CN103450446A - 一种改性双酚a环氧丙烯酸酯的合成方法 - Google Patents
一种改性双酚a环氧丙烯酸酯的合成方法 Download PDFInfo
- Publication number
- CN103450446A CN103450446A CN201310375298XA CN201310375298A CN103450446A CN 103450446 A CN103450446 A CN 103450446A CN 201310375298X A CN201310375298X A CN 201310375298XA CN 201310375298 A CN201310375298 A CN 201310375298A CN 103450446 A CN103450446 A CN 103450446A
- Authority
- CN
- China
- Prior art keywords
- bisphenol
- epoxy acrylate
- modified bisphenol
- epoxide resin
- synthetic method
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- -1 modified bisphenol A epoxy acrylate Chemical class 0.000 title claims abstract description 24
- 238000001308 synthesis method Methods 0.000 title abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 10
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000010438 heat treatment Methods 0.000 claims abstract description 3
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 36
- 239000003822 epoxy resin Substances 0.000 claims description 17
- 229920000647 polyepoxide Polymers 0.000 claims description 17
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 15
- 238000010189 synthetic method Methods 0.000 claims description 11
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 claims description 6
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical group COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 claims description 6
- JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical group [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 claims description 5
- 238000000034 method Methods 0.000 abstract description 7
- 238000004383 yellowing Methods 0.000 abstract description 5
- 239000003054 catalyst Substances 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 2
- 239000006223 plastic coating Substances 0.000 abstract description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 abstract 4
- 239000004841 bisphenol A epoxy resin Substances 0.000 abstract 3
- 239000003112 inhibitor Substances 0.000 abstract 1
- 238000000016 photochemical curing Methods 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 229940106691 bisphenol a Drugs 0.000 description 14
- 239000004593 Epoxy Substances 0.000 description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 238000009413 insulation Methods 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 4
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 4
- 238000010792 warming Methods 0.000 description 4
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000007664 blowing Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 238000001723 curing Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Landscapes
- Epoxy Resins (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201310375298.XA CN103450446B (zh) | 2013-08-26 | 2013-08-26 | 一种改性双酚a环氧丙烯酸酯的合成方法 |
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CN201310375298.XA CN103450446B (zh) | 2013-08-26 | 2013-08-26 | 一种改性双酚a环氧丙烯酸酯的合成方法 |
Publications (2)
Publication Number | Publication Date |
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CN103450446A true CN103450446A (zh) | 2013-12-18 |
CN103450446B CN103450446B (zh) | 2016-02-03 |
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CN201310375298.XA Expired - Fee Related CN103450446B (zh) | 2013-08-26 | 2013-08-26 | 一种改性双酚a环氧丙烯酸酯的合成方法 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108727948A (zh) * | 2018-05-21 | 2018-11-02 | 安徽朗凯奇防水科技股份有限公司 | 一种改性丙烯酸乳液防水材料及其制备工艺 |
CN110078895A (zh) * | 2019-05-27 | 2019-08-02 | 江苏睿浦树脂科技有限公司 | 一种增韧改性uv光固化环氧丙烯酸酯树脂及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101928508A (zh) * | 2010-08-24 | 2010-12-29 | 华南理工大学 | 一种聚乙二醇改性的环氧丙烯酸酯涂料及其制备方法 |
CN102585693A (zh) * | 2012-03-09 | 2012-07-18 | 常熟市协新冶金材料有限公司 | 制备环氧丙烯酸酯改性水性聚氨酯涂料的方法 |
-
2013
- 2013-08-26 CN CN201310375298.XA patent/CN103450446B/zh not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101928508A (zh) * | 2010-08-24 | 2010-12-29 | 华南理工大学 | 一种聚乙二醇改性的环氧丙烯酸酯涂料及其制备方法 |
CN102585693A (zh) * | 2012-03-09 | 2012-07-18 | 常熟市协新冶金材料有限公司 | 制备环氧丙烯酸酯改性水性聚氨酯涂料的方法 |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108727948A (zh) * | 2018-05-21 | 2018-11-02 | 安徽朗凯奇防水科技股份有限公司 | 一种改性丙烯酸乳液防水材料及其制备工艺 |
CN110078895A (zh) * | 2019-05-27 | 2019-08-02 | 江苏睿浦树脂科技有限公司 | 一种增韧改性uv光固化环氧丙烯酸酯树脂及其制备方法 |
CN110078895B (zh) * | 2019-05-27 | 2022-03-08 | 江苏睿浦树脂科技有限公司 | 一种增韧改性uv光固化环氧丙烯酸酯树脂及其制备方法 |
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CN103450446B (zh) | 2016-02-03 |
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Effective date of registration: 20151231 Address after: 214000 Xinhua Road, Wuxi province national high tech Industrial Development Zone, No. innovation Creative Industrial Park, building, room 109, B, China, Jiangsu Applicant after: Jiangsu Gaobo Zhirong Technology Co., Ltd. Address before: 214000 Jiangsu Province, Wuxi city Xishan District Beizhen Zhang Shan chemical District Jingquan tin Applicant before: Wuxi Jinsheng Auxiliaries Factory |
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C41 | Transfer of patent application or patent right or utility model | ||
CB03 | Change of inventor or designer information |
Inventor after: Liang Kai Inventor after: Liang Guohui Inventor after: Liang Dan Inventor before: Zhu Renzu |
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TR01 | Transfer of patent right |
Effective date of registration: 20170110 Address after: 518000 Guangdong city of Shenzhen province Baoan District Guanlan Street Town Community Bamboo Village Industrial Zone Chuk Yuen Source Industrial Park 3 floor Room 301 Patentee after: SHENZHEN BANGDA TECHNOLOGY CO., LTD. Address before: 214000 Xinhua Road, Wuxi province national high tech Industrial Development Zone, No. innovation Creative Industrial Park, building, room 109, B, China, Jiangsu Patentee before: Jiangsu Gaobo Zhirong Technology Co., Ltd. |
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CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160203 Termination date: 20180826 |