CN108324678A - A kind of liquid blush for being suitable for sensitive skin crowd and using - Google Patents

A kind of liquid blush for being suitable for sensitive skin crowd and using Download PDF

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Publication number
CN108324678A
CN108324678A CN201810467310.2A CN201810467310A CN108324678A CN 108324678 A CN108324678 A CN 108324678A CN 201810467310 A CN201810467310 A CN 201810467310A CN 108324678 A CN108324678 A CN 108324678A
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China
Prior art keywords
dimethyl silicone
silicone polymer
sensitive skin
peg
poly
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Granted
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CN201810467310.2A
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Chinese (zh)
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CN108324678B (en
Inventor
杜洪良
杜建
豆刘超
郑天琪
其他发明人请求不公开姓名
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Zhejiang Yanzhuang Cosmetic Co Ltd
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Zhejiang Yanzhuang Cosmetic Co Ltd
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Priority to CN201810467310.2A priority Critical patent/CN108324678B/en
Publication of CN108324678A publication Critical patent/CN108324678A/en
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/99Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from microorganisms other than algae or fungi, e.g. protozoa or bacteria
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/345Alcohols containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/08Preparations containing skin colorants, e.g. pigments for cheeks, e.g. rouge
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/005Preparations for sensitive skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/007Preparations for dry skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/592Mixtures of compounds complementing their respective functions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/85Products or compounds obtained by fermentation, e.g. yoghurt, beer, wine

Abstract

The invention discloses a kind of liquid blushes for being suitable for sensitive skin crowd and using, using the compounding of plant extracts and biological metabolite, salubrious non-greasy, mild low-stimulation, safety is good, and sensitive skin crowd especially children can be safe to use, not in the negative effect for worrying that liquid blush is brought.

Description

A kind of liquid blush for being suitable for sensitive skin crowd and using
Technical field
The present invention relates to Cosmetic Manufacture technical field, more particularly to a kind of liquid for being suitable for sensitive skin crowd and using Blush.
Background technology
Blush is to be coated in the cosmetics for making the colour of skin ruddy on the contours of the face, has two kinds of silty and oil, cheek can be made after use The ruddy color of health is presented.Blush is the best tool modified shape of face, beautified the complexion.After use, entire face can be allowed to embody Go out a kind of U.S. of natural health.But conventional grease blush texture is not salubrious enough, and mineralogical composition and chemical synthesis raw material, gives skin Cause damage unnecessary or even allergy.Especially special skin crowd, such as crowd of easy allergic constitution.With science and technology Development, it is American-European early in 2010 to begin to seek with TaiWan, China naturally, safety, environmentally friendly product, to meet consumer to peace The demand of full product, keeps Cosmetic Market foreground more wide.
Relative to adult, the skin of children is more sensitive, and allergy is easier using blush, and therefore, the requirement to blush is more Height, but children will often perform various programs, need frequently to use blush, therefore, be badly in need of exploitation and be suitble to sensitive skin crowd, The blush that especially children use.
Invention content
The purpose of the present invention is to provide a kind of liquid blushes for being suitable for sensitive skin crowd and using, and quality is slim and graceful, clearly Refreshing non-greasy, using the compounding of plant extracts and biological metabolite, mild low-stimulation, safety is good, and sensitive skin crowd is outstanding It is that children can be safe to use, no longer worries the negative effect that blush is brought.
The technical solution adopted by the present invention to solve the technical problems is:
A kind of liquid blush for being suitable for sensitive skin crowd and using, is mixed by following component by weight percentage:It is pungent Acid/Triglyceride DDD 6.0-7.0%, mica powder 5.5-6.0%, the poly- trimethicone 4.0-5.0% of methyl, distearyl two First ammonium hectorite 0.7-0.9%, isomery dodecane 7.0-8.0%, octyl polymethyl siloxane 4.5-5.5%, diphenylmethyl Siloxy phenyl trimethicone 3.5-4.5%, Dimethicone Crosspolymer (and) polydimethylsiloxanes The poly- diformazan of alkane 3.0-4.0%, lauryl PEG-9 dimethyl silicone polymer ethyl dimethyl silicone polymer 1.0-1.4%, PEG-10 Radical siloxane 0.4-0.6%, cetyl PEG/PPG-10/1 dimethyl silicone polymer 1.0-1.4%, coconut oil 1.94- 3.88%, Tahiti cape jasmine flower extract 0.04-0.08%, vitamin E 0.08-0.1%, deionized water 30.609-38%, Sodium chloride 0.4-0.6%, glycerine 3.5-4.5%, 1,3-BDO 6.0-7.0%, propylene glycol 3.0-4.0%, bacillus hair Ferment product 0.001-0.002%, hexylene glycol 0.05-0.06%, colorant 2.29-3.29%, pearl powder 2.2-3.0%;More than The summation of component is 100%.
The effect of octyl polymethyl siloxane is moisturizing;The poly- trimethicone effect of diphenyl silicon phenyl is to adjust Manage skin;Dimethicone Crosspolymer (and) dimethyl silicone polymer effect be skin care, improve texture;Lauryl PEG-9 dimethyl silicone polymer ethyls dimethyl silicone polymer, PEG-10 Polydimethylsiloxane, cetyl PEG/PPG-10/1 Dimethyl silicone polymer is emulsifier;Sodium chloride thickening power;Pearl powder highlights.
Silicon emulsification system (lauryl PEG-9 dimethyl silicone polymer ethyls dimethyl silicone polymer, PEG-10 poly dimethyls The system of siloxanes, cetyl PEG/PPG-10/1 dimethyl silicone polymer threes composition) impart the salubrious non-greasy of product Characteristic;Fermentation of bacillus product acts on restraining and sterilizing bacteria, moisturizing;(coconut oil, Tahiti gardenia carry plant extracts of the present invention Take object) with the compounding of biofermentation product (fermentation of bacillus product), assign product moisturizing, make skin-tightening, anti-inflammatory, assist The effect of antiallergic.Color make-up is set to be combined with skin care, to realize that the product is suitable for the effect of sensitive skin.
Preferably, fermentation of bacillus product:Hexylene glycol:Coconut oil:The mass ratio of Tahiti cape jasmine flower extract= 0.1:5:194:4.Using proportioning specific in this way, product moisturizing compacts, assists anti-inflammatory and antiallergic effect good.
Preferably, the one kind or several of the colorant in iron oxide red, titanium dioxide, iron oxide yellow, iron oxide black Kind.
Preferably, preparation method is:
((1) crushes mica powder and colorant through high speed, and base-material is obtained after color development;
(2) by caprylic/capric triglyceride, the poly- trimethicone of methyl, distearyl dimethylammonium hectorite, isomery 12 Alkane, octyl polymethyl siloxane, the poly- trimethicone of diphenyl silicon phenyl, dimethyl silicone polymer cross-linked polymeric Object (and) dimethyl silicone polymer, lauryl PEG-9 dimethyl silicone polymer ethyls dimethyl silicone polymer, the poly- diformazans of PEG-10 Radical siloxane, cetyl PEG/PPG-10/1 dimethyl silicone polymers, coconut oil, Tahiti cape jasmine flower extract, vitamin E fill Point mixing obtains oil phase;
(3) by hexylene glycol and fermentation of bacillus product mixing, be then added deionized water, sodium chloride, glycerine, 1.3 butanediols, Propylene glycol mixes well to obtain water phase;
(4) oil phase is added in base-material, is uniformly dispersed to obtain dispersed phase with homogenizer;
(5) it emulsifies:Dispersed phase is added in water phase, emulsifies 8-13min;
(6) it is eventually adding pearl powder to stir evenly, obtains finished product.
Preferably, the rotating speed control of homogenizer is that 2500-3000 turns/min when emulsification.
The beneficial effects of the invention are as follows:The present invention imparts the characteristic of the salubrious non-greasy of product by silicon emulsification system;It plants The compounding of object extract and biofermentation product, so that product is had can prevent dry skin from cracking, and further restore and keep flesh The natural elasticity of skin, while anti-inflammatory can also be played the role of, antiallergic is assisted, color make-up is made to be combined with skin care, to realize that the product is suitable For the effect of sensitive skin, meets the needs of sensitive skin consumer is to cosmetic product.
Specific implementation mode
Below by specific embodiment, technical scheme of the present invention will be further explained in detail.
In the present invention, if not refering in particular to, used raw material and equipment etc. are commercially available or commonly used in the art. Method in following embodiments is unless otherwise instructed the conventional method of this field.
Coconut oil is purchased from Guangzhou Xian Ting trade Co., Ltds, and Tahiti cape jasmine flower extract is limited purchased from the celestial graceful trade in Guangzhou Company.Fermentation of bacillus product is purchased from the safe bio tech ltd in Beijing, model ADP-100 or ADP-300.
Dimethicone Crosspolymer (and) dimethyl silicone polymer (English name:DOW 9041Silicone Elastomer Blend, Dow corning 9041Sil).
Lauryl PEG-9 dimethyl silicone polymer ethyls dimethyl silicone polymer (KF-6038, Japanese SHIN-ETSU HANTOTAI), PEG-10 (ABIL EM 90 are won for dimethyl silicone polymer (FZ-2233, DOW CORNING), cetyl PEG/PPG-10/1 dimethyl silicone polymers Wound Germany)
Other raw materials are commercial product.
Embodiment:
A kind of liquid blush for being suitable for sensitive skin crowd and using, is mixed by following component, is had by weight percentage Body proportioning is shown in Table 1:
Liquid blush is made in the component of embodiment 1-3 according to the following steps:
(1) C group components are weighed and is uniformly mixed, input pulverizer crushes (1500-3000 revs/min of rotating speed, time 30- 60min), base-material is obtained after color development, it is spare;
(2) A group components are weighed, with blender, is mixed well, it is spare;
(3) B group components are weighed, with homogenizer, is mixed well, it is spare;
(4) oil phase is added in base-material, is uniformly dispersed to obtain dispersed phase with homogenizer;
(5) it emulsifies:By after mixing B groups be added dispersed phase emulsification, homogenizer rotating speed control be 2500-3000 turn/ Min, time 8-13min;
(6) pearl powder is added, stirs evenly, obtains finished product;
(7) it is packed by GMP requirements.
The liquid blush used for sensitive skin that embodiment 1-3 is prepared to gained is tested, its microorganism is detected Challenge, stability, content of beary metal, physical and chemical index etc..
Test result is as shown in table 2- tables 5.
2 Microbial Challenge test result of table
3 levels of toxic substances of table is tested
4 physical and chemical index of table
5 hygienic chemistry index of table
Microbial Challenge experimental method is with reference to USP51,52,62 tests.
Stability test refers to 50 DEG C of accelerated tests one month in -5 DEG C, 40 DEG C, 45 DEG C of accelerated tests three months, and - 5~40 DEG C of hot and cold alternations recycle one week, and UV lamp tests a week.It is unchanged after recovery room temperature, energy normal use, as judgement Standard.
Levels of toxic substances test method (lead, arsenic, mercury, cadmium) is with reference to China cosmetic 2015 editions physics and chemistry of technical specification of security Test method.
According to test result illustrated above, it can be deduced that, the embodiment of the present invention 1-3 can pass through stability test.
This formula, which is not added with essence and traditional preservatives etc., may cause the raw material of adverse reaction.The present invention is emulsified by silicon System imparts the characteristic of the salubrious non-greasy of product;The compounding of plant extracts and biofermentation product, so that product is had can prevent Only dry skin cracking, further restores and keeps the natural elasticity of skin.It can also play the role of anti-inflammatory simultaneously, assist antiallergic. Therefore the product is suitable for the crowd especially children of sensitive skin.
Sensitivity tests invites 100 subjects, sensitive skin adult 50,50 people of children that the production of the present invention is used continuously Product do not find allergic phenomena after 15 days.
In addition, the present invention can be implemented in the range of following restrictions, it is not limited to embodiment 1-3:
A kind of liquid blush for being suitable for sensitive skin crowd and using, is mixed by following component by weight percentage:It is pungent Acid/Triglyceride DDD 6.0-7.0%, mica powder 5.5-6.0%, the poly- trimethicone 4.0-5.0% of methyl, distearyl two First ammonium hectorite 0.7-0.9%, isomery dodecane 7.0-8.0%, octyl polymethyl siloxane 4.5-5.5%, diphenylmethyl Siloxy phenyl trimethicone 3.5-4.5%, Dimethicone Crosspolymer (and) polydimethylsiloxanes The poly- diformazan of alkane 3.0-4.0%, lauryl PEG-9 dimethyl silicone polymer ethyl dimethyl silicone polymer 1.0-1.4%, PEG-10 Radical siloxane 0.4-0.6%, cetyl PEG/PPG-10/1 dimethyl silicone polymer 1.0-1.4%, coconut oil 1.94- 3.88%, Tahiti cape jasmine flower extract 0.04-0.08%, vitamin E 0.08-0.1%, deionized water 30.609-38%, Sodium chloride 0.4-0.6%, glycerine 3.5-4.5%, 1,3-BDO 6.0-7.0%, propylene glycol 3.0-4.0%, bacillus hair Ferment product 0.001-0.002%, hexylene glycol 0.05-0.06%, colorant 2.29-3.29%, pearl powder 2.2-3.0%.Coloring Agent is selected from one or more of iron oxide red, titanium dioxide, iron oxide yellow, iron oxide black.
Above-mentioned embodiment is only a preferred solution of the present invention, not the present invention is made in any form Limitation, on the premise of not exceeding the technical scheme recorded in the claims also other variations and modifications.

Claims (5)

1. a kind of liquid blush for being suitable for sensitive skin crowd and using, which is characterized in that by weight percentage by with the following group Part is mixed:Caprylic/capric triglyceride 6.0-7.0%, mica powder 5.5-6.0%, the poly- trimethicone 4.0- of methyl 5.0%, distearyl dimethylammonium hectorite 0.7-0.9%, isomery dodecane 7.0-8.0%, octyl polymethyl siloxane 4.5- 5.5%, the poly- trimethicone 3.5-4.5% of diphenyl silicon phenyl, Dimethicone Crosspolymer (and) dimethyl silicone polymer 3.0-4.0%, lauryl PEG-9 dimethyl silicone polymer ethyl dimethyl silicone polymers 1.0- 1.4%, PEG-10 Polydimethylsiloxane 0.4-0.6%, cetyl PEG/PPG-10/1 dimethyl silicone polymers 1.0- 1.4%, coconut oil 1.94-3.88%, Tahiti cape jasmine flower extract 0.04-0.08%, vitamin E 0.08-0.1%, go from Sub- water 30.609-38%, sodium chloride 0.4-0.6%, glycerine 3.5-4.5%, 1,3-BDO 6.0-7.0%, propylene glycol 3.0- 4.0%, fermentation of bacillus product 0.001-0.002%, hexylene glycol 0.05-0.06%, colorant 2.29-3.29%, pearly-lustre Powder 2.2-3.0%;The summation of the above component is 100%.
2. a kind of liquid blush for being suitable for sensitive skin crowd and using according to claim 1, which is characterized in that gemma Bacillus fermentation product:Hexylene glycol:Coconut oil:Mass ratio=0.1 of Tahiti cape jasmine flower extract:5:194:4.
3. a kind of liquid blush for being suitable for sensitive skin crowd and using according to claim 1, which is characterized in that described Colorant is selected from one or more of iron oxide red, titanium dioxide, iron oxide yellow, iron oxide black.
4. a kind of liquid blush for being suitable for sensitive skin crowd and using according to claim 1, which is characterized in that prepare Method is:
(1) mica powder and colorant are crushed through high speed, base-material is obtained after color development;
(2) by caprylic/capric triglyceride, the poly- trimethicone of methyl, distearyl dimethylammonium hectorite, isomery 12 Alkane, octyl polymethyl siloxane, the poly- trimethicone of diphenyl silicon phenyl, dimethyl silicone polymer cross-linked polymeric Object (and) dimethyl silicone polymer, lauryl PEG-9 dimethyl silicone polymer ethyls dimethyl silicone polymer, the poly- diformazans of PEG-10 Radical siloxane, cetyl PEG/PPG-10/1 dimethyl silicone polymers, coconut oil, Tahiti cape jasmine flower extract, vitamin E fill Point mixing obtains oil phase;
(3) by hexylene glycol and fermentation of bacillus product mixing, be then added deionized water, sodium chloride, glycerine, 1.3 butanediols, Propylene glycol mixes well to obtain water phase;
(4) oil phase is added in base-material, is uniformly dispersed to obtain dispersed phase with homogenizer;
(5) it emulsifies:Dispersed phase is added in water phase, emulsifies 8-13min;
(6) it is eventually adding pearl powder to stir evenly, obtains finished product.
5. a kind of liquid blush for being suitable for sensitive skin crowd and using according to claim 4, which is characterized in that emulsification When homogenizer rotating speed control be 2500-3000 turn/min.
CN201810467310.2A 2018-05-16 2018-05-16 A kind of liquid blush used suitable for sensitive skin crowd Active CN108324678B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108904333A (en) * 2018-08-31 2018-11-30 广州铭泽恒基生物科技有限公司 A kind of liquid blush and preparation method thereof
CN109464305A (en) * 2019-01-04 2019-03-15 中山市美源化妆品有限公司 A kind of air cushion blush and its manufacturing method
CN115778861A (en) * 2022-12-15 2023-03-14 广州多多化妆品有限公司 Mousse blush suitable for sensitive muscle and preparation method thereof

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CN103816064A (en) * 2012-11-19 2014-05-28 天津博莱恩科技发展有限公司 Itching-relieving shampoo containing fructus gardeniae and philippine violet herb
CN104771352A (en) * 2015-04-27 2015-07-15 广州源大生物科技有限公司 Air cushion BB cream and preparation method thereof
CN105878058A (en) * 2016-06-16 2016-08-24 成都荣乐化妆品有限公司 EE cream
CN105902412A (en) * 2015-02-23 2016-08-31 株式会社爱茉莉太平洋 Cosmetic composition containing silicone oil and emolient
CN107519034A (en) * 2017-08-17 2017-12-29 成都新柯力化工科技有限公司 A kind of skin deep layer of the bioactie agent containing chelating repairs liquid and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102665650A (en) * 2009-11-27 2012-09-12 株式会社爱茉莉太平洋 Cosmetic composition stabilized higher oily part
CN103816064A (en) * 2012-11-19 2014-05-28 天津博莱恩科技发展有限公司 Itching-relieving shampoo containing fructus gardeniae and philippine violet herb
CN105902412A (en) * 2015-02-23 2016-08-31 株式会社爱茉莉太平洋 Cosmetic composition containing silicone oil and emolient
CN104771352A (en) * 2015-04-27 2015-07-15 广州源大生物科技有限公司 Air cushion BB cream and preparation method thereof
CN105878058A (en) * 2016-06-16 2016-08-24 成都荣乐化妆品有限公司 EE cream
CN107519034A (en) * 2017-08-17 2017-12-29 成都新柯力化工科技有限公司 A kind of skin deep layer of the bioactie agent containing chelating repairs liquid and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108904333A (en) * 2018-08-31 2018-11-30 广州铭泽恒基生物科技有限公司 A kind of liquid blush and preparation method thereof
CN109464305A (en) * 2019-01-04 2019-03-15 中山市美源化妆品有限公司 A kind of air cushion blush and its manufacturing method
CN115778861A (en) * 2022-12-15 2023-03-14 广州多多化妆品有限公司 Mousse blush suitable for sensitive muscle and preparation method thereof

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Inventor after: Du Hongliang

Inventor after: Du Jian

Inventor after: Dou Liuchao

Inventor after: Zheng Tianqi

Inventor after: Other inventors ask not to disclose names

Inventor before: Du Hongliang

Inventor before: Du Jian

Inventor before: Dou Liuchao

Inventor before: Zheng Tianqi

Inventor before: Other inventors ask not to disclose names