CN103205701A - A vapor deposition mask plate and a production method thereof - Google Patents

A vapor deposition mask plate and a production method thereof Download PDF

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Publication number
CN103205701A
CN103205701A CN2012100107847A CN201210010784A CN103205701A CN 103205701 A CN103205701 A CN 103205701A CN 2012100107847 A CN2012100107847 A CN 2012100107847A CN 201210010784 A CN201210010784 A CN 201210010784A CN 103205701 A CN103205701 A CN 103205701A
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China
Prior art keywords
mask plate
deposition mask
etching
icon
opening
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Pending
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CN2012100107847A
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Chinese (zh)
Inventor
魏志凌
高小平
郑庆靓
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Kunshan Power Stencil Co Ltd
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Kunshan Power Stencil Co Ltd
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Priority to CN2012100107847A priority Critical patent/CN103205701A/en
Publication of CN103205701A publication Critical patent/CN103205701A/en
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F1/00Etching metallic material by chemical means
    • C23F1/02Local etching
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/04Coating on selected surface areas, e.g. using masks
    • C23C14/042Coating on selected surface areas, e.g. using masks using masks

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electroluminescent Light Sources (AREA)

Abstract

The present invention relates to a vapor deposition mask plate and a production method thereof. The production method comprises the following steps: step one, substrate pre-treatment; step two, film mounting; step three, exposure, and development; step four, etching; and step five, film stripping. The vapor deposition mask plate is provided with opening pattern areas and icon pattern areas, wherein the icon pattern area are through holes; and icon patterns and opening patterns are integrally molded. According to the vapor deposition mask plate and the production method thereof provided by the present invention, the opening patterns and the icon patterns are integrally molded, the production cost is low, the icons patterns are variable, the deposition precision is high, and the process is simple, so broad market prospects are provided.

Description

Deposition mask plate and preparation method thereof
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Technical field
The present invention relates to a kind of deposition mask plate and preparation method thereof, relate in particular to a kind of be used to the mask plate that is manufactured with organic electroluminescence devices making method extremely.
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Background technology
Electroluminescent device is a kind of effective optical device, and it has: spacious angle of visibility, high-quality contrast gradient and corresponding speed etc. is a bit faster.Organic electroluminescenoe device and inorganic light-emitting device are formed electroluminescent device.The difference of the two is based on the difference of the substance classes that forms electroluminescent layer.Organic electroluminescenoe device is compared with the inorganic electroluminescent device, has higher sharpness and quicker response.And it has better colored display performance.
Organic electroluminescenoe device comprises several sections: transparent substrate; Have predetermined pattern first electrode (as anode), be formed on the described transparent substrate; Organic luminous layer, it has on the described transparent substrate of electrode by the vacuum deposition method evaporation; Second electrode (as negative electrode), it is formed on the described organic luminous layer with the direction with described first electrode crossing.
In the process of making organic electroluminescenoe device, first electrode is made by ITO.The pattern of ITO is made by photolithography usually.Namely use the etching solution that contains iron(ic) chloride to form pattern by wet etch method.Because when making second electrode, if still make of etching method, moisture may enter into organic luminous layer and second gaps between electrodes, thereby has influence on the performance of organic electroluminescenoe device, seriously can influence its work-ing life.So adopt vacuum deposition method to be formed with the organic electroluminescent material of airport electroluminescent layer now.The mask that has in this process with the second electrode identical patterns can be arranged on the electroluminescent layer, and the material that is used to form second electrode can be deposited.
Mention a kind of main mask with fine pitches pattern in the documents 200410087462.8 and have the separable mask of icon pattern with another, be used for forming the icon pattern at organic luminous layer.There is certain problem in this kind icon forming method:
The icon pattern is fixed, and is immutable, and evaporation icon pattern has limitation;
Have the mask strips of icon pattern and becoming flexible in conjunction with producing of main mask, in evaporate process, can produce accuracy error;
Evaporate process needs mask plate to be close to substrate, and the fit mask integral slab face unfairness phenomenon that can produce of this mask set influences the evaporation effect;
Do not change the mask graph zone though can change icon, this kind mask plate manufacture craft is loaded down with trivial details, the cost height.
Therefore, need a kind of new mask plate to address the above problem, and form the icon pattern.
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Summary of the invention
The technical problem to be solved in the present invention provides a kind of deposition mask plate and preparation method thereof, and mask plate is one-body molded, can not become flexible in evaporate process, can not produce accuracy error, and the icon pattern is variable, the vapor deposition accuracy height.
In order to solve the problems of the technologies described above, the technical scheme that the present invention takes is as follows:
A kind of making method of deposition mask plate is characterized in that, may further comprise the steps:
The first step: pretreatment of base material;
Second step: pad pasting;
The 3rd step: exposure, development;
The 4th step: etching;
The 5th step: demoulding.
The described the first step comprises carries out two-sided sandblast to base material, removes the impurity of substrate surface, improves the bonding force between dry film and the base material.
Described second step comprises carries out two-sided pad pasting to the base material after handling.
Described the 3rd step comprises: the base material behind the pad pasting is carried out double-sided exposure, and the exposure area is the dry film zone except opening figure and icon graphic; Base material after the exposure is developed, and remove unexposed dry film, be i.e. the dry film in opening figure and icon graphic zone.
Described the 4th step comprises carries out etching to the base material behind the exposure imaging, and etching area is no dry film zone, i.e. opening figure and icon graphic zone.
Described etched parameter is as follows: etching parameter is as follows: the etching useful length is 5-10m; Etch temperature is 50 ± 1 ℃; Liquid etching composition is iron(ic) chloride, sodium chlorate, concentrated hydrochloric acid; Etching solution proportion is 1.35-1.50g/cm 3The etching transfer rate is 30-50Hz; Etching solution pH is 1.5-1.7.
Described the 5th step comprises that the base material after the etching is carried out demoulding to be handled.
Base material is Invar alloy, Rhometal, nickel cobalt (alloy) or pure nickel.
A kind of deposition mask plate is characterized in that, is made with above-mentioned method.
Be provided with opening figure zone and icon area of the pattern at described evaporation mask plate, described icon pattern is through hole; Described icon pattern and opening figure are one-body molded.
The material of described deposition mask plate is Invar alloy, Rhometal, nickel cobalt (alloy) or pure nickel.
The thickness of described deposition mask plate is 20-100 μ m.
The invention provides a kind of deposition mask plate and preparation method thereof, opening figure and icon pattern are one-body molded, and cost of manufacture is low, and the icon pattern is variable, the vapor deposition accuracy height, and technology is simple, has vast market prospect.
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Description of drawings
Below in conjunction with accompanying drawing the specific embodiment of the present invention is described in further detail.
Fig. 1 is the structure iron of deposition mask plate;
Fig. 2 is Figure 1A part enlarged view;
1 is mask plate among the figure, and 2 is the opening figure zone, and 3 is the icon area of the pattern, and 4 is opening, and 5 is icon.
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Embodiment
Embodiment 1:
A kind of making method of deposition mask plate, concrete processing step is as follows: pretreatment of base material → pad pasting → exposure → development → etching → demoulding.
Wherein pre-treatment: base material is carried out two-sided sandblast, remove the impurity of substrate surface, improve the bonding force between dry film and the plate.
Base material after handling is carried out two-sided pad pasting.
Carry out double-sided exposure behind the pad pasting, exposed feature is that the exposure area is the dry film zone except opening figure and icon graphic.
Base material after the exposure is carried out developing process, remove unexposed dry film, be i.e. the dry film in opening figure zone and icon graphic zone.Can expose any icon pattern according to different demands, technology is simple.
Described etching parameter is as follows:
The etching useful length is 5-10m;
Etch temperature is 50 ± 1 ℃;
Liquid etching composition is iron(ic) chloride, sodium chlorate, concentrated hydrochloric acid;
Etching solution proportion is 1.35-1.50g/cm 3
The etching transfer rate is 30-50Hz;
Etching solution pH is 1.5-1.7.
Etching area is no dry film zone, i.e. opening figure zone and icon graphic zone.
By the control to etching parameter, reach the sharpness of icon pattern and the control of anti-degree of cleaning.
Base material after the etching is carried out demoulding to be handled.
Etched icon graphic top and bottom are smooth, and in the evaporation process, mask plate needs to fit tightly with substrate, otherwise can cause film forming material in the evaporate process to infiltrate in the slit between mask plate and the substrate, reduce the yield polymer films of organic materials.
Shown in Fig. 1-2, a kind of deposition mask plate comprises opening figure zone 2, icon area of the pattern 3, opening 4 and icon 5.The pattern of described icon 5 is through hole; Opening 4 is slit, and the described deposition mask plate that has icon pattern and an opening figure is one-body molded.The material of described deposition mask plate is Invar alloy.The thickness of described deposition mask plate is 20-100 μ m.
A kind of deposition mask plate that the present invention relates to is be used to the mask plate that is manufactured with organic electroluminescence devices, specifically is the making for a thin layer of this organic light-emitting device.
Embodiment 2:
A kind of making method of deposition mask plate, concrete processing step is as follows: pretreatment of base material → pad pasting → exposure → development → etching → demoulding.
Wherein pre-treatment: base material is carried out two-sided sandblast, remove the impurity of substrate surface, improve the bonding force between dry film and the plate.
Base material after handling is carried out two-sided pad pasting.
Carry out double-sided exposure behind the pad pasting, exposed feature is that the exposure area is the dry film zone except opening figure and icon graphic.
Base material after the exposure is carried out developing process, remove unexposed dry film, be i.e. the dry film in opening figure zone and icon graphic zone.Can expose any icon pattern according to different demands, technology is simple.
Described etching parameter is as follows:
The etching useful length is 6-10m;
Etch temperature is 50 ± 1 ℃;
Liquid etching composition is iron(ic) chloride, sodium chlorate, concentrated hydrochloric acid;
Etching solution proportion is 1.39-1.47g/cm 3
The etching transfer rate is 30-50Hz;
Etching solution pH is 1.5-1.7.
Etching area is no dry film zone, i.e. opening figure zone and icon graphic zone.
By the control to etching parameter, reach the sharpness of icon pattern and the control of anti-degree of cleaning.
Base material after the etching is carried out demoulding to be handled.
Etched icon graphic top and bottom are smooth, and in the evaporation process, mask plate needs to fit tightly with substrate, otherwise can cause film forming material in the evaporate process to infiltrate in the slit between mask plate and the substrate, reduce the yield polymer films of organic materials.
Shown in Fig. 1-2, a kind of deposition mask plate comprises opening figure zone 2, icon area of the pattern 3, opening 4 and icon 5.The pattern of described icon 5 is through hole; Opening 4 is slit, and the described deposition mask plate that has icon pattern and an opening figure is one-body molded.The material of described deposition mask plate is Rhometal.The thickness of described deposition mask plate is 20-100 μ m.
A kind of deposition mask plate that the present invention relates to is be used to the mask plate that is manufactured with organic electroluminescence devices, specifically is the making for a thin layer of this organic light-emitting device.
Embodiment 3:
A kind of making method of deposition mask plate, concrete processing step is as follows: pretreatment of base material → pad pasting → exposure → development → etching → demoulding.
Wherein pre-treatment: base material is carried out two-sided sandblast, remove the impurity of substrate surface, improve the bonding force between dry film and the plate.
Base material after handling is carried out two-sided pad pasting.
Carry out double-sided exposure behind the pad pasting, exposed feature is that the exposure area is the dry film zone except opening figure and icon graphic.
Base material after the exposure is carried out developing process, remove unexposed dry film, be i.e. the dry film in opening figure zone and icon graphic zone.Can expose any icon pattern according to different demands, technology is simple.
Described etching parameter is as follows:
The etching useful length is 6-8m;
Etch temperature is 50 ± 1 ℃;
Liquid etching composition is iron(ic) chloride, sodium chlorate, concentrated hydrochloric acid;
Etching solution proportion is 1.35-1.47g/cm 3
The etching transfer rate is 30-50Hz;
Etching solution pH is 1.5-1.7.
Etching area is no dry film zone, i.e. opening figure zone and icon graphic zone.
By the control to etching parameter, reach the sharpness of icon pattern and the control of anti-degree of cleaning.
Base material after the etching is carried out demoulding to be handled.
Etched icon graphic top and bottom are smooth, and in the evaporation process, mask plate needs to fit tightly with substrate, otherwise can cause film forming material in the evaporate process to infiltrate in the slit between mask plate and the substrate, reduce the yield polymer films of organic materials.
Shown in Fig. 1-2, a kind of deposition mask plate comprises opening figure zone 2, icon area of the pattern 3, opening 4 and icon 5.The pattern of described icon 5 is through hole; Opening 4 is slit, and the described deposition mask plate that has icon pattern and an opening figure is one-body molded.The material of described deposition mask plate is nickel cobalt (alloy).The thickness of described deposition mask plate is 20-100 μ m.
A kind of deposition mask plate that the present invention relates to is be used to the mask plate that is manufactured with organic electroluminescence devices, specifically is the making for a thin layer of this organic light-emitting device.
Embodiment 4:
A kind of making method of deposition mask plate, concrete processing step is as follows: pretreatment of base material → pad pasting → exposure → development → etching → demoulding.
Wherein pre-treatment: base material is carried out two-sided sandblast, remove the impurity of substrate surface, improve the bonding force between dry film and the plate.
Base material after handling is carried out two-sided pad pasting.
Carry out double-sided exposure behind the pad pasting, exposed feature is that the exposure area is the dry film zone except opening figure and icon graphic.
Base material after the exposure is carried out developing process, remove unexposed dry film, be i.e. the dry film in opening figure zone and icon graphic zone.Can expose any icon pattern according to different demands, technology is simple.
Described etching parameter is as follows:
The etching useful length is 6-8m;
Etch temperature is 50 ± 1 ℃;
Liquid etching composition is iron(ic) chloride, sodium chlorate, concentrated hydrochloric acid;
Etching solution proportion is 1.40-1.45g/cm 3
The etching transfer rate is 30-50Hz;
Etching solution pH is 1.5-1.7.
Etching area is no dry film zone, i.e. opening figure zone and icon graphic zone.
By the control to etching parameter, reach the sharpness of icon pattern and the control of anti-degree of cleaning.
Base material after the etching is carried out demoulding to be handled.
Etched icon graphic top and bottom are smooth, and in the evaporation process, mask plate needs to fit tightly with substrate, otherwise can cause film forming material in the evaporate process to infiltrate in the slit between mask plate and the substrate, reduce the yield polymer films of organic materials.
Shown in Fig. 1-2, a kind of deposition mask plate comprises opening figure zone 2, icon area of the pattern 3, opening 4 and icon 5.The pattern of described icon 5 is through hole; Opening 4 is slit, and the described deposition mask plate that has icon pattern and an opening figure is one-body molded.The material of described deposition mask plate is pure nickel.The thickness of described deposition mask plate is 20-50 μ m.
A kind of deposition mask plate that the present invention relates to is be used to the mask plate that is manufactured with organic electroluminescence devices, specifically is the making for a thin layer of this organic light-emitting device.
Above embodiment purpose is to illustrate the present invention, and unrestricted protection scope of the present invention, all application that come by simple change of the present invention all drop in protection scope of the present invention.

Claims (10)

1. the making method of a deposition mask plate is characterized in that, may further comprise the steps:
The first step: pretreatment of base material;
Second step: pad pasting;
The 3rd step: exposure, development;
The 4th step: etching;
The 5th step: demoulding.
2. the making method of deposition mask plate according to claim 1 is characterized in that, the described the first step comprises carries out two-sided sandblast to base material, removes the impurity of substrate surface, improves the bonding force between dry film and the plate.
3. the making method of deposition mask plate according to claim 1 is characterized in that, described second step comprises carries out two-sided pad pasting to the base material after handling.
4. the making method of deposition mask plate according to claim 1 is characterized in that, described the 3rd step comprises: the base material behind the pad pasting is carried out double-sided exposure, and the exposure area is the dry film zone except opening figure and icon graphic; Base material after the exposure is developed, and remove unexposed dry film, be i.e. the dry film in opening figure and icon graphic zone.
5. the making method of deposition mask plate according to claim 1 is characterized in that, described the 4th step comprises carries out etching to the base material behind the exposure imaging, and etching area is no dry film zone, i.e. opening figure and icon graphic zone.
6. the making method of deposition mask plate according to claim 5 is characterized in that, described etched parameter is as follows: the etching useful length is 5-10m; Etch temperature is 50 ± 1 ℃; Liquid etching composition is iron(ic) chloride, sodium chlorate, concentrated hydrochloric acid; Etching solution proportion is 1.35-1.50g/cm 3The etching transfer rate is 30-50Hz; Etching solution pH is 1.5-1.7.
7. a deposition mask plate is characterized in that, is made with the described method of claim 1-6.
8. deposition mask plate according to claim 7 is characterized in that, is provided with opening figure zone and icon area of the pattern at described evaporation mask plate, and described icon pattern is through hole; Described icon pattern and opening figure are one-body molded.
9. deposition mask plate according to claim 7 is characterized in that, the material of described deposition mask plate be Invar alloy,, Rhometal, nickel cobalt (alloy) or pure nickel.
10. according to claim 7 or 8 described deposition mask plates, it is characterized in that the thickness of described deposition mask plate is 20-100 μ m.
CN2012100107847A 2012-01-16 2012-01-16 A vapor deposition mask plate and a production method thereof Pending CN103205701A (en)

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CN103556113A (en) * 2013-10-30 2014-02-05 昆山允升吉光电科技有限公司 Method for producing high-precision mask plate
CN104505471A (en) * 2014-12-22 2015-04-08 昆山工研院新型平板显示技术中心有限公司 Preparation method of high-opening-ratio mask board and mask board
CN104854254A (en) * 2013-01-10 2015-08-19 大日本印刷株式会社 Metal plate, metal plate production method, and method for producing vapor deposition mask using metal plate
CN106460150A (en) * 2015-02-10 2017-02-22 大日本印刷株式会社 Manufacturing method for deposition mask, metal sheet used for producing deposition mask, and manufacturing method for said metal sheet
CN108149190A (en) * 2017-12-06 2018-06-12 信利(惠州)智能显示有限公司 Mask plate and preparation method thereof
CN109306450A (en) * 2018-11-28 2019-02-05 武汉华星光电半导体显示技术有限公司 Evaporation mask plate group
US10233546B2 (en) 2013-09-13 2019-03-19 Dai Nippon Printing Co., Ltd. Metal plate, method of manufacturing metal plate, and method of manufacturing mask by use of metal plate
CN109735802A (en) * 2019-03-11 2019-05-10 南京高光半导体材料有限公司 A kind of support metal mask version and mask plate component and photomask manufacturing method
CN109913808A (en) * 2019-04-16 2019-06-21 南京高光半导体材料有限公司 The metal mask version and production method for preventing evaporated metal layer from falling off
US10600963B2 (en) 2014-05-13 2020-03-24 Dai Nippon Printing Co., Ltd. Metal plate, method of manufacturing metal plate, and method of manufacturing mask by using metal plate
CN112458462A (en) * 2020-11-18 2021-03-09 匠博先进材料科技(广州)有限公司 Vapor deposition mask manufacturing method, vapor deposition mask assembly, vapor deposition mask manufacturing device, and display device
US11486031B2 (en) 2013-10-15 2022-11-01 Dai Nippon Printing Co., Ltd. Metal plate
CN115627443A (en) * 2020-11-18 2023-01-20 匠博先进材料科技(广州)有限公司 Vapor deposition mask, vapor deposition module, vapor deposition device, display device, and method and device for manufacturing display device

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US10731261B2 (en) 2013-09-13 2020-08-04 Dai Nippon Printing Co., Ltd. Metal plate, method of manufacturing metal plate, and method of manufacturing mask by use of metal plate
US10233546B2 (en) 2013-09-13 2019-03-19 Dai Nippon Printing Co., Ltd. Metal plate, method of manufacturing metal plate, and method of manufacturing mask by use of metal plate
US11486031B2 (en) 2013-10-15 2022-11-01 Dai Nippon Printing Co., Ltd. Metal plate
CN103556113A (en) * 2013-10-30 2014-02-05 昆山允升吉光电科技有限公司 Method for producing high-precision mask plate
US11217750B2 (en) 2014-05-13 2022-01-04 Dai Nippon Printing Co., Ltd. Metal plate, method of manufacturing metal plate, and method of manufacturing mask by using metal plate
US10600963B2 (en) 2014-05-13 2020-03-24 Dai Nippon Printing Co., Ltd. Metal plate, method of manufacturing metal plate, and method of manufacturing mask by using metal plate
CN104505471A (en) * 2014-12-22 2015-04-08 昆山工研院新型平板显示技术中心有限公司 Preparation method of high-opening-ratio mask board and mask board
CN104505471B (en) * 2014-12-22 2017-12-29 昆山工研院新型平板显示技术中心有限公司 A kind of preparation method and mask plate of high aperture mask plate
CN106460150B (en) * 2015-02-10 2020-01-10 大日本印刷株式会社 Method for manufacturing vapor deposition mask, metal plate for manufacturing vapor deposition mask, and method for manufacturing metal plate
US10570498B2 (en) 2015-02-10 2020-02-25 Dai Nippon Printing Co., Ltd. Manufacturing method for deposition mask, metal plate used for producing deposition mask, and manufacturing method for said metal sheet
CN110965020A (en) * 2015-02-10 2020-04-07 大日本印刷株式会社 Method for screening metal plate and method for manufacturing vapor deposition mask
US10612124B2 (en) 2015-02-10 2020-04-07 Dai Nippon Printing Co., Ltd. Manufacturing method for deposition mask, metal plate used for producing deposition mask, and manufacturing method for said metal sheet
CN110965020B (en) * 2015-02-10 2022-05-17 大日本印刷株式会社 Method for screening metal plate and method for manufacturing vapor deposition mask
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Application publication date: 20130717