CN103282429B - 具有三嗪-环氧交联体系的压敏粘合剂 - Google Patents
具有三嗪-环氧交联体系的压敏粘合剂 Download PDFInfo
- Publication number
- CN103282429B CN103282429B CN201180063682.5A CN201180063682A CN103282429B CN 103282429 B CN103282429 B CN 103282429B CN 201180063682 A CN201180063682 A CN 201180063682A CN 103282429 B CN103282429 B CN 103282429B
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- China
- Prior art keywords
- meth
- acid
- monomers
- weight
- epoxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 0 CC(c1c(*)c(*)c(*)c(*)c1)=C Chemical compound CC(c1c(*)c(*)c(*)c(*)c1)=C 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/062—Copolymers with monomers not covered by C08L33/06
- C08L33/068—Copolymers with monomers not covered by C08L33/06 containing glycidyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
- C08F220/325—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals containing glycidyl radical, e.g. glycidyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/062—Copolymers with monomers not covered by C09J133/06
- C09J133/068—Copolymers with monomers not covered by C09J133/06 containing glycidyl groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
- C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/385—Acrylic polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201061428088P | 2010-12-29 | 2010-12-29 | |
| US61/428,088 | 2010-12-29 | ||
| PCT/US2011/061119 WO2012091817A1 (en) | 2010-12-29 | 2011-11-17 | Pressure-sensitive adhesives with triazine-epoxy crosslinking system |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103282429A CN103282429A (zh) | 2013-09-04 |
| CN103282429B true CN103282429B (zh) | 2015-11-25 |
Family
ID=45316055
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201180063682.5A Expired - Fee Related CN103282429B (zh) | 2010-12-29 | 2011-11-17 | 具有三嗪-环氧交联体系的压敏粘合剂 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US9260638B2 (enExample) |
| EP (1) | EP2658921B1 (enExample) |
| JP (1) | JP5897037B2 (enExample) |
| KR (1) | KR20140006839A (enExample) |
| CN (1) | CN103282429B (enExample) |
| WO (1) | WO2012091817A1 (enExample) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8785517B2 (en) | 2011-05-25 | 2014-07-22 | 3M Innovative Properties Company | Pressure-sensitive adhesives with onium-epdxy crosslinking system |
| KR20140047666A (ko) | 2011-06-23 | 2014-04-22 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 오늄-에폭시 수지 가교결합 시스템을 갖는 감압 접착제 |
| EP2970725A1 (en) | 2013-03-13 | 2016-01-20 | 3M Innovative Properties Company | Adhesives comprising epoxy-acid crosslinked groups and methods |
| KR101854493B1 (ko) * | 2014-08-29 | 2018-05-04 | 삼성에스디아이 주식회사 | 점착필름, 및 이를 이용한 디스플레이 부재 |
| KR20170110154A (ko) * | 2015-02-18 | 2017-10-10 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 보호된 광가교결합제로부터의 아크릴계 접착제 조성물 |
| CN108633284A (zh) * | 2015-05-18 | 2018-10-09 | 3M创新有限公司 | 包含含环氧官能团的(甲基)丙烯酸类聚合物和三嗪交联剂的压敏粘合剂 |
| WO2018080834A1 (en) | 2016-10-27 | 2018-05-03 | 3M Innovative Properties Company | Crosslinkable composition including a (meth)acrylic polymer and methods of making a crosslinked composition |
| WO2019123176A1 (en) | 2017-12-20 | 2019-06-27 | 3M Innovative Properties Company | Polymeric substrates with attached thiocarbonylthio-containing groups |
| WO2019123177A1 (en) | 2017-12-20 | 2019-06-27 | 3M Innovative Properties Company | Polymeric substrates with attached polymeric chains |
| EP3715432A1 (en) * | 2019-03-27 | 2020-09-30 | 3M Innovative Properties Company | Pressure-sensitive adhesive composition with transparency characteristics |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3931444A (en) * | 1973-02-20 | 1976-01-06 | Monsanto Company | Backing sheet coated with catalyst and self curing interpolymer adhesive |
| WO1981002262A1 (en) * | 1980-02-14 | 1981-08-20 | Minnesota Mining & Mfg | Photoactive mixture of acrylic monomers and chromophore-substituted halomethyl-striazine |
Family Cites Families (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3691140A (en) | 1970-03-09 | 1972-09-12 | Spencer Ferguson Silver | Acrylate copolymer microspheres |
| US4166152B1 (en) | 1977-08-17 | 1999-05-18 | Minnesota Mining & Mfg | Tacky polymeric microspheres |
| US4329384A (en) | 1980-02-14 | 1982-05-11 | Minnesota Mining And Manufacturing Company | Pressure-sensitive adhesive tape produced from photoactive mixture of acrylic monomers and polynuclear-chromophore-substituted halomethyl-2-triazine |
| US4391687A (en) | 1980-02-14 | 1983-07-05 | Minnesota Mining And Manufacturing Company | Photoactive mixture of acrylic monomers and chromophore-substituted halomethyl-1-triazine |
| GB2170427B (en) | 1985-02-01 | 1989-06-07 | Sanyo Kokusaku Pulp Co | Pressure-sensitive adhesive tapes or sheets |
| US4656218A (en) | 1985-02-08 | 1987-04-07 | Sanyo Kokusaku Pulp Co., Ltd. | Adhesive copolymer microspheres-containing aqueous suspension and method for producing the same |
| US5045569A (en) | 1988-11-30 | 1991-09-03 | Minnesota Mining And Manufacturing Company | Hollow acrylate polymer microspheres |
| CA2034274A1 (en) | 1990-02-07 | 1991-08-08 | James A. Bonham | Polymers containing halomethyl-1,3,5-triazine moieties |
| US5264278A (en) | 1991-03-20 | 1993-11-23 | Minnesota Mining And Manufacturing Company | Radiation-curable acrylate/silicone pressure-sensitive adhesive coated tapes adherable to paint coated substrates |
| JP3114166B2 (ja) * | 1992-10-22 | 2000-12-04 | ジェイエスアール株式会社 | マイクロレンズ用感放射線性樹脂組成物 |
| JPH0733855A (ja) | 1993-07-21 | 1995-02-03 | Japan Synthetic Rubber Co Ltd | 感放射線性樹脂組成物 |
| US5506279A (en) | 1993-10-13 | 1996-04-09 | Minnesota Mining And Manufacturing Company | Acrylamido functional disubstituted acetyl aryl ketone photoinitiators |
| US5616670A (en) | 1993-11-10 | 1997-04-01 | Minnesota Mining And Manufacturing Company | Pressure sensitive adhesives with good oily surface adhesion |
| US5683798A (en) | 1993-11-10 | 1997-11-04 | Minnesota Mining And Manufacturing Company | Tackified pressure sensitive adhesives |
| CA2187889A1 (en) | 1994-04-29 | 1995-11-09 | Bruce A. Nerad | Light modulating device having a matrix prepared from acid reactants |
| GB2289680A (en) | 1994-05-25 | 1995-11-29 | Minnesota Mining & Mfg | Flame-retardant pressure sensitive adhesives and tapes |
| JP3545414B2 (ja) | 1994-07-29 | 2004-07-21 | ミネソタ マイニング アンド マニュファクチャリング カンパニー | 架橋結合された粘弾性高分子材料に硬化可能なシロップ |
| WO1998024859A1 (en) | 1996-12-04 | 1998-06-11 | Minnesota Mining And Manufacturing Company | Pavement marking article |
| EP0887706A1 (en) | 1997-06-25 | 1998-12-30 | Wako Pure Chemical Industries Ltd | Resist composition containing specific cross-linking agent |
| JP3721770B2 (ja) | 1998-03-10 | 2005-11-30 | 住友化学株式会社 | 着色感光性樹脂組成物 |
| JP3952484B2 (ja) * | 1998-08-20 | 2007-08-01 | Jsr株式会社 | 表示パネルスペーサー用感放射線性樹脂組成物 |
| US6448337B1 (en) * | 1999-10-07 | 2002-09-10 | 3M Innovative Properties Company | Pressure sensitive adhesives possessing high load bearing capability |
| JP4042142B2 (ja) | 2000-09-08 | 2008-02-06 | Jsr株式会社 | El表示素子の隔壁形成用感放射線性樹脂組成物、隔壁およびel表示素子 |
| US20050081993A1 (en) | 2003-10-16 | 2005-04-21 | Ilkka Steven J. | Method of bonding glass |
| TWI432904B (zh) | 2006-01-25 | 2014-04-01 | Dow Corning | 用於微影技術之環氧樹脂調配物 |
| JP5371250B2 (ja) | 2008-01-24 | 2013-12-18 | 三菱レイヨン株式会社 | 硬化性樹脂組成物、光学部材及び積層物 |
| US7652103B2 (en) | 2008-02-14 | 2010-01-26 | 3M Innovative Properties Company | Acrylic pressure-sensitive adhesives with aziridine crosslinking agents |
| US7714076B2 (en) * | 2008-03-27 | 2010-05-11 | 3M Innovative Properties Company | Acrylic pressure-sensitive adhesives with aziridine crosslinking agents |
| WO2010046240A1 (en) | 2008-10-20 | 2010-04-29 | Basf Se | Sulfonium derivatives and the use therof as latent acids |
| US8067504B2 (en) | 2009-08-25 | 2011-11-29 | 3M Innovative Properties Company | Acrylic pressure-sensitive adhesives with acylaziridine crosslinking agents |
| US8148471B2 (en) | 2009-11-23 | 2012-04-03 | 3M Innovative Properties Company | Acrylic pressure-sensitive adhesives with aziridinyl-epoxy crosslinking system |
| CN102108133B (zh) | 2009-12-23 | 2014-12-10 | 3M创新有限公司 | (甲基)丙烯酰基-氮丙啶交联剂和粘合剂聚合物 |
| CN102127183B (zh) | 2010-01-20 | 2014-08-20 | 3M创新有限公司 | 可交联的丙烯酸酯粘合剂聚合物组合物 |
| US8222340B2 (en) | 2010-04-05 | 2012-07-17 | 3M Innovative Properties Company | Crosslinkable syrup copolymers with aminoalkyl (meth)acryloyl solvent monomers |
-
2011
- 2011-11-17 CN CN201180063682.5A patent/CN103282429B/zh not_active Expired - Fee Related
- 2011-11-17 WO PCT/US2011/061119 patent/WO2012091817A1/en not_active Ceased
- 2011-11-17 US US13/990,130 patent/US9260638B2/en not_active Expired - Fee Related
- 2011-11-17 JP JP2013547476A patent/JP5897037B2/ja not_active Expired - Fee Related
- 2011-11-17 EP EP11794286.2A patent/EP2658921B1/en not_active Not-in-force
- 2011-11-17 KR KR1020137019605A patent/KR20140006839A/ko not_active Abandoned
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3931444A (en) * | 1973-02-20 | 1976-01-06 | Monsanto Company | Backing sheet coated with catalyst and self curing interpolymer adhesive |
| WO1981002262A1 (en) * | 1980-02-14 | 1981-08-20 | Minnesota Mining & Mfg | Photoactive mixture of acrylic monomers and chromophore-substituted halomethyl-striazine |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20140006839A (ko) | 2014-01-16 |
| US9260638B2 (en) | 2016-02-16 |
| EP2658921B1 (en) | 2016-04-06 |
| EP2658921A1 (en) | 2013-11-06 |
| CN103282429A (zh) | 2013-09-04 |
| US20130289219A1 (en) | 2013-10-31 |
| JP2014503013A (ja) | 2014-02-06 |
| JP5897037B2 (ja) | 2016-03-30 |
| WO2012091817A1 (en) | 2012-07-05 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151125 Termination date: 20191117 |