CN103342711A - 制备工艺简单的LiODFB电解质盐的制备方法 - Google Patents
制备工艺简单的LiODFB电解质盐的制备方法 Download PDFInfo
- Publication number
- CN103342711A CN103342711A CN201310313951XA CN201310313951A CN103342711A CN 103342711 A CN103342711 A CN 103342711A CN 201310313951X A CN201310313951X A CN 201310313951XA CN 201310313951 A CN201310313951 A CN 201310313951A CN 103342711 A CN103342711 A CN 103342711A
- Authority
- CN
- China
- Prior art keywords
- lithium
- boron
- oxalic acid
- preparation
- liodfb
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 150000003839 salts Chemical class 0.000 title claims abstract description 7
- 239000003792 electrolyte Substances 0.000 title abstract description 5
- WXNUAYPPBQAQLR-UHFFFAOYSA-N B([O-])(F)F.[Li+] Chemical compound B([O-])(F)F.[Li+] WXNUAYPPBQAQLR-UHFFFAOYSA-N 0.000 title abstract 2
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims abstract description 65
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 23
- 239000002904 solvent Substances 0.000 claims abstract description 16
- -1 salt compounds Chemical class 0.000 claims abstract description 12
- 150000001875 compounds Chemical class 0.000 claims abstract description 11
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052796 boron Inorganic materials 0.000 claims abstract description 9
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000011737 fluorine Substances 0.000 claims abstract description 8
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 235000006408 oxalic acid Nutrition 0.000 claims description 21
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 18
- 235000010338 boric acid Nutrition 0.000 claims description 16
- 229960002645 boric acid Drugs 0.000 claims description 16
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 claims description 16
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 15
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 11
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 6
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 5
- CXHHBNMLPJOKQD-UHFFFAOYSA-M methyl carbonate Chemical compound COC([O-])=O CXHHBNMLPJOKQD-UHFFFAOYSA-M 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000004327 boric acid Substances 0.000 claims description 4
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 claims description 3
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 3
- MIMUSZHMZBJBPO-UHFFFAOYSA-N 6-methoxy-8-nitroquinoline Chemical compound N1=CC=CC2=CC(OC)=CC([N+]([O-])=O)=C21 MIMUSZHMZBJBPO-UHFFFAOYSA-N 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 claims description 2
- LDDQLRUQCUTJBB-UHFFFAOYSA-N ammonium fluoride Chemical compound [NH4+].[F-] LDDQLRUQCUTJBB-UHFFFAOYSA-N 0.000 claims description 2
- 229910021538 borax Inorganic materials 0.000 claims description 2
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims description 2
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims description 2
- 229910001947 lithium oxide Inorganic materials 0.000 claims description 2
- HQRPHMAXFVUBJX-UHFFFAOYSA-M lithium;hydrogen carbonate Chemical compound [Li+].OC([O-])=O HQRPHMAXFVUBJX-UHFFFAOYSA-M 0.000 claims description 2
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 claims description 2
- 229910001635 magnesium fluoride Inorganic materials 0.000 claims description 2
- VGTPKLINSHNZRD-UHFFFAOYSA-N oxoborinic acid Chemical compound OB=O VGTPKLINSHNZRD-UHFFFAOYSA-N 0.000 claims description 2
- 238000002203 pretreatment Methods 0.000 claims description 2
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 2
- 239000004328 sodium tetraborate Substances 0.000 claims description 2
- 239000002994 raw material Substances 0.000 abstract description 14
- 238000010438 heat treatment Methods 0.000 abstract description 10
- 238000000498 ball milling Methods 0.000 abstract description 9
- 238000000034 method Methods 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 230000007797 corrosion Effects 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 4
- 230000001988 toxicity Effects 0.000 abstract description 3
- 231100000419 toxicity Toxicity 0.000 abstract description 3
- 239000003960 organic solvent Substances 0.000 abstract description 2
- 239000000047 product Substances 0.000 description 13
- 229910003002 lithium salt Inorganic materials 0.000 description 9
- 159000000002 lithium salts Chemical class 0.000 description 8
- 229910013063 LiBF 4 Inorganic materials 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 229910013188 LiBOB Inorganic materials 0.000 description 5
- 229910013870 LiPF 6 Inorganic materials 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 4
- 229910001416 lithium ion Inorganic materials 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 229910013075 LiBF Inorganic materials 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- QGHDLJAZIIFENW-UHFFFAOYSA-N 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxy-3-prop-2-enylphenyl)propan-2-yl]-2-prop-2-enylphenol Chemical group C1=C(CC=C)C(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C(CC=C)=C1 QGHDLJAZIIFENW-UHFFFAOYSA-N 0.000 description 1
- 229910015900 BF3 Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229910003902 SiCl 4 Inorganic materials 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 239000000010 aprotic solvent Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001639 boron compounds Chemical class 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- YNQRWVCLAIUHHI-UHFFFAOYSA-L dilithium;oxalate Chemical compound [Li+].[Li+].[O-]C(=O)C([O-])=O YNQRWVCLAIUHHI-UHFFFAOYSA-L 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002642 lithium compounds Chemical class 0.000 description 1
- 229910001496 lithium tetrafluoroborate Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 230000005501 phase interface Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000007774 positive electrode material Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 231100000004 severe toxicity Toxicity 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- RIUWBIIVUYSTCN-UHFFFAOYSA-N trilithium borate Chemical compound [Li+].[Li+].[Li+].[O-]B([O-])[O-] RIUWBIIVUYSTCN-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Secondary Cells (AREA)
Abstract
Description
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310313951.XA CN103342711B (zh) | 2011-06-22 | 2011-06-22 | 制备工艺简单的LiODFB电解质盐的制备方法 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2011101689535A CN102260282B (zh) | 2011-06-22 | 2011-06-22 | 一种二氟草酸硼酸锂电解质盐的制备方法 |
CN201310313951.XA CN103342711B (zh) | 2011-06-22 | 2011-06-22 | 制备工艺简单的LiODFB电解质盐的制备方法 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2011101689535A Division CN102260282B (zh) | 2011-06-22 | 2011-06-22 | 一种二氟草酸硼酸锂电解质盐的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103342711A true CN103342711A (zh) | 2013-10-09 |
CN103342711B CN103342711B (zh) | 2015-10-28 |
Family
ID=45007142
Family Applications (5)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310303302.1A Expired - Fee Related CN103333187B (zh) | 2011-06-22 | 2011-06-22 | 适合工业大批量生产的LiODFB电解质盐的制备方法 |
CN201310304275.XA Active CN103319510B (zh) | 2011-06-22 | 2011-06-22 | 安全环保的二氟草酸硼酸锂电解质盐的制备方法 |
CN201310313951.XA Active CN103342711B (zh) | 2011-06-22 | 2011-06-22 | 制备工艺简单的LiODFB电解质盐的制备方法 |
CN201310303190.XA Active CN103333186B (zh) | 2011-06-22 | 2011-06-22 | LiODFB电解质盐的制备方法 |
CN2011101689535A Expired - Fee Related CN102260282B (zh) | 2011-06-22 | 2011-06-22 | 一种二氟草酸硼酸锂电解质盐的制备方法 |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310303302.1A Expired - Fee Related CN103333187B (zh) | 2011-06-22 | 2011-06-22 | 适合工业大批量生产的LiODFB电解质盐的制备方法 |
CN201310304275.XA Active CN103319510B (zh) | 2011-06-22 | 2011-06-22 | 安全环保的二氟草酸硼酸锂电解质盐的制备方法 |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310303190.XA Active CN103333186B (zh) | 2011-06-22 | 2011-06-22 | LiODFB电解质盐的制备方法 |
CN2011101689535A Expired - Fee Related CN102260282B (zh) | 2011-06-22 | 2011-06-22 | 一种二氟草酸硼酸锂电解质盐的制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (5) | CN103333187B (zh) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104557995A (zh) * | 2013-10-12 | 2015-04-29 | 陈琛 | 一种二氟草酸硼酸锂的制备方法 |
CN105541890A (zh) * | 2016-01-27 | 2016-05-04 | 太原理工大学 | 一种二氟草酸硼酸钠的合成方法 |
CN107004912A (zh) * | 2014-11-13 | 2017-08-01 | 巴斯夫公司 | 电解质和金属氢化物电池 |
CN111153918A (zh) * | 2019-12-16 | 2020-05-15 | 山东石大胜华化工集团股份有限公司 | 一种双草酸硼酸锂的制备方法 |
CN112093807A (zh) * | 2020-07-30 | 2020-12-18 | 浙江工业大学 | 一种利用硼酸合成卤化硼酸锂的方法 |
CN112093806A (zh) * | 2020-07-30 | 2020-12-18 | 浙江工业大学 | 一种卤化硼酸锂的合成方法 |
CN112830498A (zh) * | 2020-11-13 | 2021-05-25 | 厦门永力鑫新能源科技有限公司 | 锂盐及其制备方法、锂离子电池电解液添加剂、锂离子电池电解液和锂离子电池 |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103265569A (zh) * | 2013-05-17 | 2013-08-28 | 太原理工大学 | 一种二氟草酸硼酸锂的合成方法 |
CN104230970B (zh) * | 2013-06-21 | 2017-02-15 | 湖南省正源储能材料与器件研究所 | 一种草酸二氟硼酸锂电解质盐的制备方法 |
CN108912155A (zh) * | 2018-08-29 | 2018-11-30 | 苏州松湖新能源材料有限公司 | 一种二氟草酸硼酸盐的制备方法 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1195834B1 (en) * | 2000-10-03 | 2010-09-15 | Central Glass Company, Limited | Electrolyte for electrochemical device |
US6849752B2 (en) * | 2001-11-05 | 2005-02-01 | Central Glass Company, Ltd. | Process for synthesizing ionic metal complex |
CN1290851C (zh) * | 2005-04-11 | 2006-12-20 | 北京科技大学 | 一种双草酸基硼酸锂合成方法 |
CN101139352A (zh) * | 2007-09-29 | 2008-03-12 | 张家港市国泰华荣化工新材料有限公司 | 二氟草酸硼酸锂的制备方法 |
CN101643481B (zh) * | 2009-08-28 | 2011-08-17 | 张家港市国泰华荣化工新材料有限公司 | 一种得到二氟草酸硼酸锂与双草酸硼酸锂的合成工艺 |
CN101648963A (zh) * | 2009-08-28 | 2010-02-17 | 张家港市国泰华荣化工新材料有限公司 | 一种得到二氟草酸硼酸锂与四氟硼酸锂的合成工艺 |
CN102010436A (zh) * | 2010-11-10 | 2011-04-13 | 兰州理工大学 | 草酸二氟硼酸锂的制备方法 |
-
2011
- 2011-06-22 CN CN201310303302.1A patent/CN103333187B/zh not_active Expired - Fee Related
- 2011-06-22 CN CN201310304275.XA patent/CN103319510B/zh active Active
- 2011-06-22 CN CN201310313951.XA patent/CN103342711B/zh active Active
- 2011-06-22 CN CN201310303190.XA patent/CN103333186B/zh active Active
- 2011-06-22 CN CN2011101689535A patent/CN102260282B/zh not_active Expired - Fee Related
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104557995A (zh) * | 2013-10-12 | 2015-04-29 | 陈琛 | 一种二氟草酸硼酸锂的制备方法 |
CN104557995B (zh) * | 2013-10-12 | 2017-02-15 | 陈琛 | 一种二氟草酸硼酸锂的制备方法 |
CN107004912A (zh) * | 2014-11-13 | 2017-08-01 | 巴斯夫公司 | 电解质和金属氢化物电池 |
CN105541890A (zh) * | 2016-01-27 | 2016-05-04 | 太原理工大学 | 一种二氟草酸硼酸钠的合成方法 |
CN105541890B (zh) * | 2016-01-27 | 2017-08-29 | 太原理工大学 | 一种二氟草酸硼酸钠的合成方法 |
CN111153918A (zh) * | 2019-12-16 | 2020-05-15 | 山东石大胜华化工集团股份有限公司 | 一种双草酸硼酸锂的制备方法 |
CN112093807A (zh) * | 2020-07-30 | 2020-12-18 | 浙江工业大学 | 一种利用硼酸合成卤化硼酸锂的方法 |
CN112093806A (zh) * | 2020-07-30 | 2020-12-18 | 浙江工业大学 | 一种卤化硼酸锂的合成方法 |
CN112830498A (zh) * | 2020-11-13 | 2021-05-25 | 厦门永力鑫新能源科技有限公司 | 锂盐及其制备方法、锂离子电池电解液添加剂、锂离子电池电解液和锂离子电池 |
Also Published As
Publication number | Publication date |
---|---|
CN103333187B (zh) | 2015-08-12 |
CN102260282A (zh) | 2011-11-30 |
CN103333186B (zh) | 2015-08-12 |
CN103319510B (zh) | 2015-09-16 |
CN103342711B (zh) | 2015-10-28 |
CN103319510A (zh) | 2013-09-25 |
CN103333187A (zh) | 2013-10-02 |
CN102260282B (zh) | 2013-08-21 |
CN103333186A (zh) | 2013-10-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102260282B (zh) | 一种二氟草酸硼酸锂电解质盐的制备方法 | |
CN101643481B (zh) | 一种得到二氟草酸硼酸锂与双草酸硼酸锂的合成工艺 | |
US8962194B2 (en) | Lithium ion conducting sulfide based crystallized glass and method for production thereof | |
CN101080361B (zh) | 二氟磷酸盐的制造方法、用于二次电池的非水电解液及非水电解液二次电池 | |
CN104185636B (zh) | 金属二氟螯合硼酸盐的制备方法及其在原电池中作为电池电解质或添加剂的用途 | |
CN104387411B (zh) | 一种草酸二氟硼酸锂盐的串联一锅法合成方法 | |
US9991562B2 (en) | Symmetrical and unsymmetrical organosilicon molecules and electrolyte compositions and electrochemical devices containing them | |
CN111224164B (zh) | 一种二氟磷酸锂的制备方法 | |
CN111205322B (zh) | 2,4,6-三氧代-1,3,5-三嗪-三磷酸锂及其复配物用于阻燃电解质的制备方法 | |
CN102702243B (zh) | 一种二氟草酸硼酸锂的制备及纯化方法 | |
JP6921128B2 (ja) | ジフルオロリン酸リチウムの製造方法 | |
CN103030657A (zh) | 一种锂离子电池用电解质双草酸基硼酸锂的制备方法 | |
CN109535191B (zh) | 一种双草酸硼酸锂的制备方法 | |
JP6839702B2 (ja) | Liイオンバッテリ電解質のための添加剤としてのフッ素化されたアクリレート | |
CN103951689A (zh) | 液态双草酸硼酸锂的制备方法 | |
CN106785045A (zh) | 一种二氟磷酸锂的制备方法、锂离子电池电解液和离子电池 | |
WO2019018999A1 (zh) | 二氟磷酸锂的制备方法 | |
CN104557995B (zh) | 一种二氟草酸硼酸锂的制备方法 | |
CN104447828B (zh) | 一种双草酸硼酸锂的合成及提纯方法 | |
CN101914110B (zh) | 一种采用流变相方法合成双草酸基硼酸锂的方法 | |
CN110627742B (zh) | 一种含有至少一种环状配体结构的化合物的制备方法和纯化方法 | |
CN109293691B (zh) | 一种制备双草酸硼酸锂的方法 | |
CN104230970B (zh) | 一种草酸二氟硼酸锂电解质盐的制备方法 | |
Smagin et al. | Application of thermogravimetric studies for optimization of lithium hexafluorophosphate production | |
CN101962181B (zh) | 用流变相反应法制备六氟磷酸锂 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
C41 | Transfer of patent application or patent right or utility model | ||
CB03 | Change of inventor or designer information |
Inventor after: Chen Libin Inventor before: Request for anonymity |
|
COR | Change of bibliographic data | ||
GR01 | Patent grant | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20150928 Address after: 362799 No. 410, R & D building, Shishi hi tech Innovation Service Center, Quanzhou, Fujian, China -411 Applicant after: FUJIAN GANCHUANG PRECISION MACHINERY Co.,Ltd. Address before: Tang Jiao Cun Cun Wei Xin Zhuang Zhen Dong GUI Cun 214200 Jiangsu city of Wuxi province Yixing City Applicant before: Jiang Panjun |
|
TR01 | Transfer of patent right |
Effective date of registration: 20181210 Address after: 233010 409 Wu Wan Road, Yuhui District, Bengbu, Anhui Patentee after: BENGBU JINSHI NEW MATERIAL Co.,Ltd. Address before: 230031 B-1014, 10 floor, business office building, Wo Ye garden, Shushan District, Hefei, Anhui. Patentee before: HEFEI WISDOM LOTUT INTELLECTUAL PROPERTY Co.,Ltd. Effective date of registration: 20181210 Address after: 230031 B-1014, 10 floor, business office building, Wo Ye garden, Shushan District, Hefei, Anhui. Patentee after: HEFEI WISDOM LOTUT INTELLECTUAL PROPERTY Co.,Ltd. Address before: 362799 R&D Building 410 -411, Shishi High-tech Entrepreneurship Service Center, Quanzhou City, Fujian Province Patentee before: FUJIAN GANCHUANG PRECISION MACHINERY Co.,Ltd. |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20190329 Address after: 313103 South Industrial Functional Zone of Heping Town, Changxing County, Huzhou City, Zhejiang Province Patentee after: HUZHOU KUNLUN POWER BATTERY MATERIAL Co.,Ltd. Address before: 233010 409 Wu Wan Road, Yuhui District, Bengbu, Anhui Patentee before: BENGBU JINSHI NEW MATERIAL Co.,Ltd. |
|
TR01 | Transfer of patent right | ||
CP01 | Change in the name or title of a patent holder |
Address after: 313103 South Industrial Functional Zone of Heping Town, Changxing County, Huzhou City, Zhejiang Province Patentee after: Huzhou Kunlun yienke battery material Co.,Ltd. Address before: 313103 South Industrial Functional Zone of Heping Town, Changxing County, Huzhou City, Zhejiang Province Patentee before: HUZHOU KUNLUN POWER BATTERY MATERIAL Co.,Ltd. |
|
CP01 | Change in the name or title of a patent holder |