CN103321375B - Composite inorganic thermal-insulation decoration plate and manufacturing method thereof - Google Patents

Composite inorganic thermal-insulation decoration plate and manufacturing method thereof Download PDF

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CN103321375B
CN103321375B CN201310234833.XA CN201310234833A CN103321375B CN 103321375 B CN103321375 B CN 103321375B CN 201310234833 A CN201310234833 A CN 201310234833A CN 103321375 B CN103321375 B CN 103321375B
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heat
insulation layer
insulation
water
composite inorganic
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CN103321375A (en
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钟永能
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Anhui Lide Energy Saving Science & Technology Co Ltd
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Anhui Lide Energy Saving Science & Technology Co Ltd
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Abstract

The invention discloses a composite inorganic thermal-insulation decoration plate and a manufacturing method thereof and belongs to the technical field of novel construction materials. The composite inorganic thermal-insulation decoration plate comprises a thermal-insulation layer and a decoration layer and is characterized in that the thermal-insulation layer is composed of the following components by weight: 30-40 parts of cement, 2.5-5 parts of gypsum powder, 55-63 parts of glass beads, 0.3-0.5 part of water reducer, 0.6-1.0 part of hydrophobe emulsion powder, 0.2-0.4 part of silane waterproof agents and 0.5-1.0 part of capillary crystalline master batches, and the decoration layer is composed of the following components by weight: 15-25 parts of silicone acrylic emulsion, 2-5 parts of silica solution, 65-75 parts of silica sand, 0.1-0.2 part of hydroxyethyl cellulose, 0.2-0.5 part of methanesiliconic acid sodium salt and 1-5 parts of water. The decoration plate manufactured by a formula and the manufacturing method has the effect of thermal-insulation and decoration, and further has the advantages of being fireproof, waterproof, capable of automatically repairing microcracks, long in service life, low in manufacturing cost and short in production period.

Description

Composite inorganic thermal-insulation decoration plate and preparation method thereof
Technical field
The invention belongs to New Building Materials technical field, be specifically related to a kind of composite inorganic thermal-insulation decoration plate and preparation method thereof.
Background technology
Along with country more and more payes attention to Building Energy-saving, building external wall energy-saving insulation industry more and more receives publicity.Due to the deficiency that the insulation materials such as thin-coat plaster system, glue powder polyphenyl particle system exist, current exterior-wall heat insulation is gradually to heat preservation decoration integrative transition.
Heat preservation decoration integrative in architectural energy saving system refers to the insulation materials such as EPS, XPS, polyurethane, phenol formaldehyde foam or inorganic foamed material and metal finishing sheet material or inorganic pre-coating decorative plaques organic composite.The manual efficiency of construction that heat preservation decoration integrative system can overcome other external-wall external-insulation energy-saving system current is low, easily ftractures, ornamental difference, and the shortcomings such as service life is short are the exterior wall insulation energy efficient systems that a kind of comprehensive cost performance is superior.Its appearance produces great change by traditional coating industry and insulation industry, and have good market development prospect, it will become a development trend of China's building energy conservation industry.
But it is high that existing heat insulating decorative board ubiquity sheet material water absorption rate, the problems such as water resistance difference.From more existing sample projects, through exposing to the sun and rain more than a year, the appearance slab-joint cracking in various degree of the warming plate on metope, plate sweat such as to grow dim at the phenomenon.In the warm and humid deformation of inorganic composite heat-preserving plate, rainwater often penetrates into heat-insulation layer thus, causes heat-insulation layer imbibition, distortion, and this not only affects the usefulness of warming plate, also can destroy the adhesion strength of insulating composite layer, can cause time serious coming unstuck, the phenomenon such as cracking.Meanwhile, some inorganic pre-coating decorative plaques is often ignored and is carried out water-proofing treatment, particularly sheet material after building-site carries out cutting processing to plate side and back, does not carry out water-proofing treatment, causes rainwater can penetrate into coating surface along edge of crack, coating is grown dim.
Current existing heat insulating decorative board often lays particular emphasis on the improvement and bring new ideas of the thermal and insulating performance to warming plate, and the research ignored heat insulating decorative board water resistance and attention, make heat insulating decorative board in use occur many problems, bring certain trouble to user.
Summary of the invention
For problems of the prior art, the object of the invention is providing a kind of composite inorganic thermal-insulation decoration plate and preparation method thereof.
The present invention is realized by the following technical programs:
Described composite inorganic thermal-insulation decoration plate, comprise heat-insulation layer and decorative layer, it is characterized in that described heat-insulation layer is made up of the component of following parts by weight: cement 30-40 part, land plaster 2.5-5 part, glass bead 55-63 part, water reducer 0.3-0.5 part, hydrophobic latex powder 0.6-1.0 part, silane waterproofing agent 0.2-0.4 part, penetrant crystalline masterbatch 0.5-1.0 part, described decorative layer is made up of the component of following parts by weight: Silicone acrylic emulsion 15-25 part, Ludox 2-5 part, quartz sand 65-75 part, hydroxyethylcellulose 0.1-0.2 part, sodium methyl silicate 0.2-0.5 part, water 1-5 part.
Described composite inorganic thermal-insulation decoration plate; it is characterized in that described heat-insulation layer is made up of the component of following parts by weight: cement 35-40 part, land plaster 3-4 part, glass bead 57-61 part, water reducer 0.3-0.4 part, hydrophobic latex powder 0.8-1.0 part, silane waterproofing agent 0.2-0.3 part, penetrant crystalline masterbatch 0.8-1.0 part, described decorative layer is made up of the component of following parts by weight: Silicone acrylic emulsion 15-20 part, Ludox 3-4 part, quartz sand 70-72 part, hydroxyethylcellulose 0.1-0.2 part, sodium methyl silicate 0.3-0.4 part, water 2.6-4.5 part.
Described composite inorganic thermal-insulation decoration plate, is characterized in that described cement is common 425 label portland cements.
Described composite inorganic thermal-insulation decoration plate, is characterized in that described glass bead bulk density is 110-130 kg/m 3.
Described composite inorganic thermal-insulation decoration plate, is characterized in that described water reducer is NF naphthalene series high-efficiency water-reducing agent.
Described composite inorganic thermal-insulation decoration plate, is characterized in that described quartz sand is 70-100 order.
The preparation method of described composite inorganic thermal-insulation decoration plate, is characterized in that by following processing step:
1) preparation of heat-insulation layer slurry: by cement, land plaster, glass bead, water reducer, hydrophobic latex powder, silane waterproofing agent, penetrant crystalline masterbatch, the heat-insulation layer dry powder that to stir to obtain in kneader is added in described ratio, then in heat-insulation layer dry powder, water is added, stir and make heat-insulation layer slurry, for subsequent use;
2) preparation of decorative layer slurry: in another kneader, slowly add water and hydroxyethylcellulose, hydroxyethylcellulose is uniformly dissolved, then add Silicone acrylic emulsion, quartz sand, Ludox, sodium methyl silicate successively, stir and make decorative layer slurry, for subsequent use;
3) preparation of heat-insulation layer: fix mould, pours in mould by the heat-insulation layer slurry prepared in step 1), to be closed and pressurize by forcing press to mould, and make the extrusion forming of heat-insulation layer slurry obtain heat-insulation layer and to wet embryo, wherein press pressure is 20 ~ 30 kg/cm 3;
4) preparation of decorative layer: adjustment press pressure is 10 ~ 20 kg/cm 3, by step 2) in the decorative layer slurry that is stirred pour the obtained heat-insulation layer of step 3) into and wet above embryo, by closing mould and pressurizeing, make decorative layer become consolidation with heat-insulation layer, after the demoulding, be warming plate idiosome;
5) thermostatic curing: the warming plate idiosome obtained by step 4), sends in the constant temperature oven of 40 ~ 60 DEG C, dries maintenance 5 ~ 8 hours, obtain composite inorganic thermal-insulation decoration plate of the present invention.
The preparation method of described composite inorganic thermal-insulation decoration plate, is characterized in that the ratio of heat-insulation layer dry powder and water in step 1) is 100:20-30.
The preparation method of described composite inorganic thermal-insulation decoration plate, is characterized in that step 1) and step 2) described in the speed of agitator of kneader be 30-50 rev/min.
Compared to existing technology, the present invention has the following advantages:
1. the heat-insulation layer of composite inorganic thermal-insulation decoration plate and decorative layer; have employed the inorganics such as cement, gypsum, glass bead, quartz sand; fire protecting performance and the fire-protection rating of sheet material are heightened; simultaneously bilevel physical property is close, avoid cause because expanding with heat and contract with cold distortion, be full of cracks, layering, the phenomenon such as come off.
2. heat-insulation layer have employed and has hydrophobicity redispersable latex powder, organosilicon powder hydrophober, goods are made to have excellent water resistance and hydrophobicity performance, no matter be that sheet material is inner, or surface all has excellent water resistance, greatly reduce the water absorption rate of sheet material self, solve be full of cracks that existing heat insulating decorative board causes because of water suction problem, rise rouse, come off, the problem such as mouldy, bleeding.Simultaneously when after sheet material water suction, active chemistry in the penetrant crystalline masterbatch added is that carrier permeates to inside concrete with water, water-fast crystalline solid is formed in concrete, blocking capillary channel, thus make the finer and close more waterproof of sheet material, thus make sheet material have the function of automatically repairing the defects such as micro-crack, make sheet material have effect of permanent waterproof.Composite inorganic thermal-insulation decoration plate obtained by the present invention, through inspection, water absorption rate≤0.3%, its water resistance is far away higher than market like product.
3. decorative layer, abandon the way of traditional polymer cement mortar decorative layer, have employed Silicone acrylic emulsion and the sodium methyl silicate waterproofing agent of resistance to water and excellent in weather, greatly improve waterproof and the hydrophobicity performance of decorative layer, simultaneously the adding of Ludox, also improve the adhesion strength of decorative layer.
4. composite inorganic thermal-insulation decoration plate, adopt the brand-new production technology of the compressing and constant temperature drying maintenance of twice, mould, the techniques such as the bonding between conventional vacuum layer and decorative layer, anchoring, spraying are abandoned, carry out workshopization to produce, the heat insulating decorative board of machine-shaping, technique is advanced, and mechanization degree is high, reduce production and processing cost, save the production cycle.
Accompanying drawing explanation
Fig. 1 is structural representation of the present invention;
In figure: 1-heat-insulation layer, 2-decorative layer.
Detailed description of the invention
Below in conjunction with Figure of description, the present invention is described in further detail, and provides detailed description of the invention.
As shown in Figure 1, composite inorganic thermal-insulation decoration plate of the present invention is suppressed successively by heat-insulation layer 1 and decorative layer 2 and is formed.Wherein heat-insulation layer 1 is made up of cement, land plaster, glass bead, water reducer, hydrophobic latex powder, silane waterproofing agent, penetrant crystalline masterbatch, and decorative layer 2 is made up of Silicone acrylic emulsion, Ludox, quartz sand, hydroxyethylcellulose, sodium methyl silicate, water.
Wherein, in heat-insulation layer, cement is common 425 label portland cements, and glass bead bulk density is 110 ~ 130kg/m 3water reducer is NF naphthalene series high-efficiency water-reducing agent, hydrophobic latex powder is Germany's watt 8031H latex powder that gram chemical company is produced, silane waterproofing agent is Germany's watt Powder D organosilicon powder hydrophober that gram chemical company is produced, penetrant crystalline masterbatch is the Activated-Crystal 8106 that Shanghai Fu Yuan company produces, in decorative layer, quartz sand is 70 ~ 100 orders, and the molecular weight of hydroxyethylcellulose is about 100,000.
Embodiment 1
By cement 30 parts, land plaster 5 parts, glass bead 63 parts, water reducer 0.3 part, hydrophobic latex powder 1 part, silane waterproofing agent 0.2 part, penetrant crystalline masterbatch 0.5 part; add in kneader by above-mentioned weight ratio; stir obtained heat-insulation layer dry powder under the rotating speed of 45 revs/min; under stirring; water is added in heat-insulation layer dry powder; by heat-insulation layer dry powder total amount: the weight ratio of water=100:20 adds water, stir obtained heat-insulation layer slurry, for subsequent use.In another kneader, by weight slowly adding 2.6 parts, water, hydroxyethylcellulose 0.1 part, both stirring and dissolving are even, be add Silicone acrylic emulsion 25 parts, quartz sand 70 parts, Ludox 2 parts, sodium methyl silicate 0.3 part successively under the condition of 45 revs/min at kneader speed of agitator, stir obtained decorative layer slurry, for subsequent use.
Fix mould, pour in mould by the heat-insulation layer slurry be stirred, being closed mould by forcing press and pressurize, is 20kg/cm in press pressure 3pressure condition under.Make the extrusion forming of heat-insulation layer slurry obtain heat-insulation layer to wet embryo.Heat-insulation layer wets after embryo prepares, and adjustment press pressure is 15kg/cm 3, the decorative layer slurry be stirred is poured into heat-insulation layer and wets above embryo, then by forcing press mould closed and pressurize, heat-insulation layer and decorative laminate being integrated, after the demoulding, being warming plate idiosome.By the warming plate idiosome after the demoulding, send in the constant temperature oven of 40 DEG C, dry maintenance 7 hours, be i.e. obtained composite inorganic thermal-insulation decoration plate of the present invention.
Embodiment 2
By cement 35 parts, land plaster 3 parts, glass bead 59.7 parts, water reducer 0.4 part, hydrophobic latex powder 0.8 part, silane waterproofing agent 0.3 part, penetrant crystalline masterbatch 0.8 part; add in kneader by above-mentioned weight ratio; stir obtained heat-insulation layer dry powder under the rotating speed of 30 revs/min; under stirring; water is added in heat-insulation layer dry powder; by heat-insulation layer dry powder total amount: the weight ratio of water=100:25 adds water, stir obtained heat-insulation layer slurry, for subsequent use.In another kneader, by weight slowly adding 4.5 parts, water, hydroxyethylcellulose 0.1 part, both stirring and dissolving are even, be add Silicone acrylic emulsion 20 parts, quartz sand 72 parts, Ludox 3 parts, sodium methyl silicate 0.4 part successively under the condition of 30 revs/min at kneader speed of agitator, stir obtained decorative layer slurry, for subsequent use.
Fix mould, pour in mould by the heat-insulation layer slurry be stirred, being closed mould by forcing press and pressurize, is 15kg/cm in press pressure 3pressure condition under.Make the extrusion forming of heat-insulation layer slurry obtain heat-insulation layer to wet embryo.Heat-insulation layer wets after embryo prepares, and adjustment press pressure is 10kg/cm 3, the decorative layer slurry be stirred is poured into heat-insulation layer and wets above embryo, then by forcing press mould closed and pressurize, heat-insulation layer and decorative laminate being integrated, after the demoulding, being warming plate idiosome.By the warming plate idiosome after the demoulding, send in the constant temperature oven of 50 DEG C, dry maintenance 6 hours, be i.e. obtained composite inorganic thermal-insulation decoration plate of the present invention.
Embodiment 3
By cement 40 parts, land plaster 2.5 parts, glass bead 55 parts, water reducer 0.5 part, hydrophobic latex powder 0.6 part, silane waterproofing agent 0.4 part, penetrant crystalline masterbatch 1.0 parts; add in kneader by above-mentioned weight ratio; stir obtained heat-insulation layer dry powder under the rotating speed of 50 revs/min; under stirring; water is added in heat-insulation layer dry powder; by heat-insulation layer dry powder total amount: the weight ratio of water=100:30 adds water, stir obtained heat-insulation layer slurry, for subsequent use.In another kneader, by weight slowly adding 5 parts, water, hydroxyethylcellulose 0.2 part, both stirring and dissolving are even, be add Silicone acrylic emulsion 18 parts, quartz sand 65 parts, Ludox 4 parts, sodium methyl silicate 0.5 part successively under the condition of 50 revs/min at kneader speed of agitator, stir obtained decorative layer slurry, for subsequent use.
Fix mould, pour in mould by the heat-insulation layer slurry be stirred, being closed mould by forcing press and pressurize, is 20kg/cm in press pressure 3pressure condition under.Make the extrusion forming of heat-insulation layer slurry obtain heat-insulation layer to wet embryo.Heat-insulation layer wets after embryo prepares, and adjustment press pressure is 10kg/cm 3, the decorative layer slurry be stirred is poured into heat-insulation layer and wets above embryo, then by forcing press mould closed and pressurize, heat-insulation layer and decorative laminate being integrated, after the demoulding, being warming plate idiosome.By the warming plate idiosome after the demoulding, send in the constant temperature oven of 60 DEG C, dry maintenance 5 hours, be i.e. obtained composite inorganic thermal-insulation decoration plate of the present invention.
Embodiment 4
By cement 38 parts, land plaster 4 parts, glass bead 61 parts, water reducer 0.35 part, hydrophobic latex powder 0.9 part, silane waterproofing agent 0.25 part, penetrant crystalline masterbatch 0.9 part; add in kneader by above-mentioned weight ratio; stir obtained heat-insulation layer dry powder under the rotating speed of 50 revs/min; under stirring; water is added in heat-insulation layer dry powder; by heat-insulation layer dry powder total amount: the weight ratio of water=100:30 adds water, stir obtained heat-insulation layer slurry, for subsequent use.In another kneader, by weight slowly adding 3.5 parts, water, hydroxyethylcellulose 0.15 part, both stirring and dissolving are even, be add Silicone acrylic emulsion 15 parts, quartz sand 65 parts, Ludox 5 parts, sodium methyl silicate 0.2 part successively under the condition of 50 revs/min at kneader speed of agitator, stir obtained decorative layer slurry, for subsequent use.
Fix mould, pour in mould by the heat-insulation layer slurry be stirred, being closed mould by forcing press and pressurize, is 15kg/cm in press pressure 3pressure condition under.Make the extrusion forming of heat-insulation layer slurry obtain heat-insulation layer to wet embryo.Heat-insulation layer wets after embryo prepares, and adjustment press pressure is 10kg/cm 3, the decorative layer slurry be stirred is poured into heat-insulation layer and wets above embryo, then by forcing press mould closed and pressurize, heat-insulation layer and decorative laminate being integrated, after the demoulding, being warming plate idiosome.By the warming plate idiosome after the demoulding, send in the constant temperature oven of 55 DEG C, dry maintenance 6 hours, be i.e. obtained composite inorganic thermal-insulation decoration plate of the present invention.
Adopt composite inorganic thermal-insulation decoration plate prepared by above-described embodiment formula and method, except there is the dual-use function of insulation and decoration, also there is the water resistance of fire prevention and excellence.Because the physical property of heat-insulation layer and decorative layer is close, the distortion, be full of cracks, the layering that cause because expanding with heat and contract with cold effectively can be avoided and the phenomenon such as to come off; The hydrophobic latex powder of adding in heat-insulation layer and silane waterproofing agent, make product surface and the inner water resistance all with excellence, greatly can reduce the water absorption rate of sheet material self, even if after sheet material absorbs water on a small quantity, active chemistry in the penetrant crystalline masterbatch added is that carrier permeates to inside concrete with water, water-fast crystalline solid is formed in concrete, blocking capillary channel, thus make the finer and close more waterproof of sheet material, through inspection, this product water absorption rate≤0.3%, water resistance is higher than market like product.

Claims (9)

1. composite inorganic thermal-insulation decoration plate; comprise heat-insulation layer and decorative layer; it is characterized in that described heat-insulation layer is made up of the component of following parts by weight: cement 30-40 part, land plaster 2.5-5 part, glass bead 55-63 part, water reducer 0.3-0.5 part, hydrophobic latex powder 0.6-1.0 part, silane waterproofing agent 0.2-0.4 part, penetrant crystalline masterbatch 0.5-1.0 part, described decorative layer is made up of the component of following parts by weight: Silicone acrylic emulsion 15-25 part, Ludox 2-5 part, quartz sand 65-75 part, hydroxyethylcellulose 0.1-0.2 part, sodium methyl silicate 0.2-0.5 part, water 1-5 part.
2. composite inorganic thermal-insulation decoration plate according to claim 1, it is characterized in that described heat-insulation layer is made up of the component of following parts by weight: cement 35-40 part, land plaster 3-4 part, glass bead 57-61 part, water reducer 0.3-0.4 part, hydrophobic latex powder 0.8-1.0 part, silane waterproofing agent 0.2-0.3 part, penetrant crystalline masterbatch 0.8-1.0 part, described decorative layer is made up of the component of following parts by weight: Silicone acrylic emulsion 15-20 part, Ludox 3-4 part, quartz sand 70-72 part, hydroxyethylcellulose 0.1-0.2 part, sodium methyl silicate 0.3-0.4 part, water 2.6-4.5 part.
3. composite inorganic thermal-insulation decoration plate according to claim 1 and 2, is characterized in that described cement is common 425 label portland cements.
4. composite inorganic thermal-insulation decoration plate according to claim 1 and 2, is characterized in that described glass bead bulk density is 110-130kg/m 3.
5. composite inorganic thermal-insulation decoration plate according to claim 1 and 2, is characterized in that described water reducer is NF naphthalene series high-efficiency water-reducing agent.
6. composite inorganic thermal-insulation decoration plate according to claim 1 and 2, is characterized in that described quartz sand is 70-100 order.
7. the preparation method of composite inorganic thermal-insulation decoration plate, is characterized in that by following processing step:
1) preparation of heat-insulation layer slurry: by cement, land plaster, glass bead, water reducer, hydrophobic latex powder, silane waterproofing agent, penetrant crystalline masterbatch, add the heat-insulation layer dry powder that to stir to obtain in kneader, then in heat-insulation layer dry powder, add water, stir and make heat-insulation layer slurry, for subsequent use; Wherein cement, land plaster, glass bead, water reducer, hydrophobic latex powder, silane waterproofing agent, penetrant crystalline masterbatch add by following components by weight percent, cement 30-40 part, land plaster 2.5-5 part, glass bead 55-63 part, water reducer 0.3-0.5 part, hydrophobic latex powder 0.6-1.0 part, silane waterproofing agent 0.2-0.4 part, penetrant crystalline masterbatch 0.5-1.0 part;
2) preparation of decorative layer slurry: in another kneader, slowly add water and hydroxyethylcellulose, hydroxyethylcellulose is uniformly dissolved, then add Silicone acrylic emulsion, quartz sand, Ludox, sodium methyl silicate successively, stir and make decorative layer slurry, for subsequent use; Wherein, the components by weight percent of each component is: Silicone acrylic emulsion 15-25 part, Ludox 2-5 part, quartz sand 65-75 part, hydroxyethylcellulose 0.1-0.2 part, sodium methyl silicate 0.2-0.5 part, water 1-5 part;
3) preparation of heat-insulation layer: fix mould, pours in mould by the heat-insulation layer slurry prepared in step 1), to be closed and pressurize by forcing press to mould, and make the extrusion forming of heat-insulation layer slurry obtain heat-insulation layer and to wet embryo, wherein press pressure is 20 ~ 30kg/cm 3;
4) preparation of decorative layer: adjustment press pressure is 10 ~ 20kg/cm 3, by step 2) in the decorative layer slurry that is stirred pour the obtained heat-insulation layer of step 3) into and wet above embryo, by closing mould and pressurizeing, make decorative layer become to be integrated with heat-insulation layer, after the demoulding, be warming plate idiosome;
5) thermostatic curing: the warming plate idiosome obtained by step 4), sends in the constant temperature oven of 40 ~ 60 DEG C, dries maintenance 5 ~ 8 hours, obtain composite inorganic thermal-insulation decoration plate of the present invention.
8. the preparation method of composite inorganic thermal-insulation decoration plate according to claim 7, is characterized in that the ratio of heat-insulation layer dry powder and water in step 1) is 100:20-30.
9. the preparation method of composite inorganic thermal-insulation decoration plate according to claim 7, is characterized in that step 1) and step 2) described in the speed of agitator of kneader be 30-50 rev/min.
CN201310234833.XA 2013-06-14 2013-06-14 Composite inorganic thermal-insulation decoration plate and manufacturing method thereof Expired - Fee Related CN103321375B (en)

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