JP4212220B2 - Body odor deodorant - Google Patents

Body odor deodorant Download PDF

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Publication number
JP4212220B2
JP4212220B2 JP2000122796A JP2000122796A JP4212220B2 JP 4212220 B2 JP4212220 B2 JP 4212220B2 JP 2000122796 A JP2000122796 A JP 2000122796A JP 2000122796 A JP2000122796 A JP 2000122796A JP 4212220 B2 JP4212220 B2 JP 4212220B2
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Japan
Prior art keywords
effect
body odor
condensed
extract
present
Prior art date
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JP2000122796A
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Japanese (ja)
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JP2001302483A (en
Inventor
悟 中田
國寛 宮本
秀樹 森本
守正 福井
清忠 野崎
和則 大西
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Nippon Menard Cosmetic Co Ltd
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Nippon Menard Cosmetic Co Ltd
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Description

【0001】
【産業上の利用分野】
本発明は縮合型カキタンニンを含有することにより不飽和アルデヒドに対する優れた消臭効果を有する体臭消臭剤を提供するものである。
【0002】
【従来の技術】
特開平11−286423号に開示されているように、中高年以降に認められるいわゆる「加齢臭」は、オクテナールやノネナール等の不飽和アルデヒドが深く関わっている全く新たなる性質の体臭である。そして、それらの「加齢臭」を除去するために従来は、発生した不飽和アルデヒドを香料によりマスキングするか若しくは、抗酸化剤による酸化抑制、抗菌剤による皮膚常在菌の増殖抑制により発生を抑えることであった。
【0003】
【発明が解決しようとする課題】
しかしながら、茶抽出物、シソ抽出物、オウゴン抽出液、キュウリ抽出物、サンショウ抽出物、パセリ抽出物、ハマメリス抽出物、タンニン酸等、いわゆる従来の消臭物質を配合した不飽和アルデヒドの消臭効果は、未だ満足できるものではなかった。
【0004】
【課題を解決するための手段】
本発明者等は、上記事項に鑑み、鋭意研究を重ねた結果、縮合型カキタンニンが、不飽和アルデヒドに対して著しい消臭効果を見出し、本発明を完成させるに至った。
【0005】
以下、本発明の構成について詳述する。配合量は特に限定されないが、好ましくは乾燥物として皮膚外用剤全量中の0.0001〜5重量%の範囲内である。好ましくは、0.001〜3重量%である。さらに好ましくは、0.01〜1重量%である。0.0001%未満では消臭効果が発揮できない。また、5重量%以上では効果の増強がなく不経済である。
【0006】
本発明に係る縮合型カキタンニンはカキノキ:Diospyros kaki Thunberg(Ebenaceae)の果実の搾汁より得られ、その製造方法は、果実を圧搾機にかけて搾汁液を得て減圧乾燥するか、搾汁液に酵素を用いて密閉保存した後に糖分を取り除き、減圧下にて脱水することにより得られる。
【0007】
本発明の皮膚外用剤は上記必須成分の他に、通常の化粧料、医薬部外品、医薬品等に用いられる各種成分、例えば油性成分、乳化剤、保湿剤、増粘剤、薬効成分、防腐剤、顔料、粉体、pH調節剤、紫外線吸収剤、抗酸化剤、香料等を適宜配合することができる。
【0008】
具体的には油性成分としては、例えば流動パラフィン、ワセリン、マイクロクリスタリンワックス、スクワラン、ホホバ油、ミツロウ、カルナウバロウ、ラノリン、オリーブ油、ヤシ油、高級アルコール、脂肪酸、高級アルコールと脂肪酸のエステル、シリコーン油等が挙げられる。乳化剤としては、例えばポリオキシエチレンアルキルエーテル、ポリオキシエチレン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ソルビタン脂肪酸エステル、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ポリオキシエチレン硬化ヒマシ油等の非イオン界面活性剤が挙げられる。保湿剤としては、例えばグリセリン、ソルビトール、キシリトール、マルチトール、プロピレングリコール、ポリエチレングリコール、1,3−ブチレングリコール、ポリオキシエチレンメチルグルコシドなどが挙げられる。増粘剤としては、例えばカルボキシビニルポリマー、キサンタンガム、メチルセルロース、ポリビニルピロリドン、ゼラチン等が挙げられる。薬効成分としては、例えばビタミンC及びその誘導体、ビタミンE誘導体、プラセンタエキス、コウジ酸、アルブチン、アラントイン、グリチルリチン酸誘導体、各種植物抽出物等が挙げられる。
【0009】
本発明の体臭剤の剤型は、ミスト、ジェル、化粧水、エアゾール、乳液等の基礎化粧料等目的に応じて任意に選択できる。
【0010】
【発明の効果】
本発明は縮合型カキタンニンを含有することにより不飽和アルデヒドに対する優れた消臭効果を有するものである。
【0011】
【実験例】
消臭効果の評価はガスクロマトグラフィーにて行い、不飽和アルデヒドの消臭率をブランクと比較した。又、不飽和アルデヒドはノネナールを使用した。
条件 Column:PEG20M(80/100)3mmφ×2.0m、Temperature:Oven 150℃、Injection:250℃、Detector:250℃、Range:10 検出器:FID
測定方法 ノネナールを1gバイエル瓶に採取し、40℃一定温度にした後、気体5mlを採取する。一方、試料を1gバイエル瓶に採取し、40℃一定温度にし、先に採取したノネナールの気体5mlを入れ10分間放置する。その気体を1ml採取し、ガスクロマトグラフィにて、ノネナールのピーク面積をブランクと比較し、消臭効果を求めた。
尚、各比較試料は、実際に市販、常使されている原料である。(製造業者:一丸ファルコス(株))
【0012】
【表1】

Figure 0004212220
【0013】
表1の結果より、縮合型カキタンニンの製剤が不飽和アルデヒドの消臭効果に優れていることが判る。
【0014】
【表2】
Figure 0004212220
【0015】
表2の結果より、縮合型カキタンニンの配合量は0.01〜5重量がより好ましいと判断出来る。
【0016】
【発明の実施の形態】
以下本発明の実施例を示すが、本発明はこれら実施例に限定されるものではない。
【0017】
【実施例】
表3〜表7のように処方設計された皮膚外用剤を調製し、加齢臭の消臭効果について下記の試験方法により評価を行った。
【0018】
あらかじめアンケート調査により、加齢臭に悩む人を被験者として消臭剤に対し各10名選抜した。被験者には加齢臭を上記症状が気になる部分に適量を2週間毎日連用させて、下記の基準で5段階評価を行った。表3〜表7にはその平均点を示した。
5:著しく効果がある。
4:かなり効果がある。
3:やや効果がある。
2:ほとんど効果なし。
1:効果なし。
【0019】
【表3】
Figure 0004212220
【0020】
【表4】
Figure 0004212220
【0021】
【表5】
Figure 0004212220
【0022】
【表6】
Figure 0004212220
【0023】
【表7】
Figure 0004212220
【0024】
表3〜表7で調製した本発明品についても、実使用試験において不飽和アルデヒドの消臭効果に優れたものであった。[0001]
[Industrial application fields]
This invention provides the body odor deodorant which has the outstanding deodorizing effect with respect to unsaturated aldehyde by containing condensed type cachytannin.
[0002]
[Prior art]
As disclosed in Japanese Patent Application Laid-Open No. 11-286423, so-called “aged odor” recognized after middle-aged and older is a completely new body odor that is deeply related to unsaturated aldehydes such as octenal and nonenal. In order to remove these “aged odors”, conventionally, the generated unsaturated aldehyde is masked with a fragrance, or it is generated by inhibiting oxidation with an antioxidant, or inhibiting growth of resident skin bacteria with an antibacterial agent. It was to suppress.
[0003]
[Problems to be solved by the invention]
However, deodorization of unsaturated aldehydes containing so-called conventional deodorizing substances such as tea extract, perilla extract, ougon extract, cucumber extract, salamander extract, parsley extract, hamamelis extract, tannic acid, etc. The effect was not yet satisfactory.
[0004]
[Means for Solving the Problems]
As a result of intensive studies in view of the above matters, the present inventors have found that condensed cachytannin has a remarkable deodorizing effect on unsaturated aldehydes, and has completed the present invention.
[0005]
Hereinafter, the configuration of the present invention will be described in detail. The blending amount is not particularly limited, but is preferably in the range of 0.0001 to 5% by weight in the total amount of the external preparation for skin as a dry product. Preferably, it is 0.001 to 3 weight%. More preferably, it is 0.01 to 1 weight%. If it is less than 0.0001%, the deodorizing effect cannot be exhibited. On the other hand, if it is 5% by weight or more, the effect is not enhanced and it is uneconomic.
[0006]
The condensed oyster tannin according to the present invention is obtained from the squeezed fruit of Diospyros kaki Thunberg (Ebenaceae), and the production method thereof comprises squeezing the fruit to obtain a squeezed liquid and drying it under reduced pressure, or It is obtained by removing sugars after dehydrating under reduced pressure after hermetically storing with.
[0007]
In addition to the above essential components, the external preparation for skin of the present invention includes various components used in normal cosmetics, quasi drugs, pharmaceuticals, etc., for example, oily components, emulsifiers, humectants, thickeners, medicinal components, preservatives Pigments, powders, pH adjusters, ultraviolet absorbers, antioxidants, fragrances and the like can be appropriately blended.
[0008]
Specific examples of the oil component include liquid paraffin, petrolatum, microcrystalline wax, squalane, jojoba oil, beeswax, carnauba wax, lanolin, olive oil, coconut oil, higher alcohol, fatty acid, ester of higher alcohol and fatty acid, silicone oil, and the like. Is mentioned. Examples of the emulsifier include nonionic surfactants such as polyoxyethylene alkyl ether, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, sorbitan fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, and polyoxyethylene hydrogenated castor oil. Is mentioned. Examples of the humectant include glycerin, sorbitol, xylitol, maltitol, propylene glycol, polyethylene glycol, 1,3-butylene glycol, polyoxyethylene methyl glucoside and the like. Examples of the thickener include carboxyvinyl polymer, xanthan gum, methyl cellulose, polyvinyl pyrrolidone, gelatin and the like. Examples of medicinal ingredients include vitamin C and its derivatives, vitamin E derivatives, placenta extract, kojic acid, arbutin, allantoin, glycyrrhizic acid derivatives, various plant extracts, and the like.
[0009]
The dosage form of the body odorant of the present invention can be arbitrarily selected according to the purpose of basic cosmetics such as mist, gel, lotion, aerosol, and emulsion.
[0010]
【The invention's effect】
The present invention has an excellent deodorizing effect on unsaturated aldehydes by containing condensed cachytannin.
[0011]
[Experimental example]
The deodorization effect was evaluated by gas chromatography, and the deodorization rate of unsaturated aldehyde was compared with that of the blank. As the unsaturated aldehyde, nonenal was used.
Conditions Column: PEG20M (80/100) 3mmφ × 2.0m, Temperature: Oven 150 ° C, Injection: 250 ° C, Detector: 250 ° C, Range: 10 Detector: FID
Method of measurement Noneal is sampled in a 1 g Bayer bottle, brought to a constant temperature of 40 ° C., and 5 ml of gas is sampled. On the other hand, a sample is collected in a 1 g Bayer bottle, brought to a constant temperature of 40 ° C., 5 ml of the previously collected nonenal gas is added and left for 10 minutes. 1 ml of the gas was sampled, and the peak area of nonenal was compared with a blank by gas chromatography to determine the deodorizing effect.
Each comparative sample is actually a commercially available and commonly used raw material. (Manufacturer: Ichimaru Falcos)
[0012]
[Table 1]
Figure 0004212220
[0013]
From the results shown in Table 1, it can be seen that the preparation of condensed cachytannin is excellent in the deodorizing effect of unsaturated aldehyde.
[0014]
[Table 2]
Figure 0004212220
[0015]
From the results shown in Table 2, it can be determined that the blending amount of the condensed oyster tannin is more preferably 0.01 to 5 wt.
[0016]
DETAILED DESCRIPTION OF THE INVENTION
Examples of the present invention are shown below, but the present invention is not limited to these examples.
[0017]
【Example】
The skin external preparations formulated and designed as shown in Tables 3 to 7 were prepared, and the deodorizing effect of the aging odor was evaluated by the following test method.
[0018]
By questionnaire survey, 10 people were selected for each deodorant as subjects who suffered from aging odor. The subject was given an appropriate amount of an aging odor at the part where the above-mentioned symptom was anxious every day for 2 weeks, and was evaluated on the basis of the following criteria. Tables 3 to 7 show the average points.
5: Remarkably effective.
4: It is quite effective.
3: There is a little effect.
2: Almost no effect.
1: No effect.
[0019]
[Table 3]
Figure 0004212220
[0020]
[Table 4]
Figure 0004212220
[0021]
[Table 5]
Figure 0004212220
[0022]
[Table 6]
Figure 0004212220
[0023]
[Table 7]
Figure 0004212220
[0024]
The products of the present invention prepared in Tables 3 to 7 were also excellent in the deodorizing effect of unsaturated aldehydes in actual use tests.

Claims (2)

必須成分として縮合型カキタンニンを含有することを特徴とする不飽和アルデヒドの消臭剤。An unsaturated aldehyde deodorant characterized by containing condensed cachytannin as an essential component. 縮合型カキタンニンの配合量が0.01〜1重量%であることを特徴とする請求項1の消臭剤。The deodorant according to claim 1, wherein the amount of condensed cachytannin is 0.01 to 1% by weight.
JP2000122796A 2000-04-24 2000-04-24 Body odor deodorant Expired - Lifetime JP4212220B2 (en)

Priority Applications (1)

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JP4212220B2 true JP4212220B2 (en) 2009-01-21

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Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006087903A (en) * 2004-08-25 2006-04-06 Nippon Gosei Senzai Kk Deodorant composition
JP4980124B2 (en) * 2007-04-17 2012-07-18 株式会社大阪製薬 Dripping deodorant composition for mammals
WO2011114544A1 (en) * 2010-03-19 2011-09-22 株式会社フォーリーフ ジャパン Bad-breath removing agent, and composition for oral cavity
JP5926199B2 (en) * 2011-02-10 2016-05-25 サントリーホールディングス株式会社 Aging odor suppressant containing oolong tea extract and / or strawberry tea extract
JP5695678B2 (en) * 2011-02-10 2015-04-08 サントリーホールディングス株式会社 Deodorant containing polyhydric alcohol
JP5965803B2 (en) * 2012-09-27 2016-08-10 株式会社マンダム Deodorant composition and deodorant agent
JP2016204263A (en) * 2015-04-15 2016-12-08 セーレン株式会社 Deodorant
JP7056903B2 (en) * 2017-07-20 2022-04-19 株式会社スタジオライン Deodorant liquid detergent composition and its manufacturing method
CN110755284A (en) * 2019-11-08 2020-02-07 奥伦国际有限公司 Deodorant fragrance-retaining composition

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