CN103429637B - 制备具有伯羟基端基的聚醚碳酸酯多元醇的方法和由其制备的聚氨酯聚合物 - Google Patents

制备具有伯羟基端基的聚醚碳酸酯多元醇的方法和由其制备的聚氨酯聚合物 Download PDF

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CN103429637B
CN103429637B CN201180060779.0A CN201180060779A CN103429637B CN 103429637 B CN103429637 B CN 103429637B CN 201180060779 A CN201180060779 A CN 201180060779A CN 103429637 B CN103429637 B CN 103429637B
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polyether carbonate
hydrogen
alkyl
polyols
mol
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CN103429637A (zh
Inventor
J.霍夫曼
C.格特勒
H.内夫茨格
N.哈恩
K.洛伦茨
T.E.米勒
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Covestro Deutschland AG
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Bayer Pharma AG
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/20—General preparatory processes
    • C08G64/32—General preparatory processes using carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4244—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
    • C08G18/4261—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups prepared by oxyalkylation of polyesterpolyols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/44—Polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4887—Polyethers containing carboxylic ester groups derived from carboxylic acids other than acids of higher fatty oils or other than resin acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/02—Aliphatic polycarbonates
    • C08G64/0208—Aliphatic polycarbonates saturated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/18—Block or graft polymers
    • C08G64/183—Block or graft polymers containing polyether sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/20—General preparatory processes
    • C08G64/32—General preparatory processes using carbon dioxide
    • C08G64/34—General preparatory processes using carbon dioxide and cyclic ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Polyethers (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN201180060779.0A 2010-12-17 2011-12-12 制备具有伯羟基端基的聚醚碳酸酯多元醇的方法和由其制备的聚氨酯聚合物 Expired - Fee Related CN103429637B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10195634A EP2465890A1 (de) 2010-12-17 2010-12-17 Verfahren zur Herstellung von Polyethercarbonatpolyolen mit primären Hydroxyl-Endgruppen und daraus hergestellte Polyurethanpolymere
EP10195634.0 2010-12-17
PCT/EP2011/072489 WO2012080192A1 (de) 2010-12-17 2011-12-12 Verfahren zur herstellung von polyethercarbonatpolyolen mit primären hydroxyl-endgruppen und daraus hergestellte polyurethanpolymere

Publications (2)

Publication Number Publication Date
CN103429637A CN103429637A (zh) 2013-12-04
CN103429637B true CN103429637B (zh) 2015-06-17

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Country Status (11)

Country Link
US (1) US20130296450A1 (enExample)
EP (2) EP2465890A1 (enExample)
JP (1) JP2014503631A (enExample)
KR (1) KR20140035328A (enExample)
CN (1) CN103429637B (enExample)
BR (1) BR112013014282A2 (enExample)
CA (1) CA2821812A1 (enExample)
ES (1) ES2525753T3 (enExample)
MX (1) MX2013006337A (enExample)
SG (1) SG190274A1 (enExample)
WO (1) WO2012080192A1 (enExample)

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EP2530101A1 (de) 2011-06-01 2012-12-05 Bayer MaterialScience AG Verfahren zur Herstellung von Polyetherpolyolen
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CN108715630A (zh) * 2012-11-07 2018-10-30 沙特阿美技术公司 高强度聚氨酯泡沫组合物及方法
CN104277194B (zh) * 2013-07-05 2018-11-30 科思创德国股份有限公司 聚氨酯树脂组合物以及由其制备的聚氨酯复合物
EP2845872A1 (de) * 2013-09-05 2015-03-11 Bayer MaterialScience AG Niederviskose Polyethercarbonatpolyole mit Seitenketten
WO2015078801A1 (de) * 2013-11-27 2015-06-04 Bayer Materialscience Ag Mischungen von polyethercarbonatpolyolen und polyetherpolyolen zur herstellung von polyurethanweichschaumstoffen
EP2894180A1 (en) * 2014-01-08 2015-07-15 Bayer MaterialScience AG Polymer Polyols comprising a Polyether Carbonate Polyol as the Base Polyol
CN106029739B (zh) * 2014-02-26 2018-09-21 科思创德国股份有限公司 制备聚醚酯碳酸酯多元醇的方法
CN104927040B (zh) * 2014-03-17 2016-09-07 中国石油化工股份有限公司 Dmc催化剂催化的脂肪族聚碳酸酯的制备方法
KR102392235B1 (ko) * 2014-04-03 2022-05-02 사우디 아람코 테크놀로지스 컴퍼니 지방족 폴리카보네이트 폴리올 조성물
US9527958B2 (en) 2014-05-02 2016-12-27 Covestro Llc Process for purification of polyether carbonate polyols
US20180127536A1 (en) * 2015-04-29 2018-05-10 Covestro Deutschland Ag Mixtures of polyether carbonate polyols and polyether polyols for producing polyurethane soft foams
CN108602933B (zh) * 2015-12-09 2021-10-22 科思创德国股份有限公司 基于聚醚碳酸酯多元醇的聚氨酯泡沫材料
KR101956662B1 (ko) * 2016-02-29 2019-03-11 아크조 노벨 케미칼즈 인터내셔널 비.브이. 디알킬-폴리알킬아민 조성물, 이의 제조 방법 및 이의 용도
CN105801789B (zh) * 2016-04-07 2018-10-16 中国科学院长春应用化学研究所 一种水性聚氨酯及其制备方法和胶粘剂
CN109790275B (zh) * 2016-10-12 2022-03-15 科思创德国股份有限公司 制备含多重键的预聚物作为弹性体前体的方法
EP3385295A1 (de) * 2017-04-05 2018-10-10 Covestro Deutschland AG Flammgeschützte phosphorfunktionelle polyethercarbonatpolyole und verfahren zu deren herstellung
EP3549969A1 (de) * 2018-04-06 2019-10-09 Covestro Deutschland AG Polyurethanschaumstoffe basierend auf polyethercarbonatpolyolen
EP3781609A1 (en) * 2018-04-18 2021-02-24 Saudi Aramco Technologies Company End-group isomerization of poly(alkylene carbonate) polymers
EP3608348A1 (de) * 2018-08-07 2020-02-12 Covestro Deutschland AG Verfahren zur herstellung eines organooxysilyl-vernetzten polymers
EP3856820A1 (en) 2018-09-24 2021-08-04 Saudi Aramco Technologies Company Polycarbonate block copolymers and methods thereof
CN109912768B (zh) * 2019-01-21 2021-05-25 聚源化学工业股份有限公司 一种聚醚组合物、低voc聚氨酯泡沫及其制备方法
CN109836556A (zh) * 2019-01-31 2019-06-04 四川大学 一种含铁盐的低voc聚氨酯发泡材料及制备方法
PT3995541T (pt) * 2019-07-02 2023-06-26 Mitsubishi Chem Corp Composição de éter de polialquilenoglicol e método para a sua produção
GB202003003D0 (en) * 2020-03-02 2020-04-15 Econic Tech Ltd A polyol block copolymer
GB202003002D0 (en) * 2020-03-02 2020-04-15 Crane Ltd Method of preparation of a polyol block copolymer
GB202017531D0 (en) * 2020-11-05 2020-12-23 Econic Tech Limited (poly)ol block copolymer

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US4487853A (en) * 1983-12-27 1984-12-11 Basf Wyandotte Corporation Low ethylene oxide/high primary hydroxyl content polyether-ester polyols and polyurethane foams based thereon
CN101511909A (zh) * 2006-07-24 2009-08-19 拜尔材料科学有限公司 通过双金属氰化物（dmc）催化制备的聚醚碳酸酯多元醇
CN101535364A (zh) * 2006-11-15 2009-09-16 巴斯夫欧洲公司 生产软质聚氨酯泡沫的方法

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CA2821812A1 (en) 2012-06-21
KR20140035328A (ko) 2014-03-21
US20130296450A1 (en) 2013-11-07
EP2465890A1 (de) 2012-06-20
WO2012080192A1 (de) 2012-06-21
BR112013014282A2 (pt) 2016-09-20
EP2652008A1 (de) 2013-10-23
EP2652008B1 (de) 2014-10-22
JP2014503631A (ja) 2014-02-13
ES2525753T3 (es) 2014-12-29
SG190274A1 (en) 2013-07-31
MX2013006337A (es) 2013-08-26
CN103429637A (zh) 2013-12-04

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