CN103556504A - Super soft printing adhesive and preparation method thereof - Google Patents
Super soft printing adhesive and preparation method thereof Download PDFInfo
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- CN103556504A CN103556504A CN201310502217.8A CN201310502217A CN103556504A CN 103556504 A CN103556504 A CN 103556504A CN 201310502217 A CN201310502217 A CN 201310502217A CN 103556504 A CN103556504 A CN 103556504A
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Abstract
The invention relates to a super soft printing adhesive. The super soft printing adhesive is prepared by the following raw materials in parts by weight: 20-30 parts of polyurethane acrylate, 9-12 parts of isophorone diisocyanate, 6-8 parts of acrylic acid, 15-18 parts of hydroxyethyl methacrylate, 4-5 parts of polyethyl silicate, 3-4 parts of alpha-hydroxyalkyl benzophenone, 1-2 parts of carboxymethyl cellulose, 3-4 parts of 2-butoxy-ethyl alcohol, 4-6 parts of isopropyl alcohol, 3-5 parts of methyl methacrylate, 2-3 parts of menthyl acetate, 1-2 parts of lauryl alcohol polyoxyethylene ether, 1-2 parts of ammonium persulfate, 4-5 parts of addition agent, and 50-55 parts of water. The adhesive has excellent optical resistance, weather fastness, and low-temperature resistance, and high abrasive resistance, adhesive power, flexibility, and peel strength. The super soft printing adhesive has wide application range and good fastness, is not easy to fracture when being used by elastic fabric, has very soft hand feel similar to reactive dyes, does not cake, and is an ideal material for top-grade fabric pigment printing.
Description
Technical field
The invention belongs to textile auxiliary's technical field, relate in particular to a kind of super soft printing adhesive and preparation method thereof.
Background technology
So-called COAT PRINTING is the effect by adhesive, by water insoluble, to fabric, do not have compatibility and reactive pigment to anchor on fabric, thereby reach painted object.According to update introduction, the PRINTED FABRIC of nearly half output is COAT PRINTING in the world at present.Pigment printing binding agent is the main component of textile printing pigment, and the quality of COAT PRINTING end product quality is directly subject to the impact of printing adhesive performance.
The quality of printing adhesive differs at present, the stamp defect rate causing because of adhesive quality problems, more than 3%, has caused huge economic loss, and the quality of printing adhesive directly has influence on quality, the fineness of stamp, the class of fabric, therefore, need to research and develop the more adhesive of high-quality.
Summary of the invention
The object of the present invention is to provide a kind of super soft printing adhesive and preparation method thereof, this adhesive has the feature of softness, wear-resisting, fast light good, strong adhesion.
Technical scheme of the present invention is as follows:
A soft printing adhesive, is characterized in that being made by the raw material of following weight portion: polyurethane acroleic acid fat 20-30, isophorone diisocyanate 9-12, acrylic acid 6-8, hydroxyethyl methylacrylate 15-18, ethyl polysilicate 4-5, alpha-hydroxyalkyl benzophenone 3-4, carboxymethyl cellulose 1-2,2-butoxy-ethanol 3-4, isopropyl alcohol 4-6, methyl methacrylate 3-5, menthyl acetate 2-3, ethoxylated dodecyl alcohol 1-2, ammonium persulfate 1-2, auxiliary agent 4-5, water 50-55; Described auxiliary agent is made by the raw material of following weight portion: Silane coupling reagent KH-570 2-3, crosslinking agent TAC1-2, styrene 3-4, maleic anhydride 2-3, Tween-81 2-3, acrylonitrile 2-3, antioxidant 1035 1-2, diethylene glycol (DEG) 7-9, ethanol 12-15; Preparation method mixes crosslinking agent TAC, styrene, maleic anhydride, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
The preparation method of described super soft printing adhesive, it is characterized in that comprising the following steps: polyurethane acroleic acid fat, isophorone diisocyanate, acrylic acid, hydroxyethyl methylacrylate, ethyl polysilicate, alpha-hydroxyalkyl benzophenone, carboxymethyl cellulose, 2-butoxy-ethanol, isopropyl alcohol, methyl methacrylate, menthyl acetate are mixed, under 800-1200 rev/min of stirring, with the speed of 7-9 ℃/minute, be heated to 60-70 ℃; Add ethoxylated dodecyl alcohol, with the speed of 6-8 ℃/minute, be heated to 80-90 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2-3 hour, obtain.
Beneficial effect of the present invention
Adhesive of the present invention has excellent resistance to optical, weather fastness, lower temperature resistance, high ABRASION RESISTANCE, adhesion, pliability, peel strength; Adhesive application scope of the present invention is wide, and fastness is good, and for elastic fabric easy fracture not, feel is extremely soft and non-caked, has the feel that REACTIVE DYES is approximate, is the desirable materials of high-grade fabric COAT PRINTING.
The specific embodiment
A soft printing adhesive, by following weight portion (kilogram) raw material make: polyurethane acroleic acid fat 25, isophorone diisocyanate 11, acrylic acid 7, hydroxyethyl methylacrylate 17, ethyl polysilicate 4.5, alpha-hydroxyalkyl benzophenone 3.5, carboxymethyl cellulose 1.5,2-butoxy-ethanol 3.5, isopropyl alcohol 5, methyl methacrylate 4, menthyl acetate 2.5, ethoxylated dodecyl alcohol 1.5, ammonium persulfate 1.5, auxiliary agent 4.5, water 53; Described auxiliary agent by following weight portion (kilogram) raw material make: Silane coupling reagent KH-570 2, crosslinking agent TAC1, styrene 4, maleic anhydride 3, Tween-81 2, acrylonitrile 2, antioxidant 1,035 2, diethylene glycol (DEG) 7, ethanol 12; Preparation method mixes crosslinking agent TAC, styrene, maleic anhydride, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
The preparation method of described super soft printing adhesive, comprise the following steps: polyurethane acroleic acid fat, isophorone diisocyanate, acrylic acid, hydroxyethyl methylacrylate, ethyl polysilicate, alpha-hydroxyalkyl benzophenone, carboxymethyl cellulose, 2-butoxy-ethanol, isopropyl alcohol, methyl methacrylate, menthyl acetate are mixed, under 1000 revs/min of stirrings, with the speed of 8 ℃/minute, be heated to 65 ℃; Add ethoxylated dodecyl alcohol, with the speed of 7 ℃/minute, be heated to 85 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2.5 hours, obtain.
This super soft printing adhesive, for stamp, is pressed GB standard detection, 3 grades of dry fastnesses, and fastness to wet rubbing is in 2-3 level, and brushing fastness 3-4 level, glues COLOR FASTNESS 3-4 level, the fastness of fading after soaping 3-4 level.
Claims (2)
1. a super soft printing adhesive, is characterized in that being made by the raw material of following weight portion: polyurethane acroleic acid fat 20-30, isophorone diisocyanate 9-12, acrylic acid 6-8, hydroxyethyl methylacrylate 15-18, ethyl polysilicate 4-5, alpha-hydroxyalkyl benzophenone 3-4, carboxymethyl cellulose 1-2,2-butoxy-ethanol 3-4, isopropyl alcohol 4-6, methyl methacrylate 3-5, menthyl acetate 2-3, ethoxylated dodecyl alcohol 1-2, ammonium persulfate 1-2, auxiliary agent 4-5, water 50-55; Described auxiliary agent is made by the raw material of following weight portion: Silane coupling reagent KH-570 2-3, crosslinking agent TAC1-2, styrene 3-4, maleic anhydride 2-3, Tween-81 2-3, acrylonitrile 2-3, antioxidant 1035 1-2, diethylene glycol (DEG) 7-9, ethanol 12-15; Preparation method mixes crosslinking agent TAC, styrene, maleic anhydride, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
2. the preparation method of super soft printing adhesive according to claim 1, it is characterized in that comprising the following steps: polyurethane acroleic acid fat, isophorone diisocyanate, acrylic acid, hydroxyethyl methylacrylate, ethyl polysilicate, alpha-hydroxyalkyl benzophenone, carboxymethyl cellulose, 2-butoxy-ethanol, isopropyl alcohol, methyl methacrylate, menthyl acetate are mixed, under 800-1200 rev/min of stirring, with the speed of 7-9 ℃/minute, be heated to 60-70 ℃; Add ethoxylated dodecyl alcohol, with the speed of 6-8 ℃/minute, be heated to 80-90 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2-3 hour, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310502217.8A CN103556504A (en) | 2013-10-23 | 2013-10-23 | Super soft printing adhesive and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310502217.8A CN103556504A (en) | 2013-10-23 | 2013-10-23 | Super soft printing adhesive and preparation method thereof |
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| CN103556504A true CN103556504A (en) | 2014-02-05 |
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| CN201310502217.8A Pending CN103556504A (en) | 2013-10-23 | 2013-10-23 | Super soft printing adhesive and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104559742A (en) * | 2014-12-24 | 2015-04-29 | 合肥协知行信息系统工程有限公司 | Polyurethane acrylic polymer water-dispersing coating and preparation method thereof |
| CN112047640A (en) * | 2020-09-16 | 2020-12-08 | 中山庞玻新型装饰玻璃有限公司 | Degerming and sterilizing functional glass |
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| WO2009118270A1 (en) * | 2008-03-25 | 2009-10-01 | Siegwerk Benelux Sa | Modified polyurethane acrylate |
| CN101748617A (en) * | 2008-12-05 | 2010-06-23 | 上海洁润丝新材料股份有限公司 | Anti-sticking soft dope printing adhesive and preparation method |
| CN102174305A (en) * | 2010-12-14 | 2011-09-07 | 北京高盟新材料股份有限公司 | Acrylate adhesive for reflective cloth and preparation method thereof |
| CN102182080A (en) * | 2011-03-23 | 2011-09-14 | 成都德美精英化工有限公司 | Pigment printing binding agent and synthesizing method thereof |
| CN102977253A (en) * | 2012-11-06 | 2013-03-20 | 中科院广州化学有限公司 | Silicone modified acrylate hybrid emulsion and preparation method and application thereof |
| CN103146325A (en) * | 2013-03-12 | 2013-06-12 | 南通高盟新材料有限公司 | Adhesive for reflective fabric with normal brightness |
| CN103276609A (en) * | 2013-05-14 | 2013-09-04 | 广州市盛勤实业有限公司 | White glue and preparation method thereof |
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2013
- 2013-10-23 CN CN201310502217.8A patent/CN103556504A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009118270A1 (en) * | 2008-03-25 | 2009-10-01 | Siegwerk Benelux Sa | Modified polyurethane acrylate |
| CN101748617A (en) * | 2008-12-05 | 2010-06-23 | 上海洁润丝新材料股份有限公司 | Anti-sticking soft dope printing adhesive and preparation method |
| CN102174305A (en) * | 2010-12-14 | 2011-09-07 | 北京高盟新材料股份有限公司 | Acrylate adhesive for reflective cloth and preparation method thereof |
| CN102182080A (en) * | 2011-03-23 | 2011-09-14 | 成都德美精英化工有限公司 | Pigment printing binding agent and synthesizing method thereof |
| CN102977253A (en) * | 2012-11-06 | 2013-03-20 | 中科院广州化学有限公司 | Silicone modified acrylate hybrid emulsion and preparation method and application thereof |
| CN103146325A (en) * | 2013-03-12 | 2013-06-12 | 南通高盟新材料有限公司 | Adhesive for reflective fabric with normal brightness |
| CN103276609A (en) * | 2013-05-14 | 2013-09-04 | 广州市盛勤实业有限公司 | White glue and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104559742A (en) * | 2014-12-24 | 2015-04-29 | 合肥协知行信息系统工程有限公司 | Polyurethane acrylic polymer water-dispersing coating and preparation method thereof |
| CN112047640A (en) * | 2020-09-16 | 2020-12-08 | 中山庞玻新型装饰玻璃有限公司 | Degerming and sterilizing functional glass |
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Application publication date: 20140205 |