CN103429630A - 水性介质中的n-乙烯基内酰胺的可控自由基聚合 - Google Patents

水性介质中的n-乙烯基内酰胺的可控自由基聚合 Download PDF

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Publication number
CN103429630A
CN103429630A CN201180056818XA CN201180056818A CN103429630A CN 103429630 A CN103429630 A CN 103429630A CN 201180056818X A CN201180056818X A CN 201180056818XA CN 201180056818 A CN201180056818 A CN 201180056818A CN 103429630 A CN103429630 A CN 103429630A
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CN
China
Prior art keywords
polymkeric substance
vinyl lactam
oxygenant
monomer
reductive agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201180056818XA
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English (en)
Chinese (zh)
Inventor
M·德斯塔拉克
A·格维诺德
S·马泽烈斯
詹姆士·威尔逊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Rhodia Operations SAS
Original Assignee
Centre National de la Recherche Scientifique CNRS
Rhodia Operations SAS
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Publication date
Application filed by Centre National de la Recherche Scientifique CNRS, Rhodia Operations SAS filed Critical Centre National de la Recherche Scientifique CNRS
Priority to CN201810208906.0A priority Critical patent/CN108440728A/zh
Publication of CN103429630A publication Critical patent/CN103429630A/zh
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F26/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F26/06—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F126/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F126/06—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
    • C08F126/10—N-Vinyl-pyrrolidone
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F226/06—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
    • C08F226/10—N-Vinyl-pyrrolidone
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/40—Redox systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L39/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions of derivatives of such polymers
    • C08L39/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
CN201180056818XA 2010-09-27 2011-09-22 水性介质中的n-乙烯基内酰胺的可控自由基聚合 Pending CN103429630A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810208906.0A CN108440728A (zh) 2010-09-27 2011-09-22 水性介质中的n-乙烯基内酰胺的可控自由基聚合

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1057770A FR2965264B1 (fr) 2010-09-27 2010-09-27 Polymerisation radicalaire controlee de n-vinyl lactames en milieu aqueux
FR1057770 2010-09-27
PCT/FR2011/052185 WO2012045944A1 (fr) 2010-09-27 2011-09-22 Polymérisation radicalaire contrôlée de n-vinyl lactames en milieu aqueux

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN201810208906.0A Division CN108440728A (zh) 2010-09-27 2011-09-22 水性介质中的n-乙烯基内酰胺的可控自由基聚合

Publications (1)

Publication Number Publication Date
CN103429630A true CN103429630A (zh) 2013-12-04

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Family Applications (2)

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CN201810208906.0A Pending CN108440728A (zh) 2010-09-27 2011-09-22 水性介质中的n-乙烯基内酰胺的可控自由基聚合
CN201180056818XA Pending CN103429630A (zh) 2010-09-27 2011-09-22 水性介质中的n-乙烯基内酰胺的可控自由基聚合

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CN201810208906.0A Pending CN108440728A (zh) 2010-09-27 2011-09-22 水性介质中的n-乙烯基内酰胺的可控自由基聚合

Country Status (7)

Country Link
US (1) US9574022B2 (ko)
EP (1) EP2621972B1 (ko)
JP (1) JP5897581B2 (ko)
KR (1) KR101837224B1 (ko)
CN (2) CN108440728A (ko)
FR (1) FR2965264B1 (ko)
WO (1) WO2012045944A1 (ko)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106414528A (zh) * 2014-03-24 2017-02-15 罗地亚经营管理公司 两亲性多嵌段聚合物
CN108329426A (zh) * 2018-02-08 2018-07-27 博爱新开源医疗科技集团股份有限公司 一种n-乙烯基吡咯烷酮和n-乙烯基己内酰胺的无规共聚物溶液及其制备方法
CN108504074A (zh) * 2017-02-27 2018-09-07 国药集团化学试剂有限公司 亚甲基蓝在无氧或低氧条件下用作聚合抑制剂的用途

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2986235B1 (fr) * 2012-01-31 2015-02-06 Rhodia Operations Stabilisants reactifs poly(n-vinyl lactame) vivants pour polymerisation en phase dispersee
FR2986234B1 (fr) * 2012-01-31 2014-06-13 Rhodia Operations Stabilisants reactifs poly(n-vinyl lactame) vivants pour polymerisation en phase dispersee
US9487598B2 (en) 2012-01-31 2016-11-08 Rhodia Operations Live poly(n-vinyl lactam) reactive stabilizers for dispersed phase polymerization
RU2607523C1 (ru) * 2016-03-02 2017-01-10 Федеральное государственное бюджетное образовательное учреждение высшего образования "Московский технологический университет" Способ получения высокомолекулярного полимера поли-n-винилкапролактама в воде
KR20240120788A (ko) 2023-01-31 2024-08-08 한국과학기술원 미세 액적을 이용한 라디칼 중합 방법

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EP1510533A1 (fr) * 2003-09-01 2005-03-02 L'oreal Copolymères éthyléniques sequences comprenant une sequence vinyllactame, compositions cosmétiques les contenant, et utilisation de ces copolymères en cosmétique
WO2010078149A1 (en) * 2008-12-30 2010-07-08 Bausch & Lomb Incorporated Brush copolymers

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DE19727476A1 (de) * 1997-06-27 1999-01-07 Basf Ag Verfahren zur Herstellung von niedermolekularen Homopolymerisaten des N-Vinylpyrrolidons
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JP3773408B2 (ja) * 2000-06-15 2006-05-10 第一工業製薬株式会社 ビニルピロリドン重合体の製造方法
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EP1510533A1 (fr) * 2003-09-01 2005-03-02 L'oreal Copolymères éthyléniques sequences comprenant une sequence vinyllactame, compositions cosmétiques les contenant, et utilisation de ces copolymères en cosmétique
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106414528A (zh) * 2014-03-24 2017-02-15 罗地亚经营管理公司 两亲性多嵌段聚合物
CN106414528B (zh) * 2014-03-24 2020-04-10 罗地亚经营管理公司 两亲性多嵌段聚合物
CN108504074A (zh) * 2017-02-27 2018-09-07 国药集团化学试剂有限公司 亚甲基蓝在无氧或低氧条件下用作聚合抑制剂的用途
CN108329426A (zh) * 2018-02-08 2018-07-27 博爱新开源医疗科技集团股份有限公司 一种n-乙烯基吡咯烷酮和n-乙烯基己内酰胺的无规共聚物溶液及其制备方法
CN108329426B (zh) * 2018-02-08 2020-11-17 博爱新开源医疗科技集团股份有限公司 一种n-乙烯基吡咯烷酮和n-乙烯基己内酰胺的无规共聚物溶液及其制备方法

Also Published As

Publication number Publication date
FR2965264B1 (fr) 2013-11-29
KR20130099114A (ko) 2013-09-05
EP2621972A1 (fr) 2013-08-07
EP2621972B1 (fr) 2016-09-14
US9574022B2 (en) 2017-02-21
JP5897581B2 (ja) 2016-03-30
US20130289214A1 (en) 2013-10-31
KR101837224B1 (ko) 2018-03-09
JP2013538911A (ja) 2013-10-17
WO2012045944A1 (fr) 2012-04-12
CN108440728A (zh) 2018-08-24
FR2965264A1 (fr) 2012-03-30

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