CN103374188B - 含表面官能化纳米微晶纤维素的强化含氟聚合物复合物 - Google Patents
含表面官能化纳米微晶纤维素的强化含氟聚合物复合物 Download PDFInfo
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- CN103374188B CN103374188B CN201310129557.0A CN201310129557A CN103374188B CN 103374188 B CN103374188 B CN 103374188B CN 201310129557 A CN201310129557 A CN 201310129557A CN 103374188 B CN103374188 B CN 103374188B
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- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
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- 238000009832 plasma treatment Methods 0.000 description 1
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- 239000000047 product Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 239000012429 reaction media Substances 0.000 description 1
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- 150000003335 secondary amines Chemical class 0.000 description 1
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- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
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- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
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- 239000002023 wood Substances 0.000 description 1
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- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B15/00—Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
- C08B15/05—Derivatives containing elements other than carbon, hydrogen, oxygen, halogens or sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
- C08J3/247—Heating methods
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/02—Cellulose; Modified cellulose
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08J2327/20—Homopolymers or copolymers of hexafluoropropene
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Biochemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Artificial Filaments (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/446,519 US9328256B2 (en) | 2012-04-13 | 2012-04-13 | Reinforced fluoropolymer composites comprising surface functionalized nanocrystalline cellulose |
| US13/446519 | 2012-04-13 | ||
| US13/446,519 | 2012-04-13 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103374188A CN103374188A (zh) | 2013-10-30 |
| CN103374188B true CN103374188B (zh) | 2017-10-03 |
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Country Status (4)
| Country | Link |
|---|---|
| US (1) | US9328256B2 (https=) |
| JP (1) | JP6178603B2 (https=) |
| CN (1) | CN103374188B (https=) |
| DE (1) | DE102013205716A1 (https=) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2014001360A (ja) * | 2012-05-25 | 2014-01-09 | Olympus Corp | エラストマー組成物および成形体 |
| CN103588886B (zh) * | 2013-11-19 | 2016-08-17 | 武汉理工大学 | 一种易水分散纳米微晶纤维素及其制备方法 |
| CN105885096B (zh) * | 2015-01-26 | 2019-03-19 | 中国科学院理化技术研究所 | 一种疏水性纤维素材料及其制备方法和应用 |
| CN105908502B (zh) * | 2016-06-23 | 2018-03-27 | 杭州余杭兴隆绸厂 | 一种免洗剂以及采用该免洗剂处理得到的免洗面料 |
| JP7402049B2 (ja) * | 2017-04-28 | 2023-12-20 | カウンスィル オブ サイエンティフィック アンド インダストリアル リサーチ | 有機可撓性強誘電性ポリマーナノコンポジット |
| CN108276687B (zh) * | 2018-02-13 | 2020-01-24 | 太仓荣南密封件科技有限公司 | 一种纳米微晶ncc增强橡胶材料及其制备方法 |
| CN109095580A (zh) * | 2018-09-13 | 2018-12-28 | 石狮市中纺学服装及配饰产业研究院 | 一种废旧棉纺织品的再生利用方法 |
| CN109758970B (zh) * | 2018-12-12 | 2021-03-23 | 衢州学院 | 一种纳米纤维素基含氟高分子表面活性剂及其制备方法 |
| CN112663159B (zh) * | 2020-12-14 | 2022-11-11 | 哈尔滨理工大学 | 一种各向同性相和胆甾相交替排布的纤维素纳米晶纤维的制备方法 |
| CN117683450A (zh) * | 2024-02-04 | 2024-03-12 | 中建国际工程有限公司 | 一种水性纳米防水涂料及其制备方法和应用 |
Citations (1)
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| CN102791911A (zh) * | 2010-03-05 | 2012-11-21 | 奥林巴斯株式会社 | 纤维素纳米纤维及其制造方法、复合树脂组合物、成型体 |
Family Cites Families (14)
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|---|---|---|---|---|
| GB1120373A (en) * | 1966-05-31 | 1968-07-17 | Ici Ltd | Film-forming cellulose compounds |
| US4433028A (en) * | 1983-01-03 | 1984-02-21 | M.J.H. Converters, Inc. | Method of treating cellulose di-acetate fibers |
| US4549012A (en) * | 1984-08-13 | 1985-10-22 | Sharma Ashok K | Fluorinated cellulose acetate polymers |
| GB8610739D0 (en) * | 1986-05-01 | 1986-06-04 | Foseco Int | Exothermic compositions |
| WO1994002547A1 (en) * | 1992-07-21 | 1994-02-03 | E.I. Du Pont De Nemours And Company | Polytetrafluoroethylene with improved creep resistance, and preparation thereof |
| IT1312016B1 (it) * | 1999-03-19 | 2002-04-04 | Ausimont Spa | Polimeri fluorurati modificati reticolabili. |
| EP1995269B1 (en) * | 2001-10-24 | 2017-10-04 | Daikin Industries, Ltd. | PTFE powder and method of producing PTFE molding powders |
| US7135527B2 (en) * | 2004-03-30 | 2006-11-14 | Freudenberg-Nok General Partnership | Elastomeric compositions containing fluoropolymer blends |
| EP1792941B1 (en) * | 2004-09-17 | 2011-05-18 | Toray Industries, Inc. | Resin composition and molded article comprising the same |
| JP5207246B2 (ja) * | 2006-07-19 | 2013-06-12 | 国立大学法人京都大学 | セルロースｉｉ型結晶構造を有するミクロフィブリル化セルロース及び該ミクロフィブリル化セルロースを含有する成形体 |
| JP5578841B2 (ja) * | 2009-12-08 | 2014-08-27 | 日本バルカー工業株式会社 | 充填材入りフッ素樹脂シートの製造方法および充填材入りフッ素樹脂シート |
| JP2011148939A (ja) * | 2010-01-25 | 2011-08-04 | Konica Minolta Holdings Inc | 繊維複合材料 |
| JP5640447B2 (ja) * | 2010-05-06 | 2014-12-17 | コニカミノルタ株式会社 | 積層体 |
| US8674013B2 (en) * | 2012-04-13 | 2014-03-18 | Xerox Corporation | Methods for preparing reinforced fluoropolymer composites comprising surface functionalized nanocrystalline cellulose |
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- 2013-04-15 CN CN201310129557.0A patent/CN103374188B/zh not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102791911A (zh) * | 2010-03-05 | 2012-11-21 | 奥林巴斯株式会社 | 纤维素纳米纤维及其制造方法、复合树脂组合物、成型体 |
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| Title |
|---|
| "Design of Highly Oleophobic Cellulose Surfaces from Structured Silicon Templates";Christian Aulin等;《Appl. Mater. Interfaces》;20091020;第1卷(第11期);实验部分 * |
Also Published As
| Publication number | Publication date |
|---|---|
| DE102013205716A1 (de) | 2013-10-17 |
| US20130274406A1 (en) | 2013-10-17 |
| JP2013221152A (ja) | 2013-10-28 |
| CN103374188A (zh) | 2013-10-30 |
| JP6178603B2 (ja) | 2017-08-09 |
| US9328256B2 (en) | 2016-05-03 |
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