CN103461715A - Aquatic feed utilizing nano-carrier material as auxiliary material and preparing method for aquatic feed - Google Patents

Aquatic feed utilizing nano-carrier material as auxiliary material and preparing method for aquatic feed Download PDF

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CN103461715A
CN103461715A CN2013104476830A CN201310447683A CN103461715A CN 103461715 A CN103461715 A CN 103461715A CN 2013104476830 A CN2013104476830 A CN 2013104476830A CN 201310447683 A CN201310447683 A CN 201310447683A CN 103461715 A CN103461715 A CN 103461715A
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chinese herbal
aquatic feed
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CN103461715B (en
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沈建明
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Suzhou Yangcheng Lake Modern Agriculture Industrial Park Special Aquaculture Co Ltd
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Suzhou Yangcheng Lake Modern Agriculture Industrial Park Special Aquaculture Co Ltd
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Abstract

The invention discloses aquatic feed utilizing a nano-carrier material as an auxiliary material and a preparing method for the aquatic feed. The sterilized aquaculture fertilizer comprises urea, potassium phosphate, ammonium phosphate, rice bran, probiotics and a Chinese herbal medicine additive. The preparing method for the aquaculture fertilizer comprises the first step of weighing Chinese herbal medicines according to the quantity of a formula, adding water and extracting 1 to 3 times to produce a Chinese herbal medicine extracting solution and carrying out spray-drying after concentration to produce the Chinese herbal medicine additive for standby application later, the second step of weighing the urea, the potassium phosphate, the ammonium phosphate, the rice bran, the probiotics and the Chinese herbal medicine additive according to weight fraction to be stirred and mixed, conveying the raw materials to a fermentation pond to be fermented to obtain the feed. Chinese herbal medicine particles which have the sterilizing effect are added, the functions of all components can be fully achieved through fermentation, the aquatic feed can play a role quickly when applied to water, the action time is long, and the aquatic feed is friendly to the environment and has the effect of sterilization. In addition, the aquatic feed is reasonable in formula, and the preparing method is simple.

Description

A kind of nano carrier material that utilizes is as aquatic feeds of auxiliary material and preparation method thereof
technical field:
The present invention relates to a kind of fertilizer and preparation method thereof, be specifically related to a kind of nano carrier material that utilizes as aquatic feeds of auxiliary material and preparation method thereof.
background technology:
Fish disease is in water body, particularly the main cause of small-size water surface cultured fishes mortality.In several main raising fish of China, the quantity dead because of disease is also very large, if do not employ prevention accordingly and the treatment measure, the death rate can reach 30-40%, when serious, can arrive more than 80%, has affected widely the raising of unit are fish crop.
Due to high-density breeding, throw the frequency of feeding and increase, and the problem such as water pollution occurs, the various epidemic disease probabilities of infection of marine fishes raise greatly, to aquaculture, have caused huge loss.
Although can by reducing density culture or clean up the pond etc., method solves, but also can reach the bacterium that reduces pond by add sterilization component in aquaculture fertilizer, thereby reduce the various fungal diseases of infection of marine fishes, improve raiser's economic benefit.
summary of the invention:
The object of the invention is to overcome the deficiencies in the prior art, a kind of rapid-action, action time of lasting, environmental protection is provided and has aquaculture fertilizer of bactericidal effect and preparation method thereof.
To achieve these goals, technical scheme of the present invention is as follows:
A kind of aquatic feeds of nano carrier material as auxiliary material that utilize, it is characterized in that, in parts by weight, raw material consists of urea 20-30 part, potassium phosphate 10-15 part, ammonium phosphate 16-23 part, rice bran 40-50 part, lactic acid bacteria 5-15 part, Bifidobacterium 1-5 part, lactobacillus acidophilus 5-13 part, actinomyces 7-15 part and saccharomycete 16-22 part, Pinus massoniana 5-15 part, China tree 12-24 part, garlic 20-30 part, pumpkin 16-27 part, Chinese tallowtree leaf 6-13 part, kuh-seng 10-20 part, Chinese gall 15-26 part, wolf's milk 1-5 part, cordate houttuynia 20-30 part and tarragon 18-26 part, nano controlled-release carrier 20-25 part,
The preparation method of described nano controlled-release carrier is:
(1) silicon hydroxyapatite, concave convex rod, hydrotalcite, imvite, titanium dioxide, calcite, kaolin are mixed according to the mass fraction proportioning of 35-45:10-15: 10-15:8-10:8-10:7-8:5-7, join in the mixed solution of 230 parts of methyl-sulfoxides (DMSO) and 50 parts of methyl alcohol, in 65 ℃, stir 60 hours, filter, and wash and remove excessive methyl-sulfoxide (DMSO) for 3 times with the hot ethanol of 60 ℃ of temperature, put into vacuum drying chamber, dry 24 hours of 60 ℃ of temperature, grinding is sieved, and obtains modified composite one time;
(2) 1 part of modified composite, 15 parts of potassium acetates and 25 parts of distilled water are mixed, in temperature 50 C, stir more than 10 hours, in 30 ℃ of temperature, first under ultrasonic electric power 350W condition, disperse 3.5 hours, and then disperse 4 hours under ultrasonic electric power 250W condition.Filter, and wash 3 times with distillation, 80 ℃ of vacuum drying 24 hours, grinding is sieved, and obtains twice-modified compound; (3) above-mentioned 1 part of twice-modified compound is disperseed to 60min at the 600W power ultrasonic, with constant temperature heating device, be heated to 90 ℃, and stir (1200r/min) 60 minutes with mechanical agitator; Obtain the nano controlled-release carrier.
Described sterilization aquaculture fertilizer, it is characterized in that, in parts by weight, 20 parts, urea, 15 parts of potassium phosphates, 23 parts, ammonium phosphate, 40 parts, rice bran, 5 parts of lactic acid bacterias, 1 part of Bifidobacterium, 5 parts of lactobacillus acidophilus, 7 parts, actinomyces and 16 parts, saccharomycete, 5 parts of Pinus massonianas, 12 parts of China trees, 20 parts, garlic, 16 parts of pumpkin, 6 parts of Chinese tallowtree leafs, 10 parts of kuh-sengs, 15 parts, Chinese gall, 1 part of wolf's milk, 20 parts of cordate houttuynias and 18 parts of tarragons, 20 parts, nano controlled-release carrier.
Described sterilization aquaculture fertilizer, it is characterized in that 30 parts, urea, 10 parts of monopotassium phosphates, 16 parts, ammonium phosphate, 50 parts, rice bran, 15 parts of lactic acid bacterias, 5 parts of Bifidobacteriums, 13 parts of lactobacillus acidophilus, 15 parts, actinomyces and 22 parts, saccharomycete, 15 parts of Pinus massonianas, 24 parts of China trees, 30 parts, garlic, 27 parts of pumpkin, 13 parts of Chinese tallowtree leafs, 20 parts of kuh-sengs, 26 parts, Chinese gall, 5 parts of wolf's milks, 30 parts of cordate houttuynias and 26 parts of tarragons, 25 parts, nano controlled-release carrier.
The preparation method of described sterilization aquaculture fertilizer, is characterized in that, comprises following step:
(A) take each herbal component by Pinus massoniana 5-15 part, China tree 12-24 part, garlic 20-30 part, pumpkin 16-27 part, Chinese tallowtree leaf 6-13 part, kuh-seng 10-20 part, Chinese gall 15-26 part, wolf's milk 1-5 part, cordate houttuynia 20-30 part and tarragon 18-26 part, the water that adds 3 times of raw material weights after pulverizing, be 80 ℃ in temperature and extract 1-3h, extract 2 times, obtain extracts of Chinese herbal medicine, after concentrated, spray-drying obtains Chinese herb feed additive, standby;
(B) urea 20-30 part, potassium phosphate 10-15 part, ammonium phosphate 16-23 part, rice bran 40-50 part, probio 0.5-1.5 part and Chinese herb feed additive 1-3 part are mixed, then raw material is sent in fermentation vat, the water that adds raw material gross weight 50%, add again dry ferment, aspergillus and bacillus to be fermented, the addition of dry ferment, aspergillus and bacillus is respectively 1-2%, 1.5-2% and the 2.5-3% of raw material gross weight, 23-27 ℃ of bottom fermentation 8 days, obtain filter residue after filtration;
(C) filter residue obtained in step (B) is carried out to freeze drying, add the granulation of described nano controlled-release carrier 20-25 part after pulverizing, can obtain the fertilizer finished product.
Beneficial effect of the present invention is as follows:
The present invention has added the Chinese herbal medicine particle with bactericidal effect, by fermentation, makes the effect of various compositions be fully played, and is applied to that water body is rapid-action, action time is lasting, environmental protection and have bactericidal effect; In addition, the present invention fills a prescription rationally, and the preparation method is simple.Added the Chinese herbal medicine with the sick function of anti parasitic in feed, the parasite disease that can fundamentally prevent and treat, through actual verification, the present invention can reduce the generation of parasite disease and reduce the quantity that infects parasitic disease.Utilize hydroxyapatite etc. itself to there is the character of loose structure, fertilizer components is adsorbed in the inner mesh of carrier, reach the purpose of slow release.Hydroxyapatite also has biodegradable characteristic, and the gained catabolite is the various trace elements ion, and these elements can be absorbed again.The nano controlled-release additive has good biocompatibility, gastrointestinal tract mucous compatibility, each component that makes it load has controlled-release function, through twice-modified nano-complex medicine carrying amount and adsorbance, all improve a lot, the fertilizer efficiency time lengthening is more than 3 months, effectively suppress the increment of animal pathogen, improve the producer's benefit.
the specific embodiment:
For technological means, creation characteristic that the present invention is realized, reach purpose and effect is easy to understand, below in conjunction with embodiment, further set forth the present invention.
Embodiment 1:
In the present embodiment, a kind of aquatic feeds of nano carrier material as auxiliary material that utilize, it is characterized in that, in parts by weight, raw material consists of urea 20-30 part, potassium phosphate 10-15 part, ammonium phosphate 16-23 part, rice bran 40-50 part, lactic acid bacteria 5-15 part, Bifidobacterium 1-5 part, lactobacillus acidophilus 5-13 part, actinomyces 7-15 part and saccharomycete 16-22 part, Pinus massoniana 5-15 part, China tree 12-24 part, garlic 20-30 part, pumpkin 16-27 part, Chinese tallowtree leaf 6-13 part, kuh-seng 10-20 part, Chinese gall 15-26 part, wolf's milk 1-5 part, cordate houttuynia 20-30 part and tarragon 18-26 part, nano controlled-release carrier 20-25 part,
The preparation method of described nano controlled-release carrier is:
(1) silicon hydroxyapatite, concave convex rod, hydrotalcite, imvite, titanium dioxide, calcite, kaolin are mixed according to the mass fraction proportioning of 35-45:10-15: 10-15:8-10:8-10:7-8:5-7, join in the mixed solution of 230 parts of methyl-sulfoxides (DMSO) and 50 parts of methyl alcohol, in 65 ℃, stir 60 hours, filter, and wash and remove excessive methyl-sulfoxide (DMSO) for 3 times with the hot ethanol of 60 ℃ of temperature, put into vacuum drying chamber, dry 24 hours of 60 ℃ of temperature, grinding is sieved, and obtains modified composite one time;
(2) 1 part of modified composite, 15 parts of potassium acetates and 25 parts of distilled water are mixed, in temperature 50 C, stir more than 10 hours, in 30 ℃ of temperature, first under ultrasonic electric power 350W condition, disperse 3.5 hours, and then disperse 4 hours under ultrasonic electric power 250W condition.Filter, and wash 3 times with distillation, 80 ℃ of vacuum drying 24 hours, grinding is sieved, and obtains twice-modified compound; (3) above-mentioned 1 part of twice-modified compound is disperseed to 60min at the 600W power ultrasonic, with constant temperature heating device, be heated to 90 ℃, and stir (1200r/min) 60 minutes with mechanical agitator; Obtain the nano controlled-release carrier.
Described sterilization aquaculture fertilizer, it is characterized in that, in parts by weight, 20 parts, urea, 15 parts of potassium phosphates, 23 parts, ammonium phosphate, 40 parts, rice bran, 5 parts of lactic acid bacterias, 1 part of Bifidobacterium, 5 parts of lactobacillus acidophilus, 7 parts, actinomyces and 16 parts, saccharomycete, 5 parts of Pinus massonianas, 12 parts of China trees, 20 parts, garlic, 16 parts of pumpkin, 6 parts of Chinese tallowtree leafs, 10 parts of kuh-sengs, 15 parts, Chinese gall, 1 part of wolf's milk, 20 parts of cordate houttuynias and 18 parts of tarragons, 20 parts, nano controlled-release carrier.
Described sterilization aquaculture fertilizer, it is characterized in that 30 parts, urea, 10 parts of monopotassium phosphates, 16 parts, ammonium phosphate, 50 parts, rice bran, 15 parts of lactic acid bacterias, 5 parts of Bifidobacteriums, 13 parts of lactobacillus acidophilus, 15 parts, actinomyces and 22 parts, saccharomycete, 15 parts of Pinus massonianas, 24 parts of China trees, 30 parts, garlic, 27 parts of pumpkin, 13 parts of Chinese tallowtree leafs, 20 parts of kuh-sengs, 26 parts, Chinese gall, 5 parts of wolf's milks, 30 parts of cordate houttuynias and 26 parts of tarragons, 25 parts, nano controlled-release carrier.
The preparation method of described sterilization aquaculture fertilizer, is characterized in that, comprises following step:
(A) take each herbal component by Pinus massoniana 5-15 part, China tree 12-24 part, garlic 20-30 part, pumpkin 16-27 part, Chinese tallowtree leaf 6-13 part, kuh-seng 10-20 part, Chinese gall 15-26 part, wolf's milk 1-5 part, cordate houttuynia 20-30 part and tarragon 18-26 part, the water that adds 3 times of raw material weights after pulverizing, be 80 ℃ in temperature and extract 1-3h, extract 2 times, obtain extracts of Chinese herbal medicine, after concentrated, spray-drying obtains Chinese herb feed additive, standby;
(B) urea 20-30 part, potassium phosphate 10-15 part, ammonium phosphate 16-23 part, rice bran 40-50 part, probio 0.5-1.5 part and Chinese herb feed additive 1-3 part are mixed, then raw material is sent in fermentation vat, the water that adds raw material gross weight 50%, add again dry ferment, aspergillus and bacillus to be fermented, the addition of dry ferment, aspergillus and bacillus is respectively 1-2%, 1.5-2% and the 2.5-3% of raw material gross weight, 23-27 ℃ of bottom fermentation 8 days, obtain filter residue after filtration;
(C) filter residue obtained in step (B) is carried out to freeze drying, add the granulation of described nano controlled-release carrier 20-25 part after pulverizing, can obtain the fertilizer finished product.
Beneficial effect of the present invention is as follows:
The present invention has added the Chinese herbal medicine particle with bactericidal effect, by fermentation, makes the effect of various compositions be fully played, and is applied to that water body is rapid-action, action time is lasting, environmental protection and have bactericidal effect; In addition, the present invention fills a prescription rationally, and the preparation method is simple.Through actual verification, product of the present invention is rapid-action, and action time is lasting, harmless environmental protection.
Above demonstration and described basic principle of the present invention and principal character and advantage of the present invention.The technical staff of the industry should understand; the present invention is not restricted to the described embodiments; that in above-described embodiment and specification, describes just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.The claimed scope of the present invention is defined by appending claims and equivalent thereof
Figure 2013104476830100002DEST_PATH_IMAGE001
Figure 855953DEST_PATH_IMAGE001
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.

Claims (5)

1. one kind is utilized the aquatic feeds of nano carrier material as auxiliary material, it is characterized in that, in parts by weight, raw material consists of urea 20-30 part, potassium phosphate 10-15 part, ammonium phosphate 16-23 part, rice bran 40-50 part, lactic acid bacteria 5-15 part, Bifidobacterium 1-5 part, lactobacillus acidophilus 5-13 part, actinomyces 7-15 part and saccharomycete 16-22 part, Pinus massoniana 5-15 part, China tree 12-24 part, garlic 20-30 part, pumpkin 16-27 part, Chinese tallowtree leaf 6-13 part, kuh-seng 10-20 part, Chinese gall 15-26 part, nano controlled-release carrier 20-25 part;
The preparation method of described nano controlled-release carrier is:
(1) silicon hydroxyapatite, concave convex rod, hydrotalcite, imvite, titanium dioxide, calcite, kaolin are mixed according to the mass fraction proportioning of 35-45:10-15: 10-15:8-10:8-10:7-8:5-7, join in the mixed solution of 230 parts of methyl-sulfoxides (DMSO) and 50 parts of methyl alcohol, in 65 ℃, stir 60 hours, filter, and wash and remove excessive methyl-sulfoxide (DMSO) for 3 times with the hot ethanol of 60 ℃ of temperature, put into vacuum drying chamber, dry 24 hours of 60 ℃ of temperature, grinding is sieved, and obtains modified composite one time;
(2) 1 part of modified composite, 15 parts of potassium acetates and 25 parts of distilled water are mixed, in temperature 50 C, stir more than 10 hours, in 30 ℃ of temperature, first under ultrasonic electric power 350W condition, disperse 3.5 hours, and then disperse 4 hours under ultrasonic electric power 250W condition.
2. filter, and wash 3 times with distillation, 80 ℃ of vacuum drying 24 hours, grinding is sieved, and obtains twice-modified compound; (3) above-mentioned 1 part of twice-modified compound is disperseed to 60min at the 600W power ultrasonic, with constant temperature heating device, be heated to 90 ℃, and stir (1200r/min) 60 minutes with mechanical agitator; Obtain the nano controlled-release carrier.
3. aquaculture fertilizer according to claim 1, it is characterized in that, in parts by weight, 20 parts, urea, 15 parts of potassium phosphates, 23 parts, ammonium phosphate, 40 parts, rice bran, 5 parts of lactic acid bacterias, 1 part of Bifidobacterium, 5 parts of lactobacillus acidophilus, 7 parts, actinomyces and 16 parts, saccharomycete, 5 parts of Pinus massonianas, 12 parts of China trees, 20 parts, garlic, 16 parts of pumpkin, 6 parts of Chinese tallowtree leafs, 10 parts of kuh-sengs, 15 parts, Chinese gall, 1 part of wolf's milk, 20 parts of cordate houttuynias and 18 parts of tarragons, 20 parts, nano controlled-release carrier.
4. aquaculture fertilizer according to claim 1, it is characterized in that 30 parts, urea, 10 parts of monopotassium phosphates, 16 parts, ammonium phosphate, 50 parts, rice bran, 15 parts of lactic acid bacterias, 5 parts of Bifidobacteriums, 13 parts of lactobacillus acidophilus, 15 parts, actinomyces and 22 parts, saccharomycete, 15 parts of Pinus massonianas, 24 parts of China trees, 30 parts, garlic, 27 parts of pumpkin, 13 parts of Chinese tallowtree leafs, 20 parts of kuh-sengs, 26 parts, Chinese gall, 5 parts of wolf's milks, 30 parts of cordate houttuynias and 26 parts of tarragons, 25 parts, nano controlled-release carrier.
5. the preparation method of aquaculture fertilizer according to claim 1, is characterized in that, comprises following step:
(A) take each herbal component by Pinus massoniana 5-15 part, China tree 12-24 part, garlic 20-30 part, pumpkin 16-27 part, Chinese tallowtree leaf 6-13 part, kuh-seng 10-20 part, Chinese gall 15-26 part, wolf's milk 1-5 part, cordate houttuynia 20-30 part and tarragon 18-26 part, the water that adds 3 times of raw material weights after pulverizing, be 80 ℃ in temperature and extract 1-3h, extract 2 times, obtain extracts of Chinese herbal medicine, after concentrated, spray-drying obtains Chinese herb feed additive, standby;
(B) urea 20-30 part, potassium phosphate 10-15 part, ammonium phosphate 16-23 part, rice bran 40-50 part, probio 0.5-1.5 part and Chinese herb feed additive 1-3 part are mixed, then raw material is sent in fermentation vat, the water that adds raw material gross weight 50%, add again dry ferment, aspergillus and bacillus to be fermented, the addition of dry ferment, aspergillus and bacillus is respectively 1-2%, 1.5-2% and the 2.5-3% of raw material gross weight, 23-27 ℃ of bottom fermentation 8 days, obtain filter residue after filtration;
(C) filter residue obtained in step (B) is carried out to freeze drying, granulate after mixing with the nano controlled-release carrier of described umber after pulverizing, can obtain the fertilizer finished product.
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CN106490401A (en) * 2016-10-28 2017-03-15 普定鑫缘种养殖专业合作社 A kind of fish meal and preparation method thereof
CN106616058A (en) * 2016-12-30 2017-05-10 定远县仓镇恒润养殖专业合作社 Feed for enhancing immunity of lobsters
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CN107912363A (en) * 2017-11-24 2018-04-17 桂林满梓玉农业开发有限公司 A kind of disease-resistant cultural method of the emerald green duck of dragon victory
CN108719586A (en) * 2018-05-11 2018-11-02 宿松县龙源水产养殖专业合作社 A kind of improvement loach seedling constitution growth-promoting feed
CN114568586A (en) * 2022-03-14 2022-06-03 青岛品品好食品发展有限公司 Recycling method process of slag generated by refining oil

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Publication number Priority date Publication date Assignee Title
CN106490401A (en) * 2016-10-28 2017-03-15 普定鑫缘种养殖专业合作社 A kind of fish meal and preparation method thereof
CN106616058A (en) * 2016-12-30 2017-05-10 定远县仓镇恒润养殖专业合作社 Feed for enhancing immunity of lobsters
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CN107912363A (en) * 2017-11-24 2018-04-17 桂林满梓玉农业开发有限公司 A kind of disease-resistant cultural method of the emerald green duck of dragon victory
CN108719586A (en) * 2018-05-11 2018-11-02 宿松县龙源水产养殖专业合作社 A kind of improvement loach seedling constitution growth-promoting feed
CN114568586A (en) * 2022-03-14 2022-06-03 青岛品品好食品发展有限公司 Recycling method process of slag generated by refining oil

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