CN103437099B - A kind of crystalline substance of ramie/viscose blended yarn becomes method of modifying - Google Patents
A kind of crystalline substance of ramie/viscose blended yarn becomes method of modifying Download PDFInfo
- Publication number
- CN103437099B CN103437099B CN201310318050.XA CN201310318050A CN103437099B CN 103437099 B CN103437099 B CN 103437099B CN 201310318050 A CN201310318050 A CN 201310318050A CN 103437099 B CN103437099 B CN 103437099B
- Authority
- CN
- China
- Prior art keywords
- ramie
- blended yarn
- viscose blended
- pressure
- crystalline substance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Artificial Filaments (AREA)
Abstract
The crystalline substance that the present invention relates to a kind of ramie/viscose blended yarn becomes method of modifying, is that ramie/viscose blended yarn is placed in closed container, is filled with modification medium, boost to modifier pressure, then abrupt release pressure, removes modification medium, namely obtains brilliant change modified ramie/viscose blended yarn.The present invention adopts the advantage of above technical scheme as follows: 1, reach modification object by changing lattice structure, modified yarn overcomes its native defect, hole increases, degree of crystallinity reduces, soft yarns, improves the DIMENSIONAL STABILITY of product, flexibility and dyeability etc.2, adopt the method for abrupt release pressure, modified yarn farthest expanded, significantly improves bulkiness and the flexibility of yarn, thus significantly improve the spinning of yarn, knit, metachromia energy.
Description
Technical field
The crystalline substance that the present invention relates to a kind of ramie/viscose blended yarn becomes method of modifying, specifically a kind of by modification medium being pressurized to modifier pressure and the ramie/viscose blended yarn brilliant change method of modifying of abrupt release pressure after pressurize a period of time.
Background technology
Ramie/viscose blended yarn is formed by certain proportioning blending by ramee and viscose, and blending makes ramie and viscose glue be formed to have complementary advantages, both improved hard, the easy wrinkle resistance of ramie yarn and thread, maintained again the moisture permeability that it is good.But due to stiffening, scratchy, the shortcoming such as difficulty is spun, difficulty is knitted, difficulty contaminates of ramie yarn and thread, it is far from being enough for only improving its performance by blending.
In order to change above-mentioned present situation, existing a variety of method of modifying, as physical modification method, chemical modification method and biological modified method.Physical modification method mainly comprises discharge technology modification, high steam dodges quick-fried modification, ultrasonic cavitation and microwave irradiation modification, liquefied ammonia are processing modified etc.Chemical modification method mainly comprises esters modification, ethers modification, graft modification and cross-linking modified etc.
The method of modifying having formed now industrialization production both at home and abroad mainly contains the processing modified and alkali mercerized modification of liquefied ammonia.Liquid ammonia modified and alkali mercerized process has similar effect, as features such as natural crimp disappearance, cross section change circle, inner chamber diminish, but the residual alkali lye of alkali mercerized modification is not easily removed and yarn also can be caused to melt erosion and inhomogeneities, and topmost difference is that liquid ammonia modified effect is better than alkali mercerized modification.The domestic liquefied ammonia that utilizes is as modification medium, in the collect yarn of conventional boosting-pressurize in closed container-again, the method for modification medium only has certain effect to viscose yarn, and the method for once modification, swelling not thoroughly, degree of crystallinity reduce not obvious, dyeability do not have be improved significantly.
Summary of the invention
The crystalline substance that the object of this invention is to provide a kind of ramie/viscose blended yarn becomes method of modifying, specifically a kind of by modification medium being pressurized to modifier pressure and the ramie/viscose blended yarn brilliant change method of modifying of abrupt release pressure after pressurize a period of time.
The crystalline substance of a kind of ramie/viscose blended yarn of the present invention becomes method of modifying, is that ramie/viscose blended yarn is placed in closed container, is filled with modification medium, boost to modifier pressure, then abrupt release pressure, removes modification medium, namely obtains brilliant change modified ramie/viscose blended yarn.Its principle is: ramie/viscose blended yarn is placed in closed container, and this closed container can movable sealing under under high pressure movable sealing and negative pressure, and zero leakage.By pressure balance topping up and non-equilibrium constant speed topping up, adjustable be filled with modification medium in closed container flow, time and temperature, thus the rate of change of the regulation and control pressure of modification, two-phase interface and above-mentioned parameter, and then the running parameter such as the permeability of regulation and control liquid medium, infiltration rate and evaporation rate; Regulate the dwell time of modifier pressure simultaneously; Above-mentioned technique can make the diffusion coefficient of modification medium improve, modification medium penetrates in yarn tissue preferably, the intermolecular hydrogen bond network of reconstruct yarn fibers, change the microstructure of yarn fibers, the motion of aggravation macromolecular chain segment, make the intermolecular generation swelling action of yarn fibers, hole increases, degree of crystallinity reduces, and achieves the once regulation and control of yarn lattice structure.Again by high speed overflow, a large amount of liquid modified medium in abrupt release closed container, huge pressure reduction is produced instantaneously at yarn organization internal and outside, form high speed quick-fried swollen, the diffusion coefficient of modification medium is significantly improved, Perfect Reconstruction yarn fibers intermolecular hydrogen bond network, the intermolecular swelling action of yarn fibers is more thorough, hole increases obviously, and degree of crystallinity significantly reduces, and achieves the secondary regulation and control of yarn lattice structure.Finally adopt heating and vacuumize the parallel method of evaporating modification medium removed in ramie/viscose blended yarn and namely complete described crystalline substance change method of modifying.Brilliant become modified ramie/viscose blended yarn to have softness excellent, wrinkle resistant nonshrink, durable fluffy, significantly improve the spinning of yarn, knit, metachromia energy, become remarkable and newly spin material.
As preferred technical scheme:
The crystalline substance of a kind of ramie/viscose blended yarn as above becomes method of modifying, and the fineness of described ramie/viscose blended yarn is 10 ~ 80, and blending rate is 5 ~ 95:95 ~ 5 in mass ratio.
The crystalline substance of a kind of ramie/viscose blended yarn as above becomes method of modifying, by twice intermolecular hydrogen bond network of reconstruct yarn fibers, achieve the secondary regulation and control of yarn lattice structure, make the intermolecular swelling action of yarn fibers more thorough, hole obviously increases, and degree of crystallinity obviously reduces, and dye-uptake improves, COLOR FASTNESS improves, and finally adopts heating and vacuumize the parallel method of evaporating modification medium removed in ramie/viscose blended yarn namely to complete described crystalline substance change modification.Crystalline substance described in employing becomes method of modifying, and can make the microcosmic lattice of brilliant change modified ramie/viscose blended yarn compared with the microcosmic lattice of described ramie/viscose blended yarn, hole increases 16% ~ 20%, and degree of crystallinity reduces 22 ~ 28%; Described crystalline substance becomes modified ramie/viscose blended yarn compared with described ramie/viscose blended yarn, and dye-uptake improves 40% ~ 50%, and COLOR FASTNESS improves 23% ~ 25%.
The crystalline substance of a kind of ramie/viscose blended yarn as above becomes method of modifying, and modification medium is liquefied ammonia; Modification medium need possess following three point patterns: 1) have excellent diffusivity; 2) hydrogen bond that can be a large amount of with the intermolecular formation of yarn fibers, the intermolecular hydrogen bond network of reconstruct yarn fibers, improves the swelling behavior of yarn; 3) be easy to phase transformation regulation and control, be convenient to modification medium evaporation and reclaim.And liquefied ammonia has, and molecular weight is little, viscosity is little, surface tension is little, be easy to the special physical property such as phase transformation, these special natures make liquefied ammonia meet above-mentioned three features.
The crystalline substance of a kind of ramie/viscose blended yarn as above becomes method of modifying, modifier pressure abrupt release, produces larger pressure differential instantaneously, significantly can improve the diffusion coefficient of modification medium, ramie/viscose blended yarn being produced fully swelling, is the brilliant critical process process becoming modification.To different ramie/viscose blended yarns, the modifier pressure of requirement is different, and the speed of earth pressure release is different, and the pressure differential produced instantaneously is different, under the prerequisite not improving modifier pressure, obtain release pressure high as far as possible poor, modifier pressure should be made to drop to negative pressure.To ramie/viscose blended yarn, modifier pressure needs to be more than or equal to 1MPa, can reach 4MPa.Therefore described modifier pressure P should be 1 ~ 4MPa.Poor for obtaining high as far as possible release pressure, modifier pressure should be made to drop to negative pressure, therefore the abrupt release of modifier pressure, require modifier pressure drop to instantaneously modifier pressure 1% and below.
The crystalline substance of a kind of ramie/viscose blended yarn as above becomes method of modifying, and in order to specification technological standards, described pressure refers to absolute pressure.
The crystalline substance of a kind of ramie/viscose blended yarn as above becomes method of modifying, obtain excellent swelling effect, require that the time that pressure drops to 1% of modifier pressure from modifier pressure is less than or equal to 5.0 seconds, be advisable at 1 second ~ 5 seconds, therefore the moment of described release pressure is 1 second ~ 5 seconds, and the rate of pressure reduction of corresponding described release pressure is 3MPa/s ~ 5MPa/s.
The crystalline substance of a kind of ramie/viscose blended yarn as above becomes method of modifying, for obtaining the good diffusivity of modification medium and best modified effect, and modifying process energy ezpenditure is minimum, need to regulate and control the flow of ammoniacal liquor in filling process, time and temperature, reach the object of regulation and control pressure, and then regulation and control medium permeability, infiltration rate, evaporation rate, evaporation rate and phase transition process.And boost process is one of most important influence factor, different boost process need be adopted to different yarns, a large number of experiments show that: ramie/viscose blended yarn is applicable to linear boosting, and rate of pressure rise k meets relational expression
wherein t is pressure rising time, k
0for initial boost speed; For ramie/viscose blended yarn, initial boost speed k
0be not less than 0.5MPa/min, can 1.5MPa/min be reached.Therefore described initial boost speed k
0within the scope of 0.5MPa/min ~ 1.5MPa/min.
The crystalline substance of a kind of ramie/viscose blended yarn as above becomes method of modifying, in modifying process, after boosting, pressurize a period of time is to make modification medium can penetrate into more fully in yarn institutional framework, better completes the intermolecular hydrogen bond network reconstruct of yarn fibers.It is all necessary that this process becomes modification to the crystalline substance of all yarns.To ramie/viscose blended yarn, more than pressurize 1min after boosting, the dwell time is advisable at 1 ~ 15min, and therefore after described boosting, the dwell time is 1 ~ 15min.
The crystalline substance of a kind of ramie/viscose blended yarn as above becomes method of modifying, after twice reconstruct of the intermolecular hydrogen bond network of yarn, remove modification medium to be absolutely necessary technical process, this process does not affect the lattice structure of yarn, but how high efficiency, low energy consumption, this process that completes that is pollution-free, zero-emission are the key factors realizing large-scale industrial production, this directly will affect the brilliant vitality becoming method of modifying, high efficiency, low energy consumption, the completing this process and separate case will write series of patents statement again of pollution-free, zero-emission about how.Removing modification medium described in this case is the modification medium adopting heating and vacuumize in parallel method of evaporating removal ramie/viscose blended yarn.
Beneficial effect:
The present invention adopts the advantage of above technical scheme as follows:
1. the present invention reaches modification object by changing crystal structure.Yarn after modification overcomes its native defect, and hole increases, degree of crystallinity reduces, soft yarns, improves the DIMENSIONAL STABILITY of product, flexibility, level-dyeing property and dyeability etc.
2. the present invention adopts the method for abrupt release pressure, makes the maximum swelling sudden strain of a muscle of modified yarn quick-fried, and softness is excellent, wrinkle resistant nonshrink, durable fluffy, significantly improves the spinning of yarn, knits, metachromia energy, becomes remarkable and newly spins material.
Detailed description of the invention
Below in conjunction with detailed description of the invention, set forth the present invention further.Should be understood that these embodiments are only not used in for illustration of the present invention to limit the scope of the invention.In addition should be understood that those skilled in the art can make various changes or modifications the present invention, and these equivalent form of values fall within the application's appended claims limited range equally after the content of having read the present invention's instruction.
Embodiment 1
The crystalline substance of ramie/viscose blended yarn becomes a method of modifying, is 95:5(mass ratio by blending rate) 10 ramie/viscose blended yarns be placed in closed container, be filled with liquefied ammonia, linearly boosting mode boosting, rate of pressure rise k meets relational expression
initial boost speed k
0for 0.5MPa/min, boost to modifier pressure 1Mpa, pressurize 1min, then in 5 seconds with the rate of pressure reduction abrupt release of 3MPa/s to 0.005Mpa.Then adopt the heating method of evaporating parallel with vacuum pump evacuation to remove modification medium, until pressure reduces to 133Pa in closed container, now namely acquisition is brilliant becomes modified ramie/viscose blended yarn.Described crystalline substance becomes the microcosmic lattice of modified ramie/viscose blended yarn compared with the microcosmic lattice of described ramie/viscose blended yarn, and hole increases 16%, and degree of crystallinity reduces 22%; Described crystalline substance becomes modified ramie/viscose blended yarn compared with described ramie/viscose blended yarn, and dye-uptake improves 40%, and COLOR FASTNESS improves 23%.
Embodiment 2
The crystalline substance of ramie/viscose blended yarn becomes a method of modifying, is 50:50(mass ratio by blending rate) 32 ramie/viscose blended yarns be placed in closed container, be filled with liquefied ammonia, linearly boosting mode boosting, rate of pressure rise k meets relational expression
initial boost speed k
0for 1MPa/min, boost to modifier pressure 2Mpa, pressurize 5min, then in 5 seconds with the rate of pressure reduction abrupt release of 3MPa/s to 0.002Mpa.Then adopt the heating method of evaporating parallel with vacuum pump evacuation to remove modification medium, until pressure reduces to 133Pa in closed container, now namely acquisition is brilliant becomes modified ramie/viscose blended yarn.Described crystalline substance becomes the microcosmic lattice of modified ramie/viscose blended yarn compared with the microcosmic lattice of described ramie/viscose blended yarn, and hole increases 17%, and degree of crystallinity reduces 23%; Described crystalline substance becomes modified ramie/viscose blended yarn compared with described ramie/viscose blended yarn, and dye-uptake improves 42%, and COLOR FASTNESS improves 24%.
Embodiment 3
The crystalline substance of ramie/viscose blended yarn becomes a method of modifying, is 20:80(mass ratio by blending rate) 36 ramie/viscose blended yarns be placed in closed container, be filled with liquefied ammonia, linearly boosting mode boosting, rate of pressure rise k meets relational expression
initial boost speed k
0for 1MPa/min, boost to modifier pressure 3Mpa, pressurize 8min, then in 2 seconds with the rate of pressure reduction abrupt release of 4MPa/s to 0.003Mpa.Then adopt the heating method of evaporating parallel with vacuum pump evacuation to remove modification medium, until pressure reduces to 133Pa in closed container, now namely acquisition is brilliant becomes modified ramie/viscose blended yarn.Described crystalline substance becomes the microcosmic lattice of modified ramie/viscose blended yarn compared with the microcosmic lattice of described ramie/viscose blended yarn, and hole increases 18%, and degree of crystallinity reduces 23%; Described crystalline substance becomes modified ramie/viscose blended yarn compared with described ramie/viscose blended yarn, and dye-uptake improves 45%, and COLOR FASTNESS improves 23%.
Embodiment 4
The crystalline substance of ramie/viscose blended yarn becomes a method of modifying, is 5:95(mass ratio by blending rate) 80 ramie/viscose blended yarns be placed in closed container, be filled with liquefied ammonia, linearly boosting mode boosting, rate of pressure rise k meets relational expression
initial boost speed k
0for 1.5MPa/min, boost to modifier pressure 4Mpa, pressurize 10min, then in 1 second with the rate of pressure reduction abrupt release of 5MPa/s to 0.004Mpa.Then adopt the heating method of evaporating parallel with vacuum pump evacuation to remove modification medium, until pressure reduces to 133Pa in closed container, now namely acquisition is brilliant becomes modified ramie/viscose blended yarn.Described crystalline substance becomes the microcosmic lattice of modified ramie/viscose blended yarn compared with the microcosmic lattice of described ramie/viscose blended yarn, and hole increases 20%, and degree of crystallinity reduces 28%; Described crystalline substance becomes modified ramie/viscose blended yarn compared with described ramie/viscose blended yarn, and dye-uptake improves 50%, and COLOR FASTNESS improves 25%.
Claims (6)
1. the crystalline substance of ramie/viscose blended yarn becomes a method of modifying, it is characterized in that: ramie/viscose blended yarn is placed in closed container, is filled with modification medium, boost to modifier pressure, then abrupt release pressure, removes modification medium, namely obtains brilliant change modified ramie/viscose blended yarn; Described modification medium is liquefied ammonia; Described modifier pressure P is 1 ~ 4MPa, described abrupt release pressure be finger pressure drop to instantaneously described modifier pressure 1% and following; Describedly refer to 1 second ~ 5 seconds instantaneously, the rate of pressure reduction of described release pressure is 3MPa/s ~ 5MPa/s; 1min ~ 15min is kept after boosting.
2. the crystalline substance of a kind of ramie/viscose blended yarn according to claim 1 becomes method of modifying, and it is characterized in that, the fineness of described ramie/viscose blended yarn is 10 ~ 80, and blending rate is 5 ~ 95:95 ~ 5 in mass ratio.
3. the crystalline substance of a kind of ramie/viscose blended yarn according to claim 1 becomes method of modifying, it is characterized in that, described crystalline substance becomes the microcosmic lattice of modified ramie/viscose blended yarn compared with the microcosmic lattice of described ramie/viscose blended yarn, hole increases 16% ~ 20%, and degree of crystallinity reduces 22 ~ 28%; Described crystalline substance becomes modified ramie/viscose blended yarn compared with described ramie/viscose blended yarn, and dye-uptake improves 40% ~ 50%, and COLOR FASTNESS improves 23% ~ 25%.
4. the crystalline substance of a kind of ramie/viscose blended yarn according to claim 1 becomes method of modifying, and it is characterized in that, described pressure is absolute pressure.
5. the crystalline substance of a kind of ramie/viscose blended yarn according to claim 1 becomes method of modifying, it is characterized in that, described boosting is linear boosting, and rate of pressure rise k meets relational expression
wherein t is pressure rising time, k
0for initial boost speed; k
0within the scope of 0.5MPa/min ~ 1.5MPa/min.
6. the crystalline substance of a kind of ramie/viscose blended yarn according to claim 1 becomes method of modifying, it is characterized in that, described removal modification medium is the modification medium adopting heating and vacuumize in parallel method of evaporating removal ramie/viscose blended yarn.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310318050.XA CN103437099B (en) | 2013-07-26 | 2013-07-26 | A kind of crystalline substance of ramie/viscose blended yarn becomes method of modifying |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310318050.XA CN103437099B (en) | 2013-07-26 | 2013-07-26 | A kind of crystalline substance of ramie/viscose blended yarn becomes method of modifying |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103437099A CN103437099A (en) | 2013-12-11 |
| CN103437099B true CN103437099B (en) | 2016-01-06 |
Family
ID=49690811
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310318050.XA Expired - Fee Related CN103437099B (en) | 2013-07-26 | 2013-07-26 | A kind of crystalline substance of ramie/viscose blended yarn becomes method of modifying |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103437099B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102704095A (en) * | 2012-06-11 | 2012-10-03 | 东华大学 | Method for spinning high-grade knitting yarns by using long flax fibers |
| CN102787460A (en) * | 2011-05-17 | 2012-11-21 | 东华大学 | Method for modifying continuous multistage cotton and linen yarns |
| CN102839508A (en) * | 2012-09-06 | 2012-12-26 | 东华大学 | High-grade flax fabric weaving method based on crystallized and modified flax yarns |
-
2013
- 2013-07-26 CN CN201310318050.XA patent/CN103437099B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102787460A (en) * | 2011-05-17 | 2012-11-21 | 东华大学 | Method for modifying continuous multistage cotton and linen yarns |
| CN102704095A (en) * | 2012-06-11 | 2012-10-03 | 东华大学 | Method for spinning high-grade knitting yarns by using long flax fibers |
| CN102839508A (en) * | 2012-09-06 | 2012-12-26 | 东华大学 | High-grade flax fabric weaving method based on crystallized and modified flax yarns |
Non-Patent Citations (1)
| Title |
|---|
| 闪爆处理对大麻纤维结构与性能的影响;吴君南等;《纺织学报》;20080430;第29卷(第4期);第14-17页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103437099A (en) | 2013-12-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103437096B (en) | A kind of crystalline substance of cotton fiber becomes method of modifying | |
| CN103422277B (en) | A kind of compound crystal variation modification method of cotton | |
| CN103422282B (en) | A kind of crystalline substance of sodolin becomes method of modifying | |
| CN103437097B (en) | A kind of crystalline substance of ramee becomes method of modifying | |
| CN103422279B (en) | A kind of crystalline substance of linen thread and yarn becomes method of modifying | |
| CN103437148B (en) | A kind of crystalline substance of viscose yarn becomes method of modifying | |
| CN103422278B (en) | A kind of crystalline substance of cotton becomes method of modifying | |
| CN103437099B (en) | A kind of crystalline substance of ramie/viscose blended yarn becomes method of modifying | |
| CN103422280B (en) | The crystalline substance of a kind of cotton/linen blend yarn becomes method of modifying | |
| CN103422286B (en) | A kind of compound crystal variation modification method of cotton/ramie fibre mixed fabrics | |
| CN103437156B (en) | Crystal variation modification method of cotton/flax/viscose blended yarn | |
| CN103437101B (en) | A kind of compound crystal variation modification method of sodolin | |
| CN103422271B (en) | A kind of crystalline substance of tossa becomes method of modifying | |
| CN103437092B (en) | A kind of linen thread and yarn crystalline substance becomes modification and weaves the method for sodolin | |
| CN103437149B (en) | A kind of brilliant change method of modifying | |
| CN103437152B (en) | Crystal variation modification method of ambari fiber | |
| CN103437154B (en) | Crystal variation modification method of cotton/flax blended fabric | |
| CN103422284B (en) | The crystalline substance of a kind of cotton/flax MIXED FABRIC becomes method of modifying | |
| CN103422285B (en) | A kind of crystalline substance of ramie fabric becomes method of modifying | |
| CN103422276B (en) | A kind of cotton/linen blend yarn crystalline substance becomes modification and weaves the method for BLENDED FABRIC | |
| CN103422275B (en) | A kind of cotton/linen thread and yarn crystalline substance becomes modification and weaves the method for MIXED FABRIC | |
| CN103437151B (en) | Compound crystal variation modification method of ramie fiber | |
| CN103437098B (en) | A kind of crystalline substance of viscose becomes method of modifying | |
| CN103437095B (en) | A kind of crystalline substance of linen fibre becomes method of modifying | |
| CN103437093B (en) | A kind of cotton crystalline substance becomes modification and the method for woven cotton fabric |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C53 | Correction of patent for invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Sun Yize Inventor after: Meng Chuo Inventor after: Ji Chengchang Inventor after: Huang Shuang Inventor after: Sun Zhijun Inventor before: Sun Yize Inventor before: Meng Chuo Inventor before: Huang Shuang Inventor before: Sun Zhijun |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: SUN YIZE MENG NAO HUANG SHUANG SUN ZHIJUN TO: SUN YIZE MENG NAO JI CHENGCHANG HUANG SHUANG SUN ZHIJUN |
|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160106 Termination date: 20180726 |