CN103526586 A CN 103526586A
- Authority
- CN
- China
- Prior art keywords
- parts
- flame
- methacrylate
- printing adhesive
- minute
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention discloses a flame-retardant soft printing adhesive. The flame-retardant soft printing adhesive is prepared from the following raw materials in parts by weight: 20-25 parts of polyester acrylate, 2-3 parts of OP-10, 12-14 parts of butyl acrylate, 6-8 parts of methyl methacrylate, 4-5 parts of acrylonitrile, 1-2 parts of N-hydroxymethyl acrylamide, 6-8 parts of ethylene glycol, 2-3 parts of dicyclopentadiene, 13-14 parts of glycidyl methacrylate, 45-50 parts of urethane acrylates, 2-3 parts of crylic acid 1-2,4,6-tribromophenyl, 2-3 parts of 3-(Trimethoxysilyl)propanethiol, 10-12 parts of trifluoroethyl methacrylate, 1-2 parts of styrene phenol polyoxyethylene ether, 1-2 parts of ammonium persulfate, 4-5 parts of accessory ingredients and 70-80 parts of water. The flame-retardant soft printing adhesive, disclosed by the invention, is excellent in flame-retardant effect and has the characteristics of high transparency, water resistance, softness and moderate viscosity; a coating with the adhesive adopts a simple printing process, guarantees bright colors and clear outlines of fabrics, causes less pollution and has wide development prospect.
Description
Technical field
The invention belongs to textile auxiliary's technical field, relate in particular to a kind of flame-retardant flexible printing adhesive and preparation method thereof.
Background technology
So-called COAT PRINTING is the effect by adhesive, by water insoluble, to fabric, do not have compatibility and reactive pigment to anchor on fabric, thereby reach painted object.According to update introduction, the PRINTED FABRIC of nearly half output is COAT PRINTING in the world at present.Pigment printing binding agent is the main component of textile printing pigment, and the quality of COAT PRINTING end product quality is directly subject to the impact of printing adhesive performance.
The quality of printing adhesive differs at present, the stamp defect rate causing because of adhesive quality problems, more than 3%, has caused huge economic loss, and the quality of printing adhesive directly has influence on quality, the fineness of stamp, the class of fabric, therefore, need to research and develop the more adhesive of high-quality.
Summary of the invention
The object of the present invention is to provide a kind of flame-retardant flexible printing adhesive and preparation method thereof, that this adhesive has is fire-retardant, the feature of good hand touch, light.
Technical scheme of the present invention is as follows:
A kind of flame-retardant flexible printing adhesive, it is characterized in that being made by the raw material of following weight portion: polyester acrylate 20-25, OP-10 2-3, butyl acrylate 12-14, methyl methacrylate 6-8, acrylonitrile 4-5, N hydroxymethyl acrylamide 1-2, ethylene glycol 6-8, dicyclopentadiene 2-3, glycidyl methacrylate 13-14, urethane acrylate 45-50, acrylic acid 1-2, 4, 6-tribromophenyl 2-3, 3-mercaptopropyl trimethoxysilane 2-3, trifluoroethyl methacrylate 10-12, styrylphenol polyoxyethylene ether 1-2, ammonium persulfate 1-2, auxiliary agent 4-5, water 70-80, described auxiliary agent is made by the raw material of following weight portion: Silane coupling reagent KH-570 2-3, crosslinking agent TAC1-2, Tea Polyphenols 2-3, styrene 3-4, styrylphenol polyoxyethylene ether 2.5-3.0, lemon 0.1-0.2, morpholine 1-2, glycerin monostearate 4-5, neopentyl glycol 3-4, vinylacetate 2-3, antioxidant 1035 2-3, diethylene glycol (DEG) 7-9, ethanol 12-15, preparation method mixes crosslinking agent TAC, styrene, vinylacetate, neopentyl glycol, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
The preparation method of described flame-retardant flexible printing adhesive, it is characterized in that comprising the following steps: by polyester acrylate, butyl acrylate, methyl methacrylate, acrylonitrile, N hydroxymethyl acrylamide, ethylene glycol, dicyclopentadiene, glycidyl methacrylate, urethane acrylate, acrylic acid, 4,6-tribromophenyl, 3-mercaptopropyl trimethoxysilane, trifluoroethyl methacrylate, styrylphenol polyoxyethylene ether mix, under 800-1200 rev/min of stirring, with the speed of 7-9 ℃/minute, be heated to 60-70 ℃; Add OP-10, with the speed of 6-8 ℃/minute, be heated to 80-90 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2-3 hour, obtain.
Beneficial effect of the present invention
Adhesive of the present invention has excellent flame retardant effect; Also have that transparency is high, water-fast, soft, the feature of modest viscosity; Adopt the COAT PRINTING technique of this adhesive simple, color is rich and gaudy, clear-cut, do not need hot melt and efficient open washing equipment, does not need soda acid to process, and without acid-base waste fluid, forms, and saves accordingly energy resource consumption, reduces and pollute, and has wide development prospect.
The specific embodiment
A kind of flame-retardant flexible printing adhesive, by following weight portion (kilogram) raw material make: polyester acrylate 23, OP-10 2.5, butyl acrylate 13, methyl methacrylate 7, acrylonitrile 4.5, N hydroxymethyl acrylamide 1.5, ethylene glycol 7, dicyclopentadiene 2.5, glycidyl methacrylate 13, urethane acrylate 47, acrylic acid 1.5,4,6-tribromophenyl 2.5,3-mercaptopropyl trimethoxysilane 2.5, trifluoroethyl methacrylate 11, styrylphenol polyoxyethylene ether 1.5, ammonium persulfate 1.5, auxiliary agent 4.5, water 75; Described auxiliary agent by following weight portion (kilogram) raw material make: Silane coupling reagent KH-570 2, crosslinking agent TAC1, Tea Polyphenols 3, styrene 3, styrylphenol polyoxyethylene ether 2.5, lemon 0.1, morpholine 1, glycerin monostearate 4, neopentyl glycol 3, vinylacetate 2, antioxidant 1,035 2, diethylene glycol (DEG) 7, ethanol 15; Preparation method mixes crosslinking agent TAC, styrene, vinylacetate, neopentyl glycol, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
The preparation method of described flame-retardant flexible printing adhesive, comprise the following steps: by polyester acrylate, butyl acrylate, methyl methacrylate, acrylonitrile, N hydroxymethyl acrylamide, ethylene glycol, dicyclopentadiene, glycidyl methacrylate, urethane acrylate, acrylic acid, 4,6-tribromophenyl, 3-mercaptopropyl trimethoxysilane, trifluoroethyl methacrylate, styrylphenol polyoxyethylene ether mix, under 1000 revs/min of stirrings, with the speed of 8 ℃/minute, be heated to 65 ℃; Add OP-10, with the speed of 7 ℃/minute, be heated to 85 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2.5 hours, obtain.
This flame-retardant flexible printing adhesive, for PRINTED FABRIC, is pressed GB standard detection, 3 grades of dry fastnesses, and fastness to wet rubbing is in 2-3 level, and brushing fastness 3-4 level, glues 4 grades of COLOR FASTNESS, the fastness of fading after soaping 3-4 level.
Claims (2)
1. a flame-retardant flexible printing adhesive, it is characterized in that being made by the raw material of following weight portion: polyester acrylate 20-25, OP-10 2-3, butyl acrylate 12-14, methyl methacrylate 6-8, acrylonitrile 4-5, N hydroxymethyl acrylamide 1-2, ethylene glycol 6-8, dicyclopentadiene 2-3, glycidyl methacrylate 13-14, urethane acrylate 45-50, acrylic acid 1-2, 4, 6-tribromophenyl 2-3, 3-mercaptopropyl trimethoxysilane 2-3, trifluoroethyl methacrylate 10-12, styrylphenol polyoxyethylene ether 1-2, ammonium persulfate 1-2, auxiliary agent 4-5, water 70-80, described auxiliary agent is made by the raw material of following weight portion: Silane coupling reagent KH-570 2-3, crosslinking agent TAC1-2, Tea Polyphenols 2-3, styrene 3-4, styrylphenol polyoxyethylene ether 2.5-3.0, lemon 0.1-0.2, morpholine 1-2, glycerin monostearate 4-5, neopentyl glycol 3-4, vinylacetate 2-3, antioxidant 1035 2-3, diethylene glycol (DEG) 7-9, ethanol 12-15, preparation method mixes crosslinking agent TAC, styrene, vinylacetate, neopentyl glycol, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
2. the preparation method of flame-retardant flexible printing adhesive according to claim 1, it is characterized in that comprising the following steps: by polyester acrylate, butyl acrylate, methyl methacrylate, acrylonitrile, N hydroxymethyl acrylamide, ethylene glycol, dicyclopentadiene, glycidyl methacrylate, urethane acrylate, acrylic acid, 4, 6-tribromophenyl, 3-mercaptopropyl trimethoxysilane, trifluoroethyl methacrylate, styrylphenol polyoxyethylene ether mixes, under 800-1200 rev/min of stirring, speed with 7-9 ℃/minute is heated to 60-70 ℃, add OP-10, with the speed of 6-8 ℃/minute, be heated to 80-90 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2-3 hour, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310501978.1A CN103526586A (en) | 2013-10-23 | 2013-10-23 | Flame-retardant soft printing adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310501978.1A CN103526586A (en) | 2013-10-23 | 2013-10-23 | Flame-retardant soft printing adhesive and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103526586A true CN103526586A (en) | 2014-01-22 |
Family
ID=49928908
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310501978.1A Pending CN103526586A (en) | 2013-10-23 | 2013-10-23 | Flame-retardant soft printing adhesive and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103526586A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104372689A (en) * | 2014-09-28 | 2015-02-25 | 江山市联达印染助剂有限公司 | Printing adhesive and its synthesis technology |
| CN105111363A (en) * | 2015-09-19 | 2015-12-02 | 苏州大学 | Function prepolymer and preparation method and application thereof |
| CN106758389A (en) * | 2016-12-07 | 2017-05-31 | 广西大学 | A kind of textile printing paint adhesive |
| CN115181271A (en) * | 2022-08-17 | 2022-10-14 | 浙江工业职业技术学院 | Fluorine-containing vinyl polysiloxane, printing raw paste and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101736607A (en) * | 2009-12-10 | 2010-06-16 | 佛山市顺德区巴德富实业有限公司 | Environment-friendly pigment printing emulsion with favorable reviscid resistance |
| CN101748617A (en) * | 2008-12-05 | 2010-06-23 | 上海洁润丝新材料股份有限公司 | Anti-sticking soft dope printing adhesive and preparation method |
| CN102030859A (en) * | 2010-11-02 | 2011-04-27 | 山东奔腾漆业有限公司 | Water-borne acrylic resin and a preparation method thereof, as well as a water-borne dip-coating acrylic shop primer and a preparation method thereof |
| CN102108638A (en) * | 2010-12-08 | 2011-06-29 | 辽宁恒星精细化工有限公司 | Durable, waterproof, oil-proof, antistatic and antibacterial functional coating adhesive and preparation method |
| CN102604568A (en) * | 2012-03-20 | 2012-07-25 | 上海应用技术学院 | Flame-retardant polyacrylate emulsion and preparation method thereof |
| CN102786855A (en) * | 2012-07-23 | 2012-11-21 | 张家港市丰昌防腐材料有限公司 | Acrylic copolymer water dispersible paint and preparation method thereof |
| CN102952230A (en) * | 2012-10-11 | 2013-03-06 | 宿迁市神龙家纺有限公司 | Preparation method of low-temperature adhering agent for pigment printing |
-
2013
- 2013-10-23 CN CN201310501978.1A patent/CN103526586A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101748617A (en) * | 2008-12-05 | 2010-06-23 | 上海洁润丝新材料股份有限公司 | Anti-sticking soft dope printing adhesive and preparation method |
| CN101736607A (en) * | 2009-12-10 | 2010-06-16 | 佛山市顺德区巴德富实业有限公司 | Environment-friendly pigment printing emulsion with favorable reviscid resistance |
| CN102030859A (en) * | 2010-11-02 | 2011-04-27 | 山东奔腾漆业有限公司 | Water-borne acrylic resin and a preparation method thereof, as well as a water-borne dip-coating acrylic shop primer and a preparation method thereof |
| CN102108638A (en) * | 2010-12-08 | 2011-06-29 | 辽宁恒星精细化工有限公司 | Durable, waterproof, oil-proof, antistatic and antibacterial functional coating adhesive and preparation method |
| CN102604568A (en) * | 2012-03-20 | 2012-07-25 | 上海应用技术学院 | Flame-retardant polyacrylate emulsion and preparation method thereof |
| CN102786855A (en) * | 2012-07-23 | 2012-11-21 | 张家港市丰昌防腐材料有限公司 | Acrylic copolymer water dispersible paint and preparation method thereof |
| CN102952230A (en) * | 2012-10-11 | 2013-03-06 | 宿迁市神龙家纺有限公司 | Preparation method of low-temperature adhering agent for pigment printing |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104372689A (en) * | 2014-09-28 | 2015-02-25 | 江山市联达印染助剂有限公司 | Printing adhesive and its synthesis technology |
| CN105111363A (en) * | 2015-09-19 | 2015-12-02 | 苏州大学 | Function prepolymer and preparation method and application thereof |
| CN105111363B (en) * | 2015-09-19 | 2017-03-29 | 苏州大学 | A kind of function performed polymer and preparation method and application |
| CN106758389A (en) * | 2016-12-07 | 2017-05-31 | 广西大学 | A kind of textile printing paint adhesive |
| CN115181271A (en) * | 2022-08-17 | 2022-10-14 | 浙江工业职业技术学院 | Fluorine-containing vinyl polysiloxane, printing raw paste and preparation method thereof |
| CN115181271B (en) * | 2022-08-17 | 2024-02-09 | 浙江工业职业技术学院 | Fluorine-containing vinyl polysiloxane and printing raw paste and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101748617B (en) | Anti-sticking soft dope printing adhesive and preparation method | |
| CN101899784B (en) | Steam-cleaning free printing process for disperse dye | |
| CN102418294B (en) | Denim printing and dyeing technology with printing and sprinkling effect | |
| CN100547153C (en) | A kind of environmental protection type dye printing paste without steaming and washing | |
| CN103526586A (en) | Flame-retardant soft printing adhesive and preparation method thereof | |
| CN105111363B (en) | A kind of function performed polymer and preparation method and application | |
| CN102154852A (en) | Textile machinery printing pigment binding agent and manufacturing method thereof | |
| CN102603963A (en) | Preparation method of environmentally-friendly polyacrylic ester pigment printing adhesive | |
| CN102864658A (en) | Pigment printing binder | |
| CN105218686A (en) | A kind of preparation method of new reactive dyes stamp thickening material | |
| CN103526589A (en) | Aromatic polyurethane pigment printing binding agent and preparation method thereof | |
| CN103556503A (en) | Anti-stain dustproof printing adhesive and preparation method thereof | |
| CN103526588A (en) | Soap-washing-endurance pigment printing binding agent and preparation method thereof | |
| CN103541235A (en) | Water emulsion type polyester acrylate printing adhesive and preparation method thereof | |
| CN102758362A (en) | Invisible printing adhesive and printing process thereof | |
| CN103526584A (en) | Corrosion-resistance pigment printing adhesive and preparation method thereof | |
| CN103541239A (en) | Waterproof printing adhesive and preparation method thereof | |
| CN103541236A (en) | Soft corrosion-resistant printing adhesive and preparation method | |
| CN103541233A (en) | Waterproof flexible printing adhesive and preparation method thereof | |
| CN103541242A (en) | Low-shrinking percentage bright printing adhesive and preparation method thereof | |
| CN103526597A (en) | Flame-retardant printing adhesive and preparation method thereof | |
| CN103526582A (en) | Waterborne pigment printing adhesive and preparation method thereof | |
| CN103526595A (en) | Active pigment resin printing imitation binder and preparation method for same | |
| CN103541237A (en) | Quickly-solidified pigment printing adhesive and preparation method thereof | |
| CN103526591A (en) | Flame-retardant soft printing adhesive and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140122 |
|
| RJ01 | Rejection of invention patent application after publication |