CN103520019A - Preparation method of beautifying, sun-blocking and isolating emulsion containing hexagonal meso-porous silicon - Google Patents
Preparation method of beautifying, sun-blocking and isolating emulsion containing hexagonal meso-porous silicon Download PDFInfo
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- CN103520019A CN103520019A CN201310449236.9A CN201310449236A CN103520019A CN 103520019 A CN103520019 A CN 103520019A CN 201310449236 A CN201310449236 A CN 201310449236A CN 103520019 A CN103520019 A CN 103520019A
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Abstract
The invention discloses a preparation method of a beautifying, sun-blocking and isolating emulsion containing hexagonal meso-porous silicon. The hexagonal meso-porous silicon and dimethyl silicon oil are mixed uniformly and then added into a beautifying emulsion substrate, wherein the beautifying emulsion substrate is prepared by a user. By the aid of the special structural feature and hole size, the excellent biocompatibility and the safety of the hexagonal meso-porous silicon, the hexagonal meso-porous silicon has different effects in different cosmetic formulas, for example, the hexagonal meso-porous silicon is high in sun-blocking efficiency and can serve as a novel oil-control ingredient; in addition, active matters and active ingredients can be loaded by the aid of the structural characteristics of the meso-porous silicon, so that the stability of the active matters can be improved, and the controlled-release effect can be achieved; and the adhesiveness of the emulsion can be improved by adding the meso-porous silicon, so that the emulsion touches good. The preparation method has great advantages in the cosmetic industry, so that the emulsion becomes a novel promising carrier material in the cosmetic industry.
Description
Technical field
The present invention relates to topical compositions, particularly hexagonal mesoporous silicon application in cosmetics as adjuvant.The sun-proof isolation breast of beauty treatment containing hexagonal mesoporous silicon is provided.
Background technology
Long-time use topical compositions contain and reach moisturizing, conditioning and anti-ultraviolet effective ingredient simultaneously.Now, the destruction of ozone makes UV injury larger, and people are usually accustomed to staying in air-conditioned room, makes people more and more higher to the requirement of skin care item.Most of Orangic sunscreen and effective ingredient usually give people's sensation excessively greasy clouding, and these full-bodied compositions are dense while making with contact skin, can not reach the even release of control.When combining with granule, sticky sense improves significantly.In skin care item, add granular material, organic and inorganic particle, once had report to use reflective substance as TiO for 1996
2physical property is filled skin streakline, uses smooth and gives skin natural colour.And the friction when comprising granular material and can reduce product and use.65% of earth's surface is Silicon stone, is again silicon dioxide, and chemical formula is SiO
2.Wherein soluble silicon-metasilicic acid is the indispensable nutrients such as human skeleton, skin, hair, fingernail, blood vessel.Be that silicon let us has soft skin and hard skeleton, make health keep pliability and elasticity.Silicon can promote child's growth promoter, and silicon can also impel collagen protein to increase, and has certain anti-wrinkle cosmetic effect.While lacking silicon in human body, can cause xerosis cutis, wrinkle to increase.So the associated materials of silicon is also widely used in cosmetics, as organosilicon materials such as methyl-silicone oil, annular siloxane, methyl phenyl silicone oils, can increase moistening, ventilative, softness, antistatic, film property, radiation hardness etc.Inorganic silicon dioxide also has related application, as adsorbed, prevent bonding, control viscosity as abrasivus in the clean flour of Christian Dior snow crystal spirit whitening, is that sense of touch is finer and smoother.SiO
2in cosmetics, can be used as odour absorbents, grinding agent, opacifying agent, also can play and hide the effect that the flaw is polished simultaneously.So the application safety of the associated materials of Silicon stone in skin care item is reliable, prospect of the application is extensive.
So far, in composite skin care product, add the existing institute of granule adjuvant to report.Chinese patent 200610122710.7 discloses the ocean medicine hairdressing sun cream containing Concha Ostreae powder; Chinese patent 201110108498.X discloses a kind of Fructus Cannabis powder and the application in preparing sunscreen cream thereof; Chinese patent 201010623289.4 discloses a kind of sun screen that silicon is processed Margarita powder that adds; Recklessly forever lion etc. [lion forever recklessly, Hong Jiani, Du Qingyun, Li Maoxing. containing Herba Oxytropis falcatae chromocor compound and nano-TiO
2the formulating of sunscreen cream, PLA's Acta Pharmaceutica Sinica, 2010 (04)] employing nano-TiO
2as the physical sunscreen agent of sunscreen cream, carry out formulating; [Jin Minghui, Wang Lifang, for the SiO of cosmetics for Jin Minghui etc.
2/ TiO
2the preparation and characterization of complex microsphere, daily chemical industry, 2006 (04)] prepare SiO2/TiO2 complex microsphere as the physical sunscreen agent in skin care item.Yet, using hexagonal mesoporous silicon as granule adjuvant, add and in skin care item, have no report.
Summary of the invention
The object of the present invention is to provide mesoporous silicon in the novel different application of cosmetic field, preparation is containing the sun-proof isolation breast of beauty treatment of nano-hexagonal mesoporous silicon.
The newborn preparation method of the sun-proof isolation of beauty treatment of hexagonal mesoporous silicon, comprises the following steps:
(1) preparation beauty treatment emulsion matrix:
1) by stearic acid, glyceryl monostearate, hexadecanol, IPM, mixing, be heated to 75 ~ 85 ℃, at rotating speed, be under 200 ~ 300rpm condition, to carry out magnetic agitation dissolving, obtain A phase;
2) by glycerol, carbamide, D-panthenol, potassium hydroxide, at rotating speed, be under 150 ~ 300rpm condition, to carry out magnetic agitation mixing, be heated to 75 ~ 85 ℃, obtain B phase;
3) B is added to A mutually in, at rotating speed, be under 150 ~ 300rpm condition, to carry out magnetic agitation, be warming up to 90 ~ 95 ℃ and keep 8 ~ 10min to be cooled to again 60 ~ 65 ℃, then add deionized water, mix, with high-shear homogenizer homogenizing 10 ~ 15min under 5000 ~ 8000rpm speed;
4) remain on 60 ~ 65 ℃, under 300 ~ 500rpm condition, with dasher, stir 30 ~ 40min, while cooling to again 40 ~ 50 ℃, add vitamin E, with dasher, at rotating speed, be to stir under 300 ~ 500rpm condition, fully emulsified after, then add ethyl hydroxybenzoate, spice, continue stirring until bubble is all driven away, be cooled to room temperature and obtain the emulsion matrix of improving looks;
(2) hexagonal mesoporous silicon and beauty treatment emulsion matrix are composite:
1) at room temperature will not be written into salicylic acid or be written into salicylic hexagonal mesoporous silicon and dimethicone agate mortar mix homogeneously, forming after homogeneous mixture, adding in beauty treatment emulsion matrix;
2) at rotating speed, be with dasher, constantly to stir and be cooled to room temperature under 300 ~ 500rpm condition, obtain the sun-proof isolation breast of beauty treatment containing hexagonal mesoporous silicon.
In said method, described beauty treatment emulsion matrix comprises the emulsion matrix that following quality percentage composition material forms: stearic acid 10 ~ 18%, glyceryl monostearate 1.5 ~ 2%, hexadecanol 1.5 ~ 3%, IPM 3 ~ 6%, vitamin e 1 ~ 2%, glycerol 6 ~ 8%, carbamide 4 ~ 7%, D-panthenol 1 ~ 2%, ethyl hydroxybenzoate 0.1 ~ 0.3%, spice 0.2 ~ 0.4%, potassium hydroxide 0.5 ~ 0.7%, deionized water 50 ~ 71.2%.
In said method, the described preparation method that is written into salicylic hexagonal mesoporous silicon is: take salicylic acid and be dissolved in dehydrated alcohol and be placed in seal glass tank, add hexagonal mesoporous silicon, put into 36 ~ 38 ℃ of shaking tables, centrifugal through deionized water wash 3 times, after being deposited in 50 ~ 70 ℃ of baking ovens of obtaining dried to 24 ~ 30h, obtain product and be put in exsiccator standby;
In said method, described in step (2), the concentration of salicylic acid in dehydrated alcohol is 0.02 ~ 0.03g/mL; The mass ratio of salicylic acid and mesoporous silicon is 1.5 ~ 2.5:1.
A kind of sun-proof isolation breast of beauty treatment containing hexagonal mesoporous silicon is comprised of beauty treatment emulsion matrix, hexagonal mesoporous silicon, dimethicone, and the mass ratio of the emulsion matrix of wherein improving looks, hexagonal mesoporous silicon, dimethicone is 60 ~ 100:1 ~ 5:5 ~ 25.
Preferably, described hexagonal mesoporous silicon is not for being written into salicylic acid or being written into salicylic hexagonal mesoporous silicon.
Compared with prior art, the invention has the advantages that:
(1) add in sunscreen product, because its special loose structure produces multi-angle scattering, sun-proof result is improved greatly.
(2) loose structure of hexagonal mesoporous silicon can load various active composition, as carrier, carries out slow release, improves stability, reduces zest; Simultaneously due to its feature pore passage structure, high specific surface area, high adsorption capacity, can be used as novel control oil component.
(3) hexagonal mesoporous silicon joins in cosmetics, nonpoisonous and tasteless, and safety and stability can be improved the cohesiveness of emulsion, makes sense of touch good, improves its dispersibility simultaneously, improves product efficiency.
The specific embodiment
Following examples will further illustrate the preferred embodiment belonging in the scope of the invention.These embodiment only provide and are not interpreted as limitation of the present invention for illustrational object, because the present invention can have many change programmes under the prerequisite that does not deviate from essence of the present invention or scope.
case study on implementation 1:
(1) preparation beauty treatment emulsion matrix
1) by 10g stearic acid, 1.5g glyceryl monostearate, 1.5g hexadecanol, 3g IPM, mixing, be heated to 75 ℃, 300rpm magnetic agitation is dissolved, and obtains A phase.
2) 6g glycerol, 4g carbamide, 1gD-pantothenylol, 0.5g potassium hydroxide are mixed, in 300rpm magnetic agitation, be heated to 75 ℃, obtain B phase.
3) B is slowly joined mutually A mutually in, 300rpm magnetic agitation, is warming up to 90 ℃ and keeps 10min to be cooled to 60 ℃ again, then add the deionized water of 71.2g, mixes, with high-shear homogenizer homogenizing 15min under 5000rpm.
4) keep 60 ℃, under 300rpm condition, with dasher, stir 40min, then add 1g vitamin E while cooling to 40 ℃, dasher 300pm stirs and makes it fully emulsified.Add again 0.1g ethyl hydroxybenzoate, 0.2g spice, continue stirring until bubble is all driven away, be cooled to room temperature and obtain 100g beauty treatment emulsion matrix.
(2) carry the preparation of salicylic hexagonal mesoporous silicon
Taking 0.4g salicylic acid is dissolved in and in 20mL dehydrated alcohol, is placed in seal glass tank, add again the hexagonal mesoporous silicon of 266mg, put into 37 ℃ of shaking tables, centrifugal through 3 washings of deionized water, the 24h in 60 ℃ of baking ovens that is deposited in obtaining is dried, and obtains product and is put in exsiccator standby.
(3) hexagonal mesoporous silicon and beauty treatment emulsion matrix are composite
1) at room temperature get that 1g is written into salicylic hexagonal mesoporous silicon and 5g dimethicone evenly mixes with agate mortar, form after homogeneous mixture, add in 60g beauty treatment emulsion matrix.
2) with dasher, under 300rpm condition, constantly stir and be cooled to room temperature, obtain the sun-proof isolation breast of beauty treatment containing hexagonal mesoporous silicon.
Obtain containing the sun-proof isolation breast of the beauty treatment of hexagonal mesoporous silicon exquisiteness, by it at the centrifugal 30min of centrifuge 2500r/min, without lamination.Be placed in respectively 55 ℃ of baking oven 12h ,-15 ℃ of refrigerator 12h, circulate one week, still stable without lamination.Be placed in 40 ℃ of baking ovens, 5 ℃ of refrigerators one month, still keep uniform and stable, without the mould phenomenon that loses.
case study on implementation 2:
(1) preparation beauty treatment emulsion matrix
1) by 15g stearic acid, 1.8g glyceryl monostearate, 2.5g hexadecanol, 5g IPM, mixing, be heated to 78 ℃, 250rpm magnetic agitation is dissolved, and obtains A phase.
2) 7g glycerol, 6g carbamide, 1.5gD-pantothenylol, 0.6 g potassium hydroxide are mixed, 250rpm magnetic agitation, is heated to 78 ℃, obtains B phase.
3) B is slowly joined mutually A mutually in, 250rpm magnetic agitation, is warming up to 95 ℃ and keeps 10min to be cooled to 65 ℃ again, then add the deionized water of 58.6g, mixes, with high-shear homogenizer homogenizing 15min under 6000rpm.
4) remain on 65 ℃, under 300rpm condition, with dasher, stir 30min, then add 1.5g vitamin E while cooling to 50 ℃, with dasher, under 500rpm condition, stir and make it fully emulsified.Add again 0.2g ethyl hydroxybenzoate, 0.3g spice, continue stirring until bubble is all driven away, be cooled to room temperature and obtain 100g beauty treatment emulsion matrix.
(2) carry the preparation of salicylic hexagonal mesoporous silicon
Taking 0.5g salicylic acid is dissolved in and in 20mL dehydrated alcohol, is placed in seal glass tank, add again the hexagonal mesoporous silicon of 250mg, put into 37 ℃ of shaking tables, centrifugal through 3 washings of deionized water, the 24h in 60 ℃ of baking ovens that is deposited in obtaining is dried, and obtains product and is put in exsiccator standby.
(3) hexagonal mesoporous silicon and beauty treatment emulsion matrix are composite
1) at room temperature get that 5g is written into salicylic hexagonal mesoporous silicon and 25g dimethicone evenly mixes with agate mortar, form after homogeneous mixture, add in 100g beauty treatment emulsion matrix.
2) with dasher, under 500rpm condition, constantly stir and be cooled to room temperature, obtain the sun-proof isolation breast of beauty treatment containing hexagonal mesoporous silicon.
Obtain containing the sun-proof isolation breast of the beauty treatment of hexagonal mesoporous silicon exquisiteness, by it at the centrifugal 30min of centrifuge 2500r/min, without lamination.Be placed in respectively 55 ℃ of baking oven 12h ,-15 ℃ of refrigerator 12h, circulate one week, still stable without lamination.Be placed in 40 ℃ of baking ovens, 5 ℃ of refrigerators one month, still keep uniform and stable, without the mould phenomenon that loses.
case study on implementation 3:
(1) preparation beauty treatment emulsion matrix
1) by 18g stearic acid, 2g glyceryl monostearate, 3g hexadecanol, 6g IPM, mixing, be heated to 75 ℃, 200pm magnetic agitation is dissolved, and obtains A phase.
2) 8g glycerol, 7g carbamide, 2gD-pantothenylol, 0.7 g potassium hydroxide are mixed, 300rpm magnetic agitation, is heated to 75 ℃, obtains B phase.
3) B is slowly joined mutually A mutually in, 150rpm magnetic agitation, is warming up to 95 ℃ and keeps 8min to be cooled to 65 ℃ again, then add the deionized water of 50.6g, mixes, with high-shear homogenizer homogenizing 10min under 8000rpm.
4) keep 65 ℃, under 300rpm condition, with dasher, stir 40min, then add 2g vitamin E while cooling to 50 ℃, dasher 300rpm stirs and makes it fully emulsified.Add again 0.3g ethyl hydroxybenzoate, 0.4g spice, continue stirring until bubble is all driven away, be cooled to room temperature and obtain 100g beauty treatment emulsion matrix.
(2) carry the preparation of salicylic hexagonal mesoporous silicon
Taking 0.6g salicylic acid is dissolved in and in 20mL dehydrated alcohol, is placed in seal glass tank, add again the hexagonal mesoporous silicon of 240mg, put into 37 ℃ of shaking tables, centrifugal through 3 washings of deionized water, the 24h in 60 ℃ of baking ovens that is deposited in obtaining is dried, and obtains product and is put in exsiccator standby.
(3) hexagonal mesoporous silicon and beauty treatment emulsion matrix are composite
1) at room temperature get the hexagonal mesoporous silicon of 3g and 15g dimethicone and evenly mix with agate mortar, form after homogeneous mixture, add in 80g beauty treatment emulsion matrix.
2) with dasher, under 500rpm condition, constantly stir and be cooled to room temperature, be cooled to room temperature and obtain the sun-proof isolation breast of beauty treatment containing hexagonal mesoporous silicon.
Obtain containing the sun-proof isolation breast of the beauty treatment of hexagonal mesoporous silicon exquisiteness, by it at the centrifugal 30min of centrifuge 2500r/min, without lamination.Be placed in respectively 55 ℃ of baking oven 12h ,-15 ℃ of refrigerator 12h, circulate one week, still stable without lamination.Be placed in 40 ℃ of baking ovens, 5 ℃ of refrigerators one month, still keep uniform and stable, without the mould phenomenon that loses.
case implements 4:
(1) preparation beauty treatment emulsion matrix
1) by 15g stearic acid, 1.8g glyceryl monostearate, 2.5g hexadecanol, 5g IPM, mixing, be heated to 78 ℃, 250rpm magnetic agitation is dissolved, and obtains A phase.
2) 7g glycerol, 6g carbamide, 1.5gD-pantothenylol, 0.6 g potassium hydroxide are mixed, 250rpm magnetic agitation, is heated to 78 ℃, obtains B phase.
3) B is slowly joined mutually A mutually in, 250rpm magnetic agitation, is warming up to 95 ℃ and keeps 10min to be cooled to 65 ℃ again, then add the deionized water of 58.6g, mixes, with high-shear homogenizer homogenizing 15min under 6000rpm.
4) remain on 65 ℃, under 300rpm condition, with dasher, stir 30min, then add 1.5g vitamin E while cooling to 50 ℃, with dasher, under 500rpm condition, stir and make it fully emulsified.Add again 0.2g ethyl hydroxybenzoate, 0.3g spice, continue stirring until bubble is all driven away, be cooled to room temperature and obtain 100g beauty treatment emulsion matrix.
(2) hexagonal mesoporous silicon and beauty treatment emulsion matrix are composite
1) at room temperature get that 5g is not written into salicylic hexagonal mesoporous silicon and 25g dimethicone evenly mixes with agate mortar, form after homogeneous mixture, add in 100g beauty treatment emulsion matrix.
2) with dasher, under 500rpm condition, constantly stir and be cooled to room temperature, obtain the sun-proof isolation breast of beauty treatment containing hexagonal mesoporous silicon.
Obtain containing the sun-proof isolation breast of the beauty treatment of hexagonal mesoporous silicon exquisiteness, by it at the centrifugal 30min of centrifuge 2500r/min, without lamination.Be placed in respectively 55 ℃ of baking oven 12h ,-15 ℃ of refrigerator 12h, circulate one week, still stable without lamination.Be placed in 40 ℃ of baking ovens, 5 ℃ of refrigerators one month, still keep uniform and stable, without the mould phenomenon that loses.
case study on implementation 5:
To executing the prepared newborn measure of merit of the sun-proof isolation of beauty treatment containing hexagonal mesoporous silicon of case 1:
For understanding the result of use of product of the present invention, with the formal expansion investigation on probation widely of questionnaire survey, select trier 50 people, male 10 people wherein, women 40 people, at 20 ~ 48 years old age, regain 50 parts of questionnaires altogether.After clean of every day in morning, be applied to face and exposed part, once a day, smear 30 days.
According to trier's range estimation and sense learning through practice, indices and result of use self evaluation result are as follows:
1. moisten comfortable: 88% trier have moisten comfortable, soft, without the use sense of greasy feeling.
2. control oil effect: 68% trier has obvious sensation to control the effect of oily water conservation.
3. buffer action: 72% trier feel significantly isolation color make-up or extraneous effect.
4. sun-proof: 86% trier feel to have significantly sun-proof, resist ultraviolet effect.
5. safety: 100% trier is without anaphylaxis.
Same, for case study on implementation 2,3,4, also done corresponding investigation on probation, the effect evaluation result of survey result and case study on implementation 1 is without significant difference, can find out containing the sun-proof isolation of beauty treatment of hexagonal mesoporous silicon newborn to skin nonirritant, and use comfortable, moisten without greasy feeling, have good isolation anti-sunlight function.
Claims (5)
1. containing the newborn preparation method of the sun-proof isolation of beauty treatment of hexagonal mesoporous silicon, it is characterized in that, comprise the following steps:
(1) preparation beauty treatment emulsion matrix:
1) by stearic acid, glyceryl monostearate, hexadecanol, IPM, mixing, be heated to 75 ~ 85 ℃, at rotating speed, be under 200 ~ 300rpm condition, to carry out magnetic agitation dissolving, obtain A phase;
2) by glycerol, carbamide, D-panthenol, potassium hydroxide, at rotating speed, be under 150 ~ 300rpm condition, to carry out magnetic agitation mixing, be heated to 75 ~ 85 ℃, obtain B phase;
3) B is added to A mutually in, at rotating speed, be under 150 ~ 300rpm condition, to carry out magnetic agitation, be warming up to 90 ~ 95 ℃ and keep 8 ~ 10min to be cooled to again 60 ~ 65 ℃, then add deionized water, mix, with high-shear homogenizer homogenizing 10 ~ 15min under 5000 ~ 8000rpm speed;
4) remain on 60 ~ 65 ℃, under 300 ~ 500rpm condition, with dasher, stir 30 ~ 40min, while cooling to again 40 ~ 50 ℃, add vitamin E, with dasher, at rotating speed, be to stir under 300 ~ 500rpm condition, fully emulsified after, then add ethyl hydroxybenzoate, spice, continue stirring until bubble is all driven away, be cooled to room temperature and obtain the emulsion matrix of improving looks;
(2) hexagonal mesoporous silicon and beauty treatment emulsion matrix are composite:
1) at room temperature will not be written into salicylic acid or be written into salicylic hexagonal mesoporous silicon and dimethicone agate mortar mix homogeneously, forming after homogeneous mixture, adding in beauty treatment emulsion matrix;
2) at rotating speed, be with dasher, constantly to stir and be cooled to room temperature under 300 ~ 500rpm condition, obtain the sun-proof isolation breast of beauty treatment containing hexagonal mesoporous silicon.
2. a kind of newborn preparation method of the sun-proof isolation of beauty treatment containing hexagonal mesoporous silicon according to claim 1, it is characterized in that, described beauty treatment emulsion matrix comprises following quality percentage composition material: stearic acid 10 ~ 18%, glyceryl monostearate 1.5 ~ 2%, hexadecanol 1.5 ~ 3%, IPM 3 ~ 6%, vitamin e 1 ~ 2%, glycerol 6 ~ 8%, carbamide 4 ~ 7%, D-panthenol 1 ~ 2%, ethyl hydroxybenzoate 0.1 ~ 0.3%, spice 0.2 ~ 0.4%, potassium hydroxide 0.5 ~ 0.7%, deionized water 50 ~ 71.2%.
3. a kind of newborn preparation method of the sun-proof isolation of beauty treatment containing hexagonal mesoporous silicon according to claim 1, is characterized in that, described in be written into salicylic hexagonal mesoporous silicon preparation method be:
Taking salicylic acid is dissolved in dehydrated alcohol and is placed in seal glass tank, add hexagonal mesoporous silicon, put into 36 ~ 38 ℃ of shaking tables, centrifugal through deionized water wash 3 times, after being deposited in 50 ~ 70 ℃ of baking ovens of obtaining dried to 24 ~ 30h, obtain product and be put in exsiccator standby.
4. a kind of newborn preparation method of the sun-proof isolation of beauty treatment containing hexagonal mesoporous silicon according to claim 3, is characterized in that, described in step (2), the concentration of salicylic acid in dehydrated alcohol is 0.02 ~ 0.03g/mL; The mass ratio of salicylic acid and mesoporous silicon is 1.5 ~ 2.5:1.
5. a kind of newborn preparation method of the sun-proof isolation of beauty treatment containing hexagonal mesoporous silicon according to claim 1, the mass ratio of it is characterized in that improving looks emulsion matrix, hexagonal mesoporous silicon, dimethicone is 60 ~ 100:1 ~ 5:5 ~ 25.
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| CN103816084A (en) * | 2014-02-28 | 2014-05-28 | 华南理工大学 | Slow- release lotion carrier for whitening and spot removing, and preparation method thereof |
| CN103830112A (en) * | 2014-02-28 | 2014-06-04 | 华南理工大学 | Emulsion with functions of persistently moisturizing and removing wrinkles and preparation method thereof |
| CN104225600A (en) * | 2014-09-11 | 2014-12-24 | 华南理工大学 | Preparation method of wound antibacterial emulsion containing hexagonal mesoporous silica |
| CN104258456A (en) * | 2014-08-29 | 2015-01-07 | 华南理工大学 | Wound repair gel containing hexagonal mesoporous silicon and preparation method thereof |
| CN105902464A (en) * | 2016-05-20 | 2016-08-31 | 秦瑜 | Sun-blocking concealer |
| WO2017127021A1 (en) * | 2016-01-18 | 2017-07-27 | Agency For Science, Technology And Research | Hexagonal silica platelets and methods of synthesis thereof |
| CN108815065A (en) * | 2018-05-28 | 2018-11-16 | 苏州郎旭志远科技有限公司 | A kind of whitening and spot eliminating cream and preparation method thereof with lasting slow releasing function |
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| CN114557921A (en) * | 2022-02-23 | 2022-05-31 | 上海正喧品牌管理有限公司 | Multiple-oil skin softening composition, preparation method thereof, scalp nourishing and moisturizing composition and scalp anti-dandruff oil-control deodorizing composition |
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| CN103816084A (en) * | 2014-02-28 | 2014-05-28 | 华南理工大学 | Slow- release lotion carrier for whitening and spot removing, and preparation method thereof |
| CN103830112A (en) * | 2014-02-28 | 2014-06-04 | 华南理工大学 | Emulsion with functions of persistently moisturizing and removing wrinkles and preparation method thereof |
| CN103816084B (en) * | 2014-02-28 | 2015-12-09 | 华南理工大学 | A kind of whitening and speckle dispelling slow release breast carrier and preparation method thereof |
| CN104258456A (en) * | 2014-08-29 | 2015-01-07 | 华南理工大学 | Wound repair gel containing hexagonal mesoporous silicon and preparation method thereof |
| CN104258456B (en) * | 2014-08-29 | 2016-06-22 | 华南理工大学 | A kind of wound repair gel containing hexagonal mesoporous silicon and preparation method thereof |
| CN104225600A (en) * | 2014-09-11 | 2014-12-24 | 华南理工大学 | Preparation method of wound antibacterial emulsion containing hexagonal mesoporous silica |
| CN104225600B (en) * | 2014-09-11 | 2016-09-21 | 华南理工大学 | A kind of preparation method of the Wound antibiotic breast containing hexagonal mesoporous silicon |
| WO2017127021A1 (en) * | 2016-01-18 | 2017-07-27 | Agency For Science, Technology And Research | Hexagonal silica platelets and methods of synthesis thereof |
| CN105902464A (en) * | 2016-05-20 | 2016-08-31 | 秦瑜 | Sun-blocking concealer |
| CN108815065A (en) * | 2018-05-28 | 2018-11-16 | 苏州郎旭志远科技有限公司 | A kind of whitening and spot eliminating cream and preparation method thereof with lasting slow releasing function |
| CN111956506A (en) * | 2019-05-20 | 2020-11-20 | 珀莱雅化妆品股份有限公司 | Active ingredient fixed-point pressing release type skin care pad pasting |
| CN114557921A (en) * | 2022-02-23 | 2022-05-31 | 上海正喧品牌管理有限公司 | Multiple-oil skin softening composition, preparation method thereof, scalp nourishing and moisturizing composition and scalp anti-dandruff oil-control deodorizing composition |
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Effective date of registration: 20211220 Address after: 510663 No. a401, 403 and 405, zone a, Guangzhou International Business Incubator, No. 3, Juquan Road, Science City, Huangpu District, Guangzhou City, Guangdong Province Patentee after: Guangzhou Zhiyuan Biotechnology Co.,Ltd. Address before: 511458 Guangzhou Institute of industry, Huagong University, No. 25, Huanshi Avenue South, Nansha District, Guangzhou, Guangdong Patentee before: SOUTH CHINA University OF TECHNOLOGY |