CN103351550B - 一种pvc电缆料及其制备方法 - Google Patents
一种pvc电缆料及其制备方法 Download PDFInfo
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- CN103351550B CN103351550B CN201310243525.3A CN201310243525A CN103351550B CN 103351550 B CN103351550 B CN 103351550B CN 201310243525 A CN201310243525 A CN 201310243525A CN 103351550 B CN103351550 B CN 103351550B
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- minute
- ester
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- chloroprene rubber
- calcium stearate
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- 239000000463 material Substances 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229920001084 poly(chloroprene) Polymers 0.000 claims abstract description 16
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims abstract description 14
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims abstract description 10
- 235000013539 calcium stearate Nutrition 0.000 claims abstract description 10
- 239000008116 calcium stearate Substances 0.000 claims abstract description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 8
- -1 dimethyl dimercapto 2-ethyl hexyl ethanoate tin Chemical compound 0.000 claims abstract description 8
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004593 Epoxy Substances 0.000 claims abstract description 7
- 229960000892 attapulgite Drugs 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 7
- 238000012986 modification Methods 0.000 claims abstract description 7
- 230000004048 modification Effects 0.000 claims abstract description 7
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 7
- 229910017083 AlN Inorganic materials 0.000 claims abstract description 5
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 claims abstract description 5
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 4
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000005642 Oleic acid Substances 0.000 claims abstract description 4
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 4
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 4
- 239000006229 carbon black Substances 0.000 claims abstract description 4
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 4
- 239000011651 chromium Substances 0.000 claims abstract description 4
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 229920002545 silicone oil Polymers 0.000 claims abstract description 4
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 4
- 239000011787 zinc oxide Substances 0.000 claims abstract description 4
- 229940126062 Compound A Drugs 0.000 claims description 6
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims description 3
- 229940037003 alum Drugs 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- OMQSJNWFFJOIMO-UHFFFAOYSA-J zirconium tetrafluoride Chemical compound F[Zr](F)(F)F OMQSJNWFFJOIMO-UHFFFAOYSA-J 0.000 claims description 3
- 239000000178 monomer Substances 0.000 claims 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 2
- 229920002554 vinyl polymer Polymers 0.000 claims 2
- 150000002148 esters Chemical class 0.000 abstract description 5
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 abstract description 5
- 239000006185 dispersion Substances 0.000 abstract description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 10
- 239000004800 polyvinyl chloride Substances 0.000 description 10
- 239000003063 flame retardant Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
- Insulated Conductors (AREA)
Abstract
Description
项 目 | 单 位 | 本发明电缆料 |
原始拉伸强度 | MPa 不小于 | 18.00 |
原始断裂伸长率 | % 不小于 | 430 |
耐158℃×168h老化后 | ||
断裂强度 | MPa 不小于 | 17 |
断裂伸长率 | % 不小于 | 410 |
20℃体积电阻率 | Ω·m | 1.0×1012 |
200℃热稳定时间 | Min | 50 |
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201310243525.3A CN103351550B (zh) | 2013-06-19 | 2013-06-19 | 一种pvc电缆料及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201310243525.3A CN103351550B (zh) | 2013-06-19 | 2013-06-19 | 一种pvc电缆料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN103351550A CN103351550A (zh) | 2013-10-16 |
CN103351550B true CN103351550B (zh) | 2015-11-25 |
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CN201310243525.3A Active CN103351550B (zh) | 2013-06-19 | 2013-06-19 | 一种pvc电缆料及其制备方法 |
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Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103756192B (zh) * | 2014-01-10 | 2016-05-04 | 安徽瑞升电气科技有限公司 | 一种耐温125℃的聚氯乙烯电缆料 |
CN104109302A (zh) * | 2014-06-21 | 2014-10-22 | 朱六璋 | 一种架空绝缘电缆料 |
CN104194417B (zh) * | 2014-08-06 | 2016-04-20 | 明光市国星凹土有限公司 | 一种改性凹凸棒土填料及其制备方法 |
CN104194088B (zh) * | 2014-08-06 | 2016-06-08 | 明光市国星凹土有限公司 | 一种耐热橡胶填料及其制备方法 |
CN104194459A (zh) * | 2014-08-06 | 2014-12-10 | 明光市国星凹土有限公司 | 一种涂料用改性凹凸棒土填料及其制备方法 |
CN105111656A (zh) * | 2015-09-30 | 2015-12-02 | 淄博夸克医药技术有限公司 | 一种电缆绝缘层用改性天然橡胶复合材料 |
CN106432976A (zh) * | 2016-10-18 | 2017-02-22 | 苏天平 | 一种加强型铜芯电缆的制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5020585B2 (ja) * | 2006-09-27 | 2012-09-05 | 株式会社トプコン | 測定システム |
CN102964724A (zh) * | 2012-11-27 | 2013-03-13 | 宁波一舟塑胶有限公司 | 一种汽车用薄壁绝缘电线料及其制备方法 |
CN103224671A (zh) * | 2013-03-26 | 2013-07-31 | 安徽五洲特种电缆集团有限公司 | 一种高强度耐扭转风能电缆料及其制备方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS58143134A (ja) * | 1982-02-18 | 1983-08-25 | Toyota Motor Corp | 内燃機関の運転調整装置 |
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5020585B2 (ja) * | 2006-09-27 | 2012-09-05 | 株式会社トプコン | 測定システム |
CN102964724A (zh) * | 2012-11-27 | 2013-03-13 | 宁波一舟塑胶有限公司 | 一种汽车用薄壁绝缘电线料及其制备方法 |
CN103224671A (zh) * | 2013-03-26 | 2013-07-31 | 安徽五洲特种电缆集团有限公司 | 一种高强度耐扭转风能电缆料及其制备方法 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
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Denomination of invention: PVC cable material and preparation method thereof Effective date of registration: 20190412 Granted publication date: 20151125 Pledgee: Tianchang Science and Technology Financing Guarantee Co., Ltd. Pledgor: Anhui Cable Co., Ltd. Registration number: 2019340000197 |
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Denomination of invention: PVC cable material and preparation method thereof Effective date of registration: 20200421 Granted publication date: 20151125 Pledgee: Tianchang Science and Technology Financing Guarantee Co., Ltd. Pledgor: ANHUI CABLE Co.,Ltd. Registration number: Y2020980001678 |
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Date of cancellation: 20210414 Granted publication date: 20151125 Pledgee: Tianchang Science and Technology Financing Guarantee Co.,Ltd. Pledgor: ANHUI CABLE Co.,Ltd. Registration number: Y2020980001678 |
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Denomination of invention: A PVC cable material and its preparation method Effective date of registration: 20210416 Granted publication date: 20151125 Pledgee: Tianchang Science and Technology Financing Guarantee Co.,Ltd. Pledgor: ANHUI CABLE Co.,Ltd. Registration number: Y2021980002725 |
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Date of cancellation: 20220408 Granted publication date: 20151125 Pledgee: Tianchang Science and Technology Financing Guarantee Co.,Ltd. Pledgor: ANHUI CABLE Co.,Ltd. Registration number: Y2021980002725 |
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Denomination of invention: PVC cable material and preparation method thereof Effective date of registration: 20220414 Granted publication date: 20151125 Pledgee: Tianchang Science and Technology Financing Guarantee Co.,Ltd. Pledgor: ANHUI CABLE Co.,Ltd. Registration number: Y2022980004178 |