CN103539877A - 生产氯丁胶乳 - Google Patents
生产氯丁胶乳 Download PDFInfo
- Publication number
- CN103539877A CN103539877A CN201310367438.9A CN201310367438A CN103539877A CN 103539877 A CN103539877 A CN 103539877A CN 201310367438 A CN201310367438 A CN 201310367438A CN 103539877 A CN103539877 A CN 103539877A
- Authority
- CN
- China
- Prior art keywords
- latex
- multipolymer
- temperature
- chloroprene
- homopolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000126 latex Polymers 0.000 title claims abstract description 103
- 229920001084 poly(chloroprene) Polymers 0.000 title claims abstract description 50
- 239000004816 latex Substances 0.000 claims abstract description 102
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 31
- 239000000178 monomer Substances 0.000 claims abstract description 29
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 claims abstract description 15
- 238000007720 emulsion polymerization reaction Methods 0.000 claims abstract description 14
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims description 42
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 33
- 230000009466 transformation Effects 0.000 claims description 19
- 229920001519 homopolymer Polymers 0.000 claims description 18
- 238000007334 copolymerization reaction Methods 0.000 claims description 15
- 239000006185 dispersion Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 8
- 239000000835 fiber Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 239000004744 fabric Substances 0.000 claims description 6
- 239000013518 molded foam Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 238000007654 immersion Methods 0.000 claims description 5
- 238000004513 sizing Methods 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 238000002791 soaking Methods 0.000 claims description 3
- 239000011230 binding agent Substances 0.000 claims description 2
- 238000007598 dipping method Methods 0.000 claims description 2
- 238000005728 strengthening Methods 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 abstract description 3
- 239000012141 concentrate Substances 0.000 description 11
- 239000003999 initiator Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000000539 dimer Substances 0.000 description 9
- 239000006227 byproduct Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 230000001131 transforming effect Effects 0.000 description 4
- NYYSPVRERVXMLJ-UHFFFAOYSA-N 4,4-difluorocyclohexan-1-one Chemical compound FC1(F)CCC(=O)CC1 NYYSPVRERVXMLJ-UHFFFAOYSA-N 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- 229920001174 Diethylhydroxylamine Polymers 0.000 description 2
- 239000004159 Potassium persulphate Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- FVCOIAYSJZGECG-UHFFFAOYSA-N diethylhydroxylamine Chemical compound CCN(O)CC FVCOIAYSJZGECG-UHFFFAOYSA-N 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 238000004442 gravimetric analysis Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
- 235000019394 potassium persulphate Nutrition 0.000 description 2
- 238000003822 preparative gas chromatography Methods 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000007790 solid phase Substances 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- PCPYTNCQOSFKGG-UHFFFAOYSA-N 1-chlorobuta-1,3-diene Chemical compound ClC=CC=C PCPYTNCQOSFKGG-UHFFFAOYSA-N 0.000 description 1
- WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 235000014493 Crataegus Nutrition 0.000 description 1
- 241001092040 Crataegus Species 0.000 description 1
- 238000005698 Diels-Alder reaction Methods 0.000 description 1
- 239000004908 Emulsion polymer Substances 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- HRKQOINLCJTGBK-UHFFFAOYSA-N dihydroxidosulfur Chemical compound OSO HRKQOINLCJTGBK-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical class CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- SBGKURINHGJRFN-UHFFFAOYSA-N hydroxymethanesulfinic acid Chemical compound OCS(O)=O SBGKURINHGJRFN-UHFFFAOYSA-N 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- ZRSNZINYAWTAHE-UHFFFAOYSA-N p-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C=C1 ZRSNZINYAWTAHE-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229950000688 phenothiazine Drugs 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000010517 secondary reaction Methods 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 230000008786 sensory perception of smell Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 1
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000001149 thermolysis Methods 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F36/14—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated containing elements other than carbon and hydrogen
- C08F36/16—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated containing elements other than carbon and hydrogen containing halogen
- C08F36/18—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated containing elements other than carbon and hydrogen containing halogen containing chlorine
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J111/00—Adhesives based on homopolymers or copolymers of chloroprene
- C09J111/02—Latex
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006045128A DE102006045128A1 (de) | 2006-09-25 | 2006-09-25 | Verfahren zur Herstellung von Polychloropren-Latices |
| DE102006045128.7 | 2006-09-25 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2007101546605A Division CN101153063A (zh) | 2006-09-25 | 2007-09-20 | 生产氯丁胶乳 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103539877A true CN103539877A (zh) | 2014-01-29 |
Family
ID=38861824
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310367438.9A Pending CN103539877A (zh) | 2006-09-25 | 2007-09-20 | 生产氯丁胶乳 |
| CNA2007101546605A Pending CN101153063A (zh) | 2006-09-25 | 2007-09-20 | 生产氯丁胶乳 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2007101546605A Pending CN101153063A (zh) | 2006-09-25 | 2007-09-20 | 生产氯丁胶乳 |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US8063136B2 (https=) |
| EP (1) | EP1903063B1 (https=) |
| JP (1) | JP5525684B2 (https=) |
| CN (2) | CN103539877A (https=) |
| DE (1) | DE102006045128A1 (https=) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110669160A (zh) * | 2019-10-31 | 2020-01-10 | 重庆化医长寿化工集团有限公司 | 一种工程防水用氯丁胶乳的制备方法 |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8389674B2 (en) | 2009-04-17 | 2013-03-05 | Lanxess Deutschland Gmbh | Method for producing a polychloroprene-based polymer dispersion and system for producing a polychloroprene-based polymer dispersion |
| EP2241580A1 (de) * | 2009-04-17 | 2010-10-20 | LANXESS Deutschland GmbH | Verfahren zur Herstellung einer Polymer-Dispersion auf Basis von Polychloropren sowie Anlage zur Herstellung einer Polymer-Dispersion auf Basis von Polychloropren |
| DE102010005994B4 (de) | 2010-01-27 | 2022-07-28 | Tianjin Shenglong Fibre Co., Ltd. | Verfahren zur Hestellung eines Hybrid-Polsterelements, insbesondere eines Sitz- und Lehnenpolsterelements zur Verwendung in einem Kraftfahrzeug, ein Polsterelement und ein Fahrzeugsitz mit einem Polsterelement. |
| CA2805555A1 (en) * | 2010-08-06 | 2012-02-09 | Denki Kagaku Kogyo Kabushiki Kaisha | Polychloroprene latex, rubber-asphalt composition and utilization method thereof, sheet, and waterproof coating film |
| CN102492072A (zh) * | 2011-11-16 | 2012-06-13 | 山西合成橡胶集团有限责任公司 | 一种高粘度中等结晶型氯丁橡胶的制备方法 |
| CN108779193A (zh) * | 2016-03-31 | 2018-11-09 | 日本瑞翁株式会社 | 共聚物的制造方法及胶乳的制造方法 |
| US10626016B2 (en) * | 2017-11-27 | 2020-04-21 | Brandeis University | Method and composition of humidity-controlled generation of chlorine dioxide in polymers and superabsorbent hydrogels |
| CN116685655A (zh) | 2020-12-28 | 2023-09-01 | 株式会社力森诺科 | 聚氯丁二烯胶乳组合物 |
| WO2024204249A1 (ja) * | 2023-03-29 | 2024-10-03 | デンカ株式会社 | クロロプレン系ラテックス組成物、クロロプレン系ラテックス組成物の製造方法、及び水性接着剤 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1545104A (en) * | 1975-05-07 | 1979-05-02 | Bayer Ag | Process for the production of concentrated polychloroprene latices |
| CN1137277A (zh) * | 1993-12-07 | 1996-12-04 | 纳幕尔杜邦公司 | 制备2-氯-1，3-丁二烯接枝共聚物的方法 |
| US20030182704A1 (en) * | 2001-09-21 | 2003-10-02 | Denki Kagaku Kogyo Kabushiki Kaisha | Aqueous adhesive, foamed rubber material using the same, method for bonding diving suit, and its bonded structure |
| CN1760217A (zh) * | 2004-10-14 | 2006-04-19 | 拜尔材料科学股份公司 | 含水的粘合剂分散体 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3337485A (en) * | 1965-09-24 | 1967-08-22 | Du Pont | Chloroprene-methacrylic acid copolymer adhesives containing salicylic acid |
| US3887539A (en) | 1973-04-30 | 1975-06-03 | Union Carbide Corp | Adhesive compositions |
| US3904590A (en) * | 1973-09-20 | 1975-09-09 | Du Pont | Process for polymerizing chlorobutadienes |
| US3925340A (en) * | 1974-05-08 | 1975-12-09 | Du Pont | Preparation of sol chloroprene polymers |
| DE2536970A1 (de) * | 1975-08-20 | 1977-03-03 | Bayer Ag | Konzentrierte polychloroprenlatices mit reaktiven gruppen |
| DE3111138A1 (de) * | 1981-03-21 | 1982-09-30 | Bayer Ag, 5090 Leverkusen | Verfahren zur polymerisation von chloropren |
| DE3605332A1 (de) * | 1986-02-19 | 1987-08-20 | Bayer Ag | Chloropren-polymerisation |
| USH2092H1 (en) | 1999-06-30 | 2003-12-02 | Dupont Dow Elastomers L.L.C. | Process for production of polychloroprene having low odor |
| DE10318107A1 (de) * | 2003-04-22 | 2004-11-11 | Bayer Materialscience Ag | Wässrige Klebstoff-Dispersionen |
| ITMI20041194A1 (it) * | 2004-06-15 | 2004-09-15 | Polimeri Europa Spa | Procedimento per la preparazione di lattici a base di policloroprene e loro uso come adesivi |
-
2006
- 2006-09-25 DE DE102006045128A patent/DE102006045128A1/de not_active Withdrawn
-
2007
- 2007-08-29 US US11/897,135 patent/US8063136B2/en not_active Expired - Fee Related
- 2007-09-17 EP EP07116588.0A patent/EP1903063B1/de not_active Not-in-force
- 2007-09-20 CN CN201310367438.9A patent/CN103539877A/zh active Pending
- 2007-09-20 CN CNA2007101546605A patent/CN101153063A/zh active Pending
- 2007-09-21 JP JP2007245906A patent/JP5525684B2/ja not_active Expired - Fee Related
-
2011
- 2011-09-28 US US13/247,219 patent/US8304491B2/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1545104A (en) * | 1975-05-07 | 1979-05-02 | Bayer Ag | Process for the production of concentrated polychloroprene latices |
| CN1137277A (zh) * | 1993-12-07 | 1996-12-04 | 纳幕尔杜邦公司 | 制备2-氯-1，3-丁二烯接枝共聚物的方法 |
| US20030182704A1 (en) * | 2001-09-21 | 2003-10-02 | Denki Kagaku Kogyo Kabushiki Kaisha | Aqueous adhesive, foamed rubber material using the same, method for bonding diving suit, and its bonded structure |
| CN1760217A (zh) * | 2004-10-14 | 2006-04-19 | 拜尔材料科学股份公司 | 含水的粘合剂分散体 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110669160A (zh) * | 2019-10-31 | 2020-01-10 | 重庆化医长寿化工集团有限公司 | 一种工程防水用氯丁胶乳的制备方法 |
| CN110669160B (zh) * | 2019-10-31 | 2022-05-20 | 重庆化医长寿化工集团有限公司 | 一种工程防水用氯丁胶乳的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20080076855A1 (en) | 2008-03-27 |
| US8063136B2 (en) | 2011-11-22 |
| EP1903063A2 (de) | 2008-03-26 |
| JP2008081741A (ja) | 2008-04-10 |
| EP1903063B1 (de) | 2015-08-12 |
| JP5525684B2 (ja) | 2014-06-18 |
| CN101153063A (zh) | 2008-04-02 |
| DE102006045128A1 (de) | 2008-03-27 |
| US8304491B2 (en) | 2012-11-06 |
| US20120022213A1 (en) | 2012-01-26 |
| EP1903063A3 (de) | 2009-10-14 |
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