CN103347545B - Deodorant containing polyvalent alcohol - Google Patents
Deodorant containing polyvalent alcohol Download PDFInfo
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- CN103347545B CN103347545B CN201280008030.6A CN201280008030A CN103347545B CN 103347545 B CN103347545 B CN 103347545B CN 201280008030 A CN201280008030 A CN 201280008030A CN 103347545 B CN103347545 B CN 103347545B
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- deodorant
- smelly
- extract
- butylene glycol
- age
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Abstract
The problem addressed by the present invention is to provide a deodorant for deodorizing body odor, particularly the "old person smell" inherent to middle- and old-aged people, the deodorant being safe to use and having a strong deodorizing effect. By having the deodorant contain polyvalent alcohol, in particular 1,3-butylene glycol, as an active ingredient, it is possible to provide a deodorant with an outstanding deodorizing effect. The deodorant is particularly effective in deodorizing unsaturated aldehydes, which are the main cause of "old person smell".
Description
Technical field
The present invention relates to deodorant.Say in further detail, the present invention is containing polyhydric alcohol, the particularly 1,3 butylene glycol deodorant as effective ingredient, the invention reside in provide to add smelly inhibitor in age for what have an excellent smelly eliminating effect as the unsaturated aldehyde adding smelly reason material in age.In addition, the present invention relates to and coordinated 1,3 butylene glycol, oolong tea extract and sweet tea extract and the compositions formed.
Background technology
In recent years, be subject to the impact of the value of the consumer pursuing more comfortable living space, the raising of demand, develop various deodorant, deodorant or aromatic.In addition, the care of consumer to body odor also progressively improves, and the demand in recent years for the product with deodorizing effect also increases gradually.
Known among body odor, as mainly stink, i.e. so-called " adding age smelly " of recognizing by middle-aged and elderly people profoundly relevant to the unsaturated aldehyde of octenal, nonenyl aldehyde etc.Specifically, the known palmitoleic acid (palmitoleic acid) increased in the sebum of person in middle and old age's layer in age is by the oxidation Decomposition of being undertaken by lipid peroxide or reside bacterium by skin and decompose, and can produce the nonenyl aldehyde (patent documentation 1) as odorant.
Add smelly technology in age as removing, report the method (patent documentation 1) be in harmonious proportion by perfume masking by the unsaturated aldehyde of generation, the method (patent documentation 2) caught with ethanolamine.In addition, there was reported and suppress the generation becoming unsaturated aldehyde in the sebum of the reason adding smelly generation in age to suppress to add smelly method in age.Specifically, report the method suppressing unsaturated aldehyde to produce by the following method, by antioxidant inhibited oxidation (patent documentation 3), suppress the generation (patent documentation 4) of lipid peroxide by lipoxygenase inhibitor, resided the antibacterial Inhibit proliferaton (patent documentation 5) of bacterium by the skin relevant to the generation of fatty acid.
On the other hand, in cosmetic preparation, coordinated the cosmetic preparation of polyhydric alcohol a lot, often used glycerol, propylene glycol, dipropylene glycol, 1,3 butylene glycol from the viewpoint of supply stability.Among those, known have non-volatile, hypotoxicity, moisture retention character due to 1,3 butylene glycol, thus useful in cosmetic applications.Specifically, it is reported that there is moisture-keeping function (patent documentation 6), antibacterial action antisepsis (patent documentation 7).
Prior art document
Patent documentation
Patent documentation 1 Japanese Unexamined Patent Publication 11-286428 publication
Patent documentation 2 Japanese Unexamined Patent Publication 2001-97838 publication
Patent documentation 3 Japanese Unexamined Patent Publication 11-286423 publication
Patent documentation 4 Japanese Unexamined Patent Publication 11-286424 publication
Patent documentation 5 Japanese Unexamined Patent Publication 11-286425 publication
Patent documentation 6 Japanese Unexamined Patent Publication 8-259433 publication (Japan Patent No. 3159622 publication)
Patent documentation 7 Japanese Unexamined Patent Publication 2003-238328 publication
Summary of the invention
The object of the present invention is to provide smelly eliminating effective and the high deodorant of safety or compositions.
Present inventors etc. have carried out further investigation repeatedly, found that polyhydric alcohol, particularly 1,3 butylene glycol have smelly eliminating effect.Particularly find that they have obvious smelly eliminating effect for as the unsaturated aldehyde adding smelly reason material in age, thus complete the present invention.
Namely the present invention relates to following content, but be not limited to this.
(1) deodorant, is characterized in that, the C2 ~ C6 alcohol containing 2 yuan or 3 yuan is as effective ingredient.
(2) according to the deodorant described in (1), it is characterized in that, described alcohol is 1,3 butylene glycol.
(3) according to (1) or the deodorant described in (2), it is characterized in that, for adding smelly smelly eliminating in age.
(4) according to the deodorant according to any one of (1) ~ (3), it is characterized in that, malodorous elements is unsaturated aldehyde.
(5) according to the deodorant described in (4), it is characterized in that, unsaturated aldehyde is nonenyl aldehyde or octenal.
(6) a smelly eliminating compositions, is characterized in that, coordinated (1) ~ (5) according to any one of deodorant and formed.
(7) according to the smelly eliminating compositions described in (6), it is characterized in that, be skin preparations for extenal use.
(8) compositions, is characterized in that, has coordinated 1,3 butylene glycol, oolong tea extract and sweet tea extract and has formed.
The invention reside in providing package containing polyhydric alcohol, the particularly 1,3 butylene glycol deodorant with excellent smelly eliminating effect as effective ingredient.Because deodorant of the present invention particularly has inhibition, so can be coupled in the smelly eliminating compositions for the purpose of smelly eliminating suppresses for adding age smelly reason material.Wherein, can be coupled in the smelly eliminating compositions added for the purpose of smelly suppression in age.In addition, in alternate manner of the present invention, the compositions by coordinating 1,3 butylene glycol, oolong tea extract and sweet tea extract with excellent smelly eliminating effect can be provided.
Detailed description of the invention
< deodorant >
The feature of deodorant of the present invention is to comprise C2 ~ C6 alcohol of polyhydric alcohol, specifically 2 yuan or 3 yuan as effective ingredient.
Deodorant of the present invention is for the purpose of the smelly eliminating for various malodorous elements, wherein using as along with the adding for the purpose of smelly smelly eliminating in age of body odor adding age, provide especially for as the deodorant of unsaturated aldehyde (nonenyl aldehyde, octenal etc.) adding smelly reason material in age.
Below, embodiments of the present invention are described in detail.
the effective ingredient of deodorant
The effective ingredient of deodorant of the present invention is polyhydric alcohol, is specifically C2 ~ C6 alcohol of 2 yuan or 3 yuan.As C2 ~ C6 alcohol of 2 yuan or 3 yuan, include, for example glycerol, ethylene glycol, propylene glycol, BDO, diethylene glycol, dipropylene glycol, 1,3 butylene glycol, pentanediol, hexanediol etc.Among those, preferably C2 ~ C6 alcohol of 2 yuan, particularly preferably 1,3 butylene glycol.
The amount of the above-mentioned effective ingredient in deodorant is not particularly limited, and effective ingredient can be 100 % by weight, also can be 0.01 ~ 99 % by weight, preferably 1 ~ 50 % by weight, further preferably 5 ~ 30 % by weight.
smelly eliminating effect
Deodorant of the present invention all has effect for various stink.Include, for example stink, the stink of Nicotiana tabacum L., the stink of clothes, the stink etc. of footwear of body odor (stink, halitosis etc. of bromhidrosis, foot odor, fetid sweat, scalp), the stink of house pet, the stink in lavatory, the stink in kitchen, the food such as stink, fish, vegetable of refrigerator.
Therefore, deodorant of the present invention, such as, can be used as in halitosis deodorant, body odor deodorant, house pet deodorant, domestic animal deodorant, deodorant for kitchen use, lavatory deodorant, indoor deodorant, life deodorant, car and use with deodorant, industrial deodorant etc.
In addition, deodorant of the present invention is particularly for smellyly having effect the age that adds in body odor.Smelly as adding age, be not particularly limited as long as add age smelly middle comprised stink, the unsaturated aldehyde especially for nonenyl aldehyde and octenal etc. has effect.
Deodorant of the present invention also can remain on carrier and use.As the example of carrier, the glue class of agar, gelatin, carrageenan, arabic gum etc. can be enumerated, the gel of polyvinyl alcohol, polyacrylamide etc., the fiber of various celluloses etc., the porous material etc. of zeolite, porous glass, pottery, activated carbon, silicon dioxide, silicate etc.
< smelly eliminating compositions >
Smelly eliminating compositions of the present invention can coordinate above-mentioned deodorant to prepare.
The use level of the deodorant in smelly eliminating compositions is not particularly limited, and above-mentioned effective ingredient can be 100 % by weight, also can be 0.01 ~ 99 % by weight, preferably 1 ~ 50 % by weight, further preferably 5 ~ 30 % by weight.
Deodorant of the present invention can be coordinated separately, also can combine to coordinate with other deodorizing ingredient in addition.The deodorizing ingredient that can share, without limit processed especially, include, for example known screening agent, adsorbent, porous material etc.In addition, adding smelly inhibition in age to improve further, can share known for adding smelly deodorant in age, such as antioxidant, lipoxygenase inhibitor, antibacterial, shelter and be in harmonious proportion spice, ethanolamine etc.In addition, extract or the ground product of the such plant component of oolong tea, Folium hydrangeae strigosae, green tea, persimmon, Radix Scutellariae, Radix Oenotherae erythrosepalae, Caulis Sacchari sinensis can also be added.Wherein, can preferably use adding the smelly oolong tea of smelly eliminating excellent effect or the extract of Folium hydrangeae strigosae or ground product in age.
As the mode of smelly eliminating compositions, preferably use as skin preparations for extenal use.Such as, Cleansing Foam, soap, oral care product (collutory (mouthwash), dentifrice etc.), shampoo, Rinsing, hair conditioner, suppurative mastitis, hair liquid, hair growth liquor can be enumerated, educate and send out hair growth promoter, astringent, emulsion, cream etc.
In addition, in the scope not damaging effect of the present invention, other composition, additive can also be coordinated in smelly eliminating compositions of the present invention.As these compositions, additive, the wax class of the oils of plant wet goods, lanoline, Cera Flava etc., hydro carbons, fatty acid, higher alcohols, esters, various surfactants, wetting agent, whitening agent, pigment, coloring agent, pigment, sweeting agent, nutrition enhancer, spice, vitamins, aminoacid, plant animal extract component, UV absorbent, antioxidant, anticorrosion and bactericidal agent etc. can be enumerated.
< compositions >
Compositions in an embodiment of the invention contains 1,3 butylene glycol, oolong tea extract and sweet tea extract.In addition, also can coordinate green tea extract and/or persimmon extract further in the present compositions, also can coordinate other composition.Particularly preferably compositions is used as smelly eliminating compositions.
The preparation of oolong tea extract, sweet tea extract, green tea extract and persimmon extract is undertaken by any one method known in those skilled in the art.And these extracts can be solid also can be liquid, the pulverized product of leaf, fruit also can be comprised.In addition, as long as comprise the unrequired abstraction process of mode from the effective ingredient of oolong tea, Folium hydrangeae strigosae, green tea and persimmon.
The content of the 1,3 butylene glycol in compositions of the present invention is not particularly limited, and is 0.01 ~ 99 % by weight, preferably 1 ~ 70 % by weight, further preferably 5 ~ 60 % by weight.In addition, total use level of the oolong tea extract in compositions and sweet tea extract or add total use level also special indefinite of total extract of green tea extract and/or persimmon extract in the composition further, convert with dry weight and make to become 0.0001 ~ 90 % by weight, preferably 0.005 ~ 50 % by weight, preferably 0.001 ~ 10 % by weight to coordinate further.
The use level of each extract is also not particularly limited, such as, when using 2 kinds of oolong tea extract and sweet tea extract or add the extract of green tea extract and/or persimmon extract 3 kinds or 4 kinds in them, the match ratio of the extract in each combination is not particularly limited, but the dry weight of the extract of amount that can be minimum is standard, make that the dry weight of other extract becomes 1 ~ 10 times amount, preferably 1 ~ 5 times amount, preferably 1 ~ 2 times amount coordinates further respectively.
Be coupled to the composition comprised in the composition or the green tea extract that can coordinate further and/or persimmon extract comprised in oolong tea extract in compositions of the present invention and sweet tea extract to be not particularly limited, the main constituent as these extracts can enumerate polyphenol.Polyphenol is the general name of the compound in 1 molecule with multiple phenolic hydroxyl group, is not particularly limited, and is the tannin, flavonoid, catechin etc. that extract from the Folium Camelliae sinensis, persimmon etc. of oolong tea, Folium hydrangeae strigosae, green tea etc.
As the compositions in an embodiment of the invention, preferably use as skin preparations for extenal use.Such as, Cleansing Foam, soap, oral care product (collutory (mouthwash), dentifrice etc.), shampoo, Rinsing, hair conditioner, suppurative mastitis, hair liquid, hair growth liquor can be enumerated, educate and send out hair growth promoter, astringent, emulsion, cream etc.
In addition, in the scope not damaging effect of the present invention, also other composition, additive can be coordinated in as the compositions of an embodiment of the invention.As these compositions, additive, the extract obtained from plant material of Radix Scutellariae, Radix Oenotherae erythrosepalae, Caulis Sacchari sinensis etc. or the wax class, hydro carbons, fatty acid, higher alcohols, esters, various surfactants, wetting agent, whitening agent, pigment, coloring agent, pigment, sweeting agent, nutrition enhancer, spice, vitamins, aminoacid, plant animal extract component, UV absorbent, antioxidant, anticorrosion and bactericidal agent etc. of ground product, lanoline, Cera Flava etc. can be enumerated.In addition, the deodorizing ingredient that can share, without limit processed especially, such as, can enumerate known screening agent, adsorbent, porous material etc.In addition, also can share known for adding smelly deodorant in age, such as antioxidant, lipoxygenase inhibitor, antibacterial, sheltering and be in harmonious proportion spice, ethanolamine etc.
Embodiment
Below, explain the present invention based on embodiment, but the present invention is not limited to these embodiments.
［ embodiment 1 ］ is for the smelly eliminating effect test 1(sensory evaluation of unsaturated aldehyde):
1%1, the 3-butanediol aqueous solutions of 20mL are added in each bottle.Add 0.5% nonenyl aldehyde (material by after trans-2-nonenyl aldehyde (one-level, Wako Pure Chemical Industries, Ltd.) Fructus Canarii albi squalane (NIKKOL purify Fructus Canarii albi squalane, Nikko Chemicals Co., Ltd's system) dilution) of 0.5mL wherein, rapidly rubber stopper beyond the Great Wall.Leave standstill under the condition of 40 DEG C and carry out sensory evaluation after 10 minutes.
［ result ］
Shown in table 1 described as follows, result show 1,3 butylene glycol with without compared with adding, for the smelly eliminating excellent effect that nonenyl aldehyde is smelly.
Table 1
Zero: the smelly eliminating effect had
×: almost there is no smelly eliminating effect
［ embodiment 2 ］ is for the smelly eliminating effect test 2 of unsaturated aldehyde:
Use 24%1,3-butanediol aqueous solution, carry out the smelly eliminating effect test for unsaturated aldehyde by following method.In addition, use nonenyl aldehyde as unsaturated aldehyde, its slip carries out assay by high performance liquid chromatography.
< test method >
Reagent and utensil
Smelly bag (25cm × 40cm) ［ limited company Miyakobiniru processing place ］
Nonenyl aldehyde gas: use the gas produced by trans-2-nonenyl aldehyde (one-level) ［ Wako Pure Chemical Industries, Ltd. ］.
DNPH pillar: GL-Pak mini AERO DNPH ［ GL Sciences Co., Ltd. ］
Assess sample
As assess sample, use 24%1,3-butanediol aqueous solution, contrast (water).
Operation
Assess sample and contrast (water) are added smelly bag respectively, after sealing, encloses 4L air, then add the gas concentration that nonenyl aldehyde gas becomes setting.Left standstill, often through certain hour (after 0,30,60,180 minute) by the collection and confinement of gases in 300mL bag on DNPH pillar.The DNPH pillar that have collected gas passes into 5mL acetonitrile and carrys out eluting DNPH derivant, then this eluent is measured by high performance liquid chromatography, thus calculate the gas concentration in bag.The operating condition of high performance liquid chromatography is as follows.
High performance liquid chromatography operating condition
Instrument kind: LC-2010AHT ［ Shimadzu Scisakusho Ltd ］
Detector: UV detector
Chromatographic column: RP-Amide, φ 4.6mm × 25cm ［ Sigma-Aldrich Japan K.K. ］
Column temperature: 40 DEG C
Mobile phase: the mixed liquor (acetonitrile: water=80:20) of acetonitrile and water
Mobile phase flow rate: 1.5mL/min
Measure wavelength: 360nm
Sample size: 40 μ L
Experimental condition
Tested material use amount: assess sample (24%1,3-butanediol aqueous solution) 5mL, contrast (water) 5mL
Subjects gas: nonenyl aldehyde (initial vapor concentration: 22ppm)
Temperature conditions: room temperature
< result >
Shown in table 2 described as follows, result shows that the slip of 24%1,3-butanediol aqueous solution unsaturated aldehyde is compared with the control large, has excellent smelly eliminating effect.
Table 2
※ slip (%)=100-[the nonenyl aldehyde concentration in each elapsed time (after 30,60,180 minutes)]/[the nonenyl aldehyde concentration in elapsed time (0 minute)] × 100
［ embodiment 3 ］ is for the smelly eliminating effect test 3 of unsaturated aldehyde:
Use 100%1,3-butanediol, the smelly eliminating effect test for unsaturated aldehyde is undertaken by following method.In addition, use nonenyl aldehyde as unsaturated aldehyde, its slip carries out analyzing evaluating with the condition identical with embodiment 2 by high performance liquid chromatography.
< test method >
Except using 100%1,3-butanediol (5mL) as assess sample and using water (5mL) in contrast, the initial vapor concentration as the nonenyl aldehyde of subjects gas is beyond 18ppm, and other carries out smelly eliminating evaluation test by the method identical with embodiment 2.
< result >
As described in Table 3,24%1,3-butanediol aqueous solutions of 100%1,3-butanediol and embodiment 2 are compared, and the slip of unsaturated aldehyde increases further, have significant smelly eliminating effect.
Table 3
※ slip (%)=100-[the nonenyl aldehyde concentration in each elapsed time (after 30,60,180 minutes)]/[x crosses the nonenyl aldehyde concentration of time (0 point of kind)] × 100
［ embodiment 4 ］ is for the smelly eliminating effect test 4 of unsaturated aldehyde:
< test method >
Assess sample
As oolong tea extracting solution, using with oolong tea extract is the commercially available cosmetic material (oolong tea extracting solution BG(Maruzen Pharmaceuticals Co., Ltd. system) of main constituent: 50%1,3-butanediol solution).In addition, as Folium hydrangeae strigosae extracting solution, using with sweet tea extract is the commercially available cosmetic material (Folium hydrangeae strigosae extracting solution BGW(Maruzen Pharmaceuticals Co., Ltd. system) of main constituent: 50%1,3-butanediol solution).And then, as green tea extractive liquor, using with green tea extract is that the commercially available cosmetic material of main constituent is (with ism green tea (Maruzen Pharmaceuticals Co., Ltd.'s system: 50%1,3-butanediol solution), as persimmon extracting solution, the commercially available cosmetic material (Pancil BA-210-1, RILIS Scientific Industries Co., Ltd. system) that to use with persimmon extract be main constituent.
Above-mentioned oolong tea extracting solution (2.5mL), Folium hydrangeae strigosae extracting solution (2.5mL) are coordinated as follows and prepares 1, the assess sample (5mL) of 3-butanediol+2 kinds of mixed extracts, even if extract component (comprising polyphenol as main constituent) becomes 1 % by weight and the amount of each extract component becomes equivalent.The content of 1,3 butylene glycol is (50 % by weight).Similarly above-mentioned oolong tea extracting solution, Folium hydrangeae strigosae extracting solution and green tea extractive liquor are coordinated as follows the assess sample preparing 1,3 butylene glycol+3 kinds of mixed extracts (1), even if extract component becomes 1 % by weight and the amount of each extract component becomes equivalent.And then, above-mentioned oolong tea extracting solution, Folium hydrangeae strigosae extracting solution and persimmon extracting solution are coordinated as follows the assess sample preparing 1,3 butylene glycol+3 kinds of extracts (2), even if extract component becomes 1 % by weight and the amount of each extract component becomes equivalent.And then, above-mentioned oolong tea extracting solution, Folium hydrangeae strigosae extracting solution, green tea extractive liquor and persimmon extracting solution are coordinated as follows and prepares 1, the assess sample of 3-butanediol+4 kinds of mixed extracts, even if extract component becomes 1 % by weight and the amount of each extract component becomes equivalent.
Operation
As assess sample, 1 is contained except use is above-mentioned, beyond the mixed extract of 3-butanediol and water (5mL) in contrast, the method identical with above-described embodiment 2 can be adopted to carry out for 1 respectively, 3-butanediol+2 kinds of mixed extracts, 1, the smelly eliminating effect test for unsaturated aldehyde of the assess sample of 3-butanediol+4 kinds of mixed extracts, 1,3 butylene glycol+3 kinds of mixed extracts (1) and 1,3 butylene glycol+3 kinds of mixed extracts (2).In addition, use nonenyl aldehyde as unsaturated aldehyde, its slip carries out analyzing evaluating with the condition identical with embodiment 2 by high performance liquid chromatography.And when evaluating as the sample that the initial vapor concentration of the nonenyl aldehyde of subjects gas is respectively 20ppm(above-mentioned 2 kinds 4 kinds), the sample of above-mentioned 3 kinds of 20ppm(is when evaluating).
< result >
Shown in table described as follows, result shows that the slip of any one unsaturated aldehyde compared with the control in above-mentioned 1,3 butylene glycol+2 kinds of mixed extracts, 3 kinds of mixed extracts (1) and (2), 4 kinds of mixed extracts is large, smelly eliminating excellent effect.
Table 4
［ Production Example 1 ］ soap
Below, the Production Example of the smelly eliminating compositions having coordinated 1,3 butylene glycol is shown.
The use level of raw material is as shown in table 5.By soap mix and blend, drop into 1,3 butylene glycol and each extract mix homogeneously aftershaping thereafter.
Table 5
［ Production Example 2 ］ shampoo
The use level of raw material is as shown in table 6.
The antiseptic be dissolved in 1,3 butylene glycol is dropped in purified water.Drop into sodium lauryl tri(oxyethyl) sulfate, coconut oil fatty acid monoethanolamide after stirring, drop into thereafter mixing and stirring after pigment, spice and remaining 1,3 butylene glycol again.
Table 6
［ Production Example 3 ］ hair conditioner
The use level of raw material is as shown in table 7.
(1) heat in stearyl dimethyl benzyl ammonium chloride and Sal input purified water to 80 DEG C of dissolvings.
(2) 18 hexadecanol and single stearic glyceride are heated to 80 DEG C of dissolvings.
(3) (1) is stirred while add (2) by mulser, carries out after interpolation stirring in advance for 5 minutes,
(4) after pre-stirring terminates, stir and cool to 50 DEG C, after adding 1,3 butylene glycol, then stirring is cooled to 35 DEG C to prepare further.
Table 7
［ Production Example 4 ］ hair growth liquor
The use level of raw material is as shown in table 8.
In purified water, drop into salicylic acid, the vitamin E be dissolved in ethanol, MENTHOL, then drop into further the glycyrrhizin being dissolved into a part for purified water, drop into thereafter 1,3 butylene glycol mix homogeneously and prepare.
Table 8
［ Production Example 5 ］ spray liquid
The use level of raw material is as shown in table 9.
Citric acid and sodium citrate dissolving is dropped in purified water.Thereafter the antiseptic be dissolved in ethanol and polyoxyethylene sorbitan monoleate is dropped into.Thereafter drop into 1,3 butylene glycol to stir to prepare.
Table 9
［ Production Example 6 ］ astringent
The use level of raw material is as shown in table 10.
Citric acid and sodium citrate dissolving is dropped in purified water.Next drop into glycerol, 1,3 butylene glycol and sodium versenate in order, more further drop into oleic alcohol polyoxyethylene (18) ether be dissolved in ethanol, vitamin E is stirred to and evenly prepares.
Table 10
［ Production Example 7 ］ emulsion
The use level of raw material is as shown in table 11.
(1) stearic acid, spermol, octyl dodecanol myristinate and liquid paraffin are heated to 80 DEG C of dissolvings.
(2) triethanolamine, hyaluronate sodium, glycerol, 1,3 butylene glycol, polyoxyethylene (10) monoleate and hydroxyl ethylenediamine triacetic acid sodium are put in purified water heat to 80 DEG C.
(3) (1) is stirred while drop into (2) by mulser, carry out after input stirring in advance for 5 minutes.
(4) pre-stirring is cooled to 50 DEG C after terminating, then is cooled to 35 DEG C further to prepare.
Table 11
［ Production Example 8 ］ cream
The use level of raw material is as shown in table 12.
(1) stearic acid, glyceryl monostearate, sorbitan sesquioleate, polyoxyethylene 20 sorbitan monooleate, 18 hexadecanol, liquid paraffin, dipentaerythritol six (hydroxy stearic acid/stearic acid/rosin acid) ester, glycerol three (2 ethyl hexanoic acid) ester and simethicone are heated to 80 DEG C of dissolvings.
(2) in purified water, drop into glycerol, 1,3 butylene glycol, sodium hydroxide and methyl parahydroxybenzoate, heat to 80 DEG C of dissolvings.
(3) (1) is stirred while drop into (2) by mulser, carry out after input stirring in advance for 5 minutes.
(4) pre-stirring is cooled to 50 DEG C after terminating, then is cooled to 35 DEG C further to prepare.
Table 12
Claims (7)
1.1,3-butanediol, oolong tea extract and sweet tea extract are as the purposes added in the effective ingredient of smelly smelly eliminating deodorant in age.
2. according to the purposes described in claim 1, it is characterized in that, malodorous elements is unsaturated aldehyde.
3. according to the purposes described in claim 2, it is characterized in that, unsaturated aldehyde is nonenyl aldehyde or octenal.
4. the purposes according to any one of claims 1 to 3, is characterized in that, as effective ingredient also containing green tea extract and persimmon extract.
5. the purposes according to any one of claims 1 to 3, is characterized in that, with the dry weight of the extract of minimum amount for standard, the dry weight of other extract is 1 ~ 10 times amount.
6. the purposes according to any one of claims 1 to 3, is characterized in that, described in add age smelly smelly eliminating deodorant and be coupled in smelly eliminating compositions.
7. the purposes according to any one of claims 1 to 3, is characterized in that, described in add age smelly smelly eliminating deodorant and be coupled in skin preparations for extenal use.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011-027083 | 2011-02-10 | ||
| JP2011027083 | 2011-02-10 | ||
| JP2011-135716 | 2011-06-17 | ||
| JP2011135716 | 2011-06-17 | ||
| PCT/JP2012/052950 WO2012108494A1 (en) | 2011-02-10 | 2012-02-09 | Deodorant containing polyvalent alcohol |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103347545A CN103347545A (en) | 2013-10-09 |
| CN103347545B true CN103347545B (en) | 2015-05-13 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280008030.6A Active CN103347545B (en) | 2011-02-10 | 2012-02-09 | Deodorant containing polyvalent alcohol |
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| Country | Link |
|---|---|
| JP (1) | JP5695678B2 (en) |
| CN (1) | CN103347545B (en) |
| HK (1) | HK1187285A1 (en) |
| TW (1) | TWI554287B (en) |
| WO (1) | WO2012108494A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103191453A (en) * | 2013-04-09 | 2013-07-10 | 潘运平 | Slow-release antibacterial deodorant gel and preparation method thereof |
| CN106039978A (en) * | 2016-06-22 | 2016-10-26 | 深圳市龙澄高科技环保有限公司 | Gas deodorizing sustained-release monolithic gel and preparation method thereof |
| JP7260246B2 (en) * | 2017-07-07 | 2023-04-18 | Ｄｍ三井製糖株式会社 | Deodorants |
| JPWO2019130758A1 (en) * | 2017-12-26 | 2021-01-14 | サントリーホールディングス株式会社 | Volatile steroid adsorbent and deodorant composition |
| CN112156041A (en) * | 2020-10-16 | 2021-01-01 | 花安堂生物科技集团有限公司 | Dry-cleaning spray composition for hair and preparation method thereof |
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| US4294821A (en) * | 1980-12-15 | 1981-10-13 | S. C. Johnson & Son, Inc. | Odor absorbing compositions |
| JP3633634B2 (en) * | 1992-03-26 | 2005-03-30 | サントリー株式会社 | Deodorant composition and food and cosmetics containing the same |
| GB9524158D0 (en) * | 1995-11-25 | 1996-01-24 | Procter & Gamble | Liquid deodorant compositions |
| JPH11286423A (en) * | 1998-03-31 | 1999-10-19 | Shiseido Co Ltd | Composition for suppressing body odor |
| JP2000229118A (en) * | 1999-02-09 | 2000-08-22 | Nisshin Oil Mills Ltd:The | Tea extract-containing composition for deodorizing and anti-oxidizing |
| JP4212220B2 (en) * | 2000-04-24 | 2009-01-21 | 日本メナード化粧品株式会社 | Body odor deodorant |
| JP5357369B2 (en) * | 2001-03-02 | 2013-12-04 | 花王株式会社 | Deodorant for nursing odor |
| JP2003019190A (en) * | 2001-07-10 | 2003-01-21 | Kao Corp | Deodorant for pet excrement |
| JP2003081801A (en) * | 2001-09-10 | 2003-03-19 | Mandom Corp | Deodorant cosmetic |
| JP2004262816A (en) * | 2003-02-28 | 2004-09-24 | Shiseido Co Ltd | Composition for perfume removal |
| JP2005350354A (en) * | 2003-09-09 | 2005-12-22 | Kao Corp | Composition for deodorizing hircismus, and skin cosmetic and deodorant for fiber containing the same |
| US7198807B2 (en) * | 2003-12-01 | 2007-04-03 | Triarco Industries, Inc. | Inhibition of P. acnes using botanical extracts |
| CN1966090B (en) * | 2005-11-18 | 2012-09-05 | 花王株式会社 | Deodorant compositions |
| WO2007063065A1 (en) * | 2005-11-29 | 2007-06-07 | Ambria Dermatology Ab | Use of a composition comprising pentane-1, 5-diol as deodorant |
| JP4781865B2 (en) * | 2006-03-22 | 2011-09-28 | 高砂香料工業株式会社 | Liquid deodorant composition and deodorization method |
| US8691201B2 (en) * | 2008-02-15 | 2014-04-08 | Toray Opelontex Co., Ltd. | Deodorant material |
-
2012
- 2012-02-09 JP JP2012556926A patent/JP5695678B2/en active Active
- 2012-02-09 CN CN201280008030.6A patent/CN103347545B/en active Active
- 2012-02-09 WO PCT/JP2012/052950 patent/WO2012108494A1/en active Application Filing
- 2012-02-10 TW TW101104367A patent/TWI554287B/en active
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2014
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|---|---|
| TWI554287B (en) | 2016-10-21 |
| JPWO2012108494A1 (en) | 2014-07-03 |
| WO2012108494A1 (en) | 2012-08-16 |
| CN103347545A (en) | 2013-10-09 |
| HK1187285A1 (en) | 2014-04-04 |
| JP5695678B2 (en) | 2015-04-08 |
| TW201235054A (en) | 2012-09-01 |
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