CN103403059B - 制备包含醚键的二氧化碳/环氧化物共聚物的方法 - Google Patents

制备包含醚键的二氧化碳/环氧化物共聚物的方法 Download PDF

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Publication number
CN103403059B
CN103403059B CN201280011890.5A CN201280011890A CN103403059B CN 103403059 B CN103403059 B CN 103403059B CN 201280011890 A CN201280011890 A CN 201280011890A CN 103403059 B CN103403059 B CN 103403059B
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atoms
atom
alkyl
aryl
halogen
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CN103403059A (zh
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郑智水
罗盛载
苏吉·苏德维安
玉明岸
韩龙圭
丁光镇
李泍烈
柯迪燕·瓦吉斯·约比
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Aiskai Zhixin Co Ltd
SK Innovation Co Ltd
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SK Innovation Co Ltd
SK Global Chemical Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/20—General preparatory processes
    • C08G64/32—General preparatory processes using carbon dioxide
    • C08G64/34—General preparatory processes using carbon dioxide and cyclic ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/20—General preparatory processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/20—General preparatory processes
    • C08G64/32—General preparatory processes using carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyesters Or Polycarbonates (AREA)
CN201280011890.5A 2011-03-08 2012-02-29 制备包含醚键的二氧化碳/环氧化物共聚物的方法 Active CN103403059B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
KR10-2011-0020143 2011-03-08
KR1020110020143A KR101404702B1 (ko) 2011-03-08 2011-03-08 에테르 결합 단위체를 함유한 이산화탄소/에폭사이드 공중합체의 제조 방법
PCT/KR2012/001528 WO2012121508A2 (en) 2011-03-08 2012-02-29 Method for preparing carbon dioxide/epoxide copolymers containing ether linkages

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CN103403059A CN103403059A (zh) 2013-11-20
CN103403059B true CN103403059B (zh) 2015-03-25

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US (1) US8871898B2 (enExample)
EP (1) EP2683757A4 (enExample)
JP (1) JP2014508836A (enExample)
KR (1) KR101404702B1 (enExample)
CN (1) CN103403059B (enExample)
TW (1) TW201242990A (enExample)
WO (1) WO2012121508A2 (enExample)

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GB201308978D0 (en) 2013-05-17 2013-07-03 Imp Innovations Ltd Method for producing polymers and block copolymers
WO2016203408A1 (en) 2015-06-15 2016-12-22 King Abdullah University Of Science And Technology Use of additives to fine-tune the composition of carbonate units in the polymer formed by copolymerization of co2 with epoxide: application to the synthesis of polycarbonate-based block copolymers and of telechelics
GB201514506D0 (en) 2015-08-14 2015-09-30 Imp Innovations Ltd Multi-block copolymers
GB201515350D0 (en) * 2015-08-28 2015-10-14 Econic Technologies Ltd Method for preparing polyols
CN105482093B (zh) * 2016-01-21 2017-11-14 中国科学院长春应用化学研究所 一种二氧化碳‑环氧丙烷改性共聚物及其制备方法和二氧化碳基生物降解地膜
KR102409995B1 (ko) * 2016-02-26 2022-06-15 에스케이이노베이션 주식회사 폴리(알킬렌 카보네이트)폴리올의 제조방법
CN107793557B (zh) * 2016-08-31 2020-06-09 中国石油化工股份有限公司 一种蒽醌类聚合物的制备方法和应用
KR101804762B1 (ko) * 2017-02-16 2017-12-05 한국과학기술연구원 알킬렌 카보네이트 제조용 촉매, 그 제조 방법 및 상기 촉매를 이용한 알킬렌 카보네이트 제조 방법 및 장치
GB201703323D0 (en) * 2017-03-01 2017-04-12 Econic Tech Ltd Method for preparing polyols
GB201703324D0 (en) * 2017-03-01 2017-04-12 Econic Tech Ltd Method for preparing polyether carbonates
GB201703331D0 (en) * 2017-03-01 2017-04-12 Econic Tech Ltd Method for preparing polycarbonate ether polyols
GB201717459D0 (en) * 2017-10-24 2017-12-06 Econic Tech Limited Methods for forming polycarbonate ether polyols and high molecular weight polyether carbonates
CN108772102B (zh) * 2018-04-16 2021-04-23 兰州大学 高效催化二氧化碳合成环碳酸酯的杂多金属高效催化剂
GB201814526D0 (en) 2018-09-06 2018-10-24 Econic Tech Ltd Methods for forming polycarbonate ether polyols and high molecular weight polyether carbonates
CN111303217B (zh) * 2020-04-03 2023-04-11 陕西煤业化工技术研究院有限责任公司 一种salen型席夫碱改性DMC催化剂的制备及其应用
CN114790285A (zh) * 2021-01-26 2022-07-26 万华化学集团股份有限公司 一种用于环氧化物连续聚合的诱导体系、诱导剂以及环氧化物连续聚合的方法
GB202115335D0 (en) * 2021-10-25 2021-12-08 Econic Tech Ltd Surface-active agent
CN113801314B (zh) * 2021-11-03 2023-01-10 中国科学院过程工程研究所 一种聚碳酸酯的制备方法
CN115612085B (zh) * 2022-12-05 2023-03-31 山东联欣环保科技有限公司 一种合成二氧化碳基多元共聚物同时联产pc的方法

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Publication number Publication date
KR101404702B1 (ko) 2014-06-17
KR20120102183A (ko) 2012-09-18
US8871898B2 (en) 2014-10-28
EP2683757A4 (en) 2015-04-29
WO2012121508A2 (en) 2012-09-13
JP2014508836A (ja) 2014-04-10
EP2683757A2 (en) 2014-01-15
WO2012121508A3 (en) 2012-10-26
TW201242990A (en) 2012-11-01
CN103403059A (zh) 2013-11-20
US20120232245A1 (en) 2012-09-13

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Address after: Seoul, South Kerean

Patentee after: SK INNOVATION Co.,Ltd.

Patentee after: Aiskai Zhixin Co., Ltd

Address before: Seoul, South Kerean

Patentee before: SK INNOVATION Co.,Ltd.

Patentee before: Sk Integrated Chemical Co., Ltd