CN103422282A - Crystal transition modification method of flax fabric - Google Patents
Crystal transition modification method of flax fabric Download PDFInfo
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- CN103422282A CN103422282A CN2013103180641A CN201310318064A CN103422282A CN 103422282 A CN103422282 A CN 103422282A CN 2013103180641 A CN2013103180641 A CN 2013103180641A CN 201310318064 A CN201310318064 A CN 201310318064A CN 103422282 A CN103422282 A CN 103422282A
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Abstract
The invention relates to a crystal transition modification method of flax fabric. The flax fabric is arranged in a sealed container, a modification medium is injected in the container, the pressure is increased to the modification pressure, then the pressure is released instantly, the modification medium is removed, and the crystal transition modified flax fabric is obtained. Through the adoption of the technical scheme, the crystal transition modification method of the flax fabric has the advantages that the purpose of modification is achieved by changing a crystal lattice structure, the modified fabric overcomes the original defects, is larger in hole, is lower in crystallinity, is soft, and improves the size stability, softness, dyeing property and the like of products; through the method of releasing the pressure instantly, the modified fabric is expanded to the maximum extent, the fluffiness and softness of the fabric are largely improved, and therefore the spinning, weaving and dyeing performance of the fabric is largely improved.
Description
Technical field
The crystalline substance that the present invention relates to a kind of sodolin becomes method of modifying, specifically a kind of by the modification medium being pressurized to modifier pressure and the brilliant method of modifying that becomes of the sodolin of abrupt release pressure after pressurize a period of time.
Background technology
Sodolin is that the linen thread and yarn that Young's modulus is larger in natural yarn is made into.The advantages such as its hygroscopicity is good, static is little, warmth retention property is strong, anti-corruption is heat-resisting, but also exist hard, send out the defects such as wrinkle, shrink, difficulty are spun, difficulty is knitted, difficulty is dyed, cause its wearability poor, be difficult for making high-end weaving sodolin, the overwhelming majority is low value-added product.
In order to change above-mentioned present situation, existing a variety of method of modifying, as physical modification method, chemical modification method and biological modified method.It is processing modified etc. that physical modification method mainly comprises that discharge technology modification, high steam dodge quick-fried modification, ultrasonic cavitation and microwave irradiation modification, liquefied ammonia.Chemical modification method mainly comprises esters modification, ethers modification, graft modification and cross-linking modified etc.
The method of modifying that has formed now industrialization production both at home and abroad mainly contains the processing modified and alkali mercerized modification of liquefied ammonia.Liquid ammonia modified and alkali mercerized processing has similar effect, as characteristics such as natural crimp disappear, cross section becomes circle, inner chamber diminishes, but the residual alkali lye of alkali mercerized modification is difficult for removing and also can cause fabric to melt erosion and inhomogeneities, and topmost difference is that liquid ammonia modified effect is better than alkali mercerized modification.The domestic liquefied ammonia that utilizes is as the modification medium, the method of boost-pressurize of routine in closed container-reclaim again modification medium in fabric has certain effect to COTTON FABRIC, but the modified effect to sodolin is poor, and the method is modification for once, swelling not thoroughly, degree of crystallinity reduce not obvious, dyeability do not have be improved significantly.
Summary of the invention
The crystalline substance that the purpose of this invention is to provide a kind of sodolin becomes method of modifying, specifically a kind of by the modification medium being pressurized to modifier pressure and the brilliant method of modifying that becomes of the sodolin of abrupt release pressure after pressurize a period of time.
The crystalline substance of a kind of sodolin of the present invention becomes method of modifying, is that sodolin is placed in to closed container, is filled with the modification medium, boosts to modifier pressure, and then abrupt release pressure, remove the modification medium, obtains the brilliant modification sodolin that becomes.Its principle is: sodolin is placed in to closed container, movable sealing under the under high pressure movable sealing of this closed container and negative pressure, and zero leakage.By pressure balance topping up and non-equilibrium constant speed topping up, can regulate the flow, time and the temperature that are filled with modification medium in closed container, thereby the rate of change of pressure, two-phase interface and the above-mentioned parameter of regulation and control modification, and then the running parameters such as permeability, infiltration rate and evaporation rate of regulation and control liquid medium; Regulate the dwell time of modifier pressure simultaneously; Above-mentioned technique can make the diffusion coefficient of modification medium improve, the modification medium is penetrated in fabric tissue preferably, the intermolecular hydrogen bond network of reconstruct fabric fibre element, changed the microstructure of fabric, the motion of aggravation fabric fibre element macromolecular chain segment, make the intermolecular generation swelling action of fabric fibre element, and hole increases, degree of crystallinity reduces, and has realized the once regulation and control of fabric lattice structure.Again by the high speed overflow, a large amount of liquid modified media in the abrupt release closed container, produce huge pressure reduction in fabric tissue inside and outside moment, form high speed quick-fried swollen, the diffusion coefficient of modification medium significantly improved, Perfect Reconstruction the intermolecular hydrogen bond network of fabric fibre element, the intermolecular swelling action of fabric fibre element is more thorough, hole increases obviously, and degree of crystallinity significantly reduces, and has realized the secondary regulation and control of fabric lattice structure.The modification medium that finally adopts heating and vacuumize in parallel method of evaporating removal sodolin has completed the described brilliant method of modifying that becomes.Brilliant become after modification sodolin to have softness good, wrinkle resistant nonshrink, durable fluffy, significantly improved the spinning of fabric, knit, the metachromia energy.
As preferred technical scheme:
The crystalline substance of a kind of sodolin as above becomes method of modifying, and in described sodolin, the fineness of linen thread and yarn is 5～120; The thread count of described flax/flax blended fabric is 100～600/10cm.
The crystalline substance of a kind of sodolin as above becomes method of modifying, by twice intermolecular hydrogen bond network of reconstruct fabric fibre element, the secondary regulation and control of fabric lattice structure have been realized, make the intermolecular swelling action of fabric fibre more thorough, hole obviously increases, and degree of crystallinity obviously reduces, and dye-uptake improves, COLOR FASTNESS improves, and finally adopts the modification medium that heats and vacuumize in parallel method of evaporating removal sodolin to complete the described brilliant modification that becomes.Adopt the described brilliant method of modifying that becomes, can make the brilliant microcosmic lattice that becomes the modification sodolin compare with the microcosmic lattice of described sodolin, hole increases 15%～18%, and degree of crystallinity reduces 18%～22%; The described brilliant modification sodolin that becomes is compared with described sodolin, and dye-uptake improves 25%～30%, and COLOR FASTNESS improves 18%～21%.
The crystalline substance of a kind of sodolin as above becomes method of modifying, and the modification medium is liquefied ammonia; The modification medium need possess following 3 features: 1) have good diffusivity; 2) can and the fabric fibre element between form a large amount of hydrogen bonds, the intermolecular hydrogen bond network of reconstruct fabric fibre element, improve the swelling behavior of fabric; 3) be easy to the phase transformation regulation and control, be convenient to the evaporation of modification medium and reclaim.And liquefied ammonia has, molecular weight is little, viscosity is little, surface tension is little, be easy to the special physical propertys such as phase transformation, and these special natures make liquefied ammonia meet above-mentioned three features.
The crystalline substance of a kind of sodolin as above becomes method of modifying, the modifier pressure abrupt release, and moment produces larger pressure differential, can significantly improve the diffusion coefficient of modification medium, makes sodolin produce abundant swelling, is the brilliant critical process process that becomes modification.To different sodolins, the modifier pressure difference of requirement, the speed difference of earth pressure release, the pressure differential difference that moment produces, under the prerequisite that does not improve modifier pressure, obtain high as far as possible release pressure poor, should make modifier pressure drop to negative pressure.To sodolin, modifier pressure need to be more than or equal to 1MPa, can reach 2MPa, and therefore described modifier pressure P should be 1～2MPa.Poor for obtaining high as far as possible release pressure, should make modifier pressure drop to negative pressure, so the abrupt release of modifier pressure, require modifier pressure moment drop to modifier pressure 1% and below.
The crystalline substance of a kind of sodolin as above becomes method of modifying, and for the standard technological standards, described pressure refers to absolute pressure.
The crystalline substance of a kind of sodolin as above becomes method of modifying, obtain good swelling effect, 1% the time that requires pressure to drop to modifier pressure from modifier pressure is less than or equal to 5.0 seconds and gets final product, at 3 seconds～5 seconds, be advisable, therefore the moment of described release pressure is 3 seconds～5 seconds, and the rate of pressure reduction of corresponding described release pressure is 2MPa/s～4MPa/s.
The crystalline substance of a kind of sodolin as above becomes method of modifying, for obtaining good diffusivity and the best modified effect of modification medium, and the modifying process energy consumes minimum, the flow, time and the temperature that need ammoniacal liquor in regulation and control topping up process, reach the purpose of regulation and control pressure, and then regulation and control medium permeability, infiltration rate, evaporation rate, evaporation rate and phase transition process.And the process of boosting is one of most important influence factor, need adopt the different processes of boosting to different fabrics, a large number of experiments show that: sodolin is applicable to boosting by linearity, and rate of pressure rise k meets relational expression
Wherein t is pressure rising time, k
0For initial rate of pressure rise; For sodolin, initial rate of pressure rise k
0Be not less than 0.5MPa/min, can reach 1MPa/min, therefore described initial rate of pressure rise k
0In 0.5MPa/min～1MPa/min scope.
The crystalline substance of a kind of sodolin as above becomes method of modifying, and in modifying process, the rear pressurize a period of time of boosting is for the modification medium can be penetrated in fabric structure more fully, better completes the intermolecular hydrogen bond network reconstruct of fabric fibre element.This process is all necessary to the crystalline substance change modification of all fabrics.To sodolin, the rear pressurize 1min that boosts is above to be got final product, and the dwell time is advisable at 1～10min, and therefore the described rear dwell time of boosting is 1～10min.
The crystalline substance of a kind of sodolin as above becomes method of modifying, after twice reconstruct of the fabric fibre intermolecular hydrogen bond network of element, remove the modification medium technical process that is absolutely necessary, this process does not affect the lattice structure of fabric, but how high efficiency, low energy consumption, this process that completes pollution-free, zero-emission are to realize the key factor of large-scale industrial production, this will directly affect the brilliant vitality that becomes method of modifying, about how high efficiency, low energy consumption, pollution-free, zero-emission complete this process again separate case write the series of patents statement.Remove the modification medium described in this case and remove the modification medium in sodolin for adopting heating and vacuumizing parallel method of evaporating.
Beneficial effect:
The present invention adopts the advantage of above technical scheme as follows:
1. the present invention reaches the modification purpose by changing crystal structure.Fabric after modification overcomes its native defect, and hole increases, degree of crystallinity reduces, fabric sofetening, has improved DIMENSIONAL STABILITY, flexibility, level-dyeing property and the dyeability etc. of product.
2. the present invention adopts the method for abrupt release pressure, makes the maximum swelling of fabric after modification dodge quick-fried, and softness is good, wrinkle resistant nonshrink, durable fluffy, has significantly improved the spinning of fabric, knits, the metachromia energy.
The specific embodiment
Below in conjunction with the specific embodiment, further set forth the present invention.Should be understood that these embodiment only are not used in and limit the scope of the invention for the present invention is described.Should be understood that in addition those skilled in the art can make various changes or modifications the present invention after the content of having read the present invention's instruction, these equivalent form of values fall within the application's appended claims limited range equally.
Embodiment 1
A kind of crystalline substance of sodolin becomes method of modifying, and the sodolin of 5 * 5,250/10cm * 100/10cm is placed in to closed container, is filled with liquefied ammonia, by linear boosting mode, boosts, and rate of pressure rise k meets relational expression
Initial rate of pressure rise k
0For 0.5MPa/min, boost to modifier pressure 1Mpa, pressurize 1min, then in 5 seconds with the rate of pressure reduction abrupt release of 2MPa/s to 0.005Mpa.Then adopt heating and vavuum pump to vacuumize parallel method of evaporating and remove the modification medium, until in closed container, pressure is reduced to 133Pa, obtain the brilliant modification sodolin that becomes.The described brilliant microcosmic lattice that becomes the modification sodolin is compared with the microcosmic lattice of described sodolin, and hole increases 15%, and degree of crystallinity reduces 18%; The described brilliant modification sodolin that becomes is compared with the described sodolin that is modified, and dye-uptake improves 25%, and COLOR FASTNESS improves 18%.
Embodiment 2
A kind of crystalline substance of sodolin becomes method of modifying, and the sodolin of 30 * 36,218/10cm * 196/10cm is placed in to closed container, is filled with liquefied ammonia, by linear boosting mode, boosts, and rate of pressure rise k meets relational expression
Initial rate of pressure rise k
0For 0.8MPa/min, boost to modifier pressure 1.5Mpa, pressurize 5min, then in 5 seconds with the rate of pressure reduction abrupt release of 3MPa/s to 0.0015Mpa.Then adopt heating and vavuum pump to vacuumize parallel method of evaporating and remove the modification medium, until in closed container, pressure is reduced to 133Pa, obtain the brilliant modification sodolin that becomes.The described brilliant microcosmic lattice that becomes the modification sodolin is compared with the microcosmic lattice of described sodolin, and hole increases 16%, and degree of crystallinity reduces 19%; The described brilliant modification sodolin that becomes is compared with the described sodolin that is modified, and dye-uptake improves 26%, and COLOR FASTNESS improves 18%.
Embodiment 3
A kind of crystalline substance of sodolin becomes method of modifying, and the sodolin of 21 * 36,236/10cm * 190/10cm is placed in to closed container, is filled with liquefied ammonia, by linear boosting mode, boosts, and rate of pressure rise k meets relational expression
Initial rate of pressure rise k
0For 0.8MPa/min, boost to modifier pressure 1.5Mpa, pressurize 5min, then in 4 seconds with the rate of pressure reduction abrupt release of 3MPa/s to 0.0015Mpa.Then adopt heating and vavuum pump to vacuumize parallel method of evaporating and remove the modification medium, until in closed container, pressure is reduced to 133Pa, obtain the brilliant modification sodolin that becomes.The described brilliant microcosmic lattice that becomes the modification sodolin is compared with the microcosmic lattice of described sodolin, and hole increases 17%, and degree of crystallinity reduces 20%; The described brilliant modification sodolin that becomes is compared with the described sodolin that is modified, and dye-uptake improves 29%, and COLOR FASTNESS improves 20%.
Embodiment 4
A kind of crystalline substance of sodolin becomes method of modifying, and the sodolin of 120 * 120,600/10cm * 400/10cm is placed in to closed container, is filled with liquefied ammonia, by linear boosting mode, boosts, and rate of pressure rise k meets relational expression
Initial rate of pressure rise k
0For 1MPa/min, boost to modifier pressure 2Mpa, pressurize 10min, then in 3 seconds with the rate of pressure reduction abrupt release of 4MPa/s to 0.002Mpa.Then adopt heating and vavuum pump to vacuumize parallel method of evaporating and remove the modification medium, until in closed container, pressure is reduced to 133Pa, obtain the brilliant modification sodolin that becomes.The described brilliant microcosmic lattice that becomes the modification sodolin is compared with the microcosmic lattice of described sodolin, and hole increases 18%, and degree of crystallinity reduces 22%; The described brilliant modification sodolin that becomes is compared with the described sodolin that is modified, and dye-uptake improves 30%, and COLOR FASTNESS improves 21%.
Claims (10)
1. the crystalline substance of a sodolin becomes method of modifying, it is characterized in that: sodolin is placed in to closed container, is filled with the modification medium, boost to modifier pressure, then abrupt release pressure, remove the modification medium, obtains the brilliant modification sodolin that becomes.
2. the crystalline substance of a kind of sodolin according to claim 1 becomes method of modifying, it is characterized in that, in described sodolin, the fineness of linen thread and yarn is 5～120; The thread count of described sodolin is 100～600/10cm.
3. the crystalline substance of a kind of sodolin according to claim 1 becomes method of modifying, it is characterized in that, the described brilliant microcosmic lattice that becomes the modification sodolin is compared with the microcosmic lattice of described sodolin, and hole increases 15%～18%, and degree of crystallinity reduces 18%～22%; The described brilliant modification sodolin that becomes is compared with described sodolin, and dye-uptake improves 25%～30%, and COLOR FASTNESS improves 18%～21%.
4. the crystalline substance of a kind of sodolin according to claim 1 becomes method of modifying, it is characterized in that, described modification medium is liquefied ammonia.
5. the crystalline substance of a kind of sodolin according to claim 1 becomes method of modifying, it is characterized in that, described modifier pressure P is 1～2MPa, described abrupt release pressure refer to pressure moment drop to described modifier pressure 1% and below.
6. the crystalline substance of a kind of sodolin according to claim 5 becomes method of modifying, it is characterized in that, described pressure is absolute pressure.
7. a kind of crystalline substance of sodolin becomes method of modifying according to claim 1 or 5, it is characterized in that, and described moment refers to 3 seconds～5 seconds, the rate of pressure reduction of described release pressure is 2MPa/s～4MPa/s.
8. the crystalline substance of a kind of sodolin according to claim 1 becomes method of modifying, it is characterized in that described boosting as the linearity liter
Press, rate of pressure rise k meets relational expression
Wherein t is pressure rising time, k
0For initial rate of pressure rise, k
0For 0.5MPa/min～1MPa/min.
9. the crystalline substance of a kind of sodolin according to claim 1 becomes method of modifying, it is characterized in that, rear maintenance 1min～10min boosts.
10. the crystalline substance of a kind of sodolin according to claim 1 becomes method of modifying, it is characterized in that, described removal modification medium is removed the modification medium in sodolin for adopting heating and vacuumizing parallel method of evaporating.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310318064.1A CN103422282B (en) | 2013-07-26 | 2013-07-26 | A kind of crystalline substance of sodolin becomes method of modifying |
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| CN201310318064.1A CN103422282B (en) | 2013-07-26 | 2013-07-26 | A kind of crystalline substance of sodolin becomes method of modifying |
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Cited By (2)
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| CN104611812A (en) * | 2014-11-19 | 2015-05-13 | 浙江国诚麻纺织有限公司 | Novel cotton-feeling linen producing technology |
| CN106435934A (en) * | 2016-10-09 | 2017-02-22 | 武汉市知富企业管理咨询有限公司 | Super-wide linen fabric and production process thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104611812A (en) * | 2014-11-19 | 2015-05-13 | 浙江国诚麻纺织有限公司 | Novel cotton-feeling linen producing technology |
| CN106435934A (en) * | 2016-10-09 | 2017-02-22 | 武汉市知富企业管理咨询有限公司 | Super-wide linen fabric and production process thereof |
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| CN103422282B (en) | 2015-10-21 |
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