CN103347545A - Deodorant containing polyvalent alcohol - Google Patents
Deodorant containing polyvalent alcohol Download PDFInfo
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- CN103347545A CN103347545A CN2012800080306A CN201280008030A CN103347545A CN 103347545 A CN103347545 A CN 103347545A CN 2012800080306 A CN2012800080306 A CN 2012800080306A CN 201280008030 A CN201280008030 A CN 201280008030A CN 103347545 A CN103347545 A CN 103347545A
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- deodorant
- smelly
- extract
- compositions
- butylene glycol
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
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- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
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Abstract
The problem addressed by the present invention is to provide a deodorant for deodorizing body odor, particularly the "old person smell" inherent to middle- and old-aged people, the deodorant being safe to use and having a strong deodorizing effect. By having the deodorant contain polyvalent alcohol, in particular 1,3-butylene glycol, as an active ingredient, it is possible to provide a deodorant with an outstanding deodorizing effect. The deodorant is particularly effective in deodorizing unsaturated aldehydes, which are the main cause of "old person smell".
Description
Technical field
The present invention relates to deodorant.Say that in further detail the present invention contains polyhydric alcohol, particularly 1,3 butylene glycol as the deodorant of effective ingredient, the invention reside in to provide for what have an excellent smelly effect that disappears as the unsaturated aldehyde that adds smelly reason material in age and add smelly inhibitor in age.In addition, 1,3 butylene glycol, oolong tea extract and sweet tea extract have been the present invention relates to cooperate and the compositions that constitutes.
Background technology
In recent years, be subjected to pursuing the influence of raising of value, the demand of the consumer of more comfortable living space, developed various deodorants, deodorant or aromatic.In addition, consumer also progressively improves the care of body odor, and the demand for the product with deodorizing effect also increases gradually in recent years.
Known among body odor, as the stink of mainly being recognized by middle-aged and elderly people, namely so-called " it is smelly to add age " profoundly relevant with the unsaturated aldehyde of octenal, nonenyl aldehyde etc.Detailed says, the known palmitoleic acid that increases in the sebum of person in middle and old age's layer in age (palmitoleic acid) decomposes by the oxidation Decomposition of being undertaken by lipid peroxide or by the resident bacterium of skin, can produce the nonenyl aldehyde (patent documentation 1) as odorant.
Add smelly technology in age as removing, the method (patent documentation 2) of having reported method (patent documentation 1) that the unsaturated aldehyde that will produce is in harmonious proportion by perfume masking, having caught with ethanolamine.In addition, the generation of also having reported the unsaturated aldehyde in the sebum that suppresses to become the reason that adds smelly generation in age suppresses to add smelly method in age.Particularly, reported and suppressed the method that unsaturated aldehyde produces by the following method, resided the antibacterial inhibition propagation (patent documentation 5) of bacterium by antioxidant inhibited oxidation (patent documentation 3), by the generation (patent documentation 4) of lipoxygenase inhibitor inhibition lipid peroxide, by the skin relevant with the generation of fatty acid.
On the other hand, in the material of making up, cooperate the cosmetic material of polyhydric alcohol a lot, often used glycerol, propylene glycol, dipropylene glycol, 1,3 butylene glycol from the viewpoint of supplying with stability.Among these, that known because 1,3 butylene glycol has is non-volatile, the character of hypotoxicity, moisture retention, thereby useful in cosmetic applications.Particularly, it is reported Carboxymethyl Chitin (patent documentation 6), antibacterial action antisepsis (patent documentation 7).
The prior art document
Patent documentation
Patent documentation 1 Japanese kokai publication hei 11-286428 communique
Patent documentation 2 TOHKEMY 2001-97838 communiques
Patent documentation 3 Japanese kokai publication hei 11-286423 communiques
Patent documentation 4 Japanese kokai publication hei 11-286424 communiques
Patent documentation 5 Japanese kokai publication hei 11-286425 communiques
Patent documentation 6 Japanese kokai publication hei 8-259433 communiques (No. 3159622 communique of Japan Patent)
Patent documentation 7 TOHKEMY 2003-238328 communiques
Summary of the invention
The object of the present invention is to provide disappear smelly effective and safe deodorant or compositions.
Present inventors etc. have carried out further investigation repeatedly, found that polyhydric alcohol, particularly 1,3 butylene glycol have the smelly effect that disappears.Find that particularly they have the smelly effect that significantly disappears for the unsaturated aldehyde that conduct adds smelly reason material in age, thereby finished the present invention.
Namely the present invention relates to following content, but be not limited to this.
(1) a kind of deodorant is characterized in that, contains the C2～C6 alcohol of 2 yuan or 3 yuan as effective ingredient.
(2) according to the deodorant described in (1), it is characterized in that described alcohol is 1,3 butylene glycol.
(3) according to the deodorant described in (1) or (2), it is characterized in that, be used for adding age smelly disappear smelly.
(4) according to each described deodorant in (1)～(3), it is characterized in that the stink composition is unsaturated aldehyde.
(5) according to the deodorant described in (4), it is characterized in that unsaturated aldehyde is nonenyl aldehyde or octenal.
(6) a kind of smelly compositions of using that disappears is characterized in that, cooperated (1)～(5) in each described deodorant and forming.
(7) according to the smelly compositions of using that disappears described in (6), it is characterized in that, be skin preparations for extenal use.
(8) a kind of compositions is characterized in that, has cooperated 1,3 butylene glycol, oolong tea extract and sweet tea extract and constitutes.
The invention reside in to provide and comprise polyhydric alcohol, particularly 1,3 butylene glycol as the deodorant with the excellent smelly effect that disappears of effective ingredient.Owing to deodorant of the present invention particularly has inhibition for adding age smelly reason material, so that the smelly inhibition that can be coupled to disappear is disappearing of purpose is smelly with in the compositions.Wherein, can be coupled to add smelly inhibition in age is that disappearing of purpose is smelly with in the compositions.In addition, in alternate manner of the present invention, can provide by cooperating 1,3 butylene glycol, oolong tea extract and sweet tea extract to have the compositions of the excellent smelly effect that disappears.
The specific embodiment
＜deodorant＞
Deodorant of the present invention be characterised in that comprise polyhydric alcohol, particularly C2～C6 the alcohol of 2 yuan or 3 yuan is as effective ingredient.
Deodorant of the present invention with smelly at disappearing of various stink compositions be purpose, wherein with as be accompanied by the body odor that adds age add age smelly to disappear smelly be purpose, provide especially at as the deodorant that adds the unsaturated aldehyde (nonenyl aldehyde, octenal etc.) of smelly reason material in age.
Below, describe embodiments of the present invention in detail.
The effective ingredient of deodorant
The effective ingredient of deodorant of the present invention is polyhydric alcohol, particularly is the C2～C6 alcohol of 2 yuan or 3 yuan.As the C2～C6 alcohol of 2 yuan or 3 yuan, for example can enumerate glycerol, ethylene glycol, propylene glycol, 1,4-butanediol, diethylene glycol, dipropylene glycol, 1,3 butylene glycol, pentanediol, hexanediol etc.Among these, preferred 2 yuan C2～C6 alcohol, preferred especially 1,3 butylene glycol.
The amount of the above-mentioned effective ingredient in the deodorant is not particularly limited, and effective ingredient can be 100 weight %, also can be 0.01～99 weight %, preferred 1～50 weight %, further preferred 5～30 weight %.
Smelly effect disappears
Deodorant of the present invention all has effect for various stinks.For example can enumerate the stink of the food such as stink, fish, vegetable of stink, the refrigerator in stink, the kitchen in stink, the lavatory of body odor (stink of bromhidrosis, foot odor, fetid sweat, scalp, halitosis etc.), house pet, the stink of Nicotiana tabacum L., the stink of clothes, stink of footwear etc.
Therefore, deodorant of the present invention, for example can be used as halitosis with deodorant, body odor with deodorant, house pet with deodorant, domestic animal with deodorant, deodorant for kitchen use, lavatory with deodorant, indoor deodorant, life with waiting to use with deodorant, industrial deodorant in deodorant, the car.
In addition, deodorant of the present invention is particularly for smellyly having an effect age that adds in the body odor.Smelly as adding age, then be not particularly limited so long as add the stink that comprises in smelly age, especially the unsaturated aldehyde for nonenyl aldehyde and octenal etc. has effect.
Deodorant of the present invention also can remain on the carrier and use.Example as carrier, can enumerate the glue class of agar, gelatin, carrageenan, arabic gum etc., the gel of polyvinyl alcohol, polyacrylamide etc., the fiber of various celluloses etc., the porous material of zeolite, porous glass, pottery, activated carbon, silicon dioxide, silicate etc. etc.
＜smelly usefulness the compositions that disappears＞
Of the present invention disappearing smellyly can cooperate above-mentioned deodorant to prepare with compositions.
The smelly use level with the deodorant in the compositions that disappears is not particularly limited, and above-mentioned effective ingredient can be 100 weight %, also can be 0.01～99 weight %, preferred 1～50 weight %, further preferred 5～30 weight %.
Can cooperate deodorant of the present invention separately, also can make up to cooperate with other deodorizing ingredient in addition.The deodorizing ingredient that can share does not have special system limit, for example can enumerate known screening agent, adsorbent, porous material etc.In addition, add smelly inhibition in age in order further to improve, can share known at adding smelly deodorant in age, for example antioxidant, lipoxygenase inhibitor, antibacterial, shelter and be in harmonious proportion spice, ethanolamine etc.In addition, also can add extract or the ground product of the such plant component of oolong tea, Folium hydrangeae strigosae, green tea, persimmon, Radix Scutellariae, Radix Oenotherae erythrosepalae, Caulis Sacchari sinensis.Wherein, can preferably use the oolong tea that adds the smelly smelly effect excellence that disappears in age or extract or the ground product of Folium hydrangeae strigosae.
As the smelly mode with compositions that disappears, preferably use as skin preparations for extenal use.For example, can enumerate Cleansing Foam, soap, oral care product (collutory (mouthwash), dentifrice etc.), shampoo, Rinsing, hair conditioner, suppurative mastitis, hair liquid, hair growth liquor, educate and send out a hair growth promoter, astringent, emulsion, cream etc.
In addition, in the scope of not damaging effect of the present invention, also can be at smelly composition, the additive that cooperates other in the compositions of using that disappear of the present invention.As these compositions, additive, wax class, hydro carbons, fatty acid, higher alcohols, esters, various surfactant, wetting agent, whitening agent, pigment, coloring agent, pigment, sweeting agent, nutrition enhancer, spice, vitamins, aminoacid, the plant animals that can enumerate the oils, lanoline, Cera Flava etc. of plant wet goods extract composition, UV absorbent, antioxidant, anticorrosion and bactericidal agent etc.
＜compositions＞
Compositions in an embodiment of the invention contains 1,3 butylene glycol, oolong tea extract and sweet tea extract.In addition, in compositions of the present invention, also green tea extract and/or persimmon extract can be further cooperated, also other composition can be cooperated.Especially preferably compositions is smellyly used with compositions as disappearing.
The preparation of oolong tea extract, sweet tea extract, green tea extract and persimmon extract can be undertaken by any method known in those skilled in the art.And these extracts can be solid and also can be liquid, also can comprise the pulverizing product of leaf, fruit.In addition, so long as comprise from the essential abstraction process of the mode of the effective ingredient of oolong tea, Folium hydrangeae strigosae, green tea and persimmon.
The content of the 1,3 butylene glycol in the compositions of the present invention is not particularly limited, and is 0.01～99 weight %, preferred 1～70 weight %, further preferred 5～60 weight %.In addition, total use level of the oolong tea extract in the compositions and sweet tea extract or in compositions, further added the also special indefinite of total use level of the total extract of green tea extract and/or persimmon extract, with dry weight convert make become 0.0001～90 weight %, preferred 0.005～50 weight %, further preferred 0.001～10 weight % cooperates.
The use level of each extract also is not particularly limited, for example, use oolong tea extract and sweet tea extract 2 kinds or in them, adding green tea extract and/or during the extract of 3 kinds of the persimmon extract or 4 kinds, the match ratio of the extract in each combination is not particularly limited, but the dry weight of the extract of amount that can be minimum is standard, makes respectively that the dry weight of other extract becomes 1～10 times of amount, preferred 1～5 times of amount, further preferred 1～2 times of amount cooperates.
Be coupled to the composition that comprises in the composition that comprises in oolong tea extract in the compositions of the present invention and the sweet tea extract or the green tea extract that can further cooperate and/or the persimmon extract and be not particularly limited, can enumerate polyphenol as the main constituent of these extracts.Polyphenol is not particularly limited for to have the general name of the chemical compound of a plurality of phenol hydroxyls in 1 molecule, is the tannin that extracts from the Folium Camelliae sinensis of oolong tea, Folium hydrangeae strigosae, green tea etc., persimmon etc., flavonoid, catechin etc.
As the compositions in an embodiment of the invention, preferably use as skin preparations for extenal use.For example, can enumerate Cleansing Foam, soap, oral care product (collutory (mouthwash), dentifrice etc.), shampoo, Rinsing, hair conditioner, suppurative mastitis, hair liquid, hair growth liquor, educate and send out a hair growth promoter, astringent, emulsion, cream etc.
In addition, in the scope of not damaging effect of the present invention, also can in as the compositions of an embodiment of the invention, cooperate other composition, additive.As these compositions, additive, wax class, hydro carbons, fatty acid, higher alcohols, esters, various surfactant, wetting agent, whitening agent, pigment, coloring agent, pigment, sweeting agent, nutrition enhancer, spice, vitamins, aminoacid, the plant animals that can enumerate the extracts that obtains of Radix Scutellariae, Radix Oenotherae erythrosepalae, Caulis Sacchari sinensis etc. or ground product, lanoline, Cera Flava etc. from plant material extract composition, UV absorbent, antioxidant, anticorrosion and bactericidal agent etc.In addition, the deodorizing ingredient that can share does not have special system limit, for example, can enumerate known screening agent, adsorbent, porous material etc.In addition, also can share known at adding smelly deodorant in age, for example antioxidant, lipoxygenase inhibitor, antibacterial, shelter and be in harmonious proportion spice, ethanolamine etc.
Embodiment
Below, explain the present invention based on embodiment, but the present invention is not limited to these embodiment.
［ embodiment 1 ］ is at the smelly effect test 1(of disappearing of unsaturated aldehyde sensory evaluation):
In each bottle, add 1%1 of 20mL, 3-butanediol aqueous solution.Add 0.5% nonenyl aldehyde (with the material of trans-2-nonenyl aldehyde (one-level, Wako Pure Chemical Industries, Ltd.) after with Fructus Canarii albi squalane (NIKKOL purification Fructus Canarii albi squalane, Nikko Chemicals Co., Ltd's system) dilution) of 0.5mL therein, rapidly rubber stopper beyond the Great Wall.After leaving standstill 10 minutes under 40 ℃ the condition, carry out sensory evaluation.
［ result ］
Shown in the table 1 described as follows, the result shows that 1,3 butylene glycol do not compare with do not have adding, at the smelly smelly effect excellence that disappears of nonenyl aldehyde.
Table 1
［ embodiment 2 ］ are at the smelly effect test 2 of disappearing of unsaturated aldehyde:
Use 24%1,3-butanediol aqueous solution, undertaken at the smelly effect test of disappearing of unsaturated aldehyde by following method.In addition, use nonenyl aldehyde as unsaturated aldehyde, its slip carries out assay by high performance liquid chromatography.
＜test method＞
Reagent and utensil
Smelly bag (25cm * 40cm) ［ limited company Miyakobiniru processing place ］
Nonenyl aldehyde gas: use the gas that is produced by trans-2-nonenyl aldehyde (one-level) ［ Wako Pure Chemical Industries, Ltd. ］.
DNPH pillar: GL-Pak mini AERO DNPH ［ GL Sciences Co., Ltd. ］
Assess sample
As assess sample, use 24%1,3-butanediol aqueous solution, contrast (water).
Operation
Assess sample and contrast (water) are added smelly bag respectively, after sealing, enclose the 4L air, add the gas concentration that nonenyl aldehyde gas becomes setting again.It is left standstill, every through certain hour (after 0,30,60,180 minute) with the collection and confinement of gases in the 300mL bag to the DNPH pillar.Feed the 5mL acetonitrile at the DNPH pillar of having collected gas and come eluting DNPH derivant, again this eluent is measured by high performance liquid chromatography, thereby calculate the interior gas concentration of bag.The operating condition of high performance liquid chromatography is as follows.
The high performance liquid chromatography operating condition
Instrument kind: LC-2010AHT ［ Shimadzu Scisakusho Ltd ］
Detector: UV detector
Chromatographic column: RP-Amide, φ 4.6mm * 25cm ［ Sigma-Aldrich Japan K.K. ］
Column temperature: 40 ℃
Mobile phase: the mixed liquor of acetonitrile and water (acetonitrile: water=80:20)
Mobile phase flow rate: 1.5mL/min
Measure wavelength: 360nm
Sample size: 40 μ L
Experimental condition
Tried the thing use amount: assess sample (24%1,3-butanediol aqueous solution) 5mL, contrast (water) 5mL
Subjects gas: nonenyl aldehyde (initial vapor concentration: 22ppm)
Temperature conditions: room temperature
＜result＞
Shown in the table 2 described as follows, the result shows 24%1,3-butanediol aqueous solution, and the slip of unsaturated aldehyde is big compared with the control, has the excellent smelly effect that disappears.
Table 2
The nonenyl aldehyde concentration in ※ slip (%)=each elapsed time of 100-[(after 30,60,180 minutes)]/[the nonenyl aldehyde concentration in elapsed time (0 minute)] * 100
［ embodiment 3 ］ are at the smelly effect test 3 of disappearing of unsaturated aldehyde:
Use 100%1,3-butanediol, undertaken by following method at the smelly effect test of disappearing of unsaturated aldehyde.In addition, use nonenyl aldehyde as unsaturated aldehyde, its slip is estimated with condition analyze identical with embodiment 2 by high performance liquid chromatography.
＜test method＞
Except using 100%1,3-butanediol (5mL) as assess sample and make water (5mL) in contrast, be beyond the 18ppm as the initial vapor concentration of the nonenyl aldehyde of subjects gas, other is by the method identical with the embodiment 2 smelly evaluation test that disappears.
＜result＞
Shown in following table 3,24%1 of 100%1,3-butanediol and embodiment 2,3-butanediol aqueous solution is compared, and the slip of unsaturated aldehyde further increases, has the smelly effect that disappears significantly.
Table 3
The nonenyl aldehyde concentration in ※ slip (%)=each elapsed time of 100-[(after 30,60,180 minutes)]/[the nonenyl aldehyde concentration in elapsed time (0 minute)] * 100
［ embodiment 4 ］ are at the smelly effect test 4 of disappearing of unsaturated aldehyde:
＜test method＞
Assess sample
As the oolong tea extracting solution, use with the commercially available cosmetic material (oolong tea extracting solution BG(Maruzen Pharmaceuticals Co., Ltd. system) of oolong tea extract as main constituent: 50%1,3-butanediol solution).In addition, as the Folium hydrangeae strigosae extracting solution, use with the commercially available cosmetic material (Folium hydrangeae strigosae extracting solution BGW(Maruzen Pharmaceuticals Co., Ltd. system) of sweet tea extract as main constituent: 50%1,3-butanediol solution).And then, as green tea extractive liquor, use with green tea extract to the commercially available cosmetic material of main constituent (with ism green tea (Maruzen Pharmaceuticals Co., Ltd.'s system: 50%1, the 3-butanediol solution), as the persimmon extracting solution, use with the commercially available cosmetic material (Pancil BA-210-1, RILIS science Industrial Co., Ltd system) of persimmon extract as main constituent.
Above-mentioned oolong tea extracting solution (2.5mL), the following cooperation of Folium hydrangeae strigosae extracting solution (2.5mL) are prepared 1, the assess sample (5mL) of 3-butanediol+2 kind of mixed extract becomes equivalent even extract component becomes (comprising polyphenol as main constituent) amount of 1 weight % and each extract component.The content of 1,3 butylene glycol is (50 weight %).Similarly above-mentioned oolong tea extracting solution, Folium hydrangeae strigosae extracting solution and the following cooperation of green tea extractive liquor are prepared the assess sample of 1,3 butylene glycol+3 kind of mixed extracts (1), become equivalent even extract component becomes the amount of 1 weight % and each extract component.And then, above-mentioned oolong tea extracting solution, Folium hydrangeae strigosae extracting solution and the following cooperation of persimmon extracting solution are prepared the assess sample of 1,3 butylene glycol+3 kind of extracts (2), even becoming the amount of 1 weight % and each extract component, extract component becomes equivalent.And then, above-mentioned oolong tea extracting solution, Folium hydrangeae strigosae extracting solution, green tea extractive liquor and the following cooperation of persimmon extracting solution are prepared 1, the assess sample of 3-butanediol+4 kind of mixed extract becomes equivalent even extract component becomes the amount of 1 weight % and each extract component.
Operation
As assess sample, contain 1 except use is above-mentioned, the mixed extract of 3-butanediol and water (5mL) in contrast are in addition, can adopt the method identical with above-described embodiment 2 to carry out for 1 respectively, 3-butanediol+2 kind of mixed extract, 1, the assess sample of 3-butanediol+4 kind of mixed extract, 1,3 butylene glycol+3 kind of mixed extracts (1) and 1,3 butylene glycol+3 kind of mixed extracts (2) at the smelly effect test of disappearing of unsaturated aldehyde.In addition, use nonenyl aldehyde as unsaturated aldehyde, its slip is estimated with condition analyze identical with embodiment 2 by high performance liquid chromatography.And when estimating as the sample that the initial vapor concentration of the nonenyl aldehyde of subjects gas is respectively above-mentioned 2 kinds 4 kinds of 20ppm(), when the above-mentioned 3 kinds sample of 20ppm(is estimated).
＜result＞
Shown in the table described as follows, the result shows in above-mentioned 1,3 butylene glycol+2 kind of mixed extract, 3 kinds of mixed extracts (1) and (2), the 4 kinds of mixed extracts any, and slip of unsaturated aldehyde is big compared with the control, smelly effect excellence disappears.
Table 4
［ Production Example 1 ］ soap
Below, the Production Example that has cooperated the smelly usefulness of disappearing of 1,3 butylene glycol compositions is shown.
The use level of raw material is as shown in table 5.The soap raw material is mixed stirring, drop into 1,3 butylene glycol and each extract thereafter and mix even aftershaping.
Table 5
［ Production Example 2 ］ shampoo
The use level of raw material is as shown in table 6.
In purified water, drop into the antiseptic that is dissolved in the 1,3 butylene glycol.Sodium lauryl tri(oxyethyl) sulfate, coconut oil fatty acid monoethanolamide are dropped in the back that stirs, and drop into mixing and stirring behind pigment, spice and the remaining 1,3 butylene glycol thereafter again.
Table 6
［ Production Example 3 ］ hair conditioner
The use level of raw material is as shown in table 7.
(1) will heat to 80 ℃ of dissolvings in stearyl dimethyl benzyl ammonium chloride and the Sal input purified water.
(2) 18 hexadecanol and single stearic glyceride are heated to 80 ℃ of dissolvings.
(3) add (2) while (1) is stirred by mulser, carry out 5 minutes pre-stirrings after the interpolation,
(4) pre-stir finish after, stirs till 50 ℃ on one side and cools off, behind the interpolation 1,3 butylene glycol, further stirring is cooled to 35 ℃ and prepares again.
Table 7
［ Production Example 4 ］ hair growth liquor
The use level of raw material is as shown in table 8.
In purified water, drop into salicylic acid, be dissolved into vitamin E, L-menthol in the ethanol, further drop into the glycyrrhizin of a part that is dissolved into purified water again, drop into the 1,3 butylene glycol mix homogeneously thereafter and prepare.
Table 8
［ Production Example 5 ］ spray liquid
The use level of raw material is as shown in table 9.
In purified water, drop into citric acid and sodium citrate dissolving.Drop into antiseptic and the polyoxyethylene sorbitan monoleate that is dissolved in the ethanol thereafter.Thereafter dropping into 1,3 butylene glycol stirs to prepare.
Table 9
［ Production Example 6 ］ astringent
The use level of raw material is as shown in table 10.
In purified water, drop into citric acid and sodium citrate dissolving.Next drop into glycerol, 1,3 butylene glycol and sodium versenate in order, further drop into oleic alcohol polyoxyethylene (18) ether, the vitamin E that are dissolved in the ethanol again and be stirred to evenly and prepare.
Table 10
［ Production Example 7 ］ emulsion
The use level of raw material is as shown in table 11.
(1) stearic acid, spermol, octyl dodecanol myristinate and liquid paraffin are heated to 80 ℃ of dissolvings.
(2) triethanolamine, hyaluronate sodium, glycerol, 1,3 butylene glycol and hydroxyl ethylenediamine triacetic acid sodium are put into heated in the purified water to 80 ℃.
(3) drop into (2) while (1) is stirred by mulser, carry out 5 minutes pre-stirrings after the input.
(4) be cooled to 50 ℃ after pre-stirring finishes, further be cooled to 35 ℃ again and prepare.
Table 11
［ Production Example 8 ］ cream
The use level of raw material is as shown in table 12.
(1) stearic acid, glyceryl monostearate, anhydrous sorbitol sesquistearate, polyoxyethylene 20 sorbitan monostearate, 18 hexadecanol, liquid paraffin, dipentaerythritol six (hydroxy stearic acid/stearic acid/rosin acid) ester, glycerol three (2 ethyl hexanoic acid) ester and simethicone are heated to 80 ℃ of dissolvings.
(2) in purified water, drop into glycerol, 1,3 butylene glycol, sodium hydroxide and methyl parahydroxybenzoate, heat to 80 ℃ of dissolvings.
(3) drop into (2) while (1) is stirred by mulser, carry out 5 minutes pre-stirrings after the input.
(4) be cooled to 50 ℃ after pre-stirring finishes, further be cooled to 35 ℃ again and prepare.
Table 12
Claims (8)
1. a deodorant is characterized in that, contains the C2～C6 alcohol of 2 yuan or 3 yuan as effective ingredient.
2. according to the deodorant described in the claim 1, it is characterized in that described alcohol is 1,3 butylene glycol.
3. according to the deodorant described in claim 1 or 2, it is characterized in that, be used for adding age smelly disappear smelly.
4. according to each described deodorant in the claim 1～3, it is characterized in that the stink composition is unsaturated aldehyde.
5. according to the deodorant described in the claim 4, it is characterized in that unsaturated aldehyde is nonenyl aldehyde or octenal.
6. the smelly compositions of using that disappears is characterized in that, has cooperated each described deodorant in the claim 1～5 and forms.
7. according to the smelly compositions of using that disappears described in the claim 6, it is characterized in that, be skin preparations for extenal use.
8. a compositions is characterized in that, has cooperated 1,3 butylene glycol, oolong tea extract and sweet tea extract and constitutes.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011-027083 | 2011-02-10 | ||
| JP2011027083 | 2011-02-10 | ||
| JP2011135716 | 2011-06-17 | ||
| JP2011-135716 | 2011-06-17 | ||
| PCT/JP2012/052950 WO2012108494A1 (en) | 2011-02-10 | 2012-02-09 | Deodorant containing polyvalent alcohol |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103347545A true CN103347545A (en) | 2013-10-09 |
| CN103347545B CN103347545B (en) | 2015-05-13 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280008030.6A Active CN103347545B (en) | 2011-02-10 | 2012-02-09 | Deodorant containing polyvalent alcohol |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP5695678B2 (en) |
| CN (1) | CN103347545B (en) |
| HK (1) | HK1187285A1 (en) |
| TW (1) | TWI554287B (en) |
| WO (1) | WO2012108494A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106039978A (en) * | 2016-06-22 | 2016-10-26 | 深圳市龙澄高科技环保有限公司 | Gas deodorizing sustained-release monolithic gel and preparation method thereof |
| CN112156041A (en) * | 2020-10-16 | 2021-01-01 | 花安堂生物科技集团有限公司 | Dry-cleaning spray composition for hair and preparation method thereof |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103191453A (en) * | 2013-04-09 | 2013-07-10 | 潘运平 | Slow-release antibacterial deodorant gel and preparation method thereof |
| JP7260246B2 (en) * | 2017-07-07 | 2023-04-18 | Ｄｍ三井製糖株式会社 | Deodorants |
| WO2019130758A1 (en) * | 2017-12-26 | 2019-07-04 | サントリーホールディングス株式会社 | Adsorbent for volatile steroid and deodorant composition |
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| JP2001302483A (en) * | 2000-04-24 | 2001-10-31 | Nonogawa Shoji Kk | Deodorant |
| CN1966090A (en) * | 2005-11-18 | 2007-05-23 | 花王株式会社 | Deodorant compositions |
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| EP2243498A1 (en) * | 2008-02-15 | 2010-10-27 | Toray Opelontex Co., Ltd. | Deodorizing material |
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| JP2000229118A (en) * | 1999-02-09 | 2000-08-22 | Nisshin Oil Mills Ltd:The | Tea extract-containing composition for deodorizing and anti-oxidizing |
| JP5357369B2 (en) * | 2001-03-02 | 2013-12-04 | 花王株式会社 | Deodorant for nursing odor |
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| JP2003081801A (en) * | 2001-09-10 | 2003-03-19 | Mandom Corp | Deodorant cosmetic |
| JP2004262816A (en) * | 2003-02-28 | 2004-09-24 | Shiseido Co Ltd | Composition for perfume removal |
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| EP1956903B1 (en) * | 2005-11-29 | 2017-01-11 | Ambria Dermatology AB | Use of an absorption product comprising pentane-1, 5-diol as deodorant |
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- 2012-02-09 JP JP2012556926A patent/JP5695678B2/en active Active
- 2012-02-09 WO PCT/JP2012/052950 patent/WO2012108494A1/en active Application Filing
- 2012-02-09 CN CN201280008030.6A patent/CN103347545B/en active Active
- 2012-02-10 TW TW101104367A patent/TWI554287B/en active
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2014
- 2014-01-10 HK HK14100297.4A patent/HK1187285A1/en unknown
Patent Citations (5)
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| JPH05269187A (en) * | 1992-03-26 | 1993-10-19 | Suntory Ltd | Composition for deodorization and food and cosmetics compounded with this composition |
| JP2001302483A (en) * | 2000-04-24 | 2001-10-31 | Nonogawa Shoji Kk | Deodorant |
| CN1966090A (en) * | 2005-11-18 | 2007-05-23 | 花王株式会社 | Deodorant compositions |
| CN101405034A (en) * | 2006-03-22 | 2009-04-08 | 高砂香科工业株式会社 | Liquid deodorant composition and method of deodorizing |
| EP2243498A1 (en) * | 2008-02-15 | 2010-10-27 | Toray Opelontex Co., Ltd. | Deodorizing material |
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| CN106039978A (en) * | 2016-06-22 | 2016-10-26 | 深圳市龙澄高科技环保有限公司 | Gas deodorizing sustained-release monolithic gel and preparation method thereof |
| CN112156041A (en) * | 2020-10-16 | 2021-01-01 | 花安堂生物科技集团有限公司 | Dry-cleaning spray composition for hair and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| TW201235054A (en) | 2012-09-01 |
| JPWO2012108494A1 (en) | 2014-07-03 |
| HK1187285A1 (en) | 2014-04-04 |
| CN103347545B (en) | 2015-05-13 |
| TWI554287B (en) | 2016-10-21 |
| WO2012108494A1 (en) | 2012-08-16 |
| JP5695678B2 (en) | 2015-04-08 |
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