CN103502389A - 一种稀土掺杂荧光纳米粒子及其溶液的制备方法和系统 - Google Patents
一种稀土掺杂荧光纳米粒子及其溶液的制备方法和系统 Download PDFInfo
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- CN103502389A CN103502389A CN201180070655.0A CN201180070655A CN103502389A CN 103502389 A CN103502389 A CN 103502389A CN 201180070655 A CN201180070655 A CN 201180070655A CN 103502389 A CN103502389 A CN 103502389A
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- 229910052761 rare earth metal Inorganic materials 0.000 title claims abstract description 216
- 150000002910 rare earth metals Chemical class 0.000 title claims abstract description 215
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- 150000001768 cations Chemical class 0.000 claims abstract description 56
- 150000001875 compounds Chemical class 0.000 claims abstract description 52
- 239000002904 solvent Substances 0.000 claims abstract description 28
- 238000000034 method Methods 0.000 claims abstract description 27
- 238000002156 mixing Methods 0.000 claims abstract description 26
- 239000013078 crystal Substances 0.000 claims abstract description 18
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- 239000007791 liquid phase Substances 0.000 claims description 9
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- 238000001816 cooling Methods 0.000 claims description 7
- 229910052747 lanthanoid Inorganic materials 0.000 claims description 7
- 150000002602 lanthanoids Chemical class 0.000 claims description 7
- 229910052727 yttrium Inorganic materials 0.000 claims description 7
- 238000011437 continuous method Methods 0.000 claims description 5
- 229910052744 lithium Inorganic materials 0.000 claims description 5
- 229910052700 potassium Inorganic materials 0.000 claims description 5
- 229910052706 scandium Inorganic materials 0.000 claims description 5
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- 229910052771 Terbium Inorganic materials 0.000 claims description 3
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- 229910052691 Erbium Inorganic materials 0.000 claims description 2
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- 229910052782 aluminium Inorganic materials 0.000 claims description 2
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- ICAKDTKJOYSXGC-UHFFFAOYSA-K lanthanum(iii) chloride Chemical compound Cl[La](Cl)Cl ICAKDTKJOYSXGC-UHFFFAOYSA-K 0.000 description 4
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- BPIUIOXAFBGMNB-UHFFFAOYSA-N 1-hexoxyhexane Chemical class CCCCCCOCCCCCC BPIUIOXAFBGMNB-UHFFFAOYSA-N 0.000 description 3
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- 125000000217 alkyl group Chemical group 0.000 description 3
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- FUGIIBWTNARRSF-UHFFFAOYSA-N decane-5,6-diol Chemical compound CCCCC(O)C(O)CCCC FUGIIBWTNARRSF-UHFFFAOYSA-N 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 239000002019 doping agent Substances 0.000 description 2
- BOXVSFHSLKQLNZ-UHFFFAOYSA-K dysprosium(iii) chloride Chemical compound Cl[Dy](Cl)Cl BOXVSFHSLKQLNZ-UHFFFAOYSA-K 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000000695 excitation spectrum Methods 0.000 description 2
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- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 2
- 238000004128 high performance liquid chromatography Methods 0.000 description 2
- CBFCDTFDPHXCNY-UHFFFAOYSA-N icosane Chemical compound CCCCCCCCCCCCCCCCCCCC CBFCDTFDPHXCNY-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- DIAIBWNEUYXDNL-UHFFFAOYSA-N n,n-dihexylhexan-1-amine Chemical class CCCCCCN(CCCCCC)CCCCCC DIAIBWNEUYXDNL-UHFFFAOYSA-N 0.000 description 2
- PXSXRABJBXYMFT-UHFFFAOYSA-N n-hexylhexan-1-amine Chemical compound CCCCCCNCCCCCC PXSXRABJBXYMFT-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
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- 239000004065 semiconductor Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 230000002459 sustained effect Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 description 2
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical group CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 2
- WVPGXJOLGGFBCR-UHFFFAOYSA-N trioctyl phosphate Chemical class CCCCCCCCOP(=O)(OCCCCCCCC)OCCCCCCCC WVPGXJOLGGFBCR-UHFFFAOYSA-N 0.000 description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 2
- 229910000164 yttrium(III) phosphate Inorganic materials 0.000 description 2
- GKQBSTJUOVBUDX-UHFFFAOYSA-N 1-(2,3-dimethylphenoxy)-2,3-dimethylbenzene Chemical compound CC1=CC=CC(OC=2C(=C(C)C=CC=2)C)=C1C GKQBSTJUOVBUDX-UHFFFAOYSA-N 0.000 description 1
- MNZAKDODWSQONA-UHFFFAOYSA-N 1-dibutylphosphorylbutane Chemical compound CCCCP(=O)(CCCC)CCCC MNZAKDODWSQONA-UHFFFAOYSA-N 0.000 description 1
- PPDZLUVUQQGIOJ-UHFFFAOYSA-N 1-dihexylphosphorylhexane Chemical compound CCCCCCP(=O)(CCCCCC)CCCCCC PPDZLUVUQQGIOJ-UHFFFAOYSA-N 0.000 description 1
- SNZSAFILJOCMFM-UHFFFAOYSA-N 1-dipropylphosphorylpropane Chemical compound CCCP(=O)(CCC)CCC SNZSAFILJOCMFM-UHFFFAOYSA-N 0.000 description 1
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 description 1
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- KFDATXAEMFCUSA-UHFFFAOYSA-N CCC(C)[PH2]=O Chemical class CCC(C)[PH2]=O KFDATXAEMFCUSA-UHFFFAOYSA-N 0.000 description 1
- 229910004664 Cerium(III) chloride Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910017665 NH4HF2 Inorganic materials 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- DTQVDTLACAAQTR-UHFFFAOYSA-M Trifluoroacetate Chemical compound [O-]C(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-M 0.000 description 1
- FYAMXEPQQLNQDM-UHFFFAOYSA-N Tris(1-aziridinyl)phosphine oxide Chemical compound C1CN1P(N1CC1)(=O)N1CC1 FYAMXEPQQLNQDM-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- LDDQLRUQCUTJBB-UHFFFAOYSA-N ammonium fluoride Chemical compound [NH4+].[F-] LDDQLRUQCUTJBB-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- IQTYZHQJHQBLPZ-UHFFFAOYSA-N butan-2-ylphosphane Chemical class CCC(C)P IQTYZHQJHQBLPZ-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- VYLVYHXQOHJDJL-UHFFFAOYSA-K cerium trichloride Chemical compound Cl[Ce](Cl)Cl VYLVYHXQOHJDJL-UHFFFAOYSA-K 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- VQCBHWLJZDBHOS-UHFFFAOYSA-N erbium(III) oxide Inorganic materials O=[Er]O[Er]=O VQCBHWLJZDBHOS-UHFFFAOYSA-N 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000003682 fluorination reaction Methods 0.000 description 1
- PHNWGDTYCJFUGZ-UHFFFAOYSA-N hexyl dihydrogen phosphate Chemical compound CCCCCCOP(O)(O)=O PHNWGDTYCJFUGZ-UHFFFAOYSA-N 0.000 description 1
- CHXARDKIHSVFDK-UHFFFAOYSA-N hexylphosphane Chemical class CCCCCCP CHXARDKIHSVFDK-UHFFFAOYSA-N 0.000 description 1
- DKAGJZJALZXOOV-UHFFFAOYSA-N hydrate;hydrochloride Chemical compound O.Cl DKAGJZJALZXOOV-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- CMZUMMUJMWNLFH-UHFFFAOYSA-N sodium metavanadate Chemical compound [Na+].[O-][V](=O)=O CMZUMMUJMWNLFH-UHFFFAOYSA-N 0.000 description 1
- UYCAUPASBSROMS-UHFFFAOYSA-M sodium;2,2,2-trifluoroacetate Chemical class [Na+].[O-]C(=O)C(F)(F)F UYCAUPASBSROMS-UHFFFAOYSA-M 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- GFISHBQNVWAVFU-UHFFFAOYSA-K terbium(iii) chloride Chemical compound Cl[Tb](Cl)Cl GFISHBQNVWAVFU-UHFFFAOYSA-K 0.000 description 1
- MDDUHVRJJAFRAU-YZNNVMRBSA-N tert-butyl-[(1r,3s,5z)-3-[tert-butyl(dimethyl)silyl]oxy-5-(2-diphenylphosphorylethylidene)-4-methylidenecyclohexyl]oxy-dimethylsilane Chemical compound C1[C@@H](O[Si](C)(C)C(C)(C)C)C[C@H](O[Si](C)(C)C(C)(C)C)C(=C)\C1=C/CP(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 MDDUHVRJJAFRAU-YZNNVMRBSA-N 0.000 description 1
- TUQOTMZNTHZOKS-UHFFFAOYSA-N tributylphosphine Chemical compound CCCCP(CCCC)CCCC TUQOTMZNTHZOKS-UHFFFAOYSA-N 0.000 description 1
- RXJKFRMDXUJTEX-UHFFFAOYSA-N triethylphosphine Chemical compound CCP(CC)CC RXJKFRMDXUJTEX-UHFFFAOYSA-N 0.000 description 1
- RMZAYIKUYWXQPB-UHFFFAOYSA-N trioctylphosphane Chemical compound CCCCCCCCP(CCCCCCCC)CCCCCCCC RMZAYIKUYWXQPB-UHFFFAOYSA-N 0.000 description 1
- KCTAHLRCZMOTKM-UHFFFAOYSA-N tripropylphosphane Chemical compound CCCP(CCC)CCC KCTAHLRCZMOTKM-UHFFFAOYSA-N 0.000 description 1
- 238000000870 ultraviolet spectroscopy Methods 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- FIXNOXLJNSSSLJ-UHFFFAOYSA-N ytterbium(III) oxide Inorganic materials O=[Yb]O[Yb]=O FIXNOXLJNSSSLJ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
- C09K11/7766—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing two or more rare earth metals
- C09K11/7777—Phosphates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F17/00—Compounds of rare earth metals
- C01F17/30—Compounds containing rare earth metals and at least one element other than a rare earth metal, oxygen or hydrogen, e.g. La4S3Br6
- C01F17/36—Compounds containing rare earth metals and at least one element other than a rare earth metal, oxygen or hydrogen, e.g. La4S3Br6 halogen being the only anion, e.g. NaYF4
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
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Abstract
Description
Claims (11)
- 权利要求书1. 一种连续制备稀土掺杂荧光纳米粒子溶液的方法, 包括以下步骤: 混合阳离子源化合物、阴离子源化合物和至少一种用于控制所述稀土掺杂 荧光纳米粒子晶体生长的溶剂, 形成一个混合溶液, 和使所述混合溶液在一个微反应器中在一个预设定温度停留一预设定时间, 得到所述稀土掺杂荧光纳米粒子溶液, 其中, 所述微反应器包括一个微混合装 置和一个微换热装置, 所述微混合装置用于持续混合所述混合溶液, 所述微换 热装置用于调节所述微反应器的温度至所述预设定温度。
- 2. 如权利要求 1 所述的制备方法, 进一步包括步骤: 控制所述微反应器 压力, 使所述稀土掺杂荧光纳米粒子溶液维持液相。
- 3. 如权利要求 1或 2所述的制备方法, 其中, 所述稀土掺杂荧光纳米粒 子选自下面的一种:LnPO4: Ce: W、LnPO4: Eu、LnVO4: Ce: W、LnVO4: Eu、Ln(VO4)x(PO4)y: B (x+y=l , 其中, 0≤x≤l)、AYF4: G、AYC14: G、AYBr4: G、NaQF4: Yb: B、NaQCl4: Yb: B、NaQBr4: Yb: B、LnBO3: Ce : W、LnBO3: Eu、(YGd)BO3: Eu、DSO4: B、DSO4: Mn、 和Zn2(SiO4): Mn;其中, Ln代表镧系元素、 Y或 Sc; D代表 Ba、 Sr或 Ca; E代表 Cu、 Ag、 Eu、 Bi、 Al或 Au ; G代表 Pr、 Tm、 Er、 Yb或 Ho; Q代表 Gd、 Y、 Li 或 K; W代表 Tb或 Dy; A选自下面的一种或多种 Li、 Na、 K、 Rb、 Mgo.5、 Bao.5、 Cao.5和 SrQ.5; B代表镧系元素。
- 4. 如权利要求 1或 2所述的制备方法, 其中, 所述微反应器的预设定温 度是 200°C以上。
- 5. 如权利要求 1或 2所述的制备方法, 其中, 所述微反应器的预设定停 留时间是 30s〜 7200s。
- 6. 如权利要求 1或 2所述的制备方法, 其中, 所述微反应器前端安装至 少一个前置微换热器, 所述前置微换热器用于加热所述混合溶液。
- 7. 如权利要求 1或 2所述的制备方法, 其中, 所述微反应器后端安装至 少一个后置微换热器,所述后置微换热器用于冷却所述稀土掺杂荧光纳米粒子 溶液。
- 8. 如权利要求 1或 2所述的制备方法, 其中, 所述混合溶液包含水, 以 得到棒状的稀土掺杂荧光纳米粒子, 所述水来自阳离子源化合物或直接加入。
- 9. 一种连续制备稀土掺杂荧光纳米粒子的方法, 包括以下步骤: 将权利要求 1-8 中任意一种方法制备的稀土掺杂荧光纳米粒子溶液与一 极性溶剂混合形成一悬浮液; 和分离所述悬浮液得到所述稀土掺杂荧光纳米粒子。
- 10. 一种连续制备稀土惨杂荧光纳米粒子溶液的系统, 所述系统包括: 一个混合器, 用于将阳离子源化合物、 阴离子源化合物和至少一种用于控 制所述稀土掺杂荧光纳米粒子晶体生长的溶剂混合形成一个混合溶液,一个前置微换热器, 用于加热所述混合溶液,至少一个微反应器,用于使所述混合溶液在一个预设定温度停留一预设定 时间, 得到所述稀土惨杂荧光纳米粒子溶液, 其中, 所述微反应器包括一个微 混合装置和一个微换热装置, 所述微混合装置用于持续混合所述混合溶液, 所 述微换热装置用于调节所述微反应器的温度至所述预设定温度,一个后置微换热器, 用于冷却所述稀土掺杂荧光纳米粒子溶液, 和 一个压力控制器, 用于控制所述系统的压力, 使所述混合溶液和所述稀土 掺杂荧光纳米粒子溶液维持液相。
- 11. 一种连续制备稀土掺杂荧光纳米粒子的系统, 所述系统包括: 一个混合器, 用于将阳离子源化合物、 阴离子源化合物和至少一种用于 控制所述稀土掺杂荧光纳米粒子晶体生长的溶剂混合形成一个混合溶液, 一个前置微换热器, 用于加热所述混合溶液,至少一个微反应器,用于使所述混合溶液在一个预设定温度停留一预设定 时间, 得到一稀土掺杂荧光纳米粒子溶液, 其中, 所述微反应器包括一个微混 合装置和一个微换热装置, 所述微混合装置用于持续混合所述混合溶液, 所述 微换热装置用于调节所述微反应器的温度至所述预设定温度,一个后置微换热器, 用于冷却所述稀土掺杂荧光纳米粒子溶液, 一个压力控制器, 用于控制所述系统的压力, 使所述混合溶液和所述稀土 掺杂荧光纳米粒子溶液维持液相,一个混合装置,用于将所述稀土掺杂荧光纳米粒子溶液与一极性溶剂混合 形成一悬浮液, 和一个分离装置, 用于分离所述悬浮液, 得到所述稀土惨杂荧光纳米粒子。
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CN115433577A (zh) * | 2022-05-07 | 2022-12-06 | 广西大学 | 一种稀土掺杂含氧酸盐纳米晶荧光粉的制备方法 |
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US9982190B2 (en) * | 2015-02-20 | 2018-05-29 | General Electric Company | Color stable red-emitting phosphors |
CN108893117A (zh) * | 2018-09-20 | 2018-11-27 | 南京工业大学 | 一种铈激活的卤磷酸盐荧光粉及其制备工艺 |
CN109385278A (zh) * | 2018-11-06 | 2019-02-26 | 清华大学 | 一种连续合成稀土上转换发光纳米材料的微反应系统 |
CN110726705B (zh) * | 2019-10-25 | 2022-07-22 | 大连民族大学 | 一种基于贵金属/半导体调控的发光薄膜基底的荧光染料检测方法 |
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US20100019201A1 (en) * | 2006-07-13 | 2010-01-28 | H. C. Starck Gmbh | Hydrothermal process for producing nanosize to microsize particles |
CN101589181A (zh) * | 2006-11-21 | 2009-11-25 | 拜尔技术服务有限责任公司 | 用于合成含纳米级金属的纳米颗粒和纳米颗粒分散体的方法 |
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CN115433577A (zh) * | 2022-05-07 | 2022-12-06 | 广西大学 | 一种稀土掺杂含氧酸盐纳米晶荧光粉的制备方法 |
CN115433577B (zh) * | 2022-05-07 | 2023-08-04 | 广西大学 | 一种稀土掺杂含氧酸盐纳米晶荧光粉的制备方法 |
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